US3804730A - Control of electrolytic coloring of chromium-containing alloys - Google Patents
Control of electrolytic coloring of chromium-containing alloys Download PDFInfo
- Publication number
- US3804730A US3804730A US00349114A US34911473A US3804730A US 3804730 A US3804730 A US 3804730A US 00349114 A US00349114 A US 00349114A US 34911473 A US34911473 A US 34911473A US 3804730 A US3804730 A US 3804730A
- Authority
- US
- United States
- Prior art keywords
- potential
- metal
- chromium
- specimen
- colored
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000004040 coloring Methods 0.000 title abstract description 15
- 229910045601 alloy Inorganic materials 0.000 title abstract description 11
- 239000000956 alloy Substances 0.000 title abstract description 11
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 title description 16
- 229910052804 chromium Inorganic materials 0.000 title description 16
- 239000011651 chromium Substances 0.000 title description 16
- 238000000034 method Methods 0.000 abstract description 15
- 229910001220 stainless steel Inorganic materials 0.000 abstract description 10
- 239000010935 stainless steel Substances 0.000 abstract description 9
- 239000003792 electrolyte Substances 0.000 abstract description 7
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 abstract description 5
- 239000002253 acid Substances 0.000 abstract description 2
- 229910052751 metal Inorganic materials 0.000 description 27
- 239000002184 metal Substances 0.000 description 27
- 229910000831 Steel Inorganic materials 0.000 description 15
- 239000010959 steel Substances 0.000 description 15
- 239000000243 solution Substances 0.000 description 14
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 10
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 10
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 8
- 239000007864 aqueous solution Substances 0.000 description 7
- 238000005868 electrolysis reaction Methods 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 5
- 229910052697 platinum Inorganic materials 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- KRVSOGSZCMJSLX-UHFFFAOYSA-L chromic acid Substances O[Cr](O)(=O)=O KRVSOGSZCMJSLX-UHFFFAOYSA-L 0.000 description 4
- AWJWCTOOIBYHON-UHFFFAOYSA-N furo[3,4-b]pyrazine-5,7-dione Chemical compound C1=CN=C2C(=O)OC(=O)C2=N1 AWJWCTOOIBYHON-UHFFFAOYSA-N 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- SOCTUWSJJQCPFX-UHFFFAOYSA-N dichromate(2-) Chemical compound [O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O SOCTUWSJJQCPFX-UHFFFAOYSA-N 0.000 description 3
- 238000007654 immersion Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000011282 treatment Methods 0.000 description 3
- 239000010963 304 stainless steel Substances 0.000 description 2
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 2
- 241000220317 Rosa Species 0.000 description 2
- 229910000589 SAE 304 stainless steel Inorganic materials 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- ZOMNIUBKTOKEHS-UHFFFAOYSA-L dimercury dichloride Chemical class Cl[Hg][Hg]Cl ZOMNIUBKTOKEHS-UHFFFAOYSA-L 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 229910052750 molybdenum Inorganic materials 0.000 description 2
- 239000011733 molybdenum Substances 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- JHWIEAWILPSRMU-UHFFFAOYSA-N 2-methyl-3-pyrimidin-4-ylpropanoic acid Chemical compound OC(=O)C(C)CC1=CC=NC=N1 JHWIEAWILPSRMU-UHFFFAOYSA-N 0.000 description 1
- 229910000531 Co alloy Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 238000007792 addition Methods 0.000 description 1
- MDKXFHZSHLHFLN-UHFFFAOYSA-N alumanylidynecobalt Chemical compound [Al].[Co] MDKXFHZSHLHFLN-UHFFFAOYSA-N 0.000 description 1
- 239000010405 anode material Substances 0.000 description 1
- 239000000788 chromium alloy Substances 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 229940077449 dichromate ion Drugs 0.000 description 1
- 230000003467 diminishing effect Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- MINVSWONZWKMDC-UHFFFAOYSA-L mercuriooxysulfonyloxymercury Chemical compound [Hg+].[Hg+].[O-]S([O-])(=O)=O MINVSWONZWKMDC-UHFFFAOYSA-L 0.000 description 1
- 238000012544 monitoring process Methods 0.000 description 1
- 229910000623 nickel–chromium alloy Inorganic materials 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D9/00—Electrolytic coating other than with metals
- C25D9/04—Electrolytic coating other than with metals with inorganic materials
- C25D9/06—Electrolytic coating other than with metals with inorganic materials by anodic processes
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/34—Anodisation of metals or alloys not provided for in groups C25D11/04 - C25D11/32
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/38—Chromatising
Definitions
- This invention relates to the coloring of stainless steel and other corrosion-resistant chromium-containing alloys having a base of one or more of iron, cobalt and nickel by means of aqueous solutions consisting essentially of chromic acid and sulfuric acid, with or without other additions such as manganous sulphate.
- the present invention is based on the discovery that a more accurate indication of the progress of the coloring is provided by monitoring the potential of the steel or other metal being colored relative to a reference electrode while direct current is passing through a cell consisting of the steel or other metal being colored as anode, a solution containing chromic acid or a soluble salt of chromic acid (e.g. a chromate or dichromate) and sulfuric acid i.e., the solution contains chromate or dichromate ion or allied ionization products and sulfuric acid in water, and a cathode consisting of lead, platinum or other suitable metal. If the solution is contained in a lead-lined tank, the tank lining may conveniently be used as cathode.
- a solution containing chromic acid or a soluble salt of chromic acid e.g. a chromate or dichromate
- sulfuric acid i.e., the solution contains chromate or dichromate ion or allied ionization products and sulfur
- the reference electrode is conveniently an inert metal or alloy immersed in the coloring solution, but other standard electrodes, e.g., a saturated calomel or mercurous sulphate electrode having a bridge that is chemically stable in contact with the coloring solution, may if desired be used.
- electrolysis is discontinued when the potential reaches a predetermined value.
- the potential corresponding to the desired color is first determined during the coloring of a similar specimen of metal by simple immersion in a coloring solution of the same composition at the same temperature as is to be used for the electrolysis.
- a potentiostat is then used to maintain the potential of a further specimen of the steel or other metal being colored at a suitable constant value, relative to the reference electrode.
- the potentiostat performs this function by supplying sufiicient current flow through a cell consisting of the steel and a suitable counter-electrode, e.g., platinum or lead, to maintain a constant potential on the steel relative to the reference electrode.
- the potentiostat is set to maintain the specimen at the potential which is known, from prior calibration of the color-potential relationship, to correspond to the desired color.
- the anodic current density on the material being colored is monitored and when it falls to zero the formation of the film of desired color is complete.
- the actual potential corresponding to a particular color depends both on the composition and the surface condition of the metal as well as on the solution composition and temperature, and this simple method is only satisfactory if a series of substantially identical specimens is to be treated.
- the start of film formation is indicated by a minimum in the rate of change of potential with time (dE/dt), and this point may be readily determined from an automatically recorded trace of potential (E) as a function of time (t).
- E trace of potential
- t time
- dE/dt falls to zero, i.e., the potential remains constant for a short period and the potential at which this happens is the start potential.
- dE/dt does not always fall exactly to zero, in which case the potential-time curve exhibits a point of infiexion at which dE/dt passes through a minimum; the potential at such a point of inflexion is then taken as the start potential.
- the difference between the start potential and the potential for the desired color is first determined for the system.
- the start potential is then determined for the specimen being colored and electrolysis is continued to the end-point determined by the difference in potential corresponding to the desired color and then stopped.
- the difference between the start potential and the potential corresponding to a particular color is found to be slightly less when measured with an anodic current flowing through the metal being colored than under simple immersion conditions, and the calibration should therefore preferably be carried out with an impressed current. Also, the value of the start potential increases as the impressed current increases.
- This procedure may be carried out in the following way, with the use of a potentiostat.
- the potentiostat is set to maintain the metal to be colored at any suitable potential which will produce a conveniently measurable anodic current.
- the anodic current is found to rise to a maximum within 1 to 2 minutes.
- the potentiostat is disconnected and the potential of the metal, relative to the reference electrode, is measured. This potential corresponds to the start potential.
- the potentiostat is then reconnected and the potential set at the value corresponding to the potential for formation of a film of the desired color.
- the current flowing through the cell is monitored and when the current falls to zero, the specimen has attained the desired color. If the electrolysis is continued beyond this point, the current flowing through the material being colored becomes cathodic and coloring continues through the normal sequence of colors, although at a reduced rate.
- a galvanostat (a device supplying constant current) to maintain a constant cell current between stainless steel or other metal being colored as anode and a suitable cathode, e.g., platinum or lead.
- Providing the anodic current density is not excessive, e.g., below about 0.25 A/dm.
- a potential vs. time curve is observed having the characteristics described above.
- a film of the desired color is obtained on the anode material by maintaining the cell current constant until the potential of the anode, measured as described above, attains the required value and then terminating the treatment.
- Aqueous electrolytes useful in the present invention have compositions as follows:
- Range Preferred, g./l. g./l.
- Colored coatings produced by direct current electrolysis in accordance with the invention can be hardened and rendered more abrasion-resistant by the method described in US. patent applications Ser. Nos. 114,357, 252,459 and 301,810, and the invention includes the application of these hardening treatments to the colored coatings.
- a speciment of Type 304 stainless steel was colored by immersion in an aqueous solution of 2.5 M CrO and 5 M H SO at 70 C.
- the potential of the steel against a saturated calomel electrode was monitored, and the potential change from the plateau observed at the start potential to the development of a blue color was found to be 7 mv.
- EXAMPLE I A steel specimen was immersed in the solution at the same temperature with a platinum counter-electrode, and a potentiostat was set to maintain the potential of the specimen at a value which created a conveniently measurable anodic current in the specimen/counter-electrode cell. This current reached a maximum after 30 sec. at which time the potentiostat was switched off and the potential of the specimen relative to the reference electrode was measured as being +1110 mv. This value was taken as the start potential for color control. The potentiostat was reset to maintain the specimen potential at +1117 mv. (i.e., 7 mv. higher than the start potential) and the anodic cell current monitored. When the cell current fell to zero the specimen was removed and was found, as expected, to be co ored blue.
- EXAMPLE III A steel specimen was immersed in the same solution at 70 C. as anode with a lead cathode and a direct current power supply was used to set a potential of 2.1 v. across the specimen/lead cell. The potential of the specimen relative to the reference electrode was monitored.
- the specimen potential rose quickly to +1050 mv. (SCE) at which value it remained for 1 min. This value was taken as the start potential. The specimen potential then commenced to rise again. When the specimen potential had risen 7 mv. above the start potential the specimen was removed, and was found, as expected, to be colored blue.
- SCE +1050 mv.
- chromium-containing alloys other than steel which can be treated in accordance with the present invention usually contain at least about 12.5% by weight of chromium and include iron-based nickelchromium-m0lybdenum alloys such as an alloy containing 37% nickel, 18% chromium, 5% molybdenum, 1.2% titanium and 1.2% aluminum; cobalt-based alloys such as that containing 21% chromium, 21% nickel and 13% molybdenum; and nickel chromium alloys, such as an alloy containing 30% chromium and 1% titanium, the remainder being nickel.
- stainless steels include iron-base alloys containing greater than about 11% and up to about 30% chromium.
- a process for coloring chromium-containing metal comprising anodically treating said chromium-containing metal in an aqueous solution of chromic acid or ions derived from a water-soluble chromate or dichromate and sulfuric acid, causing cessation of flow of direct current responsible for the anodic treatment when the potential of said chromium-containing metal in said aqueous solution measured against a reference electrode reaches a pre-determined value associated with a particular color and thereupon removing the chromium-containing metal from said aqueous solution.
- a process as in claim 2 wherein said chromiumcontaining metal is stainless steel.
- a process as in claim 1 wherein said chromiumcontaining metal in said aqueous solution is part of a cathode-electrolyte-anode-potential source circuit in which an essentially constant current sufiicient to provide an anode current density of up to about 0.25 ampere/dm. is caused to flow until the potential of said chromium-containing metal measured against said reference electrode reaches said' predetermined value.
- the predetermined potential value is a value arrived at by measuring the inflexion potential of said chromium-containing metal at the start of coloring and adjusting said infiexiou potential by an increment associated with desired coloration.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Engineering & Computer Science (AREA)
- Inorganic Chemistry (AREA)
- Chemical Treatment Of Metals (AREA)
- Electrochemical Coating By Surface Reaction (AREA)
- ing And Chemical Polishing (AREA)
- Electroplating And Plating Baths Therefor (AREA)
- Electroplating Methods And Accessories (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB1794172A GB1402184A (en) | 1972-04-18 | 1972-04-18 | Anodic treatment of chromium-containing alloys |
Publications (1)
Publication Number | Publication Date |
---|---|
US3804730A true US3804730A (en) | 1974-04-16 |
Family
ID=10103927
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US00349114A Expired - Lifetime US3804730A (en) | 1972-04-18 | 1973-04-09 | Control of electrolytic coloring of chromium-containing alloys |
Country Status (16)
Country | Link |
---|---|
US (1) | US3804730A (xx) |
JP (1) | JPS5232621B2 (xx) |
AT (1) | AT326442B (xx) |
AU (1) | AU471276B2 (xx) |
BE (1) | BE798416A (xx) |
CA (1) | CA1016491A (xx) |
CH (1) | CH572990A5 (xx) |
DE (1) | DE2319383C3 (xx) |
ES (1) | ES413836A1 (xx) |
FR (1) | FR2180921B1 (xx) |
GB (1) | GB1402184A (xx) |
IL (1) | IL42003A0 (xx) |
IT (1) | IT980230B (xx) |
LU (1) | LU67434A1 (xx) |
NL (1) | NL7305356A (xx) |
ZA (1) | ZA732408B (xx) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4026737A (en) * | 1974-10-22 | 1977-05-31 | Nippon Steel Corporation | Method for coloring a stainless steel |
US4064020A (en) * | 1975-12-22 | 1977-12-20 | The Boeing Company | Preparing an environmentally stable stainless surface for bonding |
US4071416A (en) * | 1976-02-13 | 1978-01-31 | The International Nickel Company, Inc. | Treatment of chromium-containing iron alloys |
US4370210A (en) * | 1981-03-10 | 1983-01-25 | Nippon Kinzoku Co., Ltd. | Method and apparatus for continuously forming color display layer on stainless steel strip |
US4756874A (en) * | 1986-12-22 | 1988-07-12 | General Electric Company | Minimization of radioactive material deposition in water-cooled nuclear reactors |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4003054A (en) * | 1974-10-03 | 1977-01-11 | Raytheon Company | Method of compensating for imbalances in a quadrature demodulator |
DE2549407C2 (de) * | 1975-11-04 | 1987-03-05 | Poligrat GmbH, 8000 München | Verfahren zum Färben von korrosionsbeständigen Chromstählen |
JPS52122234A (en) * | 1976-04-06 | 1977-10-14 | Shiyashin Kagaku Kk | Pigmentation process for stainless steel |
JPS5357141A (en) * | 1976-11-04 | 1978-05-24 | Dipsol Chem | Automatic controlling means for chromating solution and method thereof |
AU8386982A (en) * | 1981-06-01 | 1982-12-09 | Wiggin Alloys Ltd. | Increasing absorptance of porous film on cr containing iron alloy |
US4915799A (en) * | 1986-02-21 | 1990-04-10 | Kinki Yakuhin Industrial Co., Ltd. | Electrolytic coloring method for chromium alloy |
JP5030560B2 (ja) * | 2006-11-29 | 2012-09-19 | クリナップ株式会社 | ミラーキャビネット |
WO2018143267A1 (ja) | 2017-01-31 | 2018-08-09 | アベル株式会社 | 発色ステンレス鋼板、発色ステンレス鋼コイル及びその製造方法 |
-
1972
- 1972-04-18 GB GB1794172A patent/GB1402184A/en not_active Expired
-
1973
- 1973-04-09 US US00349114A patent/US3804730A/en not_active Expired - Lifetime
- 1973-04-09 ZA ZA732408A patent/ZA732408B/xx unknown
- 1973-04-11 AU AU54374/73A patent/AU471276B2/en not_active Expired
- 1973-04-11 IL IL42003A patent/IL42003A0/xx unknown
- 1973-04-16 CA CA168,859A patent/CA1016491A/en not_active Expired
- 1973-04-16 LU LU67434A patent/LU67434A1/xx unknown
- 1973-04-16 IT IT7349471A patent/IT980230B/it active
- 1973-04-17 FR FR7313995A patent/FR2180921B1/fr not_active Expired
- 1973-04-17 NL NL7305356A patent/NL7305356A/xx unknown
- 1973-04-17 CH CH546873A patent/CH572990A5/xx not_active IP Right Cessation
- 1973-04-17 ES ES413836A patent/ES413836A1/es not_active Expired
- 1973-04-17 DE DE2319383A patent/DE2319383C3/de not_active Expired
- 1973-04-18 AT AT343273A patent/AT326442B/de not_active IP Right Cessation
- 1973-04-18 JP JP48043303A patent/JPS5232621B2/ja not_active Expired
- 1973-04-18 BE BE130179A patent/BE798416A/xx unknown
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4026737A (en) * | 1974-10-22 | 1977-05-31 | Nippon Steel Corporation | Method for coloring a stainless steel |
US4064020A (en) * | 1975-12-22 | 1977-12-20 | The Boeing Company | Preparing an environmentally stable stainless surface for bonding |
US4071416A (en) * | 1976-02-13 | 1978-01-31 | The International Nickel Company, Inc. | Treatment of chromium-containing iron alloys |
US4370210A (en) * | 1981-03-10 | 1983-01-25 | Nippon Kinzoku Co., Ltd. | Method and apparatus for continuously forming color display layer on stainless steel strip |
US4756874A (en) * | 1986-12-22 | 1988-07-12 | General Electric Company | Minimization of radioactive material deposition in water-cooled nuclear reactors |
Also Published As
Publication number | Publication date |
---|---|
JPS5232621B2 (xx) | 1977-08-23 |
AU471276B2 (en) | 1976-04-15 |
BE798416A (fr) | 1973-10-18 |
DE2319383A1 (de) | 1973-11-15 |
GB1402184A (en) | 1975-08-06 |
IL42003A0 (en) | 1973-06-29 |
DE2319383B2 (de) | 1979-01-25 |
ES413836A1 (es) | 1976-01-16 |
FR2180921B1 (xx) | 1981-10-16 |
NL7305356A (xx) | 1973-10-22 |
CA1016491A (en) | 1977-08-30 |
ZA732408B (en) | 1974-02-27 |
LU67434A1 (xx) | 1973-10-22 |
AU5437473A (en) | 1974-10-17 |
ATA343273A (de) | 1975-02-15 |
JPS4921339A (xx) | 1974-02-25 |
FR2180921A1 (xx) | 1973-11-30 |
DE2319383C3 (de) | 1979-09-20 |
IT980230B (it) | 1974-09-30 |
CH572990A5 (xx) | 1976-02-27 |
AT326442B (de) | 1975-12-10 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
US3804730A (en) | Control of electrolytic coloring of chromium-containing alloys | |
US2606866A (en) | Method of treating tin plate | |
JPH0320495A (ja) | アルミニウム合金加工部材を陽極処理する改良された方法 | |
US4042468A (en) | Process for electrolytically coloring aluminum and aluminum alloys | |
Ogura et al. | Room Temperature‐Coloration of Stainless Steel by Alternating Potential Pulse Method | |
US3772165A (en) | Method of treating surfaces of steel products | |
US3878056A (en) | Process for electrolytic coloring of the anodic oxide film on a aluminum or aluminum base alloys | |
Watson et al. | The role of chromium II catalysed olation reactions in the sustained deposition of chromium and its alloys from environmentally acceptable chromium III electrolytes | |
US4024039A (en) | Coloring methods for aluminum and aluminum alloys | |
US4070255A (en) | Process for electrolytically coloring aluminum and aluminum alloys | |
Hoare et al. | Current efficiency during the electrochemical machining of iron and nickel | |
Datta et al. | Mass transport effects during electropolishing of iron in phosphoric-sulfuric acid | |
Britton | Electrochemical assessment of chromium in passivation films on tinplate | |
Freiman et al. | Pitting corrosion of iron by perchlorate ions | |
US3832292A (en) | Catalytic cathodic hardening of oxide films | |
Gonzalez et al. | The Undercutting of Organic Lacquers on Steel | |
US3346469A (en) | Method of selectively coloring titanium bodies | |
US2714089A (en) | Electrodepositing iron | |
US3839096A (en) | Reproducibility of color in coloring stainless steel | |
US3586612A (en) | Anodic phosphating of metallic articles | |
US3929612A (en) | Process for electrolytically coloring the anodically oxidized coating on aluminum or aluminum base alloys | |
US3330744A (en) | Anodic treatment of zinc and zinc-base alloys and product thereof | |
US4840708A (en) | Process for the precise determination of the surface area of an electrically conducting shaped body | |
Fisher et al. | The basic principles of electrophoretic paint deposition and its application to the development of coating systems for metal powders on metal substrates for subsequent diffusion treatment | |
US3852172A (en) | Zinc oxidation process |