US3790342A - Process of producing a dyed cleaned material - Google Patents

Process of producing a dyed cleaned material Download PDF

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Publication number
US3790342A
US3790342A US00221831A US3790342DA US3790342A US 3790342 A US3790342 A US 3790342A US 00221831 A US00221831 A US 00221831A US 3790342D A US3790342D A US 3790342DA US 3790342 A US3790342 A US 3790342A
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US
United States
Prior art keywords
solvent
dyeing medium
dye
dyed
dyeing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US00221831A
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English (en)
Inventor
R Love
A Stewart
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
J&P Coats Ltd
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J&P Coats Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
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Publication of US3790342A publication Critical patent/US3790342A/en
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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/90General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dyes dissolved in organic solvents or aqueous emulsions thereof
    • D06P1/92General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dyes dissolved in organic solvents or aqueous emulsions thereof in organic solvents
    • D06P1/922General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dyes dissolved in organic solvents or aqueous emulsions thereof in organic solvents hydrocarbons
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B9/00Solvent-treatment of textile materials
    • D06B9/02Solvent-treatment of textile materials solvent-dyeing
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B9/00Solvent-treatment of textile materials
    • D06B9/04Successively applying two or more different solvent-based treating materials
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/0004General aspects of dyeing
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/44General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
    • D06P1/64General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
    • D06P1/651Compounds without nitrogen
    • D06P1/65106Oxygen-containing compounds
    • D06P1/65112Compounds containing aldehyde or ketone groups
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P1/00General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
    • D06P1/90General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dyes dissolved in organic solvents or aqueous emulsions thereof
    • D06P1/92General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dyes dissolved in organic solvents or aqueous emulsions thereof in organic solvents
    • D06P1/928Solvents other than hydrocarbons
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06PDYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
    • D06P5/00Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
    • D06P5/02After-treatment
    • D06P5/04After-treatment with organic compounds

Definitions

  • ABSTRACT A process of producing a dyed cleaned material comprising first applying to virgin material a dyeing medium, next drying the material and then treating the material with a cleaning substance containing acetone.
  • the acetone may be diluted with water in a proportion up to 50 percent water.
  • the dyeing medium may be a non-aqueous solvent dyeing medium.
  • the nonaqueous dyeing medium may be combined with a material for which the solvent has an affinity higher than it has for the dye, e.g., a silicone.
  • the cleaning treatment is an expensive adjunct to the dyeing operation, not only on account of the time taken, but also because of the trouble of having to subject the material to" a number of further operations.
  • the cleaning operation it is necessary to subject the material subsequently to a drying operation which itself is expensive because of the amount of heat which has to be applied to remove the aqueous constituent of the cleaning liquids.
  • the method of drying may consist in forcing hot air through the dyed and cleaned material, or in removing the residual acetone at a sub-atmospheric pressure below the vapour pressure of the cleaning substance.
  • the dyeing medium may be an aqueous dye medium, i.e., a dye in which the dyestuff is dispersed or dissolved in water which may contain auxiliary chemicals as additives intended to function as, for example, dispersing agents and buffering agents.
  • the dyeing medium may be a solvent dyeing medium.
  • a dyestuff is dispersed or dissolved in a non-aqueous solvent.
  • the solvent dyeing medium may consist of a substance incorporating a dye, a solvent of the dye and a material for which the solvent has a higher affinity than it has for the dye.
  • the components of the solvent dyeing medium may be all mixed together in one mixing operation before application to the virgin material, or the solvent and the material for which the solvent has an affinity higher than it has for the dye may be mixed together and then It would thus be a great technical advance to provide a quick, simple, cheap, easily performed process for producing dyed material free from loose surface dye.
  • a process of producing a dyed cleaned material according to the invention consists in first applying to virgin material a dyeing medium, drying the material and then treating the material with a cleaning substance consisting of acetone in a proportion from 100 to 50 percent and a diluent in a proportion from O to 50 percent.
  • the diluent may be a neutral diluent such as water.
  • the efficiency of the process is usually enhanced by operating the process at a temperature above room temperature.
  • a suitable temperature lies within the range 40 50 C.”
  • the process may include the step of drying the material after treatment with the cleaning substance.
  • the material may be treated by centrifuging the material with the cleaning substance or circulating the cleaning substance through the material or moving the material through the cleaning substance.
  • the dye either in dry form or in paste form added, the final mix being applied to the virgin material.
  • the dyeing medium may include a first component substance incorporating a dye contained in a solvent and a second component substance incorporating the material for which the solvent has a higher affinity than it has for the dye, the two component substances being either mixed before application to the virgin material or being applied consecutively and separately to the virgin material.
  • the two component substances are in liquid form or at least one may consist of at least one solid dispersed or dissolved in aliquid phase.
  • the process may include the further step of subjecting the material to a washing operation in the same solvent alone as is used in the first component substance or in another solvent after it has been treated with the two component substances.
  • the ratio of the first component substance to the complete dyeing medium may be in the range of to 5 percent and the ratio of the second component substance to the composite dyeing medium may be in the range of 10 to percent.
  • the liquor ratio of the solvent dyeing medium to the material being dyed will normally lie between 1:1 and :1 but for certain purposes ratios outside of these limits may be used.
  • Solvents with boiling points above the boiling point of water may conveniently be used and the temperature of dyeing is preferably held at a maximum of 30 C below the softening point of the material being dyed if this is synthetic material and about 10 C below the degradation temperature of a material which has no softening point, e.g., a natural fibre.
  • the aliphatic solvents may be hydrocarbons, alcohols, halogenated hydrocarbons, aldehydes, ketones and esters.
  • Aromatic solvents are hydrocarbons, phenols, aryl halides, aldehydes and ketones, and esters.
  • the second component substance may consist of a silicone fluid, an aliphatic solvent such as hydrocarbon (high boiling white spirit), an aliphatic halogenated hydrocarbon, an aromatic hydrocarbon or an aromatic halogenated hydrocarbon and includes mixture of these.
  • hydrocarbon high boiling white spirit
  • aliphatic halogenated hydrocarbon an aromatic hydrocarbon or an aromatic halogenated hydrocarbon and includes mixture of these.
  • urea is one such substance, may be incorporated in the second component substance.
  • the mode of operation of the process is that solution of the dyestuff in the solvent to form the first component substance puts the dyestuff into a form suitable for transfer to the material to be dyed.
  • the greater affinity of the solvent for the second component substance than it has for the dyestuff increases relatively the affinity of the dyestuff for the material being dyed and an enhanced dyeing effect is achieved.
  • the constituents of the component substances are readily chosen so that the component substances are nonexplosive and virtually non-inflammable.
  • a first component substance contains perchloroethylene as the solvent and silicone fluid as the second component substance.
  • perchloroethylene is extensively used in the dry-cleaning industry.
  • Suitable silicone fluids are low viscosity dimethyl-polysiloxanes. Other advantages possessed by these solvents are that they have high flash points, are virtually non-volatile, have no true boiling points, are neutral and are chemically inert.
  • the acetone performs all the required cleaning action in one operation,it dissolves not only the loose surface coating of dye but also the more strongly adherent surface dye which is not normally removed by the washing operation.
  • the acetone does not form by-products and acts with such speed that it can be applied fora time sufficien't to remove the unfixed surface dye only, i.e., not to take out any of the fixed absorbed dye.
  • the process can be operated as a batch dyeing process or as a continuous dyeing process.
  • aqueous dyes As well as solvent dyes and there are occasions where aqueous dyes are more suitable, it is preferable to use solvent dyes because the auxiliary chemicals usually required in the dye liquor not only reduce the concentration of the dyestuff but are troublesome in that they are difi'icult to render innocuous in the eflluent from the dyeing process. It thus may require a considerable amount of expenditure in making the effluent sufficiently innocuous or otherwise harmless to discharge to a drainage system or to a river or stream.
  • Another disadvantage of aqueous dyes is that water has high specific and latent heats and consequently the amount of heat required to dry the dyed material contributes substantially to the cost of the dyeing process.
  • a further advantage of the use of solvent dyes is that the material being dyed is more rapidly wetted by these non-aqueous solvents and that textile materials do not swell as much in the non-aqueous solvents as they do in water.
  • the method of applying the substance or the component substances to the virgin material includes any practicable process, e.g., immersion of the virgin material in the substance or component substances, pumping the substances or the component substances through the virgin material, or printing the substances or the component substances on to the virgin material, or any combination of these processes or other practicable processes.
  • virgin material may already have been treated in some fashion, e.g., it
  • a process of producing a dyed cleaned material consisting in first applying to material capable of being dyed a dyeing medium, next drying the material and then treating the material with a cleaning substance comprising acetone in a proportion from 100 to percent and a diluent in a proportion from 0 to 50 percent.
  • a process as claimed in claim 1 including the additional step of drying the material after treatment with the cleaning substance.
  • a process as claimed in claim 5 in which the step of drying the material consists in subjecting the material to a sub-atmospheric pressure below the vapour pressure of the cleaning substance.
  • the dyeing medium is an aqueous dyeing medium, i.e., a dyeing medium containing a dyestuff dispersed or dissolved in water.
  • the dyeing medium is a solvent dyeing medium, i.e., a dyeing medium containing a dyestuff dispersed or dissolved in a non-aqueous solvent.
  • the solvent dyeing medium is a dye, a solvent of the dye and a material for which the solvent has a higher affinity than it has for the dye.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Coloring (AREA)
US00221831A 1971-01-29 1972-01-28 Process of producing a dyed cleaned material Expired - Lifetime US3790342A (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
GB353671A GB1386072A (en) 1971-01-29 1971-01-29 Method of producing dyed material
GB353771A GB1386073A (en) 1971-01-29 1971-01-29 Method of producing dyed material
GB862371 1971-04-03

Publications (1)

Publication Number Publication Date
US3790342A true US3790342A (en) 1974-02-05

Family

ID=27254288

Family Applications (1)

Application Number Title Priority Date Filing Date
US00221831A Expired - Lifetime US3790342A (en) 1971-01-29 1972-01-28 Process of producing a dyed cleaned material

Country Status (15)

Country Link
US (1) US3790342A (de)
JP (1) JPS5040876A (de)
AU (1) AU461114B2 (de)
BE (1) BE778610A (de)
CA (1) CA964007A (de)
CH (2) CH124972A4 (de)
DE (1) DE2203882A1 (de)
ES (1) ES399268A1 (de)
FR (1) FR2123517B1 (de)
GB (2) GB1386072A (de)
IE (1) IE36044B1 (de)
IT (1) IT948335B (de)
NL (1) NL7201172A (de)
NO (1) NO135373C (de)
SE (1) SE384050B (de)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3849153A (en) * 1973-05-11 1974-11-19 L Giorgi Color correcting process
US4270236A (en) * 1971-11-09 1981-06-02 Ciba-Geigy Corporation Process for the dyeing of fibre material
US4828571A (en) * 1984-04-13 1989-05-09 Pensa Ildo E Non-aqueous process for the dyeing of dyable materials at an elevated temperature in a non-reactive environment and in a non-aqueous dye solvent
US5468417A (en) * 1994-01-07 1995-11-21 Dow Corning Corporation Silicone containing VOC complaint paint remover

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5836274A (ja) * 1981-08-24 1983-03-03 三菱レイヨン株式会社 合成樹脂成形物の染色法
JPS5836275A (ja) * 1981-08-25 1983-03-03 三菱レイヨン株式会社 表面硬化合成樹脂成形物の染色法
ES2072810B1 (es) * 1993-04-27 1996-02-16 Morell Rafael Luis Pellicer Procedimiento de estampacion de tejidos con colorantes solubles en esencia de trementina sobre agua.

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3342542A (en) * 1967-09-19 Ho o nhx c chax c chjx o oh
US3524718A (en) * 1965-07-09 1970-08-18 Geigy Ag J R Processes for the continuous dyeing and printing of cellulose ester fiber material
US3706525A (en) * 1971-03-08 1972-12-19 Du Pont Water swollen cellulose dyeing with high molecular weight disperse dye in a glycol ether solution

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL226196A (de) * 1957-03-29
CH349904A (de) * 1957-04-11 1960-10-31 Hoechst Ag Verfahren zur farbigen Gestaltung von Formkörpern aus Homo- und Mischpolymerisaten von Olefinen
DE1220385B (de) * 1960-07-09 1966-07-07 Roehm & Haas Gmbh Oberflaecheneinfaerbung von Formkoerpern aus acrylnitrilhaltigen Mischpolymerisaten
GB921063A (en) * 1960-11-22 1963-03-13 Ici Ltd Colouration of polyolefin articles
FR1392535A (fr) * 1963-12-16 1965-03-19 Nouvel adjuvant de nettoyage
FR1560532A (de) * 1968-01-29 1969-03-21
FR1603448A (de) * 1968-08-14 1971-04-19
FR2038526A5 (de) * 1969-03-18 1971-01-08 Ugine Kuhlmann

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3342542A (en) * 1967-09-19 Ho o nhx c chax c chjx o oh
US3524718A (en) * 1965-07-09 1970-08-18 Geigy Ag J R Processes for the continuous dyeing and printing of cellulose ester fiber material
US3706525A (en) * 1971-03-08 1972-12-19 Du Pont Water swollen cellulose dyeing with high molecular weight disperse dye in a glycol ether solution

Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
B. Milicevic Textile Chemist & Colorist, 2, (5), 1970, March 11, pp. 87/17 20/90, 95/25 28/93. *
WAS White, Amer. Dyestuff Reporter, July 31, 1967, pp. P591 P597. *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4270236A (en) * 1971-11-09 1981-06-02 Ciba-Geigy Corporation Process for the dyeing of fibre material
US4340387A (en) * 1971-11-09 1982-07-20 Ciba-Geigy Corporation Process for the dyeing of fibre material
US3849153A (en) * 1973-05-11 1974-11-19 L Giorgi Color correcting process
US4828571A (en) * 1984-04-13 1989-05-09 Pensa Ildo E Non-aqueous process for the dyeing of dyable materials at an elevated temperature in a non-reactive environment and in a non-aqueous dye solvent
US5468417A (en) * 1994-01-07 1995-11-21 Dow Corning Corporation Silicone containing VOC complaint paint remover

Also Published As

Publication number Publication date
DE2203882A1 (de) 1972-11-23
ES399268A1 (es) 1975-06-01
GB1386072A (en) 1975-03-05
IE36044L (en) 1972-07-29
JPS5040876A (de) 1975-04-14
GB1386073A (en) 1975-03-05
BE778610A (fr) 1972-05-16
CH567140A (de) 1975-09-30
NL7201172A (de) 1972-08-01
IE36044B1 (en) 1976-08-04
IT948335B (it) 1973-05-30
CA964007A (en) 1975-03-11
FR2123517A1 (de) 1972-09-08
FR2123517B1 (de) 1977-12-23
NO135373C (no) 1977-03-30
SE384050B (sv) 1976-04-12
NO135373B (de) 1976-12-20
AU3832772A (en) 1975-05-15
CH124972A4 (de) 1975-04-30
AU461114B2 (en) 1975-05-15

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