Classifications

• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
  • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
  • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
  • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
  • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
  • D06M15/423—Amino-aldehyde resins
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
  • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
  • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
  • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
  • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
  • D06M15/6433—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing carboxylic groups
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
  • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
  • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
  • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
  • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
  • D06M15/6436—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain containing amino groups
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
  • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
  • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
  • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
  • D06M15/643—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain
  • D06M15/653—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicon in the main chain modified by isocyanate compounds
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
  • Y10S525/906—Polysulfone
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10S525/00—Synthetic resins or natural rubbers -- part of the class 520 series
  • Y10S525/908—Polymer containing a hydantoin group

Definitions

• Another object of this invention is to provide a composition and process for finishing textiles which imparts wash and wear properties thereto and which also imparts better flat appearance.
• This invention also has as an object the provision of a textile finishing composition and process which imparts wash and wear properties to the textile with less durable press resin being required than if it were used alone.
• any of the well known durable press resins can be used in the composition of this invention.
• examples of such resins include the urea formaldehyde resins, melamineformaldehyde resins, dimethylolethylene urea resins, dimethylolpropylene urea resins, methylol imidazolidone resins, dimethylol dihydroxyethylene urea resins, glyoxal diurein resins, tetra-methoxymethyl dimethylene diureide resins, dimethylol uron resins, dimethylol-ethyl triazone resins, formaldehyde resins, glyoxal resins, methylol dimethyl hydantoin resins, epoxide resins, vinyl cyclohexene dioxide resins, 1:2 dichloropropanol resins, 1:3 dichloro- 2-propanol resins, pyridinium salt of ethylene bis-chloromethyl ether resins, tris
• the composition of this invention can contain from 50 to 99% by weight of the durable press resin, but preferably contains from 70 to 97%.
• the durable press resins commercially, are available neat or as pastes and creams in a carrier.
• the durable press resins can be incorporated into the composition of this invention via any of the aforementioned forms, however, the amounts referred to above are with respect to the resin per se.
• the carboxy functional siloxanes useful in this invention are well known types of materials whose general description and methods of preparation have been set forth in various places in the literature. Best results are believed to be obtained with a siloxane compolymer consisting essentially of about to 99 (preferably to 99) mole percent of units wherein R is selected from the group consisting of hydrocarbon, halohydrocarbon, cyanohydrocarbon, isocyanohydrocarbon, hydroxyhydrocarbon, mercaptohydrocarbon, etherhydrocarbon, esterhydrocarbon, thioetherhydrocarbon, thioesterhydrocarbon and nitrohydrocarbon radicals, and n has a value from 0 to 3, and about 1 to 25 (preferably 1 to 10) mole percent of R radical being ones wherein at least one of the R radicals is a methyl radical, at least 90 mole percent of all the siloxanes units in the copolymer having a degree of substitution of 2, and said siloxane copolymer having an overall degree of substitution in the
• the composition of this invention can contain from 1 to 50% by weight of the carboxy functional siloxane, but preferably contains from 3 to 30%
• the carboxy functional siloxanes employed herein can be used neat or in the form of a solution in an organic solvent or water. In the case of aqueous solutions, they can be mechanical emulsions of the siloxane copolymer or the emulsions obtained as a result of preparing the siloxane copolymer by emulsion polymerization. Preparation of these carboxy functional siloxane copolymers and the various types of solutions thereof are well known by those skilled in the art and will not be described in further detail here.
• R radicals which can be present in the siloxane are the methyl, ethyl, propyl, butyl, amyl,
• R radical contain from 1 to 18 carbon atoms.
• divalent linking group R is the methylene, ethylene, propylene, hexamethylene, decamethylene, -CH CH(CH )CH phenyl, naphthylene, C H CH C H -CH --C H.,C H -CH radicals. It is preferred that the R' radical contain from 2 to 10 carbon atoms.
• composition of this invention can be applied to the textile to be treated in the same manner and using the same equipment as presently used for durable press resins alone. This is of great benefit to textile finishers as no new equipment need be purchased, and no radically new processing techniques need be learned by them. Of course, other methods of applying the composition to the textile can be used if so desired.
• compositions of this invention are best applied to the textile as a solution in a suitable organic solvent or as an aqueous emulsion.
• compositions and process of this invention can be used in conjunction with any textile but the advantages thereof are mostly readily apparent with certain types of textile. For example, improvement in flat appearance is best seen with lightweight materials such as batiste or shirtweight materials such as cotton/polyester blends whereas the ability to reduce the durable press resin needed is best seen with mediumweight materials such as poplin.
• a textile finishing composition was prepared which consisted essentially of 100 pounds of ethylene urea durable press resin (Proctor EU-SO), 24 pounds of magnesium chloride curing agent for the resin, 2 pounds of a nonionic polyether surfactant (Dexopal 555), 270 pounds of water, and 16 pounds of an emulsion consisting essentially of 35% of a siloxane copolymer consisting essentially of about 97.5 mole percent (CH SiO units and about 2.5 mole percent (CH )HOOCCH SCH CH S1O units, 2% of the ammonium salt of dodecylbenzenesulfonic acid, and 63% water.
• This composition was prepared by adding the surfactant to half the water, then adding the resin, next adding the siloxane emulsion, and finally adding the curing agent in the remaining amount of water. Continuous mild agitation was used during mix- Ihe above prepared composition was applied to about 100 yards each of nine difierent styles of polyester/cotton, lightweight fabrics, which ranged from batiste weight to dress good weight. In some of these fabrics the poly ester/cotton ratio was 65/35 and in others 50/50. The fabrics were padded single dip, dried in a foot frame at a speed of about yards per minute at temperature stages of 300, 330 and 360 F.
• the hand of the fabrics treated by the above process was extremely desirable.
• the average flat appearance of the fabrics without any treatment (AATCC Test Method 124-1967) was 1.8 after one wash and less than 3.0 after five washes whereas the treated fabrics averaged 3.7 after one wash and 4.2 after five washes.
• a textile finishing composition was prepared which consisted essentially of 100 pounds of ethylene urea durable press resin (Proctor EU-SOLF), 20 pounds of zinc chloride curing catalyst for the resin, 2 pounds of a nonionic surfactant (Actopal RS-l), 260 pounds of water, and 16 pounds of the siloxane copolymer emulsion used in Example 1.
• This formulation was designed to give about a 1% pick up of the siloxane copolymer based on the dry weight of the fabric on the average fabric run.
• the above composition was applied tovarious shirt fabrics running from lightweight batiste to mediumweight oxford weave fabrics.
• the fabrics were dipped and nipped once. The speed of operation was about yards per minute. After treatment the fabrics were dried in a 110 foot frame at the foregoing speed at temperature stages of 300, 330 and 360 F. for about /2 a minute.
• the gabricir were then cured in a box for 1% minutes at In Table I below the results of various tests conducted on the above treated fabrics are set forth.
• Fabric A was a white 65/35 polyester/cotton oxford.
• Fabric B was a gray 100% filament polyester (Fortrel).
• Fabric C was a light blue 50/50 polyester/cotton material.
• Fabric D was a sky blue 50/50 polyester/cotton material.
• Fabric E was a burgundy 50/50 polyester/cotton material. Flat appear ance was measured according to AATCC Test Method 124-1967. Results of this test are an average of nine evaluations. Flex Abrasion was measured according to ASTM Test D1175-64T. Tear was measured according to ASTM Test D1424-63. Wrinkle Recovery was measured according to AATCC Test 66-1968. Handle, which is a subjective test, is reported in Table II.
• vig y ssroft, smooth, full, and very good Dry, soft, full, and good body. Dry, soft, slightly smooth, full, and good 0 D Soft), ssome dryness, full, and very good Dry, soft, slightly smooth, full, and good Dgy, s oft, slightly smooth, full, and good o y. o E Dry, soft, smooth, full, and good body-.. Dry, soft, full, andgood body Dry, goft, full, and good body.
• Composition C con- 38% 3,12% 18; g sisted essentially of about 1.5% carboxyfunctional silox- "i ane of composition A, about 83.2% water, about 0.3% :lggaggflgg; ggfigi? of a surfactant, about 12.5% of the glyoxal durable press resin of composition B, and about 2.5% of zinc nitrate curing agent for the durable press resin.
• compositions were padded onto a 50/50 polyester/cotton fabric, dried, and then cured for three EXAMPLE 5 minutes at 330 F.
• the fabric was then evaluated using Th compositions d ib d i T b VI below were various tests descnbed 1n Example 2.
• the test results are prepared 'and applied to a 100% cotton fabric using the set forth in Table III. process described in Example 4.
• the physical properties TABLE 111 of the fabrics were then evaluated using the the tests Flex wrinkle set forth in Example 2.'Results of; the evaluations are set abrasion recovery
• Tensile forth m Table VII For all footnotes for Tables VI and Fabric treatment (cycles) (grams) (degrees) (pounds) 40 VII ee Table IV a d V,
• HOKCHOzSlOhfl CH3HO0OCHCHIS10 ⁇ 11H HO (CH1) 231 195i (CH1) HOOCCHICHISCHzCHzSlO )5H CH: CH; H0O CCHzSCHzCHzlO (CHJhslO aoiCHrCI-IgS CHzCO OH JgH 35E;
• a composition consisting essentially of about 50 to 99% by weight of a durable press resin selected from the group consisting of urea-formaldehyde, melamineformaldehyde, ethylene urea, dimethylolethylene urea, dimethylolpropylene urea, methylol imidazolidone, dimethylol dihydroxyethylene urea, glyoxal diurein, tetramethoxymethyl dimethylene diureide, dimethylol uron, dimethylol-ethyl triazone, formaldehyde, glyoxal, methylol dirnethyl hydantoin, epoxide resins, vinyl cyclohexene dioxide, 1:2 dichloropropanol, 1:3 dichloro-Z-propanol, pyridiniurn salt of ethylene bis-chloromethyl ether, tris-( laziridinyl) phosphine oxide, divinyl sul
• composition as defined in claim 2 wherein (A) consists essentially of (CH SiO units and (B) consists essentially of (CH )HOOCCH SCH CH SiO units.
• composition as defined in claim 3 wherein the durable press resin is an ethylene urea.
• composition as defined in claim 3 wherein the durable press resin is a methylol imidazolidone.
• a process for finishing a textile comprising applying as the finish a composition consisting essentially of a durable press resin and a carboxy functional siloxane as defined in claim 2, the finish composition being applied to the textile in an amount such that there is a pick up on the textile, based on the weight of the textile, of 5 to 25% by weight of the durable press resin and 0.25 to 5% by weight of the carboxy functional siloxane.
• the durable press resin is a methylol imidazolidone and the siloxane 10 consists essentially of (A) about 90 to 99 mole percent (CH SiO units and (B) about 1 to 10 mole percent (CH )HOOCCH SCH CH SiO units.

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• Chemical & Material Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Engineering & Computer Science (AREA)
• Textile Engineering (AREA)
• Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Priority Applications (13)

Applications Claiming Priority (1)

Publications (1)

Family

ID=22861423

Family Applications (1)

Country Status (12)

Cited By (13)

Families Citing this family (2)

Family Cites Families (3)

• 1972
  • 1972-02-25 US US00229482A patent/US3812201A/en not_active Expired - Lifetime
  • 1972-11-24 CA CA157,408A patent/CA1005183A/en not_active Expired
  • 1972-11-29 AU AU49382/72A patent/AU468734B2/en not_active Expired
  • 1972-12-22 IT IT33434/72A patent/IT972787B/it active
• 1973
  • 1973-01-25 JP JP48010646A patent/JPS4896899A/ja active Pending
  • 1973-02-16 DE DE19732307622 patent/DE2307622B2/de active Granted
  • 1973-02-20 AT AT146973A patent/AT353218B/de not_active IP Right Cessation
  • 1973-02-21 NL NL7302388.A patent/NL157674B/xx not_active IP Right Cessation
  • 1973-02-23 CH CH268373A patent/CH588592B5/xx not_active IP Right Cessation
  • 1973-02-23 CH CH268373D patent/CH268373A4/xx unknown
  • 1973-02-23 FR FR7306487A patent/FR2173249B1/fr not_active Expired
  • 1973-02-23 GB GB889773A patent/GB1425858A/en not_active Expired
  • 1973-02-23 BE BE795864D patent/BE795864A/fr not_active IP Right Cessation

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