US3618925A - Adjustable closure for outlets in receptacles for molten metal or the like - Google Patents
Adjustable closure for outlets in receptacles for molten metal or the like Download PDFInfo
- Publication number
- US3618925A US3618925A US11232A US3618925DA US3618925A US 3618925 A US3618925 A US 3618925A US 11232 A US11232 A US 11232A US 3618925D A US3618925D A US 3618925DA US 3618925 A US3618925 A US 3618925A
- Authority
- US
- United States
- Prior art keywords
- vanes
- closure
- portions
- outlet
- molten metal
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 47
- 239000002184 metal Substances 0.000 title claims abstract description 47
- 239000000463 material Substances 0.000 claims description 13
- 239000011819 refractory material Substances 0.000 claims description 8
- 230000009969 flowable effect Effects 0.000 claims description 7
- 230000008878 coupling Effects 0.000 claims description 3
- 238000010168 coupling process Methods 0.000 claims description 3
- 238000005859 coupling reaction Methods 0.000 claims description 3
- 230000000694 effects Effects 0.000 claims description 3
- 239000012530 fluid Substances 0.000 claims description 3
- 239000007769 metal material Substances 0.000 claims description 3
- 230000001105 regulatory effect Effects 0.000 claims description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- 241000196324 Embryophyta Species 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- 230000006978 adaptation Effects 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000012768 molten material Substances 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
Images
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D41/00—Casting melt-holding vessels, e.g. ladles, tundishes, cups or the like
- B22D41/14—Closures
- B22D41/22—Closures sliding-gate type, i.e. having a fixed plate and a movable plate in sliding contact with each other for selective registry of their openings
- B22D41/24—Closures sliding-gate type, i.e. having a fixed plate and a movable plate in sliding contact with each other for selective registry of their openings characterised by a rectilinearly movable plate
Definitions
- the present invention relates to closures for outlets in receptacles for flowable materials, particularly for molten metal, such as molten steel or iron.
- Refining of metals normally necessitates treatment in liquid state including decanting of molten metal from one receptacle or vessel into another, for example, pouring of molten metal into ingot molds.
- the decanting is either continuous or intermittent; in each instance, the vessel from which molten metal is poured must be provided with a closure for its outlet to permit interruption of outflow and/or regulation of the rate of discharge.
- receptacles for molten metal for instance molten steel or iron
- closure in the form of stopper rods which are movable into engagement with a seat provided therefor at the inner end of an outlet, i.e., the stopper rod must extend into the pool of molten metalin the receptacle.
- Such closures are unsatisfactory for many reasons, for example, when the molten metal is treated with a gas which is caused to bubble through the bath of molten material or when such material is treated in vacuo in a ladle or the like.
- the stopper rod is likely to be damaged or destroyed, either as a result of violent mixingof molten metal in the receptacle or on prolonged contact with molten metal.
- a receptacle for molten metal with a composite valve which is located externally of the receptacle at a level below and opposite the outlet orifice.
- Such externally mounted valve is less likely to be rapidly affected by the hot contents of the receptacle. It normally comprises two overlapping plates or blades which are provided with cylindrical bores and are pivotable or reciprocable relative to each other to place their holes into partial or full registry and to thus determine the rate of outflow. It was found that such a valve is reasonably satisfactory when its plates are moved to fully open positions in which their holes arein full registry with each other.
- the just described valve is normally used only on or with receptacles wherein the outlet is either sealed or fully exposed, i.e., such valve is not suited to change the rate of outflow during decanting of molten metal. Consequently, the valve is useless in or on vessels serving to pour molten metal into continuous ingots which should receive metal at.a variable rate.
- An object of the invention is-to provide a novel and improved closure for use on or with receptacles for flowable materials, particularly for molten metal, and to construct and assemble the closure in such a way that it can completely seal the outlet of a receptacle as well as that it can permit convenient, accurate and repeated adjustment of the rate of outflow.
- Another object of the invention is to provide a closure which is less likely to produce turbulence in outflowing material than heretofore known closures.
- a further object of the invention is to provide a closure which insures that the jet of discharged molten metal invariably flows in a desired direction, regardless of whether the closure permits flow at a maximum rate or at any rate between the minimum rate (outlet sealed) and maximum rate.
- An additional object of the invention is to provide a closure which can be readily installed on or assembled with conventional receptacles for molten metal or the like.
- Still another object of the invention is to provide a closure which comprises a small number of relatively simple parts
- the invention is embodied in a closure for use with a receptacle having an outlet for flowable materials, particularly for molten metal.
- the closure comprises at least three adjoining vanes located in a common plane and each having a triangular portion bounded by two straight edge faces meeting at an apex and making an angle of 360/n wherein n is the number of vanes.
- each edge face of each triangular portion abuts against an edge face of the adjoining triangular portion and the vanes are movable in their common plane unidirectionally through equal distances at right angles to the lines dividing the respective apex angles between an outlet-closing position in which the apices of all triangular portions are adjacent to each other and a plurality of open positions in each of which the triangular portions define a polygonal passage of different cross-sectional area in registry with the outlet of thereceptacle.
- Each vane preferably comprises or is connected with a carriage which is reciprocable along one of several elongated guide means forming a polygonal frame and enclosing the area which accommodates the vanes.
- the carriages can be connected to each other by mechanical'me'ans to insure simultaneous movement of all vanes in a clockwise or in a counterclockwise direction, through identical distances, and while the respective edge faces remain in abutment with each other.
- the center of the polygon defined by the guide means coincides with the point where the apices of the triangular portions meet in closed positions of the vanes.
- the center of the polygonal passage defined by the triangular portions in each open position of the vanes coincides with the center of the polygon so that the core of the jet of molten'metal issuing from the receptacle in open positions of the vanes does not change its location, irrespective of the extent to which the vanes are moved from their outlet-closing position.
- FIG. 1 is a schematic front elevational view of a closure with three vanes which embodies one form of the invention and wherein the vanes are shown in outlet-closing positions;
- FIG. 2 illustrates the structure of FIG. 1 but with the vanes shown in one of their open positions
- FIG. 3 is a schematic front elevational view of a closure with four vanes which are shown in outlet-closing positions;
- FIG. 4 illustrates the structure of FIG. 3 but with the vanes in one of their open positions
- FIG. 5 is a front elevational view of all important details of a closure with three vanes which is mounted on a receptacle for molten metal;
- FIG. 6 is a sectional view as seen in the direction of arrows from the line F-O-F of FIG. 5;
- F IG. 7 is a front elevational view of a modified closure with three vanes.
- FIG. 1 illustrates the basic components of a closure with three identical vanes l, 2, 3, which are located in a common plane within the confines of a frame F forming an equilateral triangle.
- the vanes consist of refractory material and include abutting triangular inner portions la, 20, 3a whose apices meet at the center of the polygon defined by the frame F.Each of the portions 1a-3a is an isosceles triangle and is bounded by two edge faces 1b-1c, 2b-2c, 3b-3c and the edge faces 1b, 10, 2b respectively abut against the edge faces 2c, 3b, 30.
- the second or outer portions 1d, 2d, 3d of the vanes 1-3 are of rectangular outline and are slidable along the respective portions of the frame F from the closing positions shown in FIG. 1 (in which the three apices are adjacent to each other) toward the open positions shown in FIG. 2.
- the directions in which the vanes l-3 are movable from the closed positions are indicated by arrows shown in FIG. 2.
- the frame F comprises three elongated guide means 6, 7, 8 along which the outer portions 2d, 3d, 1d move while the respective edge faces remain in contact with each other.
- FIG. 2 shows the vanes in fully open positions in which the outer portions 1d, 2d, 3d respectively abut against the guide means 6, 7, 8 and in which the triangular portions 1a-3a define a triangular passage 9 of maximum cross-sectional area.
- the center of this passage coincides with the center of the triangle defined by the guide means 6-8 and with the point where the apices of the portions 1a-3a meet in the positions shown in FIG. 1.
- the vanes 1-3 can be moved to an infinite number of intermediate open positions in each of which their portions 1a-3a define a passage of a different cross-sectional area but the center of each such passage coincides with the center of the passage 9.
- the maximum distance d which the vanes 1-3 can cover during movement between the end positions shown in FIGS. 1 and 2 is less than the distance e between a corner of the polygon and the two nearest outer portions (1d, 2d or 2d, 3d or 3d, 1d) in closing positions of the vanes. Since the outer portions 1d-3d slide along the guide means 8, 6, 7 and since the edge faces of the triangular portions 1a-3a are in constant abutment with each other, movement of any one vane along the respective guide means necessarily causes equidirectional movement of the other two vanes through the same distance. In the closure of FIGS. 1 and 2, the vanes can be moved clockwise or counterclockwise.
- the portions 1a-3a prevent any leakage in closing positions of the vanes and they permit molten metal or other flowable material to escape only by way of the passage 9 (or a smaller passage) when the vanes are moved away from the closing positions.
- the area of the passage 9 grows symmetrically about the center of the triangular area which is defined by the frame F and accommodates the vanes. This is important because the core of the jet of molten metal issuing from the receptacle whose outlet is controlled by the closure of FIGS.
- molten metal can be discharged with a minimum of turbulence and the jet of such metal can be readily directed toward a selected part of the vessel (e.g., an ingot) which is to accept the outflowing material.
- FIG. 3 illustrates schematically a second closure wherein a frame F of square cross-sectional outline accommodates and guides four vanes 10, 11, 12, 13 respectively having triangular inner portions a-13a and rectangular outer portions 10d-l3.
- the angles at the apices of the triangular portions 10a-13 are identical and each thereof equals 360l4, i.e., 90.
- the distance d shown in FIG. 3 equals the distance e and each edge face of each of the triangular portions 10a-13a abuts against and is slidable along one edge face of the adjoining triangular portion.
- the directions in which the vanes 10-13 can be moved from the outlet-closing positions of FIG. 3 to the fully open positions of FIG. 4 are indicated by arrows.
- the vanes then define a square passage 14 whose center coincides with the center of the polygon defined by the four guide means of the frame F.
- the vanes 10-13 can be moved to a desired number of intermediate open positions to provide a passage of desired cross-sectional area; however, in each open position of the vanes, the center of the passage defined by the triangular portions 10a-13a coincides with the point where the apices of such triangular portions meet in the outlet-closing positions of the vanes (FIG. 3).
- the present invention can be embodied in a closure with n vanes wherein n is a whole number exceeding two, and the frame for such vanes then preferably defines a regular n-sided polygon.
- the polygonal passage defined by the vanes has n sides and the apex angles of triangular inner portions of such vanes equal 360ln.
- FIGS. 5 and 6 illustrate in greater detail a closure which is analogous to the closure of FIGS. 1-2 and which controls the outlet 37a in the bottom or sidewall 37b of a receptacle (e.g., a ladle) for molten aluminum M.
- the closure comprises the three vanes 101-103 whose outer portions are received in or form carriages or slides 17, 18, 19.
- the vanes 101-103 are relatively thick plates consisting of refractory material and are mounted directly below the outlet 37a, as viewed in FIG. 6.
- the frame 15 for these vanes defines an equilateral triangle and has flanges 15a separably secured to bolts 16 by means of cotter pins 16a.
- the bolts 16 extend downwardly from the outer panel 370 of the wall 37b.
- the frame 15 comprises three guide means or rails 25, 23, 24 having channels 20, 21, 22 for the carriages 17, 18, 19, respectively.
- the rails 23-25 consist of metal and the rail 25 is movable up and down, as viewed in FIG. 5, into abutment with and away from the rails 23, 24.
- the frame 15 comprises an extension 28 providing ways for the end portions of the rail 25 and accommodating a pair of hydraulic or pneumatic cylinders 26, 27 which bias the rail 25 against the rails 23, 24. This insures that the edge faces of the vanes 101-103 remain in requisite sealing engagement with each other to completely prevent outflow of molten metal M by way of the outlet 37a (when the vanes assume the closing positions shown in FIGS. 5-6) or to prevent leakage of molten metal between the edge faces when the vanes define a passage of desired cross-sectional area.
- the means for simultaneously moving the vanes 101-103 through identical distances comprises three identical hydraulic or pneumatic cylinders 29, 30, 31 which are respectively mounted on rails 25, 23, 24 and whose piston rods are coupled to brackets or projections 32, 33, 34 respectively provided on the carriages 17, 18, 19.
- the axes of the cylinders 29-31 are parallel to the respective sides of the triangle defined by the frame F.
- the means for synchronizing the movements of vanes 101-103 comprises a system of valves (indicated schematically at 129) which supply pressurized fluid to the chambers of cylinders 29-31 at the same rate.
- FIG. 6 shows that the vanes 101-103 are sandwiched between two apertured plates 35, 36 of refractory material.
- the plate 35 abuts against a washer which is outwardly adjacent to the nozzle 37 defining the outlet 37a.
- the nozzle 37 also consists of refractory material, the same as the wall 37b.
- a retaining member 38 is affixed to the frame 15 to hold the plate 36 against movement away from the plate 35.
- the vanes 101-103 are preferably mounted with some play (in directions toward and away from the outlet 37a) so that the retaining member 38 can exert a necessary pressure which is transmitted to the plate 35.
- FIG. 7 illustrates a further closure which comprises three vanes 201-203 having outer portions or carriages 217-219 movable in grooves defined by rails 225, 223, 224 which form part of a frame 215 having an extension 228 for the movable rail 225.
- the latter is biased upwardly, as viewed in FIG. 7, by helical springs 39.
- These helical springs can be replaced by leaf springs, by packages of dished springs.
- the means for moving the vanes 201-203 comprises an endless flexible element here shown as a chain 43 which is trained over three sprocket wheels 40, 41, 42 provided at the corners of the triangle defined by the frame 215.
- the numerals 45, 46, 47 denote couplings which respectively secure the carriages 217, 218, 219 to the chain 43.
- a linkage 48 is employed to move the vane 203 toward and away from the sprocket wheel 41 whereby the chain 43 insures that the other two vanes share such movement of the vanes 203.
- chain 43 synchronizes the movements of all vanes by insuring that each vane moves through the same distance and in the same direction.
- the numeral 44 denotes a turnbuckle or an analogous tensioning device for the chain 43. It is clear that this chain can be replaced by a cable, a belt or another endless flexible element.
- the chain 43 need not be endless; it may comprise several discrete sections each having its ends attached to two adjoining vanes and a median portion trained over one of the sprocket wheels 40, 41, 42.
- the couplings 45-47 are of the type which can be disengaged from the chain 43 so that the latter is then free to move independently of the vanes.
- the linkage 48 can be replaced by any other means which is capable of moving one of the vanes 201-203 or the chain 43 in a direction which is parallel to the respective side of the triangle, i.e., in a direction which is normal to the line halving one of the apex angles of triangular portions of the vanes.
- the chain 43 can be driven by a sprocket wheel or one of the carriages 225, 223, 224 can be provided with a rack which meshes with a pinion driven by a motor or the like.
- the frame of the closure may comprise two or more guide means which are movable relative to the other guide means in a manner as shown for the rail 25 of FIG. 5 or rail 225 of FIG. 7.
- the force of the biasing means determines the pressure with which the edge faces of the vanes abut against each other to prevent leakage.
- the pressure between the edgefaces of the vanes is distributed with greater uniformity if the frame for the vanes comprises two or more guide means which are biased toward the center of the polygon defined by such guide means.
- the vanes 201-203 of FIG. 7 are made of refractory material. However, it is clear that these vanes can consist, at least in part, of metallic material and that the previously described vanes may be entirely made of metal. The material forthe vanes will be selected in dependency on the temperature of molten metal, and other factors which effect the useful life of vanes.
- the structure shown in FIG. 1, 3, 5 or 7 may comprise an auxiliary or calibrating nozzle defining a cylindrical or conical passage for molten metal and located downstream of the passage defined by the vanes 1-3, 10-13, 101-103 or 201-203. See the phantom-line nozzle 53in FIG. 6.
- Such composite closure can be used on all types of receptacles for molten metal-in a steel processing plant or the like. It was found, however, that the polygonal passage defined by three or more vanes of my improved closure insures very satisfactory outflow of molten metal with minimal turbulence.
- the size of the passage defined by its vanes can be varied infinitely to insure satisfactory outflow of molten metal at a desired rate.
- the axis of the flow of molten metal remains stationary whatever is the cross section of the passage.
- the means for moving the vanes can be manipulated by hand, by remote control or by a suitable programming system so as to initiate, terminate or regulate the rate of outflow in accordance with a predetermined schedule.
- the receptacle employing my improved closure can form part of an auto mated metal processing plant.
- the improved closure is longer-lasting and safer than heretofore known closures for outlets which discharge molten metal. This is due to the fact that the contact with molten metal can be readily confined to selected surfaces of the vanes and that the leakage of molten metal can be reduced or eliminated by resorting to relatively simple pressure applying devices.
- a closure for said outlet including at least three adjoining vanes located in a common plane and each having a triangular portion bounded by two edge faces meeting at an apex and making an angle of 360/n wherein n is the number of said vanes, each edge face of each of said portions abutting against an edge face of the adjoining portion and'said vanes being movable in said plane unidirectionally through equal distances at right angles to the lines dividing the respective first mentioned angles between an outlet closing position in which the apices of said portions are adjacent to each other and a plurality of open positions in each of which said portions define a polygonal passage of different cross-sectional area in registry with said outlet.
- a closure for said outlet including at least three adjoining vanes located in a common plane and each having an isosceles triangular portion-bounded by two edge faces meeting at an apex and making an angle of 360ln wherein n is the number of said vanes, each edge face of each of said portions abutting against an .edge face of the adjoining portion and said vanes being movable in said plane unidirectionally through equal distances at right angles to the lines dividing the respective first mentioned angles between an outlet closing position in which the apices of said portions are adjacent to each other and a plurality of open positions in each of which said portions define a regular polygonal passage of different cross-sectional area in registry with said outlet.
- each of said second portions constitutes a carriage for the respective triangular portion.
- a closure as defined in claim 8, wherein said means for moving said second portions comprises a fluid-operated cylinder for each of said vanes and means for regulating the admission and evacuation of fluid from said cylinders to effect movements of said vanes through identical distances.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Casting Support Devices, Ladles, And Melt Control Thereby (AREA)
- Furnace Charging Or Discharging (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR6903584A FR2031968A5 (ru) | 1969-02-14 | 1969-02-14 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3618925A true US3618925A (en) | 1971-11-09 |
Family
ID=9029077
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US11232A Expired - Lifetime US3618925A (en) | 1969-02-14 | 1970-02-13 | Adjustable closure for outlets in receptacles for molten metal or the like |
Country Status (9)
Country | Link |
---|---|
US (1) | US3618925A (ru) |
AT (1) | AT295063B (ru) |
BE (1) | BE745754A (ru) |
CA (1) | CA917915A (ru) |
DE (1) | DE2004907C3 (ru) |
FR (1) | FR2031968A5 (ru) |
GB (1) | GB1229765A (ru) |
SE (1) | SE365142B (ru) |
SU (1) | SU368727A3 (ru) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3858772A (en) * | 1972-06-26 | 1975-01-07 | Conair | Hopper assembly |
US4163726A (en) * | 1977-04-29 | 1979-08-07 | Hughart Robert P | Valve assembly for cyclones or other abrasive applications |
US4260081A (en) * | 1978-08-07 | 1981-04-07 | Pol Detalle | Slide-valve output regulating throttle |
US4717052A (en) * | 1986-07-11 | 1988-01-05 | Aluminum Company Of America | Molten metal conduit |
US4728013A (en) * | 1984-09-05 | 1988-03-01 | Didier-Werke Ag | Refractory plate formed with expansion joints |
US4802611A (en) * | 1985-12-21 | 1989-02-07 | Didier-Werke Ag | Movable refractory plate assembly with movable refractory control member |
US20090101629A1 (en) * | 2007-10-19 | 2009-04-23 | Honeywell International, Inc. | Erosion resistant torch |
US20090223939A1 (en) * | 2007-10-19 | 2009-09-10 | Honeywell International, Inc. | Variable orifice torch |
US11015721B2 (en) * | 2017-07-07 | 2021-05-25 | Vadim M. SAKIZCHI | Flow control valve |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE2834643A1 (de) * | 1978-08-08 | 1980-02-28 | Detalle | Abflussregulierender schieberverschluss |
-
1969
- 1969-02-14 FR FR6903584A patent/FR2031968A5/fr not_active Expired
-
1970
- 1970-01-28 GB GB1229765D patent/GB1229765A/en not_active Expired
- 1970-02-03 SE SE01357/70A patent/SE365142B/xx unknown
- 1970-02-04 DE DE2004907A patent/DE2004907C3/de not_active Expired
- 1970-02-09 AT AT115070A patent/AT295063B/de not_active IP Right Cessation
- 1970-02-10 BE BE745754D patent/BE745754A/xx unknown
- 1970-02-12 CA CA074682A patent/CA917915A/en not_active Expired
- 1970-02-13 US US11232A patent/US3618925A/en not_active Expired - Lifetime
- 1970-02-14 SU SU1402416A patent/SU368727A3/ru active
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3858772A (en) * | 1972-06-26 | 1975-01-07 | Conair | Hopper assembly |
US4163726A (en) * | 1977-04-29 | 1979-08-07 | Hughart Robert P | Valve assembly for cyclones or other abrasive applications |
US4260081A (en) * | 1978-08-07 | 1981-04-07 | Pol Detalle | Slide-valve output regulating throttle |
US4728013A (en) * | 1984-09-05 | 1988-03-01 | Didier-Werke Ag | Refractory plate formed with expansion joints |
US4802611A (en) * | 1985-12-21 | 1989-02-07 | Didier-Werke Ag | Movable refractory plate assembly with movable refractory control member |
US4717052A (en) * | 1986-07-11 | 1988-01-05 | Aluminum Company Of America | Molten metal conduit |
US20090101629A1 (en) * | 2007-10-19 | 2009-04-23 | Honeywell International, Inc. | Erosion resistant torch |
US20090223939A1 (en) * | 2007-10-19 | 2009-09-10 | Honeywell International, Inc. | Variable orifice torch |
US7842898B2 (en) | 2007-10-19 | 2010-11-30 | Honeywell International Inc. | Variable orifice torch |
US7977599B2 (en) | 2007-10-19 | 2011-07-12 | Honeywell International Inc. | Erosion resistant torch |
US11015721B2 (en) * | 2017-07-07 | 2021-05-25 | Vadim M. SAKIZCHI | Flow control valve |
Also Published As
Publication number | Publication date |
---|---|
GB1229765A (ru) | 1971-04-28 |
BE745754A (fr) | 1970-07-16 |
FR2031968A5 (ru) | 1970-11-20 |
DE2004907C3 (de) | 1973-09-20 |
SE365142B (ru) | 1974-03-18 |
SU368727A3 (ru) | 1973-01-26 |
AT295063B (de) | 1971-12-27 |
DE2004907A1 (de) | 1970-09-10 |
DE2004907B2 (de) | 1973-03-01 |
CA917915A (en) | 1973-01-02 |
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