US3649258A - Nickel alloy - Google Patents
Nickel alloy Download PDFInfo
- Publication number
- US3649258A US3649258A US15703A US3649258DA US3649258A US 3649258 A US3649258 A US 3649258A US 15703 A US15703 A US 15703A US 3649258D A US3649258D A US 3649258DA US 3649258 A US3649258 A US 3649258A
- Authority
- US
- United States
- Prior art keywords
- percent
- nickel
- chromium
- alloy
- copper
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910000990 Ni alloy Inorganic materials 0.000 title abstract description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 61
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 30
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 27
- 239000011651 chromium Substances 0.000 claims abstract description 27
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 27
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 20
- 239000000956 alloy Substances 0.000 claims abstract description 20
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000011593 sulfur Substances 0.000 claims abstract description 15
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 15
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000010949 copper Substances 0.000 claims abstract description 13
- 229910052802 copper Inorganic materials 0.000 claims abstract description 13
- 230000035699 permeability Effects 0.000 claims description 8
- 238000001816 cooling Methods 0.000 claims description 4
- 238000000137 annealing Methods 0.000 claims description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 10
- 229910052742 iron Inorganic materials 0.000 abstract description 5
- 239000000203 mixture Substances 0.000 description 5
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 229910052710 silicon Inorganic materials 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- -1 0.002 percent Chemical compound 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- XIKYYQJBTPYKSG-UHFFFAOYSA-N nickel Chemical compound [Ni].[Ni] XIKYYQJBTPYKSG-UHFFFAOYSA-N 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C19/00—Alloys based on nickel or cobalt
Definitions
- alloys that contain nickel, chromium, copper, and iron can be formulated with substantially improved electrical properties by carefully balancing the nickel and chromium contents with respect to each other and by maintaining sulfur below a critical limit of 0.003 percent. More specifically, alloys in accordance with the invention contain about 75 to 80 percent nickel, about 1.75 to 3.5 percent chromium, about 3 to 7 percent copper, less than 0.003 percent sulfur, preferably not greater than 0.002 percent sulfur, and the balance iron. In addition, however, the nickel and chromium contents are carefully restricted with respect to each other.
- the first three heats in Table I have balanced nickel and chromium contents but the sulfur is 0.003 percent or greater.
- 0.003 percent sulfur in heat 8824 is too high and the permeability is substantially less then alloys with less than 0.003 percent sulfur, as shown in Table 11.
- Heat 81990 in Table 1 has desirably low sulfur, i.e., 0.002 percent, but the nickel and chromium contents are not properly balanced and, accordingly, the permeability is low.
- each nickel level between about 75 and percent, there exists a chromium level which is capable of developing unusually high magnetic properties.
- the nickel level is outside the specified range, the magnetic properties cannot be developed within the desired cooling rates of per hour to 1,000 F. per hour. 1n the curve of the accompanying drawing, the nickel and chromium contents are plotted against each other so that combinations of nickel and chromium can be selected which will result in alloys having superior magnetic properties.
- a number of alloys having desirable properties are listed in Table 111. The nickel and chromium contents are related to each other in the manner illustrated in the curve.
- lines A and B define the zone within which the properly balanced nickel and chromium compositions appear.
- Line C represents the optimum balancing of these elements, however the area between lines A" and B will provide related nickel and chromium content with superior properties.
- the copper content within the range of 3 to 7 percent does not affect the properties as much as nickel and chromium.
- the nickel content can extend from about 76.2 (line d f to about 77.6 percent (point e).
- the copper content should be between about 4.8 percent (line d e) to 6.2 percent (point f).
- the copper content should be between 4.8 percent (line d e) and 3.3 percent (point 3).
- Preferred nickel and copper contents for 2.8 percent chromium (point h) would be about 76.9 percent nickel (line m n) and about 4.0 percent copper (point m) to about 5.5 percent copper (point n).
- Alloys of the invention may additionally contain certain other elements which do not unduly interfere with the desirably high magnetic properties.
- these elements are manganese, silicon and carbon. As much as 1.5 percent manganese has been found to be includable without detrimentally affecting the magnetic properties.
- silicon may be included up to 1.0 percent and carbon up to 0.05 percent.
- impurities should be maintained as low as possible. This may be advantageously done by vacuum melting the alloy which greatly minimizes the risk of contamination. Other melting techniques such as consumable electrode remelting or electroslag remelting may also be employed with advantage due to the ability to control impurity levels by these melting practices.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Soft Magnetic Materials (AREA)
- Manufacture And Refinement Of Metals (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US1570370A | 1970-03-02 | 1970-03-02 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3649258A true US3649258A (en) | 1972-03-14 |
Family
ID=21773038
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US15703A Expired - Lifetime US3649258A (en) | 1970-03-02 | 1970-03-02 | Nickel alloy |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US3649258A (cg-RX-API-DMAC10.html) |
| CA (1) | CA945786A (cg-RX-API-DMAC10.html) |
| DE (1) | DE2109851A1 (cg-RX-API-DMAC10.html) |
| FR (1) | FR2081632B1 (cg-RX-API-DMAC10.html) |
| GB (1) | GB1322629A (cg-RX-API-DMAC10.html) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4004080A (en) * | 1975-07-25 | 1977-01-18 | Rca Corporation | Metal coating for video discs |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2737043B1 (fr) * | 1995-07-18 | 1997-08-14 | Imphy Sa | Alliage fer-nickel pour masque d'ombre tendu |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3553035A (en) * | 1968-08-05 | 1971-01-05 | Westinghouse Electric Corp | Process for making high initial permeability iron-nickel alloys |
Family Cites Families (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB266066A (en) * | 1925-11-20 | 1927-02-21 | Willoughby Statham Smith | New and improved magnetic alloys and their application in the manufacture of telegraphic and telephonic cables |
| DE1222271B (de) * | 1960-05-27 | 1966-08-04 | Vacuumschmelze Ag | Verfahren zur Erzeugung hochpermeabler Nickel-Eisen-Legierungen mit einer rechteckfoermigen Hysteresisschleife |
-
1970
- 1970-03-02 US US15703A patent/US3649258A/en not_active Expired - Lifetime
-
1971
- 1971-02-26 CA CA106,349A patent/CA945786A/en not_active Expired
- 1971-03-02 DE DE19712109851 patent/DE2109851A1/de active Pending
- 1971-03-02 FR FR7107151A patent/FR2081632B1/fr not_active Expired
- 1971-04-19 GB GB2362871*A patent/GB1322629A/en not_active Expired
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3553035A (en) * | 1968-08-05 | 1971-01-05 | Westinghouse Electric Corp | Process for making high initial permeability iron-nickel alloys |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4004080A (en) * | 1975-07-25 | 1977-01-18 | Rca Corporation | Metal coating for video discs |
Also Published As
| Publication number | Publication date |
|---|---|
| GB1322629A (en) | 1973-07-11 |
| FR2081632A1 (cg-RX-API-DMAC10.html) | 1971-12-10 |
| CA945786A (en) | 1974-04-23 |
| DE2109851A1 (de) | 1971-09-16 |
| FR2081632B1 (cg-RX-API-DMAC10.html) | 1975-06-06 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| AS | Assignment |
Owner name: ALLEGHENY LUDLUM CORPORATION Free format text: CHANGE OF NAME;ASSIGNOR:ALLEGHENY LUDLUM STEEL CORPORATION;REEL/FRAME:004779/0642 Effective date: 19860805 |
|
| AS | Assignment |
Owner name: PITTSBURGH NATIONAL BANK Free format text: SECURITY INTEREST;ASSIGNOR:ALLEGHENY LUDLUM CORPORATION;REEL/FRAME:004855/0400 Effective date: 19861226 |
|
| AS | Assignment |
Owner name: PITTSBURGH NATIONAL BANK Free format text: ASSIGNMENT OF ASSIGNORS INTEREST. RECORDED ON REEL 4855 FRAME 0400;ASSIGNOR:PITTSBURGH NATIONAL BANK;REEL/FRAME:005018/0050 Effective date: 19881129 |