US3607340A - Apparatus and method for spot-coating sheet and web materials - Google Patents

Apparatus and method for spot-coating sheet and web materials Download PDF

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Publication number
US3607340A
US3607340A US24426A US3607340DA US3607340A US 3607340 A US3607340 A US 3607340A US 24426 A US24426 A US 24426A US 3607340D A US3607340D A US 3607340DA US 3607340 A US3607340 A US 3607340A
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United States
Prior art keywords
coating
substrate
nozzle
apertures
area
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Expired - Lifetime
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US24426A
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English (en)
Inventor
Herman F Stroupe
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Eastman Kodak Co
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Eastman Kodak Co
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    • G—PHYSICS
    • G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
    • G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
    • G03C11/00—Auxiliary processes in photography
    • G03C11/08—Varnishing, e.g. application of protective layers on finished photographic prints
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C—APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05C11/00—Component parts, details or accessories not specifically provided for in groups B05C1/00 - B05C9/00
    • B05C11/10—Storage, supply or control of liquid or other fluent material; Recovery of excess liquid or other fluent material
    • B05C11/1002—Means for controlling supply, i.e. flow or pressure, of liquid or other fluent material to the applying apparatus, e.g. valves
    • B05C11/1015—Means for controlling supply, i.e. flow or pressure, of liquid or other fluent material to the applying apparatus, e.g. valves responsive to a conditions of ambient medium or target, e.g. humidity, temperature ; responsive to position or movement of the coating head relative to the target
    • B05C11/1021—Means for controlling supply, i.e. flow or pressure, of liquid or other fluent material to the applying apparatus, e.g. valves responsive to a conditions of ambient medium or target, e.g. humidity, temperature ; responsive to position or movement of the coating head relative to the target responsive to presence or shape of target
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
    • B29C43/22—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor of articles of indefinite length
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
    • B41M7/0027—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock using protective coatings or layers by lamination or by fusion of the coatings or layers
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06B—TREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B11/00—Treatment of selected parts of textile materials, e.g. partial dyeing
    • D06B11/0056—Treatment of selected parts of textile materials, e.g. partial dyeing of fabrics
    • D06B11/0059—Treatment of selected parts of textile materials, e.g. partial dyeing of fabrics by spraying
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H19/00—Coated paper; Coating material
    • D21H19/66—Coatings characterised by a special visual effect, e.g. patterned, textured
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00—Processes or apparatus for adding material to the pulp or to the paper
    • D21H23/78—Controlling or regulating not limited to any particular process or apparatus
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H25/00—After-treatment of paper not provided for in groups D21H17/00 - D21H23/00
    • D21H25/08—Rearranging applied substances, e.g. metering, smoothing; Removing excess material
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H27/00—Special paper not otherwise provided for, e.g. made by multi-step processes
    • D21H27/02—Patterned paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H5/00—Special paper or cardboard not otherwise provided for
    • D21H5/0005—Processes or apparatus specially adapted for applying liquids or other fluent materials to finished paper or board, e.g. impregnating, coating
    • D21H5/006—Controlling or regulating
    • D21H5/0062—Regulating the amount or the distribution, e.g. smoothing, of essentially fluent material already applied to the paper; Recirculating excess coating material applied to paper
    • D—TEXTILES; PAPER
    • D21—PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21H—PULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H5/00—Special paper or cardboard not otherwise provided for
    • D21H5/02—Patterned paper
    • D21H5/06—Apparatus

Definitions

  • This invention relates to a new method and apparatus for economically and accurately coating selected areas on a moving surface or plane. More particularly, the invention relates to spot coating a surface with apparatus having incorporated therein an antidrool valve similar to that described in Quarve US. Pat. No. 3,315,899 dated Apr. 25, 1967.
  • the roll application of coating materials, and particularly plastic coatings has been severely limited because the coating cylinder design must include adequate control apparatus as well as specially designed and etched roll plates. Additionally, if it is desired to deform the coated surface, the impression or compression rolls must be provided with recessed grippers to allow for the accurate and controlled gripping of the sheet material without interference with the associated rolls. The rolls system is further limited to dry ink treatments which obviously require undesirable delays between the printing and coating of stock material.
  • a method and apparatus is pro vided for deposition of a fluent or fluidlike coating, and in particular plastic material coatings, upon a variety of substrate materials, thus providing either a protective or functional final coating thereon.
  • the system and method employed involves the use of at least a single, and generally a plurality of antidrool type valve and nozzle arrangements with which the coating material is controlled. Upon receipt of control signals, these valves will accurately startup or cutoff with minimal tailing because of the vacuum and holding action that is effective during a selected part of their operating cycle.
  • one object of this invention is the elimination of the need for a special roller-type coating mechanism employ ing recessed grippers and other necessary and special design features as above noted.
  • Another object of this invention is to provide a simplified method and apparatus which will allow, in sheet or roll coating applications, an intermittent deposition of a coating over a specified area of substrate material with the assurance that only the predesignated area will be so treated.
  • Yet another object of this invention is to provide a method and apparatus which will not only allow particular areas of either the sheet or web material to be accurately coated, but will also permit the production of contoured areas as well.
  • FIG. 1 is a simplified flow diagram outlining the various method steps of the invention
  • FIG. 2 is a schematic diagram of a preferred embodiment of the apparatus intended to carry out the method of the invention
  • FIG. 3 is a schematic diagram of another embodiment of the apparatus which may be used to carry out the method of the invention and in which the substrate material has a substantially straight line flow-path;
  • FIG. 4 is a schematic diagram of a representative control system which may be used with and incorporated in the apparatus of the invention
  • FIG. 5 is a simplified schematic diagram of a typical timing circuit which may be used in controlling the coating operation
  • FIG. 6 is a perspective view of one of the valve and nozzle arrangements used in the coating apparatus
  • FIG. 7 is a cross section taken along lines 7-7 of FIG. 6;
  • FIG. 8 is a bottom view of the valve and nozzle arrangements as shown in FIG. 6.
  • FIG. I illustrates the general method of the invention
  • the method further contemplates the possibility of intermediate storage prior to the coating operation, and therefore it may be necessary to feed to the coating zone from a stacked formation of the substrate.
  • the multiple capabilities of this system thus presents a versatile overall method of coating in addition to achieving the prime objective of the invention; that being the development of a satisfactory spotcoating method which is either adaptable to existing equipment or easily manufactured as an integral self-contained unit.
  • the substrate material used in practicing this invention is fed to a coating zone in which the presence of the material or the area thereon to be coated is sensed and the depositing system is activated. After deposition, the inherently beaded formation is evenly spread so that the entire area to be coated is uniformly covered. Immediately thereafter, or in conjunction therewith, the coated area may be deformed in any pattern desired after which the coated substrate is forwarded to another stacking mechanism. Of course, should it be so desired, the substrate may be rerolled or forwarded to subsequent treatment areas such as, for example, cutting and slitting stations where the coated stock may be trimmed to size.
  • certain aspects of the invention anticipate the desirability of leaving a beaded or layered formation upon the substrate material without the performance of any subsequent forming steps. This would result in the formation of a predetermined design, configuration, or contoured shape.
  • a completely integral single line system be used.
  • a partial system where the substrate is transferred from stack to stack with intermediate coating may at times be desirable or necessary.
  • the feeding mechanism will remove a particular sheet, or the web material, from its respective stack or roll, pass it through the coating area to the smoothing and deforming station, and it will subsequently be recollected in its original form, assuming no further treatment is desired.
  • this invention is readily adaptable for use with practically all fluent materials, including plastics, inks, dyes, or other suitable fluids which are applicable to being applied as a spot-coating.
  • plastics inks, dyes, or other suitable fluids which are applicable to being applied as a spot-coating.
  • suitable substrate materials such as paper, ceramics, cloth, wood, metals or the like may be used in practicing this invention.
  • particular emphasis will be placed hereinafter upon the use of paper substrates.
  • the invention can be used in decorative and/or functional applications.
  • Decorative applications most commonly employ the use of inks, dyes, or other similar fluids, whereas for functional and protective purposes waxes, plastics, or the like will normally be employed.
  • Functional uses include, for example, lenticulated surfaces, contoured surfaces, braille systems, and computer tapes and cards, any or all of which may require deformation during their formation.
  • protective applications it is only necessary to thinly, evenly, and smoothly coat the substrate material.
  • a fluent or plastic melt storage and pumping system is attached to a modified printing press generally designated as 12.
  • a sheet stacker 14 containing paper or other substrate sheet materials I which may be grasped by the suction device 16 and transferred to the belt and roll feed systems 18.
  • a sensing means 20 such as a flag switch or photoelectric cell which thereupon emits a signal to activate a timing or other delay mechanism 22.
  • the sheet 1 continues to be advanced and is grasped by grippers contained upon compression cylinder 24 and is thus transferred beneath an antidrool valve and nozzle head 26, which will be more fully described hereinafter, and through which the fluent material is deposited upon any particular portion of the sheet 1.
  • a rod or roller 28 functions to smooth the beaded material deposit preparatory to a transfer of sheet 1, to compression cylinder 30.
  • Cylinder 30 has a deforming surface 32 acting in conjunction with cylinder 24 to deform the coating into the particular configuration desired.
  • a steam or water spray system 34 including a supply source 35, is directed upon a cylinder 30 in order to provide for the easy release and transfer of the plastic coated substrate therefrom and to takeoff cylinder 36. From cylinder 36 it can be seen that the sheet 1 will be grasped by the roller-chain delivery system 38 and subsequently deposited upon the stacking mechanism 40. Both of the stackers l4 and 40 can be seen as being movable in the vertical direction by any suitable powered means, so that multiple sheets may be adequately removed or deposited without difficulty.
  • a sensing means 20 for example, the photoelectric cell shown will, in response to the presence of a sheet or indicia thereupon, generate a signal to be received by a timer or delay device 22.
  • the timer 22 may be preset according to the speed of travel of the substrate material, the position where the deposit is desired, and the size or length of the deposit desired. These variables being controlled therein, the timing mechanism 22 will subsequently signal solenoid 27 which upon its activation will allow air or some other suitable activating media from a pressure source 2I to enter valve 26. This will open the valve and effect a properly placed deposit of a plastic or other fluid material, from system 10, upon the substrate.
  • timing device and sensing mechanism may be replaced by any suitable computerized or like system which may be made integral therewith.
  • a computer 42 (FIG. 4) is adapted to the overall coating system, sheet or web feed, as well as fluid material deposition may be controlled by the computer itself.
  • Template 44, card 46, tape 48 or other similar computer means may be employed therewith.
  • feed rolls advance the material through a sensing area where sensor 20 detects the substrate presence and activates a fluid control delay device 22.
  • This control delay device in turn energizes the solenoid 27 thus allowing for the deposit of the coating fluid supplied under pressure from the storage and feed system 10.
  • stacked sheets may be fed through the system of FIG. 3.
  • a stacker 14 or a direct feed from a printing press 54 can be used to supply the sheets, either of which may replace the roll stock supply 13.
  • printed materials of various forms will be coated by this method and apparatus.
  • One specific item of particular interest are lineiform pictures which when covered by a lenticulated plastic coating give a three-dimensional effect. These pictures would first be printed, then coated, and the coating surface deformed as hereinbefore mentioned.
  • the "antidrool" valve and nozzle 26 system may be placed in tandem, [as is shown in phantom in FIG.3], along the path of movement of the substrate if a layering type effect is necessary or desirable.
  • a controlled countered effect can be given to the surface of the substrate being passed through the tandem nozzle system.
  • the second or added tandem nozzles could be supplied with a different fluid thus giving the added capability of placing different fluid in a laminate array or in alternate positions upon the substrate.
  • the fluid feed and storage may consist of an extruder 8 or other suitable feed means capable of depositing the fluent material to be used as the coat into a storage tank 6.
  • pump 5 transfers the viscose fluid through a piping or conduit system 4 to the valve 26. Due to the viscosity of the materials generally being handled, such a system must be under a relatively high positive pressure, as for example, on the order of 200 p.s.i.g.
  • valve and nozzle manifold 26 used with the apparatus of the invention is more clearly depicted, one can see that, while using only a single valve 23, a plurality of nozzle openings 19 can be supplied from the head 25 which has a fluid reservoir 33 therein.
  • the nozzles I9 are preferably spaced approximately 0.10 inch apart, but, of course, such spacing depends upon the orifice size, fluid viscosity, and pressure.
  • heads 25 in order to get increased lateral coverage it is only necessary to abut the ends of heads 25 in any suitable mounting upon the coater.
  • These head lengths can range in length from about 4 inches to I2 inches, but with increased fluid pressure, the length may be as much as 107 inches or more.
  • these valve and manifold heads 25 are closely adjacent the substrate path and preferably are between 0.002 inch and 0.250 inch above the substrate surface.
  • valve stem 15 is activated by the introduction of a hydraulic or some other fluid medium through openings 29 and 31 which are at opposite ends of the cylinder 9.
  • Piston 13 is connected to valve stem 15 and is free to ride within cylinder 9 between its upper and lower ends which are defined by cap 64 and valve body 23.
  • Apparatus for forming a coating of material on a substrate comprising:
  • a nozzle manifold including a plurality of spaced aper tures positioned across the direction of advancement of said substrate through which said material is adapted to flow and be deposited on the substrate in a plurality of generally parallel beads
  • Apparatus according to claim 1 which includes means for uniformly distributing the coating on the substrate.
  • Apparatus according to claim 1 which includes means for imparting a particular surface configuration to said coating.
  • Apparatus according to claim 4 which includes means for imparting a particular surface configuration to said coating.
  • a method for applying a coating of material to a selected area of substrate material which comprises the steps of a. advancing said substrate along a path which carries a surface of said substrate past an applicator for receiving an application of material,
  • a method according to claim 7 which includes the additional step of smoothing said beads to form a coating of substantially uniform thickness.
  • a method according to claim 7 which includes the additional step of imparting a particular surface configuration to said coating.
  • a method according to claim 8 which includes the additional step of imparting a particular surface configuration to said coating.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Materials Engineering (AREA)
  • Textile Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
US24426A 1967-06-13 1970-04-06 Apparatus and method for spot-coating sheet and web materials Expired - Lifetime US3607340A (en)

Applications Claiming Priority (2)

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US64567567A 1967-06-13 1967-06-13
US2442670A 1970-04-06 1970-04-06

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US3607340A true US3607340A (en) 1971-09-21

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4243447A (en) * 1978-05-19 1981-01-06 Neturen Company Ltd. Method for continuously forming a coating layer on unbonded PC steel bars
EP0191744A1 (en) * 1985-02-14 1986-08-20 Tarkett Ab Method for making decorative plastic webs or sheets
EP0204403A3 (en) * 1985-05-01 1988-01-20 Burlington Industries, Inc. Dyeing by electrostatic application of randomly generated droplets
WO1997002949A1 (en) * 1995-07-13 1997-01-30 B & H Manufacturing Company, Inc. Applying a tactilely distinguishable marking on an article
WO1996040559A3 (en) * 1995-06-07 1997-04-10 B & H Mfg Co Inc Computer controlled labeling machine
US5858143A (en) * 1993-09-16 1999-01-12 B & H Manufacturing, Inc. Computer controlled labeling machine for applying labels including stretch labels and tactilely sensible indicia on articles
US6051280A (en) * 1997-09-01 2000-04-18 Wagner International Ag Method of controlling an electrostatic coating device and an electrostatic coating system
EP1563914A1 (de) * 2004-02-13 2005-08-17 Nordson Corporation Verfahren und Vorrichtung zur Herstellung einer ertastbaren Markierung
WO2006100273A1 (en) 2005-03-22 2006-09-28 Ten Cate Advanced Textiles B.V. Method of depositing materials on a textile substrate
US20090045372A1 (en) * 2005-03-22 2009-02-19 Johannes Antonius Craamer Composition for drop on demand finishing of a textile article

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2299537A (en) * 1995-04-06 1996-10-09 Quad Tech Forming three-dimensional graphic image

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3056337A (en) * 1959-12-01 1962-10-02 Peters Mach Co Forming and gluing machine
US3241429A (en) * 1962-05-14 1966-03-22 Pid Corp Pictorial parallax panoramagram units
US3315899A (en) * 1965-01-08 1967-04-25 Eastman Kodak Co Hot melt nozzle with reciprocating piston drip-prevention means
US3317334A (en) * 1959-12-30 1967-05-02 Harris Intertype Corp Coating apparatus
US3327680A (en) * 1964-02-06 1967-06-27 Peters Mach Co Hot melt gluing machine
US3420208A (en) * 1966-12-02 1969-01-07 Lockwood Tech Pneumatically controlled applicator system for adhesive and the like

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3056337A (en) * 1959-12-01 1962-10-02 Peters Mach Co Forming and gluing machine
US3317334A (en) * 1959-12-30 1967-05-02 Harris Intertype Corp Coating apparatus
US3241429A (en) * 1962-05-14 1966-03-22 Pid Corp Pictorial parallax panoramagram units
US3327680A (en) * 1964-02-06 1967-06-27 Peters Mach Co Hot melt gluing machine
US3315899A (en) * 1965-01-08 1967-04-25 Eastman Kodak Co Hot melt nozzle with reciprocating piston drip-prevention means
US3420208A (en) * 1966-12-02 1969-01-07 Lockwood Tech Pneumatically controlled applicator system for adhesive and the like

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4243447A (en) * 1978-05-19 1981-01-06 Neturen Company Ltd. Method for continuously forming a coating layer on unbonded PC steel bars
EP0191744A1 (en) * 1985-02-14 1986-08-20 Tarkett Ab Method for making decorative plastic webs or sheets
EP0204403A3 (en) * 1985-05-01 1988-01-20 Burlington Industries, Inc. Dyeing by electrostatic application of randomly generated droplets
US5858143A (en) * 1993-09-16 1999-01-12 B & H Manufacturing, Inc. Computer controlled labeling machine for applying labels including stretch labels and tactilely sensible indicia on articles
AU718257B2 (en) * 1995-06-07 2000-04-13 B & H Manufacturing Company, Inc. Computer controlled labeling machine for applying labels including stretch labels and tactilely sensible indicia on articles
WO1996040559A3 (en) * 1995-06-07 1997-04-10 B & H Mfg Co Inc Computer controlled labeling machine
AU715798B2 (en) * 1995-07-13 2000-02-10 B & H Manufacturing Company, Inc. Applying a tactilely distinguishable marking on an article
US5753350A (en) * 1995-07-13 1998-05-19 B&H Manufacturing Company Article labeled by a labeling machine applying a tactilely distinguishable marking
US5702559A (en) * 1995-07-13 1997-12-30 B&H Manufacturing Company, Inc. Method and apparatus for applying a tactilely distinguishable marking on an article
WO1997002949A1 (en) * 1995-07-13 1997-01-30 B & H Manufacturing Company, Inc. Applying a tactilely distinguishable marking on an article
US6051280A (en) * 1997-09-01 2000-04-18 Wagner International Ag Method of controlling an electrostatic coating device and an electrostatic coating system
EP1563914A1 (de) * 2004-02-13 2005-08-17 Nordson Corporation Verfahren und Vorrichtung zur Herstellung einer ertastbaren Markierung
WO2006100273A1 (en) 2005-03-22 2006-09-28 Ten Cate Advanced Textiles B.V. Method of depositing materials on a textile substrate
JP2008534792A (ja) * 2005-03-22 2008-08-28 テン・ケイト・アドバンスト・テクスタイルス・ビー．ブイ． 布地の基材に物質を付着させる方法
US20090045372A1 (en) * 2005-03-22 2009-02-19 Johannes Antonius Craamer Composition for drop on demand finishing of a textile article
US20090142552A1 (en) * 2005-03-22 2009-06-04 Johannes Antonius Craamer Method of Depositing Materials on a Textile Substrate
US7709061B2 (en) * 2005-03-22 2010-05-04 Ten Cate Advanced Textiles B. V. Method of depositing materials on a textile substrate

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FR1568638A (enExample) 1969-05-23

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