US3521997A - Continuous process for treating wool with chlorocyanurate - Google Patents

Continuous process for treating wool with chlorocyanurate Download PDF

Info

Publication number
US3521997A
US3521997A US629321A US3521997DA US3521997A US 3521997 A US3521997 A US 3521997A US 629321 A US629321 A US 629321A US 3521997D A US3521997D A US 3521997DA US 3521997 A US3521997 A US 3521997A
Authority
US
United States
Prior art keywords
fibres
treated
wool
solution
chlorocyanurate
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US629321A
Other languages
English (en)
Inventor
Ronald N Barber
James E Madden
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IWS Nominee Co Ltd
Original Assignee
IWS Nominee Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IWS Nominee Co Ltd filed Critical IWS Nominee Co Ltd
Application granted granted Critical
Publication of US3521997A publication Critical patent/US3521997A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
    • D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
    • D06M13/35—Heterocyclic compounds
    • D06M13/355—Heterocyclic compounds having six-membered heterocyclic rings
    • D06M13/358—Triazines
    • D06M13/364—Cyanuric acid; Isocyanuric acid; Derivatives thereof

Definitions

  • Wool fibres are apt to shrink when brought into contact with water, especially when the fibres, or articles made from them, are washed mechanically. It has been proposed to increase the resistance of wool fibres to shrinking by treating them with a dilute solution of an alkali metal salt of a chlorocyanuric acid. A measure of success has been achieved in this way, but these processes have a number of important practical disadvantages. Some of the processes require much equipment, others are very slow and cannot be used for continuous treatments, which are essential if large quantities of material are to be processed cheaply and conveniently. Yet other processes operate under conditions which raise severe corrosion problems.
  • wool fibres are continuously treated by a process which comprises passing the fibres into an impregnation zone wherein the fibres are impregnated with an aqueous solution containing at least 1% by weight of an alkali metal chlorocyanurate and having a pH in the range of -7, transferring the treated fibres to a residence zone, where they are kept for a period of at least half a minute and thereafter treating the fibres with a dechlorinating agent.
  • the successful operation of the process is especially dependent upon the pH of the solution, which can be neutral but which preferably is very slightly acid, the optimum pH range being 5.5-6.5.
  • Some wool fibres have an alkaline reaction and some acid may be required to ensure that the pH is within the desired range.
  • Various acids can be used, although water-soluble aliphatic carboxylic acids, for example formic, acetic or lactic acid, are preferred.
  • the pH can be adjusted simply by addition of the acids to the bath in which the fibres are to be impregnated.
  • the process can be applied to different forms of wool fibres, such as raw wool, combed or carded skeins, yarns, woven fabrics, knitted goods and finished articles such as blankets and clothing.
  • the material to be treated can consist wholly of wool fibres or blends of wool fibres with other natural or synthetic fibrous or filamentary materials. In general, however, the material should contain at least by weight of Wool fibres.
  • alkali metal chlorocyanurates can be used, for example, potassium and sodium salts of dichloroisocyanuric acid. Very satisfactory results have been obtained by using sodium dichloroisocyanurate which is sold under the tradename Ficlor 60S, BASOLAN DC and ORCED.
  • the amount of the chlorocyanurate which is required depends on the amount of solution applied to the fibres but is not less than 1% by weight of the solution and can be as high as 12%. For example, if the fibres are to be treated with by weight of the solution the latter preferably contains 612% by weight of the chlorocyanurate. If however, greater quantities of the solution are to be applied, then the concentration of the chlorocyanurate can be correspondingly less. Thus, if the fabrics are to be treated with 100% by weight of the solution the latter preferably contains from 3-6% by Weight of the chlorocyanurate.
  • the solution can be applied to the fibres in any convenient way, for example it can be sprayed onto the fibres or the latter can be passed through a bath containing the solution. Especially good results have been obtained by impregnating the fibres as rapidly as possible, notably within about 10 seconds, by immersing them in a bath of the solution containing both the salt and a wetting agent and thereafter expressing a proportion of the solution from the fibres so as to leave from 25 to 200% by Weight of the solution on the fibres.
  • a very satisfactory method of application uses a padding technique in which the pressure on the pad rollers is preferably adjusted to leave on the fibres between 50 and by weight of the treating solution.
  • the solution of the chlorocyanurate can be applied at ambient or elevated temperatures, preferably at l535 C. and especially at 20-25" C.
  • the solution can contain other ingredients.
  • a wetting agent is preferably included, and should be compatible with the chlorocyanurate. Especially good results have been obtained with non-ionic wetting agents.
  • the amount of wetting agent used is generally small, for example 0.2- 0.8% and preferably from DA-0.5% by weight of the solution.
  • the fibres are preferably kept in the residence zone for a predetermined period of between /2 and 4 minutes, during which time the reaction between the chlorocyanurate and the fibres proceeds.
  • the residence zone can be merely the region between the impregnating zone and the vessel containing the dechlorinating agent, provided it is large enough to ensure that the treated fibres remain in it for the desired time. In practice it is preferable to provide apparatus such as a separate container, or a festoon or slide attached to a padding machine, where the treated fibres can accumulate and remain in contact with the air for the required time before dechlorination is effected.
  • the first bowl contains just sufficient of the chlorocyanurate solution to cover the pair of guide rollers 4, so that the material to be treated is in contact with the liquid for as short a time as possible, preferably for not more than 10 seconds.
  • the second bowl 2 is empty and constitutes the residence zone and bowl 3 contains a dechlorinating liquid.
  • the relative speeds of the pairs of rollers 7, 8, and 9 can be adjusted so that the treated material can be allowed to accumulate and to remain for the desired period in bowl 2 before it is withdrawn and discharged into the bowl containing the dechlorinating liquid, which is preferably an aqueous solution of an alkali metal sulphite or bisulphite or a mixture of both, or a solution of hydrogen perioxide.
  • This solution deactives any chlorocyanurate remaining on the fibres and improves the colour of the treated material.
  • EXAMPLE 1 W001 fibres of 64s quality in sliver form were treated in the padding machine shown in FIG. 1 with an aqueous solution containing 4% by weight of Ficlor 60S and 0.5 by weight of a trimethylnonanol ethoxylate nonionic wetting agent (Tergitol TMN), The pH and the temperature of the solution were respectively 6.4 and 18 C., and the fibres retained 100% of their own weight of the solution, which is equivalent to 4% Ficlor on the weight of the fibres.
  • the speed of the rollers 7, 8, and 9 was varied to give different residence periods in the empty second bowl before dechlorination in an aqueous solution containing by weight of sodium bisulphite at 50 C. The treated sliver was then withdrawn from the dechlorinating bath and rinsed thoroughly.
  • a piece of the treated sliver of known length was wrapped in cheese cloth and vigorously washed in a mechanical washing machine for periods of 30 and 60 minutes, after which it was removed and dried, and the reduction in length determined and expressed as a percentage of the original length. For purposes of comparison a similar test was carried out on untreated sliver.
  • EXAMPLE 2 Lengths of two different fabrics, having cover factors (C.F.) of 1.0 and 1.2 respectively and knitted from yarns consisting wholly of wool fibres of 64s quality, were treated in the padding machine shown in FIG. 1 with an aqueous solution containing 4.0% by Weight of Ficlor 605. The pH and the temperature of the solution were 4 respectively 6.4 and 18 C., and each of the lengths retained by weight of the solution. Each length of fabric remained in the second bowl for a period of 30 seconds to allow further reaction to take place, where after it passed into the dechlorinating liquid consisting of an aqueous solution containing 2% by weight of sodium sulphite and 3% by weight of sodium bisulphite at 45 C. Treated and untreated fabric were subjected to the same washing test as in Example 1, shrinkage being expressed as a percentage reduction in area.
  • C.F. cover factors
  • Hand knitting yarn was treated by passing the yarn through the padding machine shown in FIG. 1 to take up 70% by weight of an aqueous solution of 5% by Weight of Ficlor 608.
  • the pH and temperature of the solution were respectively 6.4 and 18 C.
  • the treated wool was passed into a dechlorinating bath containing an aqueous solution of 5% by weight sodium bisulphite at 45 C.
  • the wool was then rinsed, dried and knitted into a 1 X l rib fabric having a cover factor of 0.8.
  • the fabric was then washed for one hour in a domestic washing machine and was found to have suffered a reduction in area of 4.0%.
  • a similar piece of fabric which had not been treated with Ficlor was reduced in area by 45% when subjected to the same washing test.
  • EXAMPLE 4 An aqueous solution of 4% sodium dichloroisocyanurate by weight was made containing 0.5% by weight TERGITOL TMN, a trimethylnonanol ethoxylate nonionic wetting agent. 50 kg. of 64s quality wool top slivers were padded through the solution and the squeeze roller pressure adjusted so that the fibres retained their own weight of solution. The solution was at ambient temperature (approximately 20 C.) and had a pH of 6.5.
  • the slivers were fed into the top of an inclined curved slide and allowed to move down the slide, the lower end of which was situated next to the following treatment tank.
  • the slivers remained on the slide for 2 minutes before they passed through three baths of a standard industrial backwash machine, containing respectively:
  • the treated material was found to have an excellent handle, and the colour was substantially better than that of wool which had been treated by conventional shrinkresist processes using dichloroisocyanuric acid or salts.
  • EXAMPLE 6 50 kg. of 64s quality dry combed wool top slivers were treated as in Example 4, except that the three backwash baths were made up as follows:
  • Percent length shrinkage, minutes 1 A process for increasing the shrink resistance of wool fibres consisting essentially of continuously passing wool fibres into an impregnation zone and impregnating the fibres with an aqueous solution at 15-35 C. containing at least 1% by weight of an alkali metal chlorocyanurate at "a pH of 5-7; continuously transferring the impregnated fibres into a residence zone and maintaining the fibres in the residence zone in contact with atmospheric air for a predetermined period of time between 0.5-4.0 minutes; and treating the fibres with an aqueous solution containing an alkali metal sulfite or bisulfite, or hydrogen peroxide.
  • chlorocyanurate-containing solution contains from 3-6% by weight of alkali metal chlorocyanurate.
  • alkali metal chlorocyanurate is sodium dichloroisocyanurate.
  • fibres are in the form of a sliver.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
US629321A 1966-04-15 1967-04-07 Continuous process for treating wool with chlorocyanurate Expired - Lifetime US3521997A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB1674266 1966-04-15
GB39835/66A GB1177503A (en) 1966-04-15 1966-04-15 Improvements in the Treatment of Wool.

Publications (1)

Publication Number Publication Date
US3521997A true US3521997A (en) 1970-07-28

Family

ID=26252215

Family Applications (1)

Application Number Title Priority Date Filing Date
US629321A Expired - Lifetime US3521997A (en) 1966-04-15 1967-04-07 Continuous process for treating wool with chlorocyanurate

Country Status (8)

Country Link
US (1) US3521997A (de)
BE (1) BE697008A (de)
DE (1) DE1619099A1 (de)
ES (1) ES339671A1 (de)
FR (1) FR1519140A (de)
GB (1) GB1177503A (de)
NL (1) NL6705292A (de)
SE (1) SE324552B (de)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3883300A (en) * 1972-06-28 1975-05-13 Stevens & Co Inc J P Process for reducing shrinkage and improving crease retention of wool-synthetic fiber blends
CN112176726A (zh) * 2020-10-11 2021-01-05 浙江梦森服饰有限公司 一种具有防皱功能的强触感羊毛面料的制备方法
CN116065385A (zh) * 2023-02-20 2023-05-05 张家港天宇精梳羊毛有限公司 一种具有防缩功能的巴素兰羊毛条生产加工方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
None *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3883300A (en) * 1972-06-28 1975-05-13 Stevens & Co Inc J P Process for reducing shrinkage and improving crease retention of wool-synthetic fiber blends
CN112176726A (zh) * 2020-10-11 2021-01-05 浙江梦森服饰有限公司 一种具有防皱功能的强触感羊毛面料的制备方法
CN112176726B (zh) * 2020-10-11 2023-02-10 浙江梦森服饰有限公司 一种具有防皱功能的羊毛面料的制备方法
CN116065385A (zh) * 2023-02-20 2023-05-05 张家港天宇精梳羊毛有限公司 一种具有防缩功能的巴素兰羊毛条生产加工方法

Also Published As

Publication number Publication date
DE1619099A1 (de) 1971-05-27
GB1177503A (en) 1970-01-14
SE324552B (de) 1970-06-08
FR1519140A (fr) 1968-03-29
NL6705292A (de) 1967-10-16
ES339671A1 (es) 1968-05-16
BE697008A (de) 1967-09-18

Similar Documents

Publication Publication Date Title
US2112499A (en) Treated artificial thread and method of producing same
US2284895A (en) Treatment of textiles to impart water-repellence
US2158494A (en) Treatment of textile materials
US2173040A (en) Desizing textiles
US3290752A (en) Woven cotton-polyester blend fabrics having recoverable stretch characteristics
US2205120A (en) Process for rendering cellulosecontaining material crease-resistant and products obtained thereby
US4008044A (en) Treatment of polyester textiles to improve soil release and wettability properties
JPH08502789A (ja) 羊毛の処理方法
US3521997A (en) Continuous process for treating wool with chlorocyanurate
US3644137A (en) Method of applying processing liquors to textile materials and apparatus therefor
Liljemark et al. Soil-Release Properties Imparted to Polyester/Cotton Fabrics by Alkali Treatment
US2497519A (en) Art of stabilizing rayon type fabric
US2702737A (en) Wool chlorination process
US4189303A (en) Method of shrinkproofing animal fibers with ozone
US3265462A (en) High-speed two-stage bleaching of cotton cloth
US1661879A (en) Treatment of cellulosic materials
US2466695A (en) Method of treating wool
US4095944A (en) Treatment of textile materials
US3932124A (en) Process for setting textiles
US2499987A (en) Process for imparting shrink resistance to wool
US2729535A (en) Process of making alkali-insoluble cellulose glycolic acid ether fabric
GB982518A (en) Improvements in the cleaning and bleaching of cotton textile materials
US3477805A (en) Process for modifying keratin fibers
US2527141A (en) Treatment of cotton fabrics with urea-alkali-zincate solution
JPS5950788B2 (ja) 編地のマ−セライズ加工方法