US3725540A - Color and odor stabilized dry aerosol antiperspirant - Google Patents

Color and odor stabilized dry aerosol antiperspirant Download PDF

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Publication number
US3725540A
US3725540A US00059691A US3725540DA US3725540A US 3725540 A US3725540 A US 3725540A US 00059691 A US00059691 A US 00059691A US 3725540D A US3725540D A US 3725540DA US 3725540 A US3725540 A US 3725540A
Authority
US
United States
Prior art keywords
percent
citric acid
antiperspirant
hexachlorophene
odor
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US00059691A
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English (en)
Inventor
E Wahl
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Application granted granted Critical
Publication of US3725540A publication Critical patent/US3725540A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q15/00—Anti-perspirants or body deodorants
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
    • A61K8/26—Aluminium; Compounds thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/36—Carboxylic acids; Salts or anhydrides thereof
    • A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
    • A61K8/37—Esters of carboxylic acids

Definitions

  • This invention relates to aerosol antiperspirant compositions of the type which are essentially anhydrous, i.e., containing only a small amount of water. Specifically, this invention relates to such compositions containing materials such as hexachlorophene and perfumes which tend to deteriorate during storage.
  • Antiperspirant compositions have been disclosed containing astringent salts, hexachlorophene, a perfume, and tartaric acid; see, e.g., U.S. Pat. No. 3,509,253.
  • Citric acid has been disclosed as a metal scavenger to protect vitamins and other oxygen-sensitive materials.
  • the amount of hexachlorophene is at least about 0.05 percent and most preferably, from about 0.1 percent to about 0.5 percent.
  • the result is a highly effective powder aerosol antiperspirant composition for use on the skin stabilized as to color and odor as compared with a similar composition which does not contain the citric acid.
  • Composition 1 Aluminum chloride lsopropyl palmitate Cab-O-Sil Trifluoromethylcarbanilide Perfume Hexachlorophene Citric acid, monohydrate SDA No. 40
  • Propellant consisting of:
  • Trilluoromethylcarbanilide Perfume Hexachlorophene Citric acid monohydrate 0.
  • Propellant consisting of:
  • dichlorotetrafluoroethane balance Composition IV A mixture of zirconyl hydroxy- 10.0 chloride, aluminum chlorhydroxide and zinc sulfocarbolate 1:1:1)
  • a dry aerosol antiperspirant composition consist- A mlxlglle of: ing essentially of: 17.15 trichlorofluoromethane; 858% dichlomdifluommethane; A.
  • Example I of the D from about 2.5 percent to about 6 percent by Mame weight of finely divided aluminum hydroxl7.l5% n butane; and y hloride; d'chlomtwaflumoethane ,/B. from about 0.3 percent to about 0.75 percent by Composition v weight of a reaction product of Bentonite and dimethyldistearylammonium chloride; A 111 mixture Ofaluminum y y- 60% C. from about 0.1 percent to about 0.5 percent by chloride and the complex of ht f h m h Example lofU.S. Pat. No. 3,407,254 8 0 or01) fine, The complex of Example I of the D.
  • a carrier liquid of low volatility selected A mixture of: from the group consisting of isopropyl myristate, isopropyl palmitate, di-n-butyl phthalate, diethyl ce sebacate, disopropyl adipate, and ethyl ethylcar- 17-15% n-bume; and bomethyl phthalate; and

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • General Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Birds (AREA)
  • Epidemiology (AREA)
  • Emergency Medicine (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Cosmetics (AREA)
US00059691A 1970-07-30 1970-07-30 Color and odor stabilized dry aerosol antiperspirant Expired - Lifetime US3725540A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US5969170A 1970-07-30 1970-07-30

Publications (1)

Publication Number Publication Date
US3725540A true US3725540A (en) 1973-04-03

Family

ID=22024615

Family Applications (1)

Application Number Title Priority Date Filing Date
US00059691A Expired - Lifetime US3725540A (en) 1970-07-30 1970-07-30 Color and odor stabilized dry aerosol antiperspirant

Country Status (5)

Country Link
US (1) US3725540A (xx)
BE (1) BE770784A (xx)
DE (1) DE2137924A1 (xx)
FR (1) FR2099687B1 (xx)
NL (1) NL7110513A (xx)

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3903258A (en) * 1973-08-06 1975-09-02 Gillette Co Zirconium aluminum complexes and method of making the same
US3979510A (en) * 1973-11-23 1976-09-07 Armour Pharmaceutical Company Aluminum-zirconium anti-perspirant systems with complex aluminum buffers
FR2364650A1 (fr) * 1976-09-17 1978-04-14 Spitzer Joseph G Compositions d'aerosols contre la transpiration delivrant une concentration elevee en sel astringent actif a un faible debit avec une bonne adherence a la peau
US4152416A (en) * 1976-09-17 1979-05-01 Marra Dorothea C Aerosol antiperspirant compositions delivering astringent salt with low mistiness and dustiness
US4174386A (en) * 1975-03-03 1979-11-13 Marra Dorothea C Aerosol antiperspirant compositions with good adherence to the skin
AU598330B2 (en) * 1986-12-23 1990-06-21 Unilever Plc Cosmetic product
US5098694A (en) * 1990-09-25 1992-03-24 The Procter & Gamble Company Natural deodorant compositions
US5102656A (en) * 1983-07-29 1992-04-07 The Mennen Company Antiperspirant creams
US5312688A (en) * 1988-08-10 1994-05-17 Teijin Limited Acaricide fiber material and process for producing same
US5605682A (en) * 1992-04-16 1997-02-25 Colgate-Palmolive Company Antiperspirant aerosol composition with high solids content
WO1999056717A1 (en) * 1998-05-07 1999-11-11 The Procter & Gamble Company Aerosol package compositions containing fluorinated hydrocarbon propellants
US20100140305A1 (en) * 2007-03-30 2010-06-10 Sera Lee/De N.V. Cosmetic composition comprising an aluminium salt
US20110212157A1 (en) * 2008-06-26 2011-09-01 Anterios, Inc. Dermal delivery
US20120328549A1 (en) * 2011-01-24 2012-12-27 Anterios, Inc. Oil compositions
WO2015055196A3 (de) * 2013-10-15 2015-06-18 Henkel Ag & Co. Kgaa Schweisshemmende kosmetische mittel mit polycarbonsäuren
US9724299B2 (en) 2006-12-01 2017-08-08 Anterios, Inc. Amphiphilic entity nanoparticles
US10532019B2 (en) 2005-12-01 2020-01-14 University Of Massachusetts Lowell Botulinum nanoemulsions
US11311496B2 (en) 2016-11-21 2022-04-26 Eirion Therapeutics, Inc. Transdermal delivery of large agents

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2608123B2 (de) * 1975-03-12 1981-07-23 Colgate-Palmolive Co., 10022 New York, N.Y. Antischweißmittel in Aerosolform
US4083956A (en) * 1976-04-29 1978-04-11 The Procter & Gamble Company Anhydrous antiperspirant creams

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3088874A (en) * 1960-05-23 1963-05-07 Union Carbide Corp Powder aerosol
GB987301A (en) * 1962-06-25 1965-03-24 Shulton Inc Aerosol compositions

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3141821A (en) * 1959-03-17 1964-07-21 Lehn & Fink Products Corp Synergistic combination of alkyl sulfonates, alkylaryl sulfonates and topical antibacterial agents for local antisepsis

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3088874A (en) * 1960-05-23 1963-05-07 Union Carbide Corp Powder aerosol
GB987301A (en) * 1962-06-25 1965-03-24 Shulton Inc Aerosol compositions

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
Lester et al., Handbook of Cosmetic Materials, 1954, pp. 96. *
Sagarin, Cosmetics Science and Technology, 1957, pp. 1,035, 1,053 and 1,067. *
Winter, Handbuch Der Gesamten Parfumerie Und Kosmetik, 1952, pp. 156 and 675. *

Cited By (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3903258A (en) * 1973-08-06 1975-09-02 Gillette Co Zirconium aluminum complexes and method of making the same
US3979510A (en) * 1973-11-23 1976-09-07 Armour Pharmaceutical Company Aluminum-zirconium anti-perspirant systems with complex aluminum buffers
US4174386A (en) * 1975-03-03 1979-11-13 Marra Dorothea C Aerosol antiperspirant compositions with good adherence to the skin
FR2364650A1 (fr) * 1976-09-17 1978-04-14 Spitzer Joseph G Compositions d'aerosols contre la transpiration delivrant une concentration elevee en sel astringent actif a un faible debit avec une bonne adherence a la peau
US4152416A (en) * 1976-09-17 1979-05-01 Marra Dorothea C Aerosol antiperspirant compositions delivering astringent salt with low mistiness and dustiness
US5102656A (en) * 1983-07-29 1992-04-07 The Mennen Company Antiperspirant creams
AU598330B2 (en) * 1986-12-23 1990-06-21 Unilever Plc Cosmetic product
US5312688A (en) * 1988-08-10 1994-05-17 Teijin Limited Acaricide fiber material and process for producing same
US5098694A (en) * 1990-09-25 1992-03-24 The Procter & Gamble Company Natural deodorant compositions
US5605682A (en) * 1992-04-16 1997-02-25 Colgate-Palmolive Company Antiperspirant aerosol composition with high solids content
WO1999056717A1 (en) * 1998-05-07 1999-11-11 The Procter & Gamble Company Aerosol package compositions containing fluorinated hydrocarbon propellants
US6136303A (en) * 1998-05-07 2000-10-24 The Procter & Gamble Company Aerosol package compositions containing fluorinated hydrocarbon propellants
US10532019B2 (en) 2005-12-01 2020-01-14 University Of Massachusetts Lowell Botulinum nanoemulsions
US10576034B2 (en) 2005-12-01 2020-03-03 University Of Massachusetts Lowell Botulinum nanoemulsions
US9724299B2 (en) 2006-12-01 2017-08-08 Anterios, Inc. Amphiphilic entity nanoparticles
US10285941B2 (en) 2006-12-01 2019-05-14 Anterios, Inc. Amphiphilic entity nanoparticles
US10758485B2 (en) 2006-12-01 2020-09-01 Anterios, Inc. Amphiphilic entity nanoparticles
US20100140305A1 (en) * 2007-03-30 2010-06-10 Sera Lee/De N.V. Cosmetic composition comprising an aluminium salt
US20110212157A1 (en) * 2008-06-26 2011-09-01 Anterios, Inc. Dermal delivery
US20120328549A1 (en) * 2011-01-24 2012-12-27 Anterios, Inc. Oil compositions
WO2015055196A3 (de) * 2013-10-15 2015-06-18 Henkel Ag & Co. Kgaa Schweisshemmende kosmetische mittel mit polycarbonsäuren
US11311496B2 (en) 2016-11-21 2022-04-26 Eirion Therapeutics, Inc. Transdermal delivery of large agents

Also Published As

Publication number Publication date
DE2137924A1 (de) 1972-02-03
FR2099687A1 (xx) 1972-03-17
NL7110513A (xx) 1972-02-01
FR2099687B1 (xx) 1974-03-29
BE770784A (fr) 1972-01-31

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