US3730783A - Process for treating a coating of aluminium deposited on a metal support,more particularly,sheet metal - Google Patents

Process for treating a coating of aluminium deposited on a metal support,more particularly,sheet metal Download PDF

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Publication number
US3730783A
US3730783A US00153976A US3730783DA US3730783A US 3730783 A US3730783 A US 3730783A US 00153976 A US00153976 A US 00153976A US 3730783D A US3730783D A US 3730783DA US 3730783 A US3730783 A US 3730783A
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United States
Prior art keywords
coating
metal
sheet
aluminium
aluminium oxide
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Expired - Lifetime
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US00153976A
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English (en)
Inventor
D Streel
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Cockerill SA
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Cockerill SA
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Publication date
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    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/22—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the process of coating
    • C23C14/56—Apparatus specially adapted for continuous coating; Arrangements for maintaining the vacuum, e.g. vacuum locks
    • C23C14/562—Apparatus specially adapted for continuous coating; Arrangements for maintaining the vacuum, e.g. vacuum locks for coating elongated substrates
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/06—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material characterised by the coating material
    • C23C14/14—Metallic material, boron or silicon
    • C23C14/16—Metallic material, boron or silicon on metallic substrates or on substrates of boron or silicon
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/58—After-treatment
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C14/00—Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
    • C23C14/58—After-treatment
    • C23C14/5846—Reactive treatment
    • C23C14/5853—Oxidation
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/68—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous solutions with pH between 6 and 8
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
    • C23C8/08—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
    • C23C8/10—Oxidising
    • C23C8/12—Oxidising using elemental oxygen or ozone

Definitions

  • ABSTRACT OF THE DISCLOSURE A process for treating an aluminium coating deposited on sheet-metal such as a steel plate, sheet or strip, comprising applying the aluminium coating by evaporation under vacuum, with a thickness less than 20 microns, onto sheet-metal which advances continuously, subjecting systematically the aluminium coating to superficial hot oxidation by passing the coated sheet-metal directly to atmosphere while its temperature is still 100 C. so as to form a film of aluminium oxide, subjecting the thus formed film of aluminium oxide to the action of a hot fluid based on water while the sheet-metal is still advancing continuously in order to transform the aluminium oxide to hydrated aluminium oxide.
  • the present invention relates to a process for treating a coating of aluminium deposited on a metal support, more particularly, sheet metal.
  • coatings are usually applied onto metal products, not only for the purpose of giving to the latter a more beautiful appearance but also and mainly for protecting these products against corrosion.
  • aluminium oflers great advantages because of some of its interesting qualities: in addition to a low price, it has a very good resistance to atmospheric corrosion and a good deformability. The latter property is of great importance in effecting forming operations which occur in the manufacture of some articles.
  • Thin steel plate provided with an aluminium coating of little thickness may be subjected to forming operations as easily and as well as thin steel plates which are uncoated.
  • an aluminium coating on a support of steel such as a steel plate, sheet, or strip may be applied by various methods, and particularly by the so-called method by evaporation under vacuum.
  • the product to be coated is passed through an enclosure in which is created a high vacuum of about 10- ton in which metal vapours are emitted from a melting-pot containing the metal which has to make up the coating and which is heated up to a high temperature, generally above the melting point of said metal.
  • the emitted metal vapours condense on the product to be coated and form thereon a well-adhering coating whose thickness may, depending on conditions, vary from several tenths to several tens of microns.
  • sheet-metal coated with an aluminium coating shows a very serious drawback.
  • the coating becomes covered with a pulverulent film of aluminium oxide which is formed immediately by oxidation of the aluminium, as soon as the coated sheet-metal going still in warm or hot condition out of the coating apparatus, comes into contact with air.
  • the pulverulent film thus formed is very porous and highly water absorbent, so that stains such as [finger strains made during handling of the sheets, are indelibly marked thereon.
  • the problem to be solved by the present invention is to provide a simple and low cost process for obtaining a stable aluminium coating which, while keeping its resistance to atmospheric corrosion, is prefectly ductile so as to undergo forming operations without damage.
  • a solution to this problem is obtained by a process for treating a metal product and, more particularly sheetmetal such as a steel plate or sheet or strip, based on the finding that contrary to the known teachings, there is a possibility of using natural oxidation of the aluminium coating of sheet-metal in the warm or hot state going out from a coating apparatus, to obtain a perfectly stable coating by transforming aluminium oxide A1 0 into hydrated aluminium oxide (Al O )(OI-I) which is stable and non porous.
  • the coating is subjected to superficial oxidation so as to form a film of aluminium oxide, and the aluminium oxide film is subjected to the action of a fluid based on water so as to have its natural porosity removed.
  • a coating of aluminium is applied onto sheet-metal by the process of evaporation under vacuum, the coating is subjected to the oxidizing action of atmospheric air by causing the coated sheet-metal to go out of the vacuum apparatus at a temperature above C., the coated and hot sheet-metal is immediately thereafter subjected to the action of hot water which is at a temperature above 60 C., the hot water being allowed to act for a variable duration comprised between 1 minute and 1 hour depending on its temperature.
  • the sheet-metal provided with the coating oxidized by air passes in a hot water bath immediately after its exit from the coating apparatus.
  • the aluminium coating ob tained by evaporation under vacuum is subjected to oxidation by ambient air and then to the direct action of steam projected by any known means such as nozzles carried by supporting means extending along the path of travel of the product being treated.
  • the coated sheet-metal passes between two such supporting means which project steam at pressures. comprised between 1 and 10 kg. cm
  • a steel strip 1 of about 0.8 mm. thickness passes continuously in an apparatus 2 where it receives an aluminium coating on each of its two faces by a process of evaporation under vacuum which needs not be described since it is well known.
  • the steel strip 1 enters the apparatus 2 by passing through a lock-chamber 3a and goes out of the apparatus through a similar lock-chamber 312 after having received an aluminium coating and enters the atmosphere while it is still at a high temperature of about 150 C.
  • the temperature of the steel strip coming out of the coating apparatus may be comprised between 100 C. and 250 C.
  • the heated aluminium coating becomes quickly oxidized and superficially covered with a film of aluminium oxide A1 having a few microns thickness. Said film is porous and water absorbent.
  • the coated steel strip After its passage into atmospheric air, the coated steel strip, still warm, passes immediately between supporting means 4 and 5 equipped with nozzles 6 and 7 which project onto said strip steam at a pressure comprised between 1 and kg./cm. said steam is fed by conduits 8 and 9 connected to a source of steam not shown.
  • the steam impinging the strip causes systematically immediate transformation of aluminium oxide A1 0 into Al2O (0H) which has a much greater specific volume than A1 0
  • the result thereof is that the superficial layer of the aluminium coating becomes compact and continuous that is without any porosity, which contributes to protecting the steel plate in a perfect way against corrosion because the coating successively oxidized and treated with steam does no longer undergo subsequent oxidation.
  • the just-described process also is particularly advantageous from economic point of view because the steel strip comes continuously out of the coating apparatus, at sufiiciently high temperature to be oxidized systematically by simple passage through air.
  • the coating treated in this way is perfectly ductile which allows the coated steel strip to undergo forming operation without fear of making the aluminium coating to burst. This capability has been noticed by subjecting a sample of coated and treated steel strip to bending tests.
  • a continuous steel strip of 0.8 mm. thickness receives by evaporation under vacuum an aluminium coating of about 3 microns on both faces.
  • the aluminium becomes immediately oxidized as soon as the strip comes out of the coating apparatus and, in the air, is covered with a film of alumina A1 0 having a thickness of about 0.1 micron which is changed to hydrated aluminium oxide by immerging then the coated strip which advances continuously directly into an opened tank containing water at a temperature close to 100 C.
  • a process for treating an aluminium coating deposited on sheet steel comprising applying to sheet steel of indeterminate length an aluminium coating by evaporation under vacuum, with a thickness less than 20 microns, while advancing the steet steel continuously, subjecting the aluminium coating to superficial hot oxidation by passing the coated sheet steel directly through the atmosphere as the sheet steel emerges from the coating apparatus at a temperature which is still comprised between C. and 250 C. so as to form a film of aluminium oxide, and continuously transforming said aluminium oxide into hydrated aluminium oxide by continuously passing the sheet steel from the atmosphere into a bath of hot aqueous fluid for between 1 minute and 1 hour.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Laminated Bodies (AREA)
  • Chemical Treatment Of Metals (AREA)
  • Wrappers (AREA)
  • Heat Treatment Of Strip Materials And Filament Materials (AREA)
US00153976A 1970-06-24 1971-06-17 Process for treating a coating of aluminium deposited on a metal support,more particularly,sheet metal Expired - Lifetime US3730783A (en)

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Application Number Priority Date Filing Date Title
BE752488 1970-06-24

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US3730783A true US3730783A (en) 1973-05-01

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Country Status (4)

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US (1) US3730783A (fr)
BE (1) BE752488A (fr)
FR (1) FR2100817B1 (fr)
GB (1) GB1324462A (fr)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4938814A (en) * 1988-07-08 1990-07-03 European Space Agency High-performance propellant combinations for a rocket engine
US5352490A (en) * 1988-09-22 1994-10-04 Nkk Corporation Method of chemical vapor deposition in a continuous treatment line
US5447291A (en) * 1993-10-08 1995-09-05 The Ohio State University Processes for fabricating structural ceramic bodies and structural ceramic-bearing composite bodies
US5672436A (en) * 1990-05-31 1997-09-30 Grumman Aerospace Corporation Oxidation protection method for titanium
KR100568916B1 (ko) * 1997-12-04 2006-04-07 로셰 디아그노스틱스 게엠베하 표면장력 증대를 위한 표면피복의 제조방법 및 표면피복

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3029488A1 (de) * 1980-08-02 1982-03-04 GHT Gesellschaft für Hochtemperaturreaktor-Technik mbH, 5060 Bergisch Gladbach Verfahren zur erzeugung einer schutzschicht auf metallischen werkstuecken
FR2603905A1 (fr) * 1986-09-12 1988-03-18 Elf France Procede de protection des surfaces metalliques contre la corrosion vanadosodique

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB406988A (en) * 1931-11-20 1934-02-28 Aluminum Colours Inc Improvements in or relating to the treatment of the surfaces of aluminium or aluminium alloy articles
GB937676A (en) * 1960-12-16 1963-09-25 Nat Standard Co Coating by vapor deposition

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4938814A (en) * 1988-07-08 1990-07-03 European Space Agency High-performance propellant combinations for a rocket engine
US4950341A (en) * 1988-07-08 1990-08-21 European Space Agency High-performance propellant combinations for a rocket engine
US5352490A (en) * 1988-09-22 1994-10-04 Nkk Corporation Method of chemical vapor deposition in a continuous treatment line
US5672436A (en) * 1990-05-31 1997-09-30 Grumman Aerospace Corporation Oxidation protection method for titanium
US5776266A (en) * 1990-05-31 1998-07-07 Northrop Grumman Corporation Oxidation protection method for titanium
US5447291A (en) * 1993-10-08 1995-09-05 The Ohio State University Processes for fabricating structural ceramic bodies and structural ceramic-bearing composite bodies
KR100568916B1 (ko) * 1997-12-04 2006-04-07 로셰 디아그노스틱스 게엠베하 표면장력 증대를 위한 표면피복의 제조방법 및 표면피복
US7025836B1 (en) 1997-12-04 2006-04-11 Roche Diagnostics Gmbh Modification of surfaces in order to increase the surface tension
US8211245B2 (en) 1997-12-04 2012-07-03 Roche Diagnostics Operations, Inc. Modification of surfaces to increase the surface tension
US8580049B2 (en) 1997-12-04 2013-11-12 Roche Diagnostics Gmbh Modification of surfaces to increase the surface tension

Also Published As

Publication number Publication date
FR2100817A1 (fr) 1972-03-24
FR2100817B1 (fr) 1974-06-21
GB1324462A (en) 1973-07-25
BE752488A (fr) 1970-12-01

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