US3560389A - Liquid detergent bleach composition - Google Patents
Liquid detergent bleach composition Download PDFInfo
- Publication number
- US3560389A US3560389A US661761A US3560389DA US3560389A US 3560389 A US3560389 A US 3560389A US 661761 A US661761 A US 661761A US 3560389D A US3560389D A US 3560389DA US 3560389 A US3560389 A US 3560389A
- Authority
- US
- United States
- Prior art keywords
- sodium
- detergent
- detergents
- alcohol
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003599 detergent Substances 0.000 title abstract description 52
- 239000000203 mixture Substances 0.000 title abstract description 52
- 239000007844 bleaching agent Substances 0.000 title abstract description 20
- 239000007788 liquid Substances 0.000 title abstract description 15
- QUCDWLYKDRVKMI-UHFFFAOYSA-M sodium;3,4-dimethylbenzenesulfonate Chemical compound [Na+].CC1=CC=C(S([O-])(=O)=O)C=C1C QUCDWLYKDRVKMI-UHFFFAOYSA-M 0.000 abstract description 19
- 239000003752 hydrotrope Substances 0.000 abstract description 13
- 238000004061 bleaching Methods 0.000 abstract description 9
- 239000007800 oxidant agent Substances 0.000 abstract description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 39
- -1 alkaline earth metal salt Chemical class 0.000 description 16
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 13
- 239000005708 Sodium hypochlorite Substances 0.000 description 13
- 229910052708 sodium Inorganic materials 0.000 description 13
- 239000011734 sodium Substances 0.000 description 13
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 13
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 11
- 229910052783 alkali metal Inorganic materials 0.000 description 11
- QTDIEDOANJISNP-UHFFFAOYSA-N 2-dodecoxyethyl hydrogen sulfate Chemical compound CCCCCCCCCCCCOCCOS(O)(=O)=O QTDIEDOANJISNP-UHFFFAOYSA-N 0.000 description 8
- 150000001340 alkali metals Chemical class 0.000 description 8
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 8
- 239000000460 chlorine Substances 0.000 description 7
- 125000004432 carbon atom Chemical group C* 0.000 description 6
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 4
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 4
- 229910052801 chlorine Inorganic materials 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 3
- WMFOQBRAJBCJND-UHFFFAOYSA-M Lithium hydroxide Chemical compound [Li+].[OH-] WMFOQBRAJBCJND-UHFFFAOYSA-M 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 3
- 239000004141 Sodium laurylsulphate Substances 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 125000000217 alkyl group Chemical group 0.000 description 3
- 150000001412 amines Chemical class 0.000 description 3
- 150000004951 benzene Polymers 0.000 description 3
- 150000001555 benzenes Polymers 0.000 description 3
- 229910052744 lithium Inorganic materials 0.000 description 3
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 3
- 125000001997 phenyl group Polymers [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 3
- RJSZFSOFYVMDIC-UHFFFAOYSA-N tert-butyl n,n-dimethylcarbamate Chemical compound CN(C)C(=O)OC(C)(C)C RJSZFSOFYVMDIC-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 150000001342 alkaline earth metals Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000008395 clarifying agent Substances 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- 150000002191 fatty alcohols Chemical class 0.000 description 2
- LWXVCCOAQYNXNX-UHFFFAOYSA-N lithium hypochlorite Chemical compound [Li+].Cl[O-] LWXVCCOAQYNXNX-UHFFFAOYSA-N 0.000 description 2
- YFVGRULMIQXYNE-UHFFFAOYSA-M lithium;dodecyl sulfate Chemical compound [Li+].CCCCCCCCCCCCOS([O-])(=O)=O YFVGRULMIQXYNE-UHFFFAOYSA-M 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- WMCMCZTWKQMHBE-UHFFFAOYSA-N 1-decoxydecane;sulfuric acid Chemical compound OS(O)(=O)=O.CCCCCCCCCCOCCCCCCCCCC WMCMCZTWKQMHBE-UHFFFAOYSA-N 0.000 description 1
- VZSRBBMJRBPUNF-UHFFFAOYSA-N 2-(2,3-dihydro-1H-inden-2-ylamino)-N-[3-oxo-3-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propyl]pyrimidine-5-carboxamide Chemical compound C1C(CC2=CC=CC=C12)NC1=NC=C(C=N1)C(=O)NCCC(N1CC2=C(CC1)NN=N2)=O VZSRBBMJRBPUNF-UHFFFAOYSA-N 0.000 description 1
- LBLYYCQCTBFVLH-UHFFFAOYSA-N 2-Methylbenzenesulfonic acid Chemical class CC1=CC=CC=C1S(O)(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-N 0.000 description 1
- ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical class CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910000288 alkali metal carbonate Inorganic materials 0.000 description 1
- 229910000318 alkali metal phosphate Inorganic materials 0.000 description 1
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 1
- 229910052936 alkali metal sulfate Inorganic materials 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- 238000005282 brightening Methods 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 235000013365 dairy product Nutrition 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Inorganic materials Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 1
- 229910003002 lithium salt Inorganic materials 0.000 description 1
- 159000000002 lithium salts Chemical class 0.000 description 1
- IRDCEJVOXCGYAV-UHFFFAOYSA-M lithium;2-dodecylbenzenesulfonate Chemical compound [Li+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O IRDCEJVOXCGYAV-UHFFFAOYSA-M 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 239000011777 magnesium Substances 0.000 description 1
- VTHJTEIRLNZDEV-UHFFFAOYSA-L magnesium dihydroxide Chemical compound [OH-].[OH-].[Mg+2] VTHJTEIRLNZDEV-UHFFFAOYSA-L 0.000 description 1
- 239000000347 magnesium hydroxide Substances 0.000 description 1
- 229910001862 magnesium hydroxide Inorganic materials 0.000 description 1
- 159000000003 magnesium salts Chemical class 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000003389 potentiating effect Effects 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- HFQQZARZPUDIFP-UHFFFAOYSA-M sodium;2-dodecylbenzenesulfonate Chemical compound [Na+].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O HFQQZARZPUDIFP-UHFFFAOYSA-M 0.000 description 1
- XZTJQQLJJCXOLP-UHFFFAOYSA-M sodium;decyl sulfate Chemical compound [Na+].CCCCCCCCCCOS([O-])(=O)=O XZTJQQLJJCXOLP-UHFFFAOYSA-M 0.000 description 1
- UPUIQOIQVMNQAP-UHFFFAOYSA-M sodium;tetradecyl sulfate Chemical compound [Na+].CCCCCCCCCCCCCCOS([O-])(=O)=O UPUIQOIQVMNQAP-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- FXZUKHDLJABRQU-UHFFFAOYSA-N sulfuric acid;1-tetradecoxytetradecane Chemical compound OS(O)(=O)=O.CCCCCCCCCCCCCCOCCCCCCCCCCCCCC FXZUKHDLJABRQU-UHFFFAOYSA-N 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/34—Organic compounds containing sulfur
- C11D3/3418—Toluene -, xylene -, cumene -, benzene - or naphthalene sulfonates or sulfates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
- C11D3/3956—Liquid compositions
Definitions
- a liquid detergent bleach composition comprising an aqueous mixture of a detergent, a bleaching or oxidizing agent, and a hydrotrope in :which the components are present in such an amount so as to provide a clear liquid at room temperature is disclosed.
- This invention relates to a stable, liquid detergentbleach composition.
- sodium lauryl ether sulphate which is a commercially available water-soluble detergent, is incompatible with sodium hypochlorite in that when the two are mixed a heavy precipitate of insoluble matter is produced making the product unsuitable as a commercial proposition.
- hydrotropes such as for example, sodium xylene sulphonate, which are known clarifying agents, when added to such a preparation not only produce a liquid which is clear at room temperature and in some cases even down to C., but also that the mixture of the three components retains its detergent power, and retains its oxidising power over a length of time at least substantially equal to that which would be expected from sodium hypochlorite alone.
- the present invention provides a liquid detergent bleach composition, comprising an aqueous mixture of a detergent, a bleaching or oxidising agent, and a hydrotrope which is an alkali metal or alkaline earth metal salt of a monoor polyalkylated benzene or naphthalene sulphonate of which the alkyl groups contain from 1 to 4 carbon atoms, the three components being present in amounts such as to provide a clear liquid at room temperature.
- alkalinity of the composition Whilst such three component compositions are stable, we have also found that there is an optimum level for alkalinity of the composition due to the presence of hydroxyl ions and this alkalinity is preferably between 1 and 2% expressed in terms of free sodium hydroxide, although in fact the alkalinity may be due to other cations provided by compounds such as magnesium hydroxide, potassium hydroxide or lithium hydroxide.
- the optimum alkalinity depends upon the particular formulation and quality of the raw materials. Thus, for example, when the bleaching agent is sodium hypochlorite, it is preferred to use a quality of sodium hypochlorite with the lowest possible sodium chloride content, but a higher content of sodium chloride can be tolerated by appropriate adjustment of the alkalinity of the mixture.
- the detergent of the present composition may be any of those detergents commonly employed and may be used alone, or in admixture with other detergents.
- a first class of detergents which may be employed in the present compositions is the metal alcohol sulphates of which the alcohol contains from 6 to 22 carbon atoms.
- the alcohol may be a synthetic alcohol, a branched chain alcohol or a fatty alcohol.
- the alcohols may be pure or may be mixtures of alcohols, particularly such mixtures of fatty alcohols as are available commercially.
- suitable detergents in this class include sodium lauryl sulphate, sodium decyl sulphate, sodium myristyl sulphate, and the corresponding lithium salts.
- the metal component of the detergents of this class is preferably an alkali metal such as sodium or lithium, or an alkaline earth metal such as magnesium.
- the second class of detergents which may be employed in the present compositions is the metal alcohol ether sulphates, of which the alcohol is the same as that of the first class of detergents and of which the metal is preferably an alkali metal or an alkaline earth metal.
- the alcohol ethers from which the second class of detergents is derived are made by reacting the alcohol with an olefin oxide.
- the preferred alcohol ethers are made by reacting the alcohol with ethylene oxide to give an ethoxylated alcohol of which the average composition comprises from 1 to 4 mols of ethylene oxide per mol of alcohol.
- this class of detergent are sodium lauryl ether sulphate (including the commercially available material which also comprises sodium decyl ether sulphate and sodium myristyl ether sulphate) and lithium lauryl ether sulphate.
- a third class of detergent which may be employed in the present compositions is the alkali metal alkyl aryl sulphonates including for example sodium dodecyl benzene sulphonate and lithium dodecyl benzene sulphonate.
- a fourth class of detergents which may be employed in the present compositions is the oxidation products of fatty amines and derivatives thereof, which products are generally known in the detergent industry as amine oxides and which are employed as detergents in their own right or as builders.
- An example of a suitable detergent in this class is dimethyl cocoamine oxide.
- the detergents may be employed alone or in admixture with one another, including mixtures of detergents within the same class and mixtures of detergents in different classes. While all the above mentioned detergents are compatible with one another, detergents in other classes not specifically mentioned may not be entirely compatible with one another and mixtures of incompatible detergents should be avoided. In particular, it is preferred not to employ mixtures of cationic and anionic detergents.
- the hydrotropes employed in the present compositions are a well known family of clarifying agents comprising the alkali metal or alkaline earth metal salts of monoor polyalkylated benzene or naphthalene sulphonates of which the alkyl groups contain from 1 to 4 carbon atoms.
- the preferred hydrotrope is sodium xylene sulphonate which is commercially available as an unspecified mixture of the isomeric sulphonates, but other hydrotropes, such as the water-soluble alkali metal and alkaline earth metal salts, e.g., the sodium, patassium, lithium and magnesium salts of xylene or toluene sulphonic acid may be used.
- the range of proportions of the three components of the mixture may be varied within wide limits but will generally be interrelated in the sense that the amount of hydrotrope required will depend upon the amount of detergent present and the nature of the detergent and the amount of detergent which may be added to the composition will depend upon the amount of hydrotrope present.
- the ratio by weight of hydrotrope to detergent Will be from 2:1 to 1:2, with a preferred ratio of 1:1 for most general commercial purposes.
- the ratio may depend upon the particular detergent may be increased to 5:1 or more for detergents which are not readily water-soluble, such as sodium lauryl sulphate.
- the amount of bleaching or oxidising agent may be varied widely and the compositions of the present invention include not only compositions which are primarily regarded as bleaching or oxidising compositions and which contain a large amount of bleaching or oxidis ing agent and a small amount of detergent for wetting purposes, such as may be used for sterilizing dairy equipment, but also compositions which are primarily regarded as detergent compositions and which contain a large amount of detergent and a small amount of bleaching or oxidising agent, such as may be used for washing diapers.
- the bleaching or oxidising agent is preferably sodium hypochlorite or lithium hypochlorite, but other agents may be. employed.
- composition may, of course, contain conventional additives such as odorifiers, builders, brightening agents and solubilisers, provided that they are compatible with the bleaching or oxidising agent.
- the amount of detergent, sodium lauryl ethersulphate, determined at the end of the test period was substantially the same as at the beginning,
- compositions which have a clarity at ambient temperature, and 0 C., and stability, comparable to the composition of Example 15.
- a liquid detergent bleach composition consisting essentially of (a) water; (b) a detergent selected from the group consisting of alkali metal and alkaline earth metal alcohol sulphates of which the alcohol contains from 6 to 22 carbon atoms, alkali metal and alkaline earth metal alcohol ether sulphates of which the alcohol contains from 6 to 22 carbon atoms and an average of 1 to 4 moles of ethylene oxide per mole of alcohol, alkali metal alkyl benzene sulphonates and fatty amine oxides; (c) an alkali metal hypochlorite bleaching agent; and (d) a hydrotrope selected from the group consisting of alkali metal and alkaline earth metal salts of monoand polyalkylated benzene and naphthalene sulphonates of which the alkyl groups contain from 1 to 4 carbon atoms; the proportions of the components (a), (b), (c) and (d) being interrelated such as to provide a clear liquid at room temperature.
- composition as claimed in claim 1 wherein the alkalinity of said composition due to the presence of hydroxyl ions and expressed in terms of free sodium hydroxide, is between 1 and 2%.
- composition as claimed in claim 1 wherein the ratio by weight of hydrotrope to detergent in the composition is from 2:1 to 1:2.
- composition as claimed in claim 1, wherein said bleaching agent is selected from the group consisting of sodium hypochlorite and lithium hypochlorite.
- composition as claimed in claim 1, wherein said detergent is sodium lauryl ether sulphate.
- composition as claimed in claim 1, wherein said detergent is sodium or lithium lauryl sulphate.
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Detergent Compositions (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB36041/66A GB1128411A (en) | 1966-08-11 | 1966-08-11 | Detergent-bleach compositions |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3560389A true US3560389A (en) | 1971-02-02 |
Family
ID=10384291
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US661761A Expired - Lifetime US3560389A (en) | 1966-08-11 | 1967-08-08 | Liquid detergent bleach composition |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US3560389A (enrdf_load_stackoverflow) |
| AT (1) | AT294750B (enrdf_load_stackoverflow) |
| DE (1) | DE1617067A1 (enrdf_load_stackoverflow) |
| GB (1) | GB1128411A (enrdf_load_stackoverflow) |
| ZA (1) | ZA674667B (enrdf_load_stackoverflow) |
Cited By (38)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3876551A (en) * | 1972-02-14 | 1975-04-08 | Int Flavors & Fragrances Inc | Perfumed aqueous hypochlorite composition and method for preparation of same |
| US3962112A (en) * | 1974-08-26 | 1976-06-08 | Charles William Shaheen | Composition and process for removing sulfur dioxide from combustion gases |
| US4051056A (en) * | 1974-09-09 | 1977-09-27 | The Procter & Gamble Company | Abrasive scouring compositions |
| US4071463A (en) * | 1975-09-11 | 1978-01-31 | The Dow Chemical Company | Stable cleaning agents of hypochlorite bleach and detergent |
| DE2855776A1 (de) * | 1977-12-22 | 1979-06-28 | Unilever Nv | Fluessiges reinigungsmittel |
| US4235732A (en) * | 1978-02-08 | 1980-11-25 | The Procter & Gamble Company | Liquid bleaching compositions |
| US4240919A (en) * | 1978-11-29 | 1980-12-23 | S. C. Johnson & Son, Inc. | Thixotropic abrasive liquid scouring composition |
| US4282109A (en) * | 1979-05-30 | 1981-08-04 | Reckitt & Colman Products Limited | Aqueous hypochlorite solutions |
| US4289640A (en) * | 1974-01-21 | 1981-09-15 | Colgate-Palmolive Company | Cleaning compositions |
| US4377489A (en) * | 1981-03-16 | 1983-03-22 | Ceil Clean Corporation, Inc. | Inorganic persulfate cleaning solution for acoustic materials |
| US4388204A (en) * | 1982-03-23 | 1983-06-14 | The Drackett Company | Thickened alkali metal hypochlorite compositions |
| US4390448A (en) * | 1981-10-22 | 1983-06-28 | International Flavors & Fragrances Inc. | Perfumed stable aqueous hypochlorite bleach compositions containing 2-methyl-2-octanol and thickened variation thereof |
| US4599186A (en) * | 1984-04-20 | 1986-07-08 | The Clorox Company | Thickened aqueous abrasive scouring cleanser |
| US4657692A (en) * | 1984-04-20 | 1987-04-14 | The Clorox Company | Thickened aqueous abrasive scouring cleanser |
| US4783283A (en) * | 1985-05-28 | 1988-11-08 | The Procter & Gamble Company | Cleaning compositions |
| US4842771A (en) * | 1986-09-29 | 1989-06-27 | Akzo N.V. | Thickened aqueous cleaning compositions |
| US4853146A (en) * | 1987-01-24 | 1989-08-01 | Akzo N.V. | Thickening compositions and thickened aqueous acid solutions |
| US4863633A (en) * | 1987-08-07 | 1989-09-05 | The Clorox Company | Mitigation of stress-cracking in stacked loads of fragranced bleach-containing bottles |
| US4946619A (en) * | 1988-07-19 | 1990-08-07 | The Clorox Company | Solubilization of brighter in liquid hypochlorite |
| US5011538A (en) * | 1987-11-17 | 1991-04-30 | The Clorox Company | Viscoelastic cleaning compositions and methods of use therefor |
| US5034150A (en) * | 1989-05-03 | 1991-07-23 | The Clorox Company | Thickened hypochlorite bleach solution and method of use |
| US5055219A (en) * | 1987-11-17 | 1991-10-08 | The Clorox Company | Viscoelastic cleaning compositions and methods of use therefor |
| US5080826A (en) * | 1987-08-07 | 1992-01-14 | The Clorox Company | Stable fragranced bleaching composition |
| US5227366A (en) * | 1987-08-07 | 1993-07-13 | The Clorox Company | Mitigation of stress-cracking in fragranced bleach-containing bottles |
| US5279758A (en) * | 1991-10-22 | 1994-01-18 | The Clorox Company | Thickened aqueous cleaning compositions |
| EP0594314A1 (en) * | 1992-10-19 | 1994-04-27 | The Clorox Company | Composition and method for developing extensional viscosity in cleaning compositions |
| US5389157A (en) * | 1988-05-20 | 1995-02-14 | The Clorox Company | Viscoelastic cleaning compositions with long relaxation times |
| US5549842A (en) * | 1993-12-29 | 1996-08-27 | Reckitt & Colman Inc. | Thickened alkali metal hypochlorite composition |
| US5705467A (en) * | 1991-10-22 | 1998-01-06 | Choy; Clement K. | Thickened aqueous cleaning compositions and methods of use |
| US5804545A (en) * | 1993-11-24 | 1998-09-08 | West Argo, Inc. | Stable alkaline chlorine compositions |
| US5833764A (en) * | 1987-11-17 | 1998-11-10 | Rader; James E. | Method for opening drains using phase stable viscoelastic cleaning compositions |
| EP0984059A1 (en) * | 1998-09-01 | 2000-03-08 | The Procter & Gamble Company | Bleaching compositions |
| EP0990696A1 (en) * | 1998-10-01 | 2000-04-05 | The Procter & Gamble Company | Stable bleaching compositions |
| EP0992576A1 (en) * | 1998-10-01 | 2000-04-12 | The Procter & Gamble Company | Stable bleaching compositions |
| US6413925B2 (en) | 1998-08-26 | 2002-07-02 | The Clorox Company | Method for increasing brightness retention of laundered fabrics |
| US6506718B1 (en) | 1998-09-01 | 2003-01-14 | The Procter & Gamble Company | Bleaching compositions |
| US9637708B2 (en) | 2014-02-14 | 2017-05-02 | Ecolab Usa Inc. | Reduced misting and clinging chlorine-based hard surface cleaner |
| EP3068759A4 (en) * | 2013-11-13 | 2017-06-28 | The Clorox Company | Mesitylene sulfonate compositions and methods thereof |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL134221C (enrdf_load_stackoverflow) * | 1969-08-29 | Unilever Nv | ||
| FR2570713B1 (fr) * | 1984-09-21 | 1987-08-21 | Lesieur Cotelle | Compositions de nettoyage aqueuses epaissies |
| FR2572419B1 (fr) * | 1984-10-31 | 1988-01-08 | Diversey France | Composition detergente et desinfectante, son utilisation notamment dans le domaine agricole et alimentaire, en particulier dans celui du nettoyage des machines a vendanger |
| NZ218730A (en) * | 1986-01-03 | 1990-04-26 | Bristol Myers Co | Bleaching composition including thickening agent |
| ATE103970T1 (de) * | 1986-09-29 | 1994-04-15 | Akzo Nv | Verdickte, waesserige reinigungsmittel. |
| ES2007221A6 (es) * | 1988-05-05 | 1989-06-01 | Henkel Iberica | Composicion blanqueante a base de hipocloritos alcalinos y procedimiento para su obtencion. |
| US4917814A (en) * | 1988-08-11 | 1990-04-17 | The Drackett Company | Pigmented hypochlorite compositions |
| DE102005062012A1 (de) * | 2005-12-22 | 2007-06-28 | Henkel Kgaa | Handgeschirrspülmittel |
-
0
- ZA ZA674667D patent/ZA674667B/xx unknown
-
1966
- 1966-08-11 GB GB36041/66A patent/GB1128411A/en not_active Expired
-
1967
- 1967-08-08 US US661761A patent/US3560389A/en not_active Expired - Lifetime
- 1967-08-09 AT AT737767A patent/AT294750B/de not_active IP Right Cessation
- 1967-08-10 DE DE19671617067 patent/DE1617067A1/de active Pending
Cited By (49)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3876551A (en) * | 1972-02-14 | 1975-04-08 | Int Flavors & Fragrances Inc | Perfumed aqueous hypochlorite composition and method for preparation of same |
| US4289640A (en) * | 1974-01-21 | 1981-09-15 | Colgate-Palmolive Company | Cleaning compositions |
| US3962112A (en) * | 1974-08-26 | 1976-06-08 | Charles William Shaheen | Composition and process for removing sulfur dioxide from combustion gases |
| US4051056A (en) * | 1974-09-09 | 1977-09-27 | The Procter & Gamble Company | Abrasive scouring compositions |
| US4071463A (en) * | 1975-09-11 | 1978-01-31 | The Dow Chemical Company | Stable cleaning agents of hypochlorite bleach and detergent |
| DE2855776A1 (de) * | 1977-12-22 | 1979-06-28 | Unilever Nv | Fluessiges reinigungsmittel |
| US4235732A (en) * | 1978-02-08 | 1980-11-25 | The Procter & Gamble Company | Liquid bleaching compositions |
| US4240919A (en) * | 1978-11-29 | 1980-12-23 | S. C. Johnson & Son, Inc. | Thixotropic abrasive liquid scouring composition |
| US4282109A (en) * | 1979-05-30 | 1981-08-04 | Reckitt & Colman Products Limited | Aqueous hypochlorite solutions |
| US4377489A (en) * | 1981-03-16 | 1983-03-22 | Ceil Clean Corporation, Inc. | Inorganic persulfate cleaning solution for acoustic materials |
| US4485028A (en) * | 1981-03-16 | 1984-11-27 | Ceil Clean Corporation, Inc. | Inorganic persulfate cleaning solution for acoustic materials |
| US4390448A (en) * | 1981-10-22 | 1983-06-28 | International Flavors & Fragrances Inc. | Perfumed stable aqueous hypochlorite bleach compositions containing 2-methyl-2-octanol and thickened variation thereof |
| US4388204A (en) * | 1982-03-23 | 1983-06-14 | The Drackett Company | Thickened alkali metal hypochlorite compositions |
| US4599186A (en) * | 1984-04-20 | 1986-07-08 | The Clorox Company | Thickened aqueous abrasive scouring cleanser |
| US4657692A (en) * | 1984-04-20 | 1987-04-14 | The Clorox Company | Thickened aqueous abrasive scouring cleanser |
| US4783283A (en) * | 1985-05-28 | 1988-11-08 | The Procter & Gamble Company | Cleaning compositions |
| US4842771A (en) * | 1986-09-29 | 1989-06-27 | Akzo N.V. | Thickened aqueous cleaning compositions |
| US4853146A (en) * | 1987-01-24 | 1989-08-01 | Akzo N.V. | Thickening compositions and thickened aqueous acid solutions |
| EP0518451A1 (en) * | 1987-08-07 | 1992-12-16 | The Clorox Company | Homogeneous fragrance preblend |
| US5080826A (en) * | 1987-08-07 | 1992-01-14 | The Clorox Company | Stable fragranced bleaching composition |
| US5227366A (en) * | 1987-08-07 | 1993-07-13 | The Clorox Company | Mitigation of stress-cracking in fragranced bleach-containing bottles |
| US4863633A (en) * | 1987-08-07 | 1989-09-05 | The Clorox Company | Mitigation of stress-cracking in stacked loads of fragranced bleach-containing bottles |
| US5055219A (en) * | 1987-11-17 | 1991-10-08 | The Clorox Company | Viscoelastic cleaning compositions and methods of use therefor |
| US5833764A (en) * | 1987-11-17 | 1998-11-10 | Rader; James E. | Method for opening drains using phase stable viscoelastic cleaning compositions |
| US5011538A (en) * | 1987-11-17 | 1991-04-30 | The Clorox Company | Viscoelastic cleaning compositions and methods of use therefor |
| US5389157A (en) * | 1988-05-20 | 1995-02-14 | The Clorox Company | Viscoelastic cleaning compositions with long relaxation times |
| US4946619A (en) * | 1988-07-19 | 1990-08-07 | The Clorox Company | Solubilization of brighter in liquid hypochlorite |
| US5034150A (en) * | 1989-05-03 | 1991-07-23 | The Clorox Company | Thickened hypochlorite bleach solution and method of use |
| US5279758A (en) * | 1991-10-22 | 1994-01-18 | The Clorox Company | Thickened aqueous cleaning compositions |
| US5705467A (en) * | 1991-10-22 | 1998-01-06 | Choy; Clement K. | Thickened aqueous cleaning compositions and methods of use |
| EP0594314A1 (en) * | 1992-10-19 | 1994-04-27 | The Clorox Company | Composition and method for developing extensional viscosity in cleaning compositions |
| US5462689A (en) * | 1992-10-19 | 1995-10-31 | The Clorox Company | Composition and method for developing extensional viscosity in cleaning compositions |
| US5916859A (en) * | 1992-10-19 | 1999-06-29 | The Clorox Company | Hexadecyl amine oxide/counterion composition and method for developing extensional viscosity in cleaning compositions |
| TR28567A (tr) * | 1992-10-19 | 1996-10-18 | Clorox Co | Temizleyici bilesimlerde genlesme viskozitesi gelistirmeye mahsus yöntem ve bilesim |
| US5804545A (en) * | 1993-11-24 | 1998-09-08 | West Argo, Inc. | Stable alkaline chlorine compositions |
| US5549842A (en) * | 1993-12-29 | 1996-08-27 | Reckitt & Colman Inc. | Thickened alkali metal hypochlorite composition |
| US6413925B2 (en) | 1998-08-26 | 2002-07-02 | The Clorox Company | Method for increasing brightness retention of laundered fabrics |
| EP0984059A1 (en) * | 1998-09-01 | 2000-03-08 | The Procter & Gamble Company | Bleaching compositions |
| WO2000012668A1 (en) * | 1998-09-01 | 2000-03-09 | The Procter & Gamble Company | Bleaching compositions |
| US6649583B2 (en) | 1998-09-01 | 2003-11-18 | Procter & Gamble Company | Bleaching compositions |
| US6506718B1 (en) | 1998-09-01 | 2003-01-14 | The Procter & Gamble Company | Bleaching compositions |
| EP0990696A1 (en) * | 1998-10-01 | 2000-04-05 | The Procter & Gamble Company | Stable bleaching compositions |
| EP0992576A1 (en) * | 1998-10-01 | 2000-04-12 | The Procter & Gamble Company | Stable bleaching compositions |
| WO2000018866A1 (en) * | 1998-10-01 | 2000-04-06 | The Procter & Gamble Company | Stable bleaching compositions |
| EP3068759A4 (en) * | 2013-11-13 | 2017-06-28 | The Clorox Company | Mesitylene sulfonate compositions and methods thereof |
| US9637708B2 (en) | 2014-02-14 | 2017-05-02 | Ecolab Usa Inc. | Reduced misting and clinging chlorine-based hard surface cleaner |
| US10220421B2 (en) | 2014-02-14 | 2019-03-05 | Ecolab Usa Inc. | Reduced misting and clinging chlorine-based hard surface cleaner |
| US10821484B2 (en) | 2014-02-14 | 2020-11-03 | Ecolab Usa Inc. | Reduced misting and clinging chlorine-based hard surface cleaner |
| US11331696B2 (en) | 2014-02-14 | 2022-05-17 | Ecolab Usa Inc. | Reduced misting and clinging chlorine based hard surface cleaner |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1617067A1 (de) | 1971-02-11 |
| ZA674667B (enrdf_load_stackoverflow) | |
| AT294750B (de) | 1971-12-10 |
| GB1128411A (en) | 1968-09-25 |
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