US3560140A - Method of treating textile materials with liquid ammonia - Google Patents

Method of treating textile materials with liquid ammonia Download PDF

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Publication number
US3560140A
US3560140A US686729A US3560140DA US3560140A US 3560140 A US3560140 A US 3560140A US 686729 A US686729 A US 686729A US 3560140D A US3560140D A US 3560140DA US 3560140 A US3560140 A US 3560140A
Authority
US
United States
Prior art keywords
ammonia
liquid ammonia
textile materials
treatment
treating textile
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US686729A
Other languages
English (en)
Inventor
Robert M Gailey
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
J&P Coats Ltd
Original Assignee
J&P Coats Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by J&P Coats Ltd filed Critical J&P Coats Ltd
Application granted granted Critical
Publication of US3560140A publication Critical patent/US3560140A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M11/00Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
    • D06M11/58Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides
    • D06M11/59Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with nitrogen or compounds thereof, e.g. with nitrides with ammonia; with complexes of organic amines with inorganic substances
    • D06M11/61Liquid ammonia
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06BTREATING TEXTILE MATERIALS USING LIQUIDS, GASES OR VAPOURS
    • D06B7/00Mercerising, e.g. lustring by mercerising
    • D06B7/08Mercerising, e.g. lustring by mercerising of fabrics of indefinite length
    • DTEXTILES; PAPER
    • D06TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06MTREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2101/00Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
    • D06M2101/02Natural fibres, other than mineral fibres
    • D06M2101/04Vegetal fibres
    • D06M2101/06Vegetal fibres cellulosic

Definitions

  • the subject of this invention is a method of treating textile materials of a cellulosic nature.
  • One of the best known methods of treating textile materials of a cellulosic nature to increase the strength and improve the lustre is the method known as mercerizing.
  • the textile materials are normally treated in solutions of certain caustic alkalies, sometimes with application of a slight degree of tension during the process.
  • caustic alkalies There are several disadvantages associated with the performance on any process which uses caustic alkalies, for example, immediately after the treatment the fibre must be washed very thoroughly otherwise it becomes detrimentally affected.
  • liquid ammonia to treat textile materials since liquid ammonia does increase the lustre Without detrimentally affecting the material and can be comparatively easily removed from the material.
  • the previous proposal for using liquid ammonia required only that the textile material should be immersed in the liquid ammonia for a few minutes, after which it is taken out of the ammonia and the ammonia removed from it.
  • the lustre of the material is enhanced by the treatment the strength of the material is little affected.
  • a process of treating textile materials of cellulosic nature consists in first treating the material with liquid ammonia, then subjecting the material to an ammonia-removing treatment and at the same time subjecting the material to a stretching action causing an elongation in the material of between 10% and 30% as measured against the length of the material immediately following the ammonia treatment.
  • the ammonia may be pure liquid ammonia.
  • the ammonia-removing treatment may be a treatment with a hot fluid.
  • the hot fluid may be an aqueous fluid such as water or steam.
  • the ammoniaremoving treatment may consist in bringing the material into a hot zone, e.g. that provided by a heating device such as a hot plate or an oven.
  • the material may be subjected to infra red radiation.
  • the ammoniaremoving treatment may consist of generating heat within the material e.g. by the use of a dielectric heating device or an induction heating device operating at high or radio frequency.
  • the process according to the invention produces an increase in the tensile strength of the textile material which in the case of sewing thread may be as much as 40% and in some cases considerably higher and also improves the lustre.
  • the increase in tensile strength produced by the process according to the invention is far greater than that produced by any previously known process or treatment.
  • the subjection of the material to the previously unknown large degree of stretch stated during the ammonia-removing treatment is an essential part of the process according to the invention and produces the quite unexpected result of the large increase in tensile strength. Extensibility of the material is also reduced and this is a desirable feature as it reduces the tendency to puckering in any fabrics sewn with thread treated by the process.
  • the degree of extensibility and the percentage increase of strength can be adjusted by altering the stretch applied within the range stated.
  • a process of treating cellulosic textile materials comprising contacting the material with liquid ammonia, then removing ammonia from the material and at the same time stretching the material causing an elongation in the material of between 10% and 30% as measured against the length of the material immediately following the ammonia treatment.
  • ammonia-removing treatment is a treatment with a hot fluid.
  • ammonia-removing treatment consists in bringing the material into a hot zone.
  • ammonia-removing treatment consists in subjecting the material to infra red radiation.
  • ammonia-removing treatment consists in generating heat within the material.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Inorganic Chemistry (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatment Of Fiber Materials (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
US686729A 1966-12-02 1967-11-29 Method of treating textile materials with liquid ammonia Expired - Lifetime US3560140A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB53960/66A GB1136417A (en) 1966-12-02 1966-12-02 Method of treating cellulosic textile materials

Publications (1)

Publication Number Publication Date
US3560140A true US3560140A (en) 1971-02-02

Family

ID=10469531

Family Applications (1)

Application Number Title Priority Date Filing Date
US686729A Expired - Lifetime US3560140A (en) 1966-12-02 1967-11-29 Method of treating textile materials with liquid ammonia

Country Status (12)

Country Link
US (1) US3560140A (xx)
AT (1) AT288311B (xx)
BE (1) BE707390A (xx)
CH (2) CH498235A (xx)
DE (1) DE1610928A1 (xx)
DK (1) DK121363B (xx)
ES (1) ES347862A1 (xx)
FR (1) FR1546099A (xx)
GB (1) GB1136417A (xx)
NL (2) NL6716398A (xx)
NO (1) NO127357B (xx)
SE (1) SE358912B (xx)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3767359A (en) * 1971-05-07 1973-10-23 Us Agriculture Process for the liquid ammonia treatment of yarns
US3849067A (en) * 1971-05-07 1974-11-19 Us Agriculture Process for the mercerization of cotton fabrics with liquid ammonia and ammonia/amine solutions
DE2523433A1 (de) * 1974-05-28 1975-12-11 Opi Cryochimie Verfahren zur behandlung von ganz oder teilweise aus cellulosefasern bestehenden materialien mit fluessigem ammoniak
US4199319A (en) * 1978-05-24 1980-04-22 Ivanovsky Nauchno-Issledovatelsky Institut Khlopchatobumazhnoi Promvshlennosti Method for treatment of cotton yarn
US4295847A (en) * 1980-01-25 1981-10-20 Basf Aktiengesellschaft Finishing process for textiles
US4475917A (en) * 1981-09-24 1984-10-09 Asahi Kasei Kogyo Kabushiki Kaisha Process for modifying regenerated cellulose fiber
EP1057919A2 (en) * 1999-05-31 2000-12-06 Nisshinbo Industries Inc. Processor and process for liquid ammonia treatment of hank yarn
CN116924472A (zh) * 2023-09-14 2023-10-24 崇义章源钨业股份有限公司 一种含钨磷酸铵镁渣综合利用的方法

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4189847A (en) * 1977-12-15 1980-02-26 Cluett, Peabody & Co., Inc. Process and apparatus for removal of ammonia in a liquid ammonia fabric treating system
US4871370A (en) * 1987-06-18 1989-10-03 The United States Of America As Represented By The Secretary Of The Agriculture Stable crystalline cellulose III polymorphs
DE4312219C2 (de) * 1993-04-14 2002-05-08 Thueringisches Inst Textil Verfahren zur Reduzierung der Fibrillierbarkeit von lösungsgesponnenen Cellulosefasern

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3767359A (en) * 1971-05-07 1973-10-23 Us Agriculture Process for the liquid ammonia treatment of yarns
US3849067A (en) * 1971-05-07 1974-11-19 Us Agriculture Process for the mercerization of cotton fabrics with liquid ammonia and ammonia/amine solutions
DE2523433A1 (de) * 1974-05-28 1975-12-11 Opi Cryochimie Verfahren zur behandlung von ganz oder teilweise aus cellulosefasern bestehenden materialien mit fluessigem ammoniak
US4213761A (en) * 1974-05-28 1980-07-22 Dalle Jean Paul Process for treating cellulosic materials with liquid ammonia
US4199319A (en) * 1978-05-24 1980-04-22 Ivanovsky Nauchno-Issledovatelsky Institut Khlopchatobumazhnoi Promvshlennosti Method for treatment of cotton yarn
US4295847A (en) * 1980-01-25 1981-10-20 Basf Aktiengesellschaft Finishing process for textiles
US4475917A (en) * 1981-09-24 1984-10-09 Asahi Kasei Kogyo Kabushiki Kaisha Process for modifying regenerated cellulose fiber
EP1057919A2 (en) * 1999-05-31 2000-12-06 Nisshinbo Industries Inc. Processor and process for liquid ammonia treatment of hank yarn
EP1057919A3 (en) * 1999-05-31 2001-10-10 Nisshinbo Industries Inc. Processor and process for liquid ammonia treatment of hank yarn
CN116924472A (zh) * 2023-09-14 2023-10-24 崇义章源钨业股份有限公司 一种含钨磷酸铵镁渣综合利用的方法

Also Published As

Publication number Publication date
NL136750C (xx)
CH498235A (fr) 1970-05-29
GB1136417A (en) 1968-12-11
BE707390A (xx) 1968-04-16
DE1610928A1 (de) 1970-07-16
AT288311B (de) 1971-02-25
NO127357B (xx) 1973-06-12
SE358912B (xx) 1973-08-13
DK121363B (da) 1971-10-11
ES347862A1 (es) 1969-02-16
FR1546099A (fr) 1968-11-15
NL6716398A (xx) 1968-06-04
CH1693767A4 (xx) 1970-05-29

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