Classifications

• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
  • D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
  • D06L1/02—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using organic solvents
  • D06L1/04—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using organic solvents combined with specific additives
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
  • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
  • D06M13/02—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with hydrocarbons
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
  • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
  • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
  • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
  • D06M15/53—Polyethers

Definitions

• the cleaned textiles are frequently subjected to a so-called dry hydrophobic treatment.
• the agent for the hydrophobic treatment is applied in the same solvents used for the chemical cleaning.
• This measure is for the purpose of making the textiles, for example poplin clothing, such as raincoats, parkas and the like, as water-repellent as possible.
• the result of the impregnation is often very detrimental, however, because the surface-active cleaning intensifiers adhering to the fiber have a more or less strongly hydrophilic action.
• cleaning intensifiers which do not or reduce only to an insignificant extent, the surface tension of the water, as for example, wool fat, cholesterol, fatty acid esters, metal soaps, and the like.
• These cleaning intensifiers are added to the organic solvent together with the necessary amount of water in the form of a water-in-oil emulsion.
• the emulsions obtained are relatively coarsely dispersed owing to the relatively small emulsifying action of such substances. This may lead to turbidity and separation of water in the cleaning bath as well as to damage of the goods to be cleaned on account of uneven wetting. The process can therefore only be used to a limited extent.
• An object of the present invention is to develop cleaning intensifiers which make possible a good dispersion of the water in the cleaning bath and which are not detrimental to a subsequent dry hydrophobic treatment.
• Another object of the present invention is in the chemical cleaning of textiles by subjecting the textiles to a chemical cleaning bath consisting of a major amount of an organic solvent, a minor amount of water and a surface-active cleaning intensifier, the improvement which comprises utilizing, as said cleaning intensifier, an addition product of 2 to 14 mols of propylene oxide to an alcohol selected from the group consisting of primary alkanols having from to carbon atoms, primary alkenols having from 10 to 20 carbon atoms and alkylphenols having from six to 12 carbon atoms in the alkyl.
• a further object of the present invention is the development of a preliminary emulsion for dilution with a chemical textile cleaning organic solvent consisting essentially of from about 20 to 50 parts by weight of an addition product of 2 to 14 mols of propylene oxide to an alcohol selected from the group consisting of primary alkanols having from 10 to 20 carbons atoms, primary alkenols having from 10 to 20 carbon atoms and alkylphenols having from six to 12 carbon atoms in the alkyl, and from about 80 to 50 parts by weight of water.
• a chemical textile cleaning organic solvent consisting essentially of from about 20 to 50 parts by weight of an addition product of 2 to 14 mols of propylene oxide to an alcohol selected from the group consisting of primary alkanols having from 10 to 20 carbons atoms, primary alkenols having from 10 to 20 carbon atoms and alkylphenols having from six to 12 carbon atoms in the alkyl, and from about 80 to 50 parts by weight of water.
• a yet further object of the present invention is the development of a preliminary emulsion for dilution with a chemical textile cleaning organic solvent consisting essentially of from 0.5 to 2 parts by weight of a chemical textile cleaning organic solvent and l part by weight of the above preliminary emul- SlOll.
• a still further object of the present invention is the development of a cleaning bath for the chemical cleaning of textiles consisting essentially of a major amount of a chemical textile cleaning organic solvent, a minor amount of water and a minor amount of an addition product of 2 to 14 mols of propylene oxide to an alcohol selected from the group consisting of primary alkanols having from 10 to 20 carbon atoms, primary alkenols having from 10 to 20 carbon atoms and alkylphenols having from six to l2 carbon atoms in the alkyl.
• the present invention therefore provides a cleaning liquor for use in a chemical cleaning process for the cleaning of textiles comprising a major amount of a chemical textile cleaning organic solvent usually utilized, a minor amount of water and a minor amount of a product of addition of 2 to 14 mols of propylene oxide to a primary alcohol with 10 to 20 carbon atoms and/or to an alkylphenol with six to 12 carbon atoms in the alkyl as a cleaning intensifier.
• the invention provides a chemical cleaning process utilizing the liquor described above.
• the cleaning intensifier products of the invention are prepared in known way by adding propylene oxide to suitable saturated or unsaturated primary alcohols or to alkylphenol.
• the alkyl chains of the alcohols or alkylphenols may be straight or branched.
• the addition of the propylene oxide is effected in known way, preferably under pressure and in the presence of alkaline catalysts.
• Suitable adducts are obtained, for example, by addition of 6 mols of propylene oxide to lauryl alcohol, 8 mols of propylene oxide to myristyl alcohol, 3 mols of propylene oxide to decyl alcohol, 14 mols of propylene oxide to a tallow alcohol mixture of chain lengths C to C 8 to 12 mols of propylene oxide to an alcohol mixture of chain lengths (I to C, obtained from coconut fats, 2 mols of propylene oxide to an alcohol mixture of chain lengths C to C obtained from coconut fats, 5 mols of propylene oxide to isotridecyl alcohol, 4 to 8 mols of propylene oxide to oleyl alcohol, 4 to 6 mols of propylene oxide to undecylenyl alcohol, and 6 or 12 mols of propylene oxide to technical nonylphenyl.
• the cleaning intensifier compounds of the invention have surface-active properties that make possible a very finely divided and stable dispersion or solubilization of the water in the cleaning bath. On account of their great affinity with the organic solvent however, the propylene oxide adducts are not adsorbed by the textiles to an appreciable extent, but remain in the cleaning liquor. Any possibly adhering amounts of the cleaning intensifier of the invention may be easily and completely removed by a subsequent rinsing with pure solvent.
• the application of the cleaning intensifier of the invention is effected suitably in the usual way by first preparing an emulsion of the cleaning intensifier and the necessary amount of water.
• This preliminary emulsion may also already contain more or less large amounts of the solvent to be used for the cleaning.
• Such preliminary emulsions have good stability and are able to be stored until they are finally used.
• Suitable preliminary emulsions comprise about 20 to 50 parts by weight of the cleaning intensifier of the invention and to 50 parts by weight of water. To this may also be added half to twice the amount of an organic solvent such as is usually used in chemical cleaning, based on the quantity of cleaning intensifier.
• organic solvents are, for example, carbon tetrachloride, perchloroethylene, trifluorotrichloroethane and other liquid halogenated hydrocarbons, as well as low boiling or higher boiling hydrocarbons, as for example, petroleum fractions of boiling range to 200, benzene or the like.
• small amounts of low molecular weight alcohols for example ethanol, propanol or isopropanol, can also be coemployed in the preparation of the preliminary emulsions.
• the preparation of the emulsion is generally effected by stirring by hand though a mechanical homogenization may possibly be used.
• the preliminary emulsion is added into the cleaning liquor in such amounts that the latter contains from 1 to 20 g. per liter, preferably from lg. per liter, of the cleaning intensifier of the invention and from 2-6 g. per liter, preferably about 4 g. per liter of water. in the undiluted state the preliminary emulsion can also be used as the preliminary spot cleaner, par ticularly if small amounts of solvent are present therein.
• the preliminary emulsion is generally added to the cleaning liquor by hand or by means of an automatic dosing device. When the liquor is circulated an extremely fine division and dispersion of the water in the cleaning liquor occurs. The cleaning liquor obtained is stable and possesses an excellent filterability.
• the dry hydrophobic treatment of the cleaned textiles is carried out by using hydrophobic agents such as paraffins, waxes, fatty acid salts of polyvalent metals, aluminum alcoholates or alcoholates of other polyvalent metals, dissolved in organic solvents, possibly in conjunction with stabilizers such as acetoacetic ester, and the like.
• hydrophobic agents such as paraffins, waxes, fatty acid salts of polyvalent metals, aluminum alcoholates or alcoholates of other polyvalent metals, dissolved in organic solvents, possibly in conjunction with stabilizers such as acetoacetic ester, and the like.
• the quantities used are in general about 40 to 80 per liter of cleaning liquor. Excellent water-repellent effects can be obtained which are not adversely affected by the cleaning intensifiers according to the invention.
• EXAMPLE I Three pieces of a cotton poplin fabric with a weight of 300 g. per square meter were impregnated for 50 minutes in a perchloroethylene solution which contained 40 g. of paraffin (solidifying point 5052) and a reaction product of 8 g. of aluminum isobutylate with 10 g. of acetoacetic ester per liter of solution.
• the first piece of fabric was cleaned for minutes simply with pure solvent without addition of a cleaning intensifier.
• the second piece of fabric was cleaned according to the process of the invention with a cleaning liquor which contained 2 g. of the adduct of 2 mols of propylene oxide to a coconut fatty alcohol mixture of chain lengths C to C and 4 cc. of water per liter of perchloroethylene, for 15 minutes at a bath ratio of M0.
• EXAMPLE H In a cleaning plant of the Bowe R 9 maxima type, 6 kg. of cotton poplin coats were cleaned in liters of perchloroethylene for 5 minutes with simultaneous filtration of the bath. The filter pump was then disconnected and a preliminary emulsion was added to the liquor which consisted of 200 g. of the adduct of 8 mols of propylene oxide to nonylphenyl and 240 cc. of water and the cleaning was continued. After 8 minutes the filter pump was switched on again and the dissolved dirt was filtered off for 3 minutes. Then the liquor was pumped into the tank and the textiles were centrifuged. After centrifuging the coats were rinsed for 3 minutes with clean solvent, centrifuged again and impregnated.
• the impregnation was effected with perchloroethylene, which contained 50 g. of paraffin (solidification point 50-52 and a reaction product from 10 g. of aluminum isopropylate and 12 g. of acetoacetic ester. After spin-drying off about 60 percent of the remaining impregnating liquor the coats were dried and finished. Both the cleaning and the waterproofing effects were very good.
• EXAMPLE III In the plant described in example 2, 6 kg. of waterproof clothing consisting of cotton/polyester mixed textile, were cleaned in 100 liters of perchloroethylene in the single baththree-stage process. In the second stage, cleaning without filtration, an addition of 200 g. of the adduct from l4 mols of propylene oxide to dodecylalcohol and 200 g. of water in the form of a preliminary emulsion was made. After the subsequent filtration until clear, the liquor was pumped off, and the clothing spin-dried and further dried as usual.
• Preliminary Reflectometer measurement cleaning I brightening k greying Adduct of l4 mols of propylene oxide to dodecyl alcohol 49.8 0.5 Commercial cleaning intensifier 50.3 0.4
• the comparative example shows that the propylene oxide adduct according to the invention has practically the same good cleaning action as the commercial cleaning intensifier.
• EXAMPLE IV In the cleaning plant described in example 2, 6 kg. of parkas and Windbreakers were cleaned in the single bath-three-stage process. After switching off the filter, a water-containing preliminary emulsion was added during the second stage with a fully automatic dosing device until the adjusted relative moisture of 88 percent was reached.
• the preliminary emulsion consisted of:
• the preliminary emulsion had a good stability and showed no troublesome separations during this stage of operation.
• the cleaning effect was good and the subsequent water-repellent application was excellent.

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• Engineering & Computer Science (AREA)
• Textile Engineering (AREA)
• Chemical & Material Sciences (AREA)
• Chemical Kinetics & Catalysis (AREA)
• Detergent Compositions (AREA)

Applications Claiming Priority (1)

Publications (1)

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Family Applications (1)

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Cited By (6)

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Citations (6)

• 0
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• 1967
  • 1967-12-08 DE DE1967H0064712 patent/DE1617136B1/de active Pending
• 1968
  • 1968-09-06 SE SE12058/68A patent/SE351244B/xx unknown
  • 1968-10-29 FR FR1590310D patent/FR1590310A/fr not_active Expired
  • 1968-11-08 NL NL6815957A patent/NL6815957A/xx unknown
  • 1968-11-18 US US776753A patent/US3628911A/en not_active Expired - Lifetime
  • 1968-12-05 BE BE724984D patent/BE724984A/xx unknown
  • 1968-12-05 TR TR16758A patent/TR16758A/xx unknown
  • 1968-12-06 GB GB57944/68A patent/GB1248757A/en not_active Expired
  • 1968-12-06 CH CH1822968A patent/CH481256A/de not_active IP Right Cessation
  • 1968-12-06 DK DK599068AA patent/DK130421B/da unknown
  • 1968-12-06 AT AT1192468A patent/AT289713B/de not_active IP Right Cessation

Patent Citations (6)

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