US3730097A - Fuze for use in firedamp-endangered and coal-dust-endangered operations - Google Patents
Fuze for use in firedamp-endangered and coal-dust-endangered operations Download PDFInfo
- Publication number
- US3730097A US3730097A US00193460A US3730097DA US3730097A US 3730097 A US3730097 A US 3730097A US 00193460 A US00193460 A US 00193460A US 3730097D A US3730097D A US 3730097DA US 3730097 A US3730097 A US 3730097A
- Authority
- US
- United States
- Prior art keywords
- explosive
- fuze
- fuze according
- casing
- synthetic resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000002360 explosive Substances 0.000 claims abstract description 60
- 239000000126 substance Substances 0.000 claims abstract description 30
- 229920003002 synthetic resin Polymers 0.000 claims abstract description 19
- 239000000057 synthetic resin Substances 0.000 claims abstract description 19
- 239000004033 plastic Substances 0.000 claims abstract description 18
- 229920003023 plastic Polymers 0.000 claims abstract description 18
- 239000002365 multiple layer Substances 0.000 claims abstract description 13
- 239000000203 mixture Substances 0.000 claims abstract description 12
- 229910052784 alkaline earth metal Inorganic materials 0.000 claims description 14
- 150000001342 alkaline earth metals Chemical class 0.000 claims description 10
- 229910001610 cryolite Inorganic materials 0.000 claims description 10
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 6
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-M Bicarbonate Chemical class OC([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-M 0.000 claims description 5
- 150000003863 ammonium salts Chemical class 0.000 claims description 5
- 150000004649 carbonic acid derivatives Chemical class 0.000 claims description 5
- 150000003467 sulfuric acid derivatives Chemical class 0.000 claims description 5
- TZRXHJWUDPFEEY-UHFFFAOYSA-N Pentaerythritol Tetranitrate Chemical compound [O-][N+](=O)OCC(CO[N+]([O-])=O)(CO[N+]([O-])=O)CO[N+]([O-])=O TZRXHJWUDPFEEY-UHFFFAOYSA-N 0.000 claims description 4
- 239000003513 alkali Substances 0.000 claims description 4
- 238000009826 distribution Methods 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 229920002239 polyacrylonitrile Polymers 0.000 claims description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 abstract description 15
- 239000000835 fiber Substances 0.000 abstract description 9
- 238000005422 blasting Methods 0.000 abstract description 6
- 229920000642 polymer Polymers 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 3
- 239000002817 coal dust Substances 0.000 abstract description 2
- 238000005065 mining Methods 0.000 description 8
- 238000012360 testing method Methods 0.000 description 7
- 238000005474 detonation Methods 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 238000001816 cooling Methods 0.000 description 4
- 239000007789 gas Substances 0.000 description 4
- 239000003245 coal Substances 0.000 description 3
- 238000004880 explosion Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000004804 winding Methods 0.000 description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 description 2
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 description 2
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 239000002802 bituminous coal Substances 0.000 description 2
- 238000000586 desensitisation Methods 0.000 description 2
- 239000010410 layer Substances 0.000 description 2
- 229920001169 thermoplastic Polymers 0.000 description 2
- 239000004416 thermosoftening plastic Substances 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000003000 extruded plastic Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- -1 polytetrafluoroethylene Polymers 0.000 description 1
- 229920001343 polytetrafluoroethylene Polymers 0.000 description 1
- 239000004810 polytetrafluoroethylene Substances 0.000 description 1
- 230000037452 priming Effects 0.000 description 1
- 239000011435 rock Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 239000012209 synthetic fiber Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 230000001960 triggered effect Effects 0.000 description 1
- 238000009834 vaporization Methods 0.000 description 1
- 230000008016 vaporization Effects 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06C—DETONATING OR PRIMING DEVICES; FUSES; CHEMICAL LIGHTERS; PYROPHORIC COMPOSITIONS
- C06C5/00—Fuses, e.g. fuse cords
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06B—EXPLOSIVES OR THERMIC COMPOSITIONS; MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES
- C06B25/00—Compositions containing a nitrated organic compound
- C06B25/32—Compositions containing a nitrated organic compound the compound being nitrated pentaerythritol
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06C—DETONATING OR PRIMING DEVICES; FUSES; CHEMICAL LIGHTERS; PYROPHORIC COMPOSITIONS
- C06C5/00—Fuses, e.g. fuse cords
- C06C5/04—Detonating fuses
-
- C—CHEMISTRY; METALLURGY
- C06—EXPLOSIVES; MATCHES
- C06C—DETONATING OR PRIMING DEVICES; FUSES; CHEMICAL LIGHTERS; PYROPHORIC COMPOSITIONS
- C06C5/00—Fuses, e.g. fuse cords
- C06C5/06—Fuse igniting means; Fuse connectors
Definitions
- the envelope is, preferably, a mixture 0 L C in n In.
- a fuze (priming cord) which does not represent any danger for mine gas mixtures (firedamp) at the given length of the shot holes, e.g. 20 m., is suitable.
- the fuze must be firedamp-proof.
- the fuze must be able to initiate with certainty all conventional and mining-approved explosives of classes II and Ill.
- the present invention is based on the problem of developing a fuze which meets all demands from the viewpoint of blasting technology and simultaneously possesses a maximum degree of firedamp dafety.
- the fuze of the present invention is characterized by a core cord having a strongly reduced explosive weight per meter of fuze, of a powdery desensitized explosive, with a hollow tube centrally disposed within the explosive core and a casing of inert substances having a flash-reducing (flame-cooling) and flame-baffling ef-- feet.
- the combination of the individual features of the core cord and the casing, as well as their mutual adaptation result in a surprising increase in the firedamp safety of the fuze which has not existed heretofore.
- the individually provided measures result, by their cooperation, in the special, firedampproof characteristics.
- the starting point is the quantity of the explosive to be utilized. Since the capability of an explosive to ignite firedamp does not solely depend on the brisance and explosion temperatures, but is influenced to the same extent by the amount of the explosive employed, the core cord of this invention is equipped with an explosive core having an explosive weight which is strongly reduced as compared to the customary fuze, ranging preferably between 2 to 5 g. per meter. With such an amount, a compact, solid explosive core will assume outer diameters ofonly 2.6 to 3.0 mm.
- a second measure is provided, namely the use of a powdery explosive in an extremely finely divided form, wherein at least 60 percent of the explosive passes through a mesh screen of 0.074 mm.
- a suitable explosive is, for example, penthrite.
- the third measure essential to the present invention is the addition of a desensitized substance to the powdery explosive.
- a desensitized substance for this purpose, all materials can be employed which genuinely reduce the brisance of the explosive, such as, cryolite, all halogenides, sulfates, bicarbonates, carbonates, and phosphates of the alkali metals and alkaline earth metals, the corresponding ammonium salts, and all oxides of the alkaline earth metals.
- care is to be taken in the selection of the desensitizirtg substance so that, with a minimum quantity of additive, a satisfactory desensitization is effected without endangering the complete detonation or detonation propagation of the explosive core.
- Cryolite proved especially suitable since it exhibits excellent flame-cooling properties.
- the fourth essential measure is the central arrangement of an endless hollow tube in the explosive core.
- This hollow tube provides, as a result of its characteristic, a hollow-charge effect, i.e. the tube effects, up to a certain extent, a directional shot which focuses a large portion of the energy liberated during the reaction of the explosive in the axial direction of the fuze and thus strongly reduces the normal uniform lateral effect.
- This hollow tube which must be adapted to the diameter of the explosive core with respect to its diameter, exhibits an optimum efficiency in cooperation with the explosive employed when occupying about one-third of the total (or outside) diameter of the explosive core.
- the hollow tube consists, for example, of any desired, deformable and stretchable synthetic resin and is uniformly round and disposed as centrally as possible within the explosive core. This tube should furthermore exhibit a uniformly round hollow channel which is not constricted or interrupted by pressure, bending or other mechanical influences.
- the thus-formed core cord is surrounded, in a fifth measure essential to the present invention, by a casing of inert substances having a flame-cooling and flamebaffling effect.
- the important feature of this casing is the density of the envelope of gas vapors and firing vapors formed by the vaporization of the inert substances.
- a dense envelope is capable of absorbing residual, laterally effective energies, hot explosion gases and glowing particles of the core cord to shield and screen off the same against any existing explosive gas mixtures, e.g., firedamp.
- the inert substances suitable for producing such a dense envelope all the materials set forth above for the desensitization of the explosive can be employed.
- thermosetting and thermoplastic synthetic resins being suitable, admixed in an extremely fine distribution to the other inert substances in a percentage of S- percent based on the weight of the other inert substances.
- Synthetic resins on the basis of polyacrolynitrile with styrene and butadiene or ABS- polymers are particularly preferable.
- other heat-resistant plastics can be successfully utilized in this connection, for example, polytetrafluoroethylene, or copolymers of polyacrylonitrile.
- the encased core cord is advantageously surrounded by an outer shell, e.g., of extruded plastic, such as soft PVC.
- the foundation of the so-called core cord is formed by the plastic hollow tube 1 disposed centrally with respect to the longitudinal axis.
- Tube 1 is surrounded and guided by several threads 2 which, in turn, are surrounded by explosive core 3 of, for example, a uniform mixture of 4 g. of extremely fine penthrite with percent (0.4 g.) of cryolite, per running meter of fuze.
- explosive core 3 of, for example, a uniform mixture of 4 g. of extremely fine penthrite with percent (0.4 g.) of cryolite, per running meter of fuze.
- the strip 4 of plastic e.g., hard PVC, encases, wound in overlapping windings, the explosive core 3.
- the multiple-layer spun casing 5 of natural and/or synthetic fibers forms the outer cover of the core cord.
- the envelope of the core cord is constituted by the jacket composition 7 of inert substances, e.g., 8 g. per running meter of fuze of a mixture of 50 percent ABS (acrylonitrile-butadiene-styrene) polymer, percent cryolite and 30 percent sodium chloride. This mixture is likewise guided in the axial direction by several threads 6, for example of cellulose-base fibers.
- the cover of the fuze comprises: strip 8 of a plastic film, e.g., hard PVC, wound in overlapping windings; the multiple-layer spun envelope 9 of threads of synthetic and/or natural fibers; and the waterproof outer shell 10, e.g., of soft PVC.
- a thus-constructed fuze exhibits a detonation velocity of 6000 i 600 m./sec., a tensile strength of 100 :t 20 kp./cm. and an outer diameter of about 5.8 mm.
- the fuze of this invention which is' distinguished by an especially high degree of firedamp safety, was tested in the chamber of an explosive testing range in various arrangements having 9 9.5 percent firedamp concentrations.
- the covering method is advantageously employed, wherein the explosive is introduced from a feeding funnel into a thin strip of paper, plastic or another suitable material which is continuously helically wound in overlapping windings at the lower end of the funnel.
- the explosivefilled strip is then provided with a cover of various layers of textile threads or the like twisted from fibers, which are helically wound or spun therearound.
- the core cord is encased with the inert mixture of substances in the same manner, and the thus-obtained fuze additionally provided with a coat of varnish, a thermoplastic synthetic resin or the like.
- the powdery explosive utilized does not exhibit fluidity it is introduced into the core cord from the feeding funnel by means of transporting threads with a rough surface traveling through the filling funnel under tension and vibration.
- transporting threads exhibits the additional advantage that these threads enhance the central positioning of the hollow tube within the core fuze, since the threads simultaneously constitute a support for the hollow tube.
- a fuze for use in firedampand coal-dust-endangered operations comprising an explosive core having a hollow center and including a powdery desensitized explosive of a strongly reduced explosive weight per meter of fuze, a hollow tube disposed within the hollow center of said explosive core, and a casing of inert substances surrounding said explosive core and having a flame-cooling and flame-baffling effect.
- a fuze according to claim 4 wherein 10 percent by weight of cryolite based on the weight of explosive is added to said explosive.
- a fuze according to claim 1 wherein said casing is comprised of a mixture of at least one powdery synthetic resin and at least one substance selected from the group consisting of cryolite, halogenides, sulfates, bicarbonates, and carbonates of the alkali and alkaline earth metals, the corresponding ammonium salts, and all oxides of the alkaline earth metals.
- a fuze according to claim 8 wherein between about 5 percent and about 70 percent of synthetic resin particles are admixed with said at least one inert substance.
- a fuze according to claim 8 wherein said at least one synthetic resin is based on polyacrylonitrile with styrene and butadiene.
- a fuze according to claim 1 further comprising an outer shell of extruded synthetic resin disposed around said casing.
- a fuze according to claim 1 further comprising a strip of wound plastic disposed between said explosive core and said casing of inert substances.
- a fuze according to claim 12 further comprising a multiple-layer spun envelope of synthetic or natural threads positioned between said strip of wound plastic and said casing of inert substances.
- a fuze according to claim 13 further comprising a second strip of wound plastic covering said casing of inert substances.
- a fuze according to claim 14 further comprising a second multiple-layer spun envelope of synthetic or natural threads encasing said second strip of wound plastic.
- a fuze according to claim 15 further comprising an outer shell of extruded synthetic resin disposed around said second multiple-layer spun envelope.
- a fuze according to claim 16 further comprising first and second thread groups, respectively, wound in a manner so as to guide the distribution of said powdery desensitized explosive and said inert substances.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Air Bags (AREA)
- Ropes Or Cables (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Chemical Or Physical Treatment Of Fibers (AREA)
- Materials For Medical Uses (AREA)
- Compositions Of Oxide Ceramics (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE2057042A DE2057042C3 (de) | 1970-11-20 | 1970-11-20 | Sprengschnur für den Einsatz in Schlagwetter- und kohlenstaubgefährdeten Betrieben |
Publications (1)
Publication Number | Publication Date |
---|---|
US3730097A true US3730097A (en) | 1973-05-01 |
Family
ID=5788630
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US00193460A Expired - Lifetime US3730097A (en) | 1970-11-20 | 1971-10-28 | Fuze for use in firedamp-endangered and coal-dust-endangered operations |
Country Status (8)
Country | Link |
---|---|
US (1) | US3730097A (enrdf_load_html_response) |
BE (1) | BE775433A (enrdf_load_html_response) |
CS (1) | CS159294B2 (enrdf_load_html_response) |
DE (1) | DE2057042C3 (enrdf_load_html_response) |
FR (1) | FR2114857A5 (enrdf_load_html_response) |
GB (1) | GB1321526A (enrdf_load_html_response) |
PL (1) | PL81423B1 (enrdf_load_html_response) |
SU (1) | SU464102A3 (enrdf_load_html_response) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3867884A (en) * | 1973-02-19 | 1975-02-25 | Ici Ltd | Explosive fuse-cord |
US4083305A (en) * | 1976-04-28 | 1978-04-11 | Teledyne Mccormick Selph, An Operating Division Of Teledyne Ind. Inc. | Mild detonating cord confinement |
US4102428A (en) * | 1976-11-03 | 1978-07-25 | Ensign-Bickford Company | No-flash seismic cord |
US4178853A (en) * | 1976-04-28 | 1979-12-18 | Teledyne Mccormick Selph, An Operating Division Of Teledyne Industries, Inc. | Mild detonating cord confinement |
Families Citing this family (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB1396471A (en) * | 1973-02-19 | 1975-06-04 | Ici Ltd | Exposive fuse-cord |
DE2529039A1 (de) * | 1975-06-28 | 1977-01-20 | Dynamit Nobel Ag | Wettersprengstoffe |
DE3020957C2 (de) * | 1980-06-03 | 1983-03-03 | Dynamit Nobel Ag, 5210 Troisdorf | Wasserfeste Sprengschnur |
RU2190587C2 (ru) * | 2000-03-21 | 2002-10-10 | Стадник Валентин Васильевич | Шнур для передачи инициирующего импульса и состав для его изготовления |
RU2215726C2 (ru) * | 2002-01-03 | 2003-11-10 | Федеральное государственное унитарное предприятие "Пермский завод им. С.М.Кирова" | Способ изготовления огнепроводного шнура |
DE102005040392A1 (de) * | 2005-08-25 | 2007-05-03 | Dynaenergetics Gmbh & Co. Kg | Sprengschnur zur Behandlung von schlecht erreichbaren Oberflächen |
DE102006007483B4 (de) * | 2006-02-17 | 2010-02-11 | Atc Establishment | Zündschlauch |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2380312A (en) * | 1942-11-19 | 1945-07-10 | Du Pont | Detonating fuse |
US2891475A (en) * | 1954-02-01 | 1959-06-23 | Ici Ltd | Fuse |
US3027839A (en) * | 1959-04-02 | 1962-04-03 | Andrew J Grandy | Tubular explosive transmission line |
US3344005A (en) * | 1966-02-23 | 1967-09-26 | Trojan Powder Co | Pentaerythritol tetranitrate-trimethylolethane trinitrate explosives |
DE1916685A1 (de) * | 1969-04-01 | 1970-12-10 | Dynamit Nobel Ag | Sprengschnur |
US3590739A (en) * | 1967-07-20 | 1971-07-06 | Nitro Nobel Ab | Fuse |
-
1970
- 1970-11-20 DE DE2057042A patent/DE2057042C3/de not_active Expired
-
1971
- 1971-10-28 US US00193460A patent/US3730097A/en not_active Expired - Lifetime
- 1971-11-09 CS CS784571A patent/CS159294B2/cs unknown
- 1971-11-12 SU SU1713683A patent/SU464102A3/ru active
- 1971-11-17 BE BE775433A patent/BE775433A/xx not_active IP Right Cessation
- 1971-11-18 FR FR7141318A patent/FR2114857A5/fr not_active Expired
- 1971-11-18 PL PL1971151641A patent/PL81423B1/pl unknown
- 1971-11-19 GB GB5395171A patent/GB1321526A/en not_active Expired
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2380312A (en) * | 1942-11-19 | 1945-07-10 | Du Pont | Detonating fuse |
US2891475A (en) * | 1954-02-01 | 1959-06-23 | Ici Ltd | Fuse |
US3027839A (en) * | 1959-04-02 | 1962-04-03 | Andrew J Grandy | Tubular explosive transmission line |
US3344005A (en) * | 1966-02-23 | 1967-09-26 | Trojan Powder Co | Pentaerythritol tetranitrate-trimethylolethane trinitrate explosives |
US3590739A (en) * | 1967-07-20 | 1971-07-06 | Nitro Nobel Ab | Fuse |
DE1916685A1 (de) * | 1969-04-01 | 1970-12-10 | Dynamit Nobel Ag | Sprengschnur |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3867884A (en) * | 1973-02-19 | 1975-02-25 | Ici Ltd | Explosive fuse-cord |
US4083305A (en) * | 1976-04-28 | 1978-04-11 | Teledyne Mccormick Selph, An Operating Division Of Teledyne Ind. Inc. | Mild detonating cord confinement |
US4178853A (en) * | 1976-04-28 | 1979-12-18 | Teledyne Mccormick Selph, An Operating Division Of Teledyne Industries, Inc. | Mild detonating cord confinement |
US4102428A (en) * | 1976-11-03 | 1978-07-25 | Ensign-Bickford Company | No-flash seismic cord |
Also Published As
Publication number | Publication date |
---|---|
DE2057042B2 (de) | 1973-10-25 |
CS159294B2 (enrdf_load_html_response) | 1974-12-27 |
BE775433A (fr) | 1972-03-16 |
FR2114857A5 (enrdf_load_html_response) | 1972-06-30 |
PL81423B1 (enrdf_load_html_response) | 1975-08-30 |
SU464102A3 (ru) | 1975-03-15 |
DE2057042A1 (de) | 1972-05-31 |
DE2057042C3 (de) | 1974-06-12 |
GB1321526A (en) | 1973-06-27 |
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