US3759700A - Process of refining metal melts by supersonic oxygen blow - Google Patents
Process of refining metal melts by supersonic oxygen blow Download PDFInfo
- Publication number
- US3759700A US3759700A US00004917A US3759700DA US3759700A US 3759700 A US3759700 A US 3759700A US 00004917 A US00004917 A US 00004917A US 3759700D A US3759700D A US 3759700DA US 3759700 A US3759700 A US 3759700A
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- Prior art keywords
- oxygen
- melt
- melts
- lance
- jet
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- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/10—Handling in a vacuum
Definitions
- This invention relates to a process for refining molten metals, particularly iron melts and steel melts, in which for example thelcarbon content and/or the content of other undesiredlelements in the metal is reduced.
- the invention also relates to apparatus for carrying out the process.
- German patent specification (Auslegeschrift) 1,216,904 describes a process for degassing a melt at greatly reduced pressure, in which the melt flows through a vacuum chamber situated above the body of melt which it is desired to degas.
- the molten metal is introduced into the vacuum chamber through an inlet pipe by means of a conveying gas.
- the vacuum vessel is arranged to move up and down to discharge degassed portions of the melt and draw in fresh portions of melt for degassing, the vessel being connected to the melt by a length of pipe whose lower end dips into the melt.
- oxygen is blown at supersonic velocity onto the surface of a melt under reduced pressure in a vacuum chamber.
- pure oxygen can be introduced into the melt in a vacuum chamber so that the resulting high heat of reaction of the oxidation reaction is utilized and high alloy melts can be produced, without the disadvantages mentioned earlier.
- the oxygen jet forms a cohesive narrow column of flowing gas which does not escape through the vacuum pump before reacting with the metal melt. Consequently, the oxygen reacts practically completely with the easily oxidized substances in the metal melt, for example with the carbon in an iron or steel melt.
- the pressure of the oxygen jet at the point it enters the vacuum chamber is below, but not too far below, the internal pressure in the vacuum chamber, otherwise there would result a very short supersonic jet which would break down at the first node by shock compression to give a useless subsonic jet.
- the pressure in the oxygen jet at the nozzle outlet is not too different from the pressure in the vacuum vessel there is formed an elongated supersonic jet which is stable through several nodes. If the pressure in the jet at the nozzle outlet is much higher than the pressure in the vacuum vessel, the jet bursts just after leaving the nozzle, and becomes useless.
- apparatus for performing a process according to the invention comprises a vacuum chamber, means for evacuating the chamber, and an oxygen lance which projects into the chamber and which is capable of directing a jet of oxygen at supersonic velocity onto the surface of a melt which in operation is contained in the chamber.
- the outlet opening at the end of the lance is preferably constructed as a Laval nozzle.
- the lance is preferably arranged so that it can be retracted into the connection through which it passes into the vacuum chamber, and there is a member which is movable to close the mouth of the connection when the lance is retracted so that the outlet end of the lance is protected when not in use. This protects the end of the lance, especially when this is a Laval nozzle, from spattered metal and slag.
- FIG. 1 is a vertical section through one example comprising a vacuum enclosure in which there rests a pan containing a metal melt;
- FIG. 2 is a vertical section through the second example showing a vacuum lifting vessel having a lower suction pipe dipping into a metal melt in a pan, the figure showing the apparatus during the refining of a portion of the melt;
- FIG. 3 is a similar view to FIG. 2, but shows the apparatus during discharging of the refined portion of the melt back into the pan.
- the apparatus shown in FIG. 1 consists of a vacuum enclosure 5 closed by a gas-tight cover 6 fitted with a connection 8 leading to a vacuum pump 7 (not shown).
- the cover 6 also has a connection 9 with a stuffing box seal 10 through which there passes, in a gas-tight but axially slidable fashion, an oxygen lance 11.
- the outlet opening of the oxygen lance 11 is in the form of 2.
- Laval nozzle 12 which causes the oxygen which issues from the lance to form a narrow, cohesive jet. Beneath the nozzle 12 of the oxygen lance 11 there is a pan 13 containing the metal melt 14 which is being processed.
- the lance 11 is not in use it is retracted upwards into the neck of the connection 9 and covered over by a flap 15, for protection against spattered metal and slag. This is particularly to protect the Laval nozzle 12.
- a vacuum lifting vessel 18 has a lower suction pipe 17 which dips into a metal melt 20 contained in a pan 19.
- the vacuum vessel 18 is connected by a connection 21 to a vacuum pump, not shown in the drawing, and also has an inlet connected to a feed device 22 for introducing alloy substances into the melt.
- the upper end of the vacuum vessel 18 is equipped with a lance connection 23 containing a stufiing box seal 24 through which an oxygen lance 25 passes in a gas-tight but axially slidable fashion.
- the lance 25 has its outlet opening in the form of a Laval nozzle 26.
- the vacuum lifting vessel 18 is also equipped with an internal flap 27 for protecting the nozzle 26 of the oxygen lance 25 when the lance is retracted and not in use.
- the arrangement illustrated in FIGS. 2 and 3 is operated intermittently, that is to say oxygen is blown only during the degassing part of the process, which is the period when a portion of the melt 20 is being lifted under vacuum, and degassed, in the degassing vessel 18. This arrangement during this part of the process is represented in FIG. 2.
- no oxygen is blown when the degassed and refined portion of melt is run down again into the pan 19, as is represented in FIG. 3.
- the lance 25 has a shut-otf valve 28, which can if desired be controlled by the lifting mechanism for the vacuum vessel 18, the vessel being lifted in order to cause the degassed portion of the melt to run back into the pan 19.
- a steel melt containing 0.3% carbon, 16% chromium and 8% nickel was refined in vacuo at a pan temperature of 1650" C., the amount of carbon in the melt being reduced to 0.03% with practically no slagging of the chromium. It should be noted that at this temperature the oxygen dissolved in the melt could not have reduced the amount of carbon to less than 0.25%.
- This arrangement provided a supersonic oxygen jet with a pressure of 15 torr at the nozzle outlet, this pressure being less than the pressure prevailing in the vacuum vessel 18 which was 20 torr.
- the supersonic jet took the form of a cohesive narrow jet directed onto the portion of the melt in the vessel 18 and this rapidly caused the removal of carbon from the melt.
- a process of refining metal melts, particularly iron and steel melts, in a vacuum chamber including the steps of supplying at least a portion of said melt to said vacuum chamber, reducing the pressure in said chamber, and blowing from a Laval nozzle onto the surface of said melt in said vacuum chamber a narrow cohesive jet of oxygen at supersonic velocity which substantially entirely impinges on the surface of the melt, and controlling said blowing whereby the pressure of said oxygen jet at the point where said jet enters said vacuum chamber is about 25% lower than said pressure in said vacuum chamber.
Abstract
IN A PROCESS OF REFINING METAL MELTS, PARTICULARY IRON MELTS AND STEEL MELTS, OXYGEN IS BLOWN AT SUPERSONIC VELOCITY FROM AN OXYGEN LANCE, PREFERABLY FITTED WITH A LAVAL NOZZLE, ONTO THE SURFACE OF THE MELT WHICH IS CONTAINED IN A VACUUM CHAMBER UNDER GREATELY REDUCED PRESSURE. THE OXYGEN JET MUST BE IN THE FORM OF A COHESIVE STREAM OF OXYGEN WHICH SUBSTANTIALLY WHOLLY IMPINGES ON THE SURFACE OF THE MELT IN THE VACUUM CHAMBER WITHOUT FIRST BREAKING UP AND BEING DISPERSED IN THE CHAMBER.
Description
Sept. 18, 1973 DIENER ETAL PROCESS OF REFINING METAL MELTS BY SUPERSONIC OXYGEN BLOW Filed Jan. 22, 1970 S Sheets-Sheet 1 FIG] Sept. 18, 1973 DlENER ETAL PROCESS OF REFINING METAL MELTS BY SUPERSONIC OXYGEN BLOW 5 Sheets-Sheet 2 Filed Jan. 22, 1970 PROCESS OF REFINING METAL MELTS BY SUPERSONIC OXYGEN BLOW 3 Sheets-Sheet 5 Filed Jan. 22, 1970 FIG.3
United States Patent 015cc 3,759,700 Patented Sept. 18, 1973 ABSTRACT OF THE DISCLOSURE In a process of refining metal melts, particularly iron melts and steel melts, oxygen is blown at supersonic velocity from an oxygen lance, preferably fitted with a Laval nozzle, onto the surface of the melt which is contained in a vacuum chamber under greatly reduced pressure. The oxygen jet must be in the form of a cohesive stream of oxygen which substantially wholly impinges on the surface of the melt in the vacuum chamber without first breaking up and being dispersed in the chamber.
. This invention relates to a process for refining molten metals, particularly iron melts and steel melts, in which for example thelcarbon content and/or the content of other undesiredlelements in the metal is reduced. The invention also relates to apparatus for carrying out the process.
It is known to accelerate the removal of carbon from steel melts at reduced pressure by adding solid oxides, for example fine-grained ores, rolling mill scale or other metal oxides. However, the addition of solid oxygen carriers involves several disadvantages. In the first place the heat required for dissolving the solid oxygen carrier is taken from the metal melt. Secondly, before the undesired elements in the melt, for example the carbon, can be oxidized, the solid oxygen carrier first has to be reduced, and this decreases the free enthalpy of the entire reaction. Moreover the oxides whichit is practical to use for this purpose, particularly the ores, contain a number of elements which have deleterious effects on the properties of the steel melt being refined.
Also known are processes for refining steels at reduced pressure, in which gases are blown into the melt from underneath. For example German patent specification (Auslegeschrift) 1,216,904 describes a process for degassing a melt at greatly reduced pressure, in which the melt flows through a vacuum chamber situated above the body of melt which it is desired to degas. The molten metal is introduced into the vacuum chamber through an inlet pipe by means of a conveying gas. In the vacuum lift degassing process, the vacuum vessel is arranged to move up and down to discharge degassed portions of the melt and draw in fresh portions of melt for degassing, the vessel being connected to the melt by a length of pipe whose lower end dips into the melt. In this process it is known to introduce the melt through the inlet pipe by means of a conveying gas.
The vacuum processes which use conveying gases must necessarily use either inert gases or at least gases which are slow to react as the conveying gas, because this gas serves merely to lift the molten metal in the inlet pipe. In these processes it is not possible to introduce pure oxygen as the conveying gas because the reaction of the pure oxygen with the molten metal, and with the other elements present in the melt, would be so violent that the refractory lining of the inlet pipe would be rapidly destroyed, The destruction of the refractory lining would be accelerated by the ferrous oxide which is produced when pure oxygen is introduced into an iron melt or into a steel melt. Ferrous oxide destroys a refractory lining very rapidly.
According to the present invention, in a process of refining metal melts, particularly iron melts and steel melts, oxygen is blown at supersonic velocity onto the surface of a melt under reduced pressure in a vacuum chamber. With such a process pure oxygen can be introduced into the melt in a vacuum chamber so that the resulting high heat of reaction of the oxidation reaction is utilized and high alloy melts can be produced, without the disadvantages mentioned earlier. At supersonic velocity the oxygen jet forms a cohesive narrow column of flowing gas which does not escape through the vacuum pump before reacting with the metal melt. Consequently, the oxygen reacts practically completely with the easily oxidized substances in the metal melt, for example with the carbon in an iron or steel melt.
Preferably, the pressure of the oxygen jet at the point it enters the vacuum chamber is below, but not too far below, the internal pressure in the vacuum chamber, otherwise there would result a very short supersonic jet which would break down at the first node by shock compression to give a useless subsonic jet. Provided that the pressure in the oxygen jet at the nozzle outlet is not too different from the pressure in the vacuum vessel there is formed an elongated supersonic jet which is stable through several nodes. If the pressure in the jet at the nozzle outlet is much higher than the pressure in the vacuum vessel, the jet bursts just after leaving the nozzle, and becomes useless.
In accordance with a further feature of the invention apparatus for performing a process according to the invention comprises a vacuum chamber, means for evacuating the chamber, and an oxygen lance which projects into the chamber and which is capable of directing a jet of oxygen at supersonic velocity onto the surface of a melt which in operation is contained in the chamber.
In order to obtain the desired oxygen jet, i.e. a cohesive narrow column of flowing oxygen, the outlet opening at the end of the lance is preferably constructed as a Laval nozzle. Also, the lance is preferably arranged so that it can be retracted into the connection through which it passes into the vacuum chamber, and there is a member which is movable to close the mouth of the connection when the lance is retracted so that the outlet end of the lance is protected when not in use. This protects the end of the lance, especially when this is a Laval nozzle, from spattered metal and slag.
Two examples of apparatus by which a process inaccordance with the invention can be performed, and one example of such a process will now be described with reference to the accompanying drawings, in which:
FIG. 1 is a vertical section through one example comprising a vacuum enclosure in which there rests a pan containing a metal melt;
FIG. 2 is a vertical section through the second example showing a vacuum lifting vessel having a lower suction pipe dipping into a metal melt in a pan, the figure showing the apparatus during the refining of a portion of the melt; and,
FIG. 3 is a similar view to FIG. 2, but shows the apparatus during discharging of the refined portion of the melt back into the pan.
The apparatus shown in FIG. 1 consists of a vacuum enclosure 5 closed by a gas-tight cover 6 fitted with a connection 8 leading to a vacuum pump 7 (not shown). The cover 6 also has a connection 9 with a stuffing box seal 10 through which there passes, in a gas-tight but axially slidable fashion, an oxygen lance 11. The outlet opening of the oxygen lance 11 is in the form of 2. Laval nozzle 12, which causes the oxygen which issues from the lance to form a narrow, cohesive jet. Beneath the nozzle 12 of the oxygen lance 11 there is a pan 13 containing the metal melt 14 which is being processed. When the lance 11 is not in use it is retracted upwards into the neck of the connection 9 and covered over by a flap 15, for protection against spattered metal and slag. This is particularly to protect the Laval nozzle 12.
In the apparatus represented in FIGS. 2 and 3 a vacuum lifting vessel 18 has a lower suction pipe 17 which dips into a metal melt 20 contained in a pan 19. The vacuum vessel 18 is connected by a connection 21 to a vacuum pump, not shown in the drawing, and also has an inlet connected to a feed device 22 for introducing alloy substances into the melt. The upper end of the vacuum vessel 18 is equipped with a lance connection 23 containing a stufiing box seal 24 through which an oxygen lance 25 passes in a gas-tight but axially slidable fashion. The lance 25 has its outlet opening in the form of a Laval nozzle 26. The vacuum lifting vessel 18 is also equipped with an internal flap 27 for protecting the nozzle 26 of the oxygen lance 25 when the lance is retracted and not in use. The arrangement illustrated in FIGS. 2 and 3 is operated intermittently, that is to say oxygen is blown only during the degassing part of the process, which is the period when a portion of the melt 20 is being lifted under vacuum, and degassed, in the degassing vessel 18. This arrangement during this part of the process is represented in FIG. 2. On the other hand, no oxygen is blown when the degassed and refined portion of melt is run down again into the pan 19, as is represented in FIG. 3. To provide control of the oxygen blow, the lance 25 has a shut-otf valve 28, which can if desired be controlled by the lifting mechanism for the vacuum vessel 18, the vessel being lifted in order to cause the degassed portion of the melt to run back into the pan 19.
In one example of a process in accordance with the invention carried out with apparatus of the kind shown in FIGS. 2 and 3, a steel melt containing 0.3% carbon, 16% chromium and 8% nickel was refined in vacuo at a pan temperature of 1650" C., the amount of carbon in the melt being reduced to 0.03% with practically no slagging of the chromium. It should be noted that at this temperature the oxygen dissolved in the melt could not have reduced the amount of carbon to less than 0.25%. The oxygen blow lance 25 had a Laval nozzle with an aperture ratio of F*/F=0.08, and through this pure oxygen was blown from an oxygen supply pipe containing oxygen at a pressure of 3 atmospheres gauge. This arrangement provided a supersonic oxygen jet with a pressure of 15 torr at the nozzle outlet, this pressure being less than the pressure prevailing in the vacuum vessel 18 which was 20 torr. With this arrangement the supersonic jet took the form of a cohesive narrow jet directed onto the portion of the melt in the vessel 18 and this rapidly caused the removal of carbon from the melt. To reach the final very low carbon content of 0.03% approximately 4 kg. of oxygen per ton of steel refined was blown.
We claim:
1. A process of refining metal melts, particularly iron and steel melts, in a vacuum chamber, including the steps of supplying at least a portion of said melt to said vacuum chamber, reducing the pressure in said chamber, and blowing from a Laval nozzle onto the surface of said melt in said vacuum chamber a narrow cohesive jet of oxygen at supersonic velocity which substantially entirely impinges on the surface of the melt, and controlling said blowing whereby the pressure of said oxygen jet at the point where said jet enters said vacuum chamber is about 25% lower than said pressure in said vacuum chamber.
2. A process as claimed in claim 1, wherein a steel melt containing chromium is refined.
References Cited UNITED STATES PATENTS 2,093,666 9/1937 Vogt -49 X 3,420,657 1/ 1969 Hansen 75-49 X 2,993,780 7/1961 Allard 7549 2,068,785 l/1937 Bain ct a1. 7549 X 3,216,714 11/1965 Eibl et al. 26634 L FOREIGN PATENTS 677,686 8/1952 Great Britain 75-60 613,372 1/1961 Canada 75-49 OTHER REFERENCES Wbsters Third New International Dictionary, G. & C. Merriam Co., Springfield, Mass., 1961, p. 2296.
Perry, -I. H.: Chemical Engineers Handbook, New York, 1963, 9th ed.; (De Laval nozzle), pp. 5-26 and 5-27.
L. DEWAYNE RUTLEDGE, Primary Examiner W. R. SATTERFIELD, Assistant Examiner US. Cl. X.R.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19691904442 DE1904442B2 (en) | 1969-01-30 | 1969-01-30 | PROCESS FOR VACUUM REFRESHING METAL MELT |
Publications (1)
Publication Number | Publication Date |
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US3759700A true US3759700A (en) | 1973-09-18 |
Family
ID=5723740
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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US00004917A Expired - Lifetime US3759700A (en) | 1969-01-30 | 1970-01-22 | Process of refining metal melts by supersonic oxygen blow |
Country Status (6)
Country | Link |
---|---|
US (1) | US3759700A (en) |
JP (1) | JPS543121B1 (en) |
DE (1) | DE1904442B2 (en) |
FR (1) | FR2029665B1 (en) |
GB (1) | GB1288336A (en) |
SE (1) | SE363846B (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0584814A2 (en) * | 1992-08-26 | 1994-03-02 | Nippon Steel Corporation | Process and apparatus for vacuum degassing molten steel |
Families Citing this family (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
NL155487B (en) * | 1965-07-22 | 1978-01-16 | Textron Inc | FILLING PEN OR SUCH WRITING OR MARKING INSTRUMENT. |
JPS5442211A (en) * | 1977-09-09 | 1979-04-04 | Yoshio Midorikawa | Feltttip pen and method and device for making said pen |
HU179333B (en) * | 1978-10-04 | 1982-09-28 | Vasipari Kutato Intezet | Method and apparatus for decreasing the unclusion contents and refining the structure of steels |
EP0328851A1 (en) * | 1988-02-16 | 1989-08-23 | Acciaierie E Ferriere Lombarde Falck S.P.A. | An apparatus for decarbonizing steels directly in the ladle |
CA1337846C (en) * | 1988-06-21 | 1996-01-02 | Hiroshi Nishikawa | Process for vacuum degassing and decarbonization with temperature drop compensating feature |
DE4442362C1 (en) * | 1994-11-18 | 1996-04-18 | Mannesmann Ag | Method and appts. for performing a variety of processes on a melt using standard equipment |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2093666A (en) * | 1934-11-23 | 1937-09-21 | Wacker Chemie Gmbh | Process for treating iron and iron alloys |
AT174069B (en) * | 1950-01-31 | 1953-02-25 | Voest Ag | Process for the production of technically pure iron |
DE975922C (en) * | 1951-03-17 | 1962-12-13 | Oesterr Alpine Montan | Process for blowing pig iron, in which oxygen is blown onto the bath surface from above with a blow nozzle |
GB761657A (en) * | 1953-01-15 | 1956-11-21 | Oesterr Alpine Montan | Improvements in methods for blowing metal baths, particularly pig iron baths |
DE1216904B (en) * | 1957-04-03 | 1966-05-18 | Heraeus Gmbh W C | Process for vacuum degassing of molten metals, in particular steel |
DE1804748U (en) * | 1958-02-22 | 1960-01-28 | Hoerder Huettenunion Ag | DEVICE FOR DEGASSING STEEL MELT. |
FR1238058A (en) * | 1958-10-11 | 1960-08-05 | Suedwestfalen Ag Stahlwerke | Process for obtaining molten baths of highly alloyed metals |
DE1194886B (en) * | 1960-06-24 | 1965-06-16 | Beteiligungs & Patentverw Gmbh | Process for refining pig iron, especially those with a high phosphorus content |
FR1277441A (en) * | 1960-10-22 | 1961-12-01 | Siderurgie Fse Inst Rech | Improvements in vacuum steel processing |
GB1027115A (en) * | 1963-06-25 | 1966-04-20 | Allegheny Ludlum Steel | Improvements in or relating to a process for producing corrosion-resisting steel |
-
1969
- 1969-01-30 DE DE19691904442 patent/DE1904442B2/en not_active Ceased
-
1970
- 1970-01-19 FR FR7001732A patent/FR2029665B1/fr not_active Expired
- 1970-01-22 US US00004917A patent/US3759700A/en not_active Expired - Lifetime
- 1970-01-29 SE SE01136/70A patent/SE363846B/xx unknown
- 1970-01-29 JP JP738670A patent/JPS543121B1/ja active Pending
- 1970-01-30 GB GB466670A patent/GB1288336A/en not_active Expired
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP0584814A2 (en) * | 1992-08-26 | 1994-03-02 | Nippon Steel Corporation | Process and apparatus for vacuum degassing molten steel |
EP0584814A3 (en) * | 1992-08-26 | 1994-09-07 | Nippon Steel Corp | Process and apparatus for vacuum degassing molten steel |
US5413623A (en) * | 1992-08-26 | 1995-05-09 | Nippon Steel Corporation | Process and apparatus for vacuum degassing molten steel |
Also Published As
Publication number | Publication date |
---|---|
JPS543121B1 (en) | 1979-02-19 |
FR2029665A1 (en) | 1970-10-23 |
SE363846B (en) | 1974-02-04 |
FR2029665B1 (en) | 1974-08-09 |
DE1904442A1 (en) | 1970-09-03 |
DE1904442B2 (en) | 1978-01-19 |
GB1288336A (en) | 1972-09-06 |
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