US3676344A - Ether amides in aqueous lubricants - Google Patents
Ether amides in aqueous lubricants Download PDFInfo
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- US3676344A US3676344A US69071A US3676344DA US3676344A US 3676344 A US3676344 A US 3676344A US 69071 A US69071 A US 69071A US 3676344D A US3676344D A US 3676344DA US 3676344 A US3676344 A US 3676344A
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M173/00—Lubricating compositions containing more than 10% water
- C10M173/02—Lubricating compositions containing more than 10% water not containing mineral or fatty oils
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/02—Water
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/04—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms
- C10M2215/042—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to acyclic or cycloaliphatic carbon atoms containing hydroxy groups; Alkoxylated derivatives thereof
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/08—Amides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/08—Amides
- C10M2215/082—Amides containing hydroxyl groups; Alkoxylated derivatives
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/28—Amides; Imides
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/241—Manufacturing joint-less pipes
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/242—Hot working
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/243—Cold working
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/245—Soft metals, e.g. aluminum
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/246—Iron or steel
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/244—Metal working of specific metals
- C10N2040/247—Stainless steel
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- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2050/00—Form in which the lubricant is applied to the material being lubricated
- C10N2050/01—Emulsions, colloids, or micelles
Definitions
- KUCESKI A TTORNEY ETHER AMIDES IN AQUEOUS LUBRICANTS eliminates the fire hazard which is present when highly heated metal and an oil are brought into contact with one another. By eliminating the fire hazard, size reduction operations can be carried out at faster speeds at which the metal is heated to a higher temperature at which the danger of fire would be increased if an oil lubricant were used.
- the solute of the aqueous lubricant used in carrying out the invention is a material which has a negative heat of solution and is more soluble in water at a lower temperature at which it is supplied to the rolling or extrusion system, and is less soluble at a higher temperature to which it is heated during the rolling or extrusion so that it separates from solution as a solid or liquid and serves as a lubricant.
- the lubricant is an organic, polar, surface-acting composiand is soluble in water at a lower temperature and separates at the higher temperature to which it is heated during the operation. It is free from mineral oil.
- R is an alkyl, cycloalkyl, aryl, aralkyl or alkaryl group of six to 24 carbon atoms; m is 0, l or 2; and n equals the number of recurring alkyl ether groups and may be any number from 2 to 100, inclusive.
- the amide group contributes water solubility equivalent to about three or four ether groups. In other words, if R+m/n+3 about 0.5 to 2.5, or preferably 0.8 to 2.0, a good lubricant is obtained with a concentration of about to or per cent of the amide in water.
- Compounds of the first formula are listed in Table l and compounds of the second formula are listed in Table 11. These compounds are listed as representative of those which can be tion-an ether amidewhich has a negative heat ofsolution used satisfactorily.
- concentrations of the chemical compounds having negative solubility, as they are used in aqueous solutions may vary from a few tenths of one per cent up to 25 or 50 per cent or more, and is usually 1 to 20 per cent, depending upon the nature of the compound and the temperatures to which the aqueous solution is subjected in the treatment of different metals. In most instances, the amount dissolved in the aqueous phase will depend on the viscosity and lubricity obtained. Generally, a clear solution which is easily pumped is required so that the solution may be filtered to remove suspended particles. Such filtration is generally essential for the production of a metal product with a bright unmarred finish.
- the temperatures of solution and separation of the lubricant will vary, depending upon the metal being treated and the method of treatment. Usually the lubricant should be soluble at about room temperature.
- the temperature of rolling will depend upon the metal, etc. In rolling, the aqueous lubricant may be sprayed on upper and lower rolls, or the lower roll may be immersed in a bath of the lubricant. In extrusion the lubricant is added in any desired manner.
- FIG. 1 is a vertical section through equipment for a rolling operation
- FIG. 2 is a vertical section through equipment used in extru- SlOIl.
- FIG. 1 is illustrative of the application of the invention to one method of rolling a metal; namely, the cold-rolling of aluminum. It will be noted that the thickness of the metal 1 is reduced to that shown at 2 as the metal is passed between the rolls 4 and 5.
- the tank 7 contains a clear, aqueous solution of lubricant which is continuously or periodically drawn off through the pipe 10 and filtered and returned through the pipe 11, usually some going to the spray head 13 and the balance being returned through the pipe 14 to the tank. If the filtering operation is carried out only periodically at long intervals, some of the clear lubricant from the tank 7 can be pumped directly to the spray 13 through pipe 14 for spraying the upper roll 4 while the lower roll is rotated while partiallysubmerged in the lubricant contained in the tank. As the aluminum or other metal is reduced from the thickness 1 to the thickness 2, a great deal of heat is given off and the rolls 4 and 5 become heated. The temperature of the bath may be controlled manually or automatically within a few degrees below the precipitation temperature to prevent overheating which would precipitate the lubricant. Water or lubricant may be added as required to maintain the desired concentration.
- the liquid sprayed on to the roller 4 and the entire liquid within the tank is clear. As the rolls 4 and 5 heat up, these rolls become hot enough to cause separation of the lubricant from the water solution either as a separate liquid phase or in particular form.
- the drawing illustrates how, after the rolls 4 and 5 have been heated .up, the liquid is converted to particulate form on the roll 4 due to its heat, and the heat of the roll 5 tends to cause separation of the solute adjacent the roll 5 as it is rotated in it.
- the lubricant is supplied as a clear aqueous solution at a lower temperature and as heat is generated by the rolling operation and the rolls 4 and 5 become more and more heated the lubricant separates more rapidly after contact with the heated roll 4, and the lubricant surrounding the roll 5 separates and the separated phase adheres to the roll as it continues to rotate and carry the separated lubricant to the interface between the roll and the metal being treated.
- the lubricant which separates at a higher temperature performs its useful function. For example, in rolling aluminum, the separation may start at any temperature between 30 and 95 C.
- the solute which separates on the roll 4 as the spray becomes heated and the solute which separates on the roll 5 as it becomes heated adhere to the rolls and are carried to the interface where they serve to lubricate the surface between the roll and the metal, thereby forming a smooth surface on the metal as well as cooling it while it is being compressed.
- lubricants used in extruding or rolling metals when used with water have been in a necessarily very stable finely divided or nearly colloidal emulsion form.
- the manufacture of a finely divided emulsion has been difficult and it has also been difficult to maintain the emulsion over different conditions of operating temperatures and speeds.
- the lubricant In order to be a good lubricant, the lubricant must be brought out and made available to the metal surface.
- the better lubricants were made as emulsions which were deliberately made unstable so that the lubricant would separate out as a distinct phase.
- unstable emulsions are difficult to handle and frequently are so heterogeneous that they do not give a uniform coating of lubricant at all times.
- This invention overcomes the above difiiculties by providing a homogeneous solution containing a controlled amount of lubricant which lubricant is freed at the point and at the time most needed for lubricity.
- the lubricant Upon cooling, the lubricant re-enters solution and maintains a uniform concentration of the bath.
- some, or nearly all, of the water is evaporated, which further concentrates the lubricant.
- This evaporation of the water leaves behind a uniform film of lubricant on the rolls 4 and 5 which is transferred to the metal.
- the remaining lubricant film is spotty and, therefore, does not yield a smooth and continuous deposit on the roll or on the metal as does the lubricant of this invention.
- the cold-rolling system when it is first started, will not contain heat in the rolls 4 or 5, or in the metal 2. Therefore, the rolls should be heated up by some means, either electrically or by steam, in
- the solutes which may be used in preparing the lubricant solutions may be compounds well known in the literature, or they may be new compounds which have properties desired in the aqueous lubricant. A mixture of compounds having different properties may be employed to give the desired solubility and lubricity at required temperatures.
- amide ethers which may be used in carrying out this invention.
- Table only two examples are shown to illustrate the effect of the ethylene oxide groups on the amide-type of derivative.
- the tallow amide is saturated and is somewhat less soluble than the unsaturated amide and separates at a lower temperature.
- the tests were made on heating a 1% aqueous solution of the amide ether:
- the ingot In rolling a metal such as aluminum, for example, the ingot is usually passed through one set of rolls in one direction and then, after narrowing the bite of the rolls, it is passed between the same rolls in the opposite direction, and this is repeated to gradually reduce the thickness of the sheet-usually without much widening of the sheet. Eventually it is often transferred to other rolls for the final rolling operation or operations. As the thinning process proceeds the temperature of the sheet increases. In operations where an oil lubricant has been employed the speed of the operation has to be reduced to prevent the metal from becoming so hot as to ignite the oil.
- An advantage of the use of an aqueous lubricant is that the danger of ignition is eliminated and the speed of the operation can be increased because the water is a better coolant and the evaporation of water operates to keep the rolls and the treating bath cool. If the speed of the operation is too fast using the conventional non-aqueous lubricants, eventually the bath temperature becomes very high and there is an economic loss of volatile hydrocarbon and ester-type of lubricant medium. The rolls also become too hot, and the rolled sheet is neither as smooth nor bright as desired.
- the advantage of using the aqueous system is that the speed of the rolling operation can be increased four or five fold because the heat is easily carried off or controlled both by the evaporation of the water and by the high heat capacity of water. The amount of water evaporated may be considerable, but this is infinitesimally small in comparison to the losses that would be effective if an equal quantity of non-aqueous lubricant were evaporated.
- the method of rolling or extruding metals which comprises rolling or extruding a metal while its surface is lubricated with mineral-oil-free aqueous solution of 1 to per cent of an ether amide which is soluble in the water at the temperature and concentration at which it is supplied for use in the method and has the formula 3.
- FIG. 2 is a stylized representation of an extruder 20 with a die opening through which metal 21, after reducing its cross section, is extruded at 22.
- the lubricant is supplied in any suitable manner It is indicated as being fed from a source through pipe 23 into a jacket 25 from which it is supplied through small conduits 27 to the metal as it is being compressed.
- the lubricant may be suppli along the metal in the extruder before beingcompressed, to be carried forward on the surface of the metal to the point where it is compressed, instead of applying it to the metal as it is compressed; v
Abstract
Metals, when rolled or otherwise compressed, are lubricated by an aqueous solution of an organic, polar, surface-acting composition having a negative heat of solution which is an ether amide which is soluble in the water at a lower temperature but insoluble in the water at the temperature to which the aqueous solution is heated during compression of the metal. This aqueous lubricant eliminates the fire hazard involved in the use of the present non-aqueous lubricants.
Description
D United States Patent 1 1 3,676,344 Kuceskl 1451 July 11, 1972 54] ETHER AMIDES IN AQUEOUS 3,523,895 8/1970 lshibashi et a]. ..252/49.5 x LUBRICANTS 2,968,999 1/1961 Breton ....2S2/49.5 X 3,341,454 9 1967 Ch t l. ..252 49.3 X [72] Inventor: Vincent P. Kuceskl, Chicago Heights, lll. or e a I73] Asaigncc: The C. P. Hall Company of II- wyman llnols/Chlcago, Illinois As'sismm Examiner-W. Cannon 22] Filed Sept 2 1970 Atmrne vGordon C. Mack I [2|] Appl. No.: 69,071 [57] ABSTRACT Related U.S. Application Dat Metals, when rolled or otherwise compressed, are lubricated by an aqueous solution of an organic, polar, surface-acting [63] fgg g gg g 'gg 7911259 composition having a negative heat of solution which is an ether amide which is soluble in the water at a lower tempera- 52 us. or. ..252/49.3 252/51 5 A 252/49 5 inwluble the temperature which 51 1111.01. .1 ..:....C 10m 1/56 aquem's is heated during the metal- [58] Field of Search ..252/49.3 49.5 51.5 A This News lubricant eliminates the fire hazard involved in the use of the present non-aqueous lubricants. [56] References Cited UNITED STATES PATENTS 2,690,426 9/1954 Jefierson et al ..252/5 1.5 A X Pmmmm 11 m2 4 HQMOGENEOUS SOLUTION FROM F/LTERS l .525 1 j JR w; 7 fi CLEAR LUBRICANT T0 FILTERS j k TPL fi INVENTOR. VINCENT P. KUCESKI A TTORNEY ETHER AMIDES IN AQUEOUS LUBRICANTS eliminates the fire hazard which is present when highly heated metal and an oil are brought into contact with one another. By eliminating the fire hazard, size reduction operations can be carried out at faster speeds at which the metal is heated to a higher temperature at which the danger of fire would be increased if an oil lubricant were used.
The solute of the aqueous lubricant used in carrying out the invention is a material which has a negative heat of solution and is more soluble in water at a lower temperature at which it is supplied to the rolling or extrusion system, and is less soluble at a higher temperature to which it is heated during the rolling or extrusion so that it separates from solution as a solid or liquid and serves as a lubricant.
The lubricant is an organic, polar, surface-acting composiand is soluble in water at a lower temperature and separates at the higher temperature to which it is heated during the operation. It is free from mineral oil.
The ether amides which are useful in carrying out this invention have the following representative formulas:
in which R is an alkyl, cycloalkyl, aryl, aralkyl or alkaryl group of six to 24 carbon atoms; m is 0, l or 2; and n equals the number of recurring alkyl ether groups and may be any number from 2 to 100, inclusive. The amide group contributes water solubility equivalent to about three or four ether groups. In other words, if R+m/n+3 about 0.5 to 2.5, or preferably 0.8 to 2.0, a good lubricant is obtained with a concentration of about to or per cent of the amide in water. Compounds of the first formula are listed in Table l and compounds of the second formula are listed in Table 11. These compounds are listed as representative of those which can be tion-an ether amidewhich has a negative heat ofsolution used satisfactorily. H
TABLE I Formula 3 R Name olAmide RCONH C2+mH4+2mO nH R n m R+m 1 89 Ste lhexethoxy amide- R-C0NH(GH1CH1O) H 17 6 0 17 9 Z-hfioxyathyl benzamide R CONH(CH2CH20)1H 6 1 0 6 g Z-hydroxy propoxy benzamide RCONH(CH2CH2O?H CH2O)H 6 2 l 7 1 0 Oct ltetraethoxy amide RCONH(CH1CH1O)4H 7 4 0 7 7 Hydroxyethylpelargonamlde- R-CONH(CH2CH2O)..H 8 1 0 g 2 222g Hydroxyethyl decanoarnide R-CONH(CH2CH10)H 9 1 0 2O 16 26 Stearyl decaethoxy trlpropoxyl amide... R-CONH(CH2CH2O)1o-(-(fH-CH2O)3H 17 13 3 Octyl hexaethoxy hexapropoiry amide RCONH(CHzCH O) ((fH-CH:0)H 8 12 6 14 16 0. 93 i CH3 Decyltetraethoxy, butoxy amide RCONH(CHzCHzO)u-(C4HaO)t 10 5 2 1 8 6 TABLE II Formula Name of amide RC ON[(Cz+m+H4+zmO) n12 R n m R-l-m n+3 R+m=n+3 Stearyl di(ethoxy hydroxyl ethyl) amide or stearyl RCON[(CHzCHzO) H]g 17 O 17 9 1. 89
di(triethoxy)amide. Oleyl di(diethoxy propoxy)amide RCON[(CHzCHz0)z($H-CH20)1H] 17 6 2 19 0 2. 15
Di(hydroxyethyl)na hthenamide". R-CON (CHzCHaOhHlt 12 2 0 13 5 2. 4 Octyl di(tetraethoxy amide R-CONICH CEOhH], 7 8 0 11 0.635
N-hydroxylpropyl,N'-ethy1hydroxy pelargonamide... )CHzCHzOXH 8 2 1 9 5 1.8
R-TC ON ((?HCH2O)H Di(hydroxyethyl) lam-amide ROONKCH CH O); 1 11 2 0 11 5 Z. 2 Di(hydroxyethyl) myristamide. RGONKCHaCHzO): 2 13 2 0 13 5 2. 6 Di(hydroxydiethoxy) palmitamide.. RCON (CHzCH20)zH 2 15 4 0 15 7 2. 14 Tallow di(hydroxytriethoxy) amide RC N (CHzCHzOhH 2 15-17 6 0 15-17 9 1. 66-1. 89 Oleyl di(hyd.roxydiethoxy propoxy) amid RCON[(CH CHO);(C CH-O)1H] 17 6 1 18 9 2.0
)CHQCHQHQOMH 17 6 3 20 9 2. 20 Linoleyl hydroxytripropoxy, hydroxytriethoxy amide. RCON ((JH ClEhOhiH H (CHzCHzOh 15-17 7 3 18-21 10 1. 8-2. 1 Talloyg hydroxytetraethoxy, hydroxy dipropoxy R-C 0N am on-omonn Tallow di-(hydroxytetraethoxy) amide R-CONKCHzCHzOflH]: 15-17 8 0 15-17 11 1. 36-1.
The concentrations of the chemical compounds having negative solubility, as they are used in aqueous solutions may vary from a few tenths of one per cent up to 25 or 50 per cent or more, and is usually 1 to 20 per cent, depending upon the nature of the compound and the temperatures to which the aqueous solution is subjected in the treatment of different metals. In most instances, the amount dissolved in the aqueous phase will depend on the viscosity and lubricity obtained. Generally, a clear solution which is easily pumped is required so that the solution may be filtered to remove suspended particles. Such filtration is generally essential for the production of a metal product with a bright unmarred finish.
The temperatures of solution and separation of the lubricant will vary, depending upon the metal being treated and the method of treatment. Usually the lubricant should be soluble at about room temperature. The temperature of rolling will depend upon the metal, etc. In rolling, the aqueous lubricant may be sprayed on upper and lower rolls, or the lower roll may be immersed in a bath of the lubricant. In extrusion the lubricant is added in any desired manner.
The invention is further described in connection with the accompanying drawings which are largely schematic.
FIG. 1 is a vertical section through equipment for a rolling operation; and
FIG. 2 is a vertical section through equipment used in extru- SlOIl.
FIG. 1 is illustrative of the application of the invention to one method of rolling a metal; namely, the cold-rolling of aluminum. It will be noted that the thickness of the metal 1 is reduced to that shown at 2 as the metal is passed between the rolls 4 and 5.
The tank 7 contains a clear, aqueous solution of lubricant which is continuously or periodically drawn off through the pipe 10 and filtered and returned through the pipe 11, usually some going to the spray head 13 and the balance being returned through the pipe 14 to the tank. If the filtering operation is carried out only periodically at long intervals, some of the clear lubricant from the tank 7 can be pumped directly to the spray 13 through pipe 14 for spraying the upper roll 4 while the lower roll is rotated while partiallysubmerged in the lubricant contained in the tank. As the aluminum or other metal is reduced from the thickness 1 to the thickness 2, a great deal of heat is given off and the rolls 4 and 5 become heated. The temperature of the bath may be controlled manually or automatically within a few degrees below the precipitation temperature to prevent overheating which would precipitate the lubricant. Water or lubricant may be added as required to maintain the desired concentration.
In starting up the operation the liquid sprayed on to the roller 4 and the entire liquid within the tank is clear. As the rolls 4 and 5 heat up, these rolls become hot enough to cause separation of the lubricant from the water solution either as a separate liquid phase or in particular form. The drawing illustrates how, after the rolls 4 and 5 have been heated .up, the liquid is converted to particulate form on the roll 4 due to its heat, and the heat of the roll 5 tends to cause separation of the solute adjacent the roll 5 as it is rotated in it. Thus the lubricant is supplied as a clear aqueous solution at a lower temperature and as heat is generated by the rolling operation and the rolls 4 and 5 become more and more heated the lubricant separates more rapidly after contact with the heated roll 4, and the lubricant surrounding the roll 5 separates and the separated phase adheres to the roll as it continues to rotate and carry the separated lubricant to the interface between the roll and the metal being treated. It is here that the lubricant which separates at a higher temperature performs its useful function. For example, in rolling aluminum, the separation may start at any temperature between 30 and 95 C.
The solute which separates on the roll 4 as the spray becomes heated and the solute which separates on the roll 5 as it becomes heated adhere to the rolls and are carried to the interface where they serve to lubricate the surface between the roll and the metal, thereby forming a smooth surface on the metal as well as cooling it while it is being compressed. The
advantages of this method of producing a lubricant are not immediately apparent.
Heretofore, lubricants used in extruding or rolling metals when used with water, have been in a necessarily very stable finely divided or nearly colloidal emulsion form. The manufacture of a finely divided emulsion has been difficult and it has also been difficult to maintain the emulsion over different conditions of operating temperatures and speeds. In order to be a good lubricant, the lubricant must be brought out and made available to the metal surface. The better lubricants were made as emulsions which were deliberately made unstable so that the lubricant would separate out as a distinct phase. However, such unstable emulsions are difficult to handle and frequently are so heterogeneous that they do not give a uniform coating of lubricant at all times.
This invention overcomes the above difiiculties by providing a homogeneous solution containing a controlled amount of lubricant which lubricant is freed at the point and at the time most needed for lubricity. Upon cooling, the lubricant re-enters solution and maintains a uniform concentration of the bath. As the lubricant is separated from the aqueous phase by the increase in temperature, some, or nearly all, of the water is evaporated, which further concentrates the lubricant. This evaporation of the water leaves behind a uniform film of lubricant on the rolls 4 and 5 which is transferred to the metal. Although evaporation also occurs in the usual emulsion system, the remaining lubricant film is spotty and, therefore, does not yield a smooth and continuous deposit on the roll or on the metal as does the lubricant of this invention.
In the practice of this invention the cold-rolling system, when it is first started, will not contain heat in the rolls 4 or 5, or in the metal 2. Therefore, the rolls should be heated up by some means, either electrically or by steam, in
The solutes which may be used in preparing the lubricant solutions may be compounds well known in the literature, or they may be new compounds which have properties desired in the aqueous lubricant. A mixture of compounds having different properties may be employed to give the desired solubility and lubricity at required temperatures.
The following are examples of the amide ethers which may be used in carrying out this invention. In the table, only two examples are shown to illustrate the effect of the ethylene oxide groups on the amide-type of derivative. The tallow amide is saturated and is somewhat less soluble than the unsaturated amide and separates at a lower temperature. The tests were made on heating a 1% aqueous solution of the amide ether:
In rolling a metal such as aluminum, for example, the ingot is usually passed through one set of rolls in one direction and then, after narrowing the bite of the rolls, it is passed between the same rolls in the opposite direction, and this is repeated to gradually reduce the thickness of the sheet-usually without much widening of the sheet. Eventually it is often transferred to other rolls for the final rolling operation or operations. As the thinning process proceeds the temperature of the sheet increases. In operations where an oil lubricant has been employed the speed of the operation has to be reduced to prevent the metal from becoming so hot as to ignite the oil. An advantage of the use of an aqueous lubricant is that the danger of ignition is eliminated and the speed of the operation can be increased because the water is a better coolant and the evaporation of water operates to keep the rolls and the treating bath cool. If the speed of the operation is too fast using the conventional non-aqueous lubricants, eventually the bath temperature becomes very high and there is an economic loss of volatile hydrocarbon and ester-type of lubricant medium. The rolls also become too hot, and the rolled sheet is neither as smooth nor bright as desired. The advantage of using the aqueous system is that the speed of the rolling operation can be increased four or five fold because the heat is easily carried off or controlled both by the evaporation of the water and by the high heat capacity of water. The amount of water evaporated may be considerable, but this is infinitesimally small in comparison to the losses that would be effective if an equal quantity of non-aqueous lubricant were evaporated.
In the practice of this invention, from 1 to 20 per cent or more of the compound, and preferably 5 to per cent, having a negative heat of solution is dissolved in water to form a clear, homogeneous solution.
I claim:
1. The method of rolling or extruding metals which comprises rolling or extruding a metal while its surface is lubricated with mineral-oil-free aqueous solution of 1 to per cent of an ether amide which is soluble in the water at the temperature and concentration at which it is supplied for use in the method and has the formula 3. The method of claim 1 in which the ether amide has the formula 4. The method of claim 1 in which the metal article is a metal sheet.
5. The method of claim 1 in which metal is lubricated as it is rolled, and the separation temperature of the aqueous lubricant is between substantially 30 and C.
UNITE STATES PATENT oTTTta CETlFlCA'lE @l ETWN Patent No. 3, 76, 3);); Dated July 11, 1973 Vincent P. Kuceski It is certified that error appears in the above-identified patent and that said Letters Patent are hereby corrected as shown below:
Column 4, line 34, after "in" at the end of the short line,
insert:
order to bring the rolls to a temperature high enough to separate the lubricant from the aqueous phase. However, it may -not be necessary to pre heat the roll if enough lubricant solutio is sprayed on the rolls while they are operating. After a number of operations are performed in the rolling of the metal, the heat generated by the compression of the metal will maintain sufficien heat in the rolls to separate the lubricant satisfactorily.
Instead of rolling the metal, it may be extruded. Fig. 2 is a stylized representation of an extruder 20 with a die opening through which metal 21, after reducing its cross section, is extruded at 22., The lubricant is supplied in any suitable manner It is indicated as being fed from a source through pipe 23 into a jacket 25 from which it is supplied through small conduits 27 to the metal as it is being compressed. The lubricant may be suppli along the metal in the extruder before beingcompressed, to be carried forward on the surface of the metal to the point where it is compressed, instead of applying it to the metal as it is compressed; v
FORM PO-1050 (10-69) USCOMM-DC 60376-P69 i ILS. GOVERNMENT PRINTING OFFICE I989 O366-334I CERTIFICATE OF CORRECTION Patent No, 3,6763% Dated July 11, 197
Inventor-(S) Vi'ncent P. Kuceski It .is eertified that error appears in the above-identified patent andrhar said Letters Paten t are hereby corrected as shown below:
In line of column 2, the formu la should be In Table I, the-headingofthe lasr column shoul d be ln'colomo 4, line 63 change the h hen to two h to indicate a dash line.- whens,
Signed and sealed this 19th day of March 1971 I EDWARD MQFLETGI-IERJR. c. MARSHALL DANN Attsting-Officer Commissioner of Patents Q M PO-w o (19-59) Y COMM-Dc scan-Pen U.5. GOVERNMENT PRINTING OFFICE: I! o-au-uq.
Claims (4)
- 2. The method of claim 1 in which the ether amide has the formula
- 3. The method of claim 1 in which the ether amide has the formula
- 4. The method of claim 1 in which the metal article is a metal sheet.
- 5. The method of claim 1 in which metal is lubricated as it is rolled, and the separation temperature of the aqueous lubricant is between substantially 30* and 95* C.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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US6907170A | 1970-09-02 | 1970-09-02 |
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US3676344A true US3676344A (en) | 1972-07-11 |
Family
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Application Number | Title | Priority Date | Filing Date |
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US69071A Expired - Lifetime US3676344A (en) | 1970-09-02 | 1970-09-02 | Ether amides in aqueous lubricants |
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Cited By (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3933661A (en) * | 1975-04-21 | 1976-01-20 | E. F. Houghton And Company | Aqueous base post pickling and cold rolling fluid |
US3965712A (en) * | 1975-04-21 | 1976-06-29 | E. F. Houghton And Company | Aqueous base post pickling and cold rolling fluid |
US4239635A (en) * | 1979-06-11 | 1980-12-16 | Cincinnati Milacron Inc. | Novel diamide and lubricants containing same |
USRE30885E (en) * | 1981-03-13 | 1982-03-23 | Cincinnati Milacron Inc. | Novel diamide and lubricants containing same |
US4557846A (en) * | 1983-12-30 | 1985-12-10 | Exxon Research And Engineering Co. | Lubricating oil compositions containing hydroxamide compounds as friction reducers |
US4828735A (en) * | 1982-01-19 | 1989-05-09 | Nippon Oil And Fats Co., Ltd. | Aqueous lubricant composition |
US5339855A (en) * | 1991-01-31 | 1994-08-23 | Berol Nobel Ab | Use of alkoxylated alkanolamide as friction-reducing agent |
US5773393A (en) * | 1991-09-16 | 1998-06-30 | The Lubrizol Corporation | Oil compositions useful in hydraulic fluids |
US5911236A (en) * | 1994-10-03 | 1999-06-15 | Akzo Nobel Nv | Alkoxylated alkanolamide together with an ionic surfactant as friction-reducing agent |
US6001784A (en) * | 1993-10-05 | 1999-12-14 | Nalco Chemical Company | High melt point solid film prelube emulsion for use on aluminum and other metals |
US10640696B2 (en) | 2017-08-15 | 2020-05-05 | Saudi Arabian Oil Company | Oil-based drilling fluids for high pressure and high temperature drilling operations |
US10647903B2 (en) | 2017-08-15 | 2020-05-12 | Saudi Arabian Oil Company | Oil-based drilling fluid compositions which include layered double hydroxides as rheology modifiers and amino amides as emulsifiers |
US10676658B2 (en) | 2017-08-15 | 2020-06-09 | Saudi Arabian Oil Company | Oil-based drilling fluids for high pressure and high temperature drilling operations |
US10745606B2 (en) | 2017-08-15 | 2020-08-18 | Saudi Arabian Oil Company | Oil-based drilling fluid compositions which include layered double hydroxides as rheology modifiers |
US10793762B2 (en) | 2017-08-15 | 2020-10-06 | Saudi Arabian Oil Company | Layered double hydroxides for oil-based drilling fluids |
US10870788B2 (en) | 2017-08-15 | 2020-12-22 | Saudi Arabian Oil Company | Thermally stable surfactants for oil based drilling fluids |
US10876039B2 (en) | 2017-08-15 | 2020-12-29 | Saudi Arabian Oil Company | Thermally stable surfactants for oil based drilling fluids |
US10988659B2 (en) | 2017-08-15 | 2021-04-27 | Saudi Arabian Oil Company | Layered double hydroxides for oil-based drilling fluids |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2690426A (en) * | 1950-03-07 | 1954-09-28 | Atlas Powder Co | Lubricating compositions |
US2968999A (en) * | 1957-12-31 | 1961-01-24 | Ernest J Breton | Process for cutting metal employing amorphous silica |
US3341454A (en) * | 1963-02-25 | 1967-09-12 | Hodson Corp | Lubricant composition |
US3523895A (en) * | 1969-04-21 | 1970-08-11 | Mobil Oil Corp | Metal working lubricant |
-
1970
- 1970-09-02 US US69071A patent/US3676344A/en not_active Expired - Lifetime
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2690426A (en) * | 1950-03-07 | 1954-09-28 | Atlas Powder Co | Lubricating compositions |
US2968999A (en) * | 1957-12-31 | 1961-01-24 | Ernest J Breton | Process for cutting metal employing amorphous silica |
US3341454A (en) * | 1963-02-25 | 1967-09-12 | Hodson Corp | Lubricant composition |
US3523895A (en) * | 1969-04-21 | 1970-08-11 | Mobil Oil Corp | Metal working lubricant |
Cited By (21)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3933661A (en) * | 1975-04-21 | 1976-01-20 | E. F. Houghton And Company | Aqueous base post pickling and cold rolling fluid |
US3965712A (en) * | 1975-04-21 | 1976-06-29 | E. F. Houghton And Company | Aqueous base post pickling and cold rolling fluid |
US4239635A (en) * | 1979-06-11 | 1980-12-16 | Cincinnati Milacron Inc. | Novel diamide and lubricants containing same |
USRE30885E (en) * | 1981-03-13 | 1982-03-23 | Cincinnati Milacron Inc. | Novel diamide and lubricants containing same |
US4828735A (en) * | 1982-01-19 | 1989-05-09 | Nippon Oil And Fats Co., Ltd. | Aqueous lubricant composition |
US4557846A (en) * | 1983-12-30 | 1985-12-10 | Exxon Research And Engineering Co. | Lubricating oil compositions containing hydroxamide compounds as friction reducers |
US5339855A (en) * | 1991-01-31 | 1994-08-23 | Berol Nobel Ab | Use of alkoxylated alkanolamide as friction-reducing agent |
EP0646157B1 (en) * | 1991-01-31 | 1997-10-29 | Berol Nobel AB | Use of alkoxylated alkanolamide as friction-reducing agent |
US5773393A (en) * | 1991-09-16 | 1998-06-30 | The Lubrizol Corporation | Oil compositions useful in hydraulic fluids |
US6001784A (en) * | 1993-10-05 | 1999-12-14 | Nalco Chemical Company | High melt point solid film prelube emulsion for use on aluminum and other metals |
US5911236A (en) * | 1994-10-03 | 1999-06-15 | Akzo Nobel Nv | Alkoxylated alkanolamide together with an ionic surfactant as friction-reducing agent |
US10640696B2 (en) | 2017-08-15 | 2020-05-05 | Saudi Arabian Oil Company | Oil-based drilling fluids for high pressure and high temperature drilling operations |
US10647903B2 (en) | 2017-08-15 | 2020-05-12 | Saudi Arabian Oil Company | Oil-based drilling fluid compositions which include layered double hydroxides as rheology modifiers and amino amides as emulsifiers |
US10676658B2 (en) | 2017-08-15 | 2020-06-09 | Saudi Arabian Oil Company | Oil-based drilling fluids for high pressure and high temperature drilling operations |
US10745606B2 (en) | 2017-08-15 | 2020-08-18 | Saudi Arabian Oil Company | Oil-based drilling fluid compositions which include layered double hydroxides as rheology modifiers |
US10793762B2 (en) | 2017-08-15 | 2020-10-06 | Saudi Arabian Oil Company | Layered double hydroxides for oil-based drilling fluids |
US10870788B2 (en) | 2017-08-15 | 2020-12-22 | Saudi Arabian Oil Company | Thermally stable surfactants for oil based drilling fluids |
US10876039B2 (en) | 2017-08-15 | 2020-12-29 | Saudi Arabian Oil Company | Thermally stable surfactants for oil based drilling fluids |
US10954425B2 (en) | 2017-08-15 | 2021-03-23 | Saudi Arabian Oil Company | Oil-based drilling fluids for high pressure and high temperature drilling operations |
US10988659B2 (en) | 2017-08-15 | 2021-04-27 | Saudi Arabian Oil Company | Layered double hydroxides for oil-based drilling fluids |
US11034880B2 (en) | 2017-08-15 | 2021-06-15 | Saudi Arabian Oil Company | Oil-based drilling fluids for high pressure and high temperature drilling operations |
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