US3503885A - Color stable washing,rinsing and cleaning composition - Google Patents

Color stable washing,rinsing and cleaning composition Download PDF

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Publication number
US3503885A
US3503885A US594409A US3503885DA US3503885A US 3503885 A US3503885 A US 3503885A US 594409 A US594409 A US 594409A US 3503885D A US3503885D A US 3503885DA US 3503885 A US3503885 A US 3503885A
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weight
agents
dichloro
chloro
hydroxy
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US594409A
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Hans Wedell
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Henkel AG and Co KGaA
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Henkel AG and Co KGaA
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    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/48—Medical, disinfecting agents, disinfecting, antibacterial, germicidal or antimicrobial compositions
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0042—Reducing agents

Definitions

  • This invention relates to surfactant compositions. It more particularly refers to such surfactant compositions which are relatively stable with respect to color changes therein.
  • Liquid washing, rinsing and cleaning agents are quite well known. They generally comprise aqueous solutions of anionic or non-ionic surfactants which may or may not have the conventional additive substances admixed therewith. These agents are generally used for the washing of textiles or for the cleaning of surfaces of other solid materials, such as surfaces of glasses or ceramic materials, plastics, varnished and polished surfaces which may also be of a metallic nature.
  • One preferred field of used is the rinsing of dishes and other implements used in the kitchen. Insofar as these cleaning processes are effected by hand, they are effected at slightly elevated temperatures at which injurious microorganisms and particularly pathogenic germs are not effected. It has, therefore, been proposed to add ordinary bacteriocides to these liquid washing and cleaning agents.
  • liquid preparations containing anionic and/ or non-ionic surface-active agents and disinfectants often discolor, particularly where there has been a relatively long shelf time.
  • one aspect of this invention includes a surfactant composition
  • a surfactant composition comprising at least one anionic and/or non-ionic surfactant, at least one organic disinfectant, and at least one watersoluble reducing agent.
  • the composition medium may be water.
  • surfactant in a proportion of about to 40 weight percent, the organic disinfectant in a proportion of about 0.1 to 5 weight percent and the reducing agent in a proportion of about 0.01 to 5 weight percent, each based upon the total amount of surfactant and disinfectant utilized.
  • the surfactant may be non-ionic or anionic in character.
  • Anionic surfactants are in general within the scope of this invention.
  • Illustrative of the types of anionic surfactants included herein, are those having at least one hydrophobic group of about 8 to 24 carbon atoms, generally in an aliphatic or alicyclic configuration. It is within the spirit and scope of this invention to utilize either saturated or unsaturated hydrophobic groups, e.g.
  • hydrophobic group is suitably joined to an anionic water-solubilizing group, either directly or via an intermediate or bridging group.
  • a bridging group it may for example be a benzene ring, a carboxylic acid ester, a carbon amide or an alkylene glycol group, e.g. ethylene or propylene glycol.
  • anionic wash-active substances there can be used soaps derived from natural or synthetic fatty acids, and possibly also from resin and naphthenic acids.
  • synthetic anionic surfactants are the sulfonates, for instance the alkylaryl sulfonates and particularly alkyl benzene sulfonates having about 9-15 carbon atoms in the alkyl radical.
  • sulfonates for instance the alkylaryl sulfonates and particularly alkyl benzene sulfonates having about 9-15 carbon atoms in the alkyl radical.
  • interest aliphatic surfactants such as can be formed from preferably saturated hydrocarbons containing about 9 to 15 carbon atoms in the molecule by sulfochlorination with sulfur dioxide and chlorine, or sulfoxidation with sulfur dioxide and oxygen and conversion of the resultant intermediate products into the sulfonates in the conventional manner.
  • the sulfonate group is usually on a secondary carbon atom; however, there can also be used aliphatic sulfonates obtained by known methods whose sulfonate group is on a primary carbon atom.
  • aliphatic sulfonates there can, furthermore, be employed products which can be obtained by sulfonation with sulfur trioxide of terminal or non-terminal C C olefins.
  • the sulfonates which are to be used in accordance with the invention also include the esters of an a-sulfo fatty acids with monohydric or polyhydric alcohols containing 1 to 4 and preferably 1 to 2 carbon atoms.
  • anionic surfactants of the sulfate type there may be mentioned fatty alcohol sulfates, sulfated fatty acid alkylolamides, sulfated fatty acid monoglycerides and the sulfonation products of ethoxylated and/or propoxylated fatty alcohols, alkyl phenols having about 8 to 15 carbon atoms in the alkyl radical, fatty acid amides, fatty acid alkylolamides, etc., about 1 to 8, and preferably about 2 to 4, glycol ether groups being possibly present in a molecule.
  • Sulfonation products of the sulfate type which can be used in the invention can also be prepared from terminal or non-terminal C -C olefins.
  • non-ionic surfactants there are preferred the addition products of alkyleneoxide, e.g. ethylene oxide, propylene oxide and/or the addition products of ethylene oxide and propylene oxide, to fatty alcohols, fatty acids, alkyl phenols, fatty acid amides, fatty acid alkylolamides and similar compounds having at least one reactive hydrogen atom.
  • alkyleneoxide e.g. ethylene oxide, propylene oxide and/or the addition products of ethylene oxide and propylene oxide
  • fatty alcohols e.g. ethylene oxide, propylene oxide and/or the addition products of ethylene oxide and propylene oxide
  • fatty alcohols e.g. ethylene oxide, propylene oxide and/or the addition products of ethylene oxide and propylene oxide
  • fatty alcohols e.g. ethylene oxide, propylene oxide and/or the addition products of ethylene oxide and propylene oxide
  • fatty alcohols e.g. ethylene oxide, propylene oxide and/or
  • foaming power of the prepartions of the invention can be increased or reduced by suitable combinations of different wash-active substances.
  • foam stabilizers there are particularly suited the well-known fatty acid alkylolamides and particularly the fatty acid monoethanol amides.
  • foam inhibitors there can be used inter-alia addition products of propylene oxide to the non-ionic polyethylene glycol ethers described above.
  • anionic or non-ionic surfactants are derived from fatty acids or fatty alcohols, they can preferably contain 12 to 14 carbon atoms per fatty acid or fatty alcohol radical.
  • the disinfectants which can be used in accordance with the invention include preferably the halogenated phenol, the halogenated diaryl or cycloalkyl urea and the halogenated N-aryl-, or cycloalkyl saliscylylamide types; however, these compounds should not have any oxidizing properties, i.e. the halogen atoms are to be bound to carbon.
  • Aryl groups may be exemplified by phenyl, xylyl, biphenyl, naphthyl, etc.
  • Cycloalkyl groups may be exemplified by cyclohexyl, cyclopentyl, cyclooctyl, methyl cyclohexyl, etc.
  • halogenated phenol types include, for instance, chlorination and bromination products of phenol such as pentachlorophenol, and furthermore halogenated cresols, xylenols such as for instance 4-bromo-3,5-xylenol, or halogenated cyclohexyl-, methylcyclohexyl or benzyl phenols; chlorobenzyl phenol; bis(halo hydroxy phenyl)- alkylene; bis(halo hydroxy phenyl)-sulfide; bis(halo hydroxy phenyl)-alkylidene; halophenyl urea; and N-halo phenyl-halo-hydroxy phenyl formamide.
  • halophenol ureas include 4,3',4-trichloro-N,N-diphenyl urea and 3,3,4-trichloro-N,N-diphenyl urea.
  • Compounds of the halogenated bisphenol type can also be ⁇ .lSfid. They can, for instance, have the following formu a:
  • X and Y are halogen atoms such as chlorine or bromine, m and n are whole numbers from 1 to 3 and R is a bivalent radical such as sulfur, or alkylene or alkylidene radicals containing about 1 to 4 carbon atoms.
  • the halo genated bisphenols which can.
  • N 1-1-0 0 NH--R of R can be taken, for instance, by the following radicals: 2-chlorophenyl-, 3-chlorophenyl, 4-chlorophenyl-, 3- brornophenyl-, 4-bromophenyl-, 2,4-dichlorophenyl, 2,3 dichlorophenyl-, 3,4,5 trichlorophenyl-, 3,4,5 tribromophenyl-, 3 chloro 4 methylphenyl, 4 chloro 3-methylphenyl-, 4-chlor-2-methylphenyl, 2,5-dichloro-4- methylphenyl-, 4-chloro-3,5-dimethylphenyl-, 4-chloro-4- ethylphenyl, 3-chloro-4-isopropylphenyl-, 3-chloro-4-n butyl-phenyl-, 3 chloro 4 tert.-butylphenyl-, chlorobiphenyl, etc. There are preferably used 3,
  • R is hydrogen, chlorine or bromine
  • X or X are hydrogen, chlorine, bromine, iodine and/or CH
  • X is hydrogen, chlorine, bromine, or trifiuoromethyl
  • X is hydrogen, chlorine or bromine, at least three f the X substituents being halogen atoms.
  • disinfectants to be combined can belong to the same type; how ever, members of different of the above-mentioned types of disinfectants can also be incorporated jointly into the products in accordance with the invention.
  • a mixture of approximately equal parts of 4',5- dibromosalicylanilide and 3,4S-tribromosalicylanilide has proven useful.
  • surfactants and the bactericidal sub stances there can also be present other addition substances which either improve the homogeneity of the preparations or make them more suitable for special purposes of use, for instance as textile washing agents.
  • hydrotropic substances and/or sedimentation stabilizers may be added thereto.
  • hydrotropic substances water-soluble organic solvents having boiling points of at least 70 C., such as the aliphatic mono-alcohols having about 2 to 4 carbon atoms as well as ether alcohols having about 3 to 10 car bon atoms, for instance the mono-ethers of mono-, di or triethylene glycol with methyl, ethyl, propyl or butyl alcohols, as well as water-soluble partial ethers of said monohydric alcohols with glycerin, di-glyoerin or tri-glycerin, etc. have been found to be useful.
  • lower aromatic sulfonates such as benzene, to u ene, xylene or naphthalene sulfonate.
  • Urea can also be used as hydrotropic substance.
  • Stability upon storage and, in particular, sedimentation stability can be obtained where required by incorporating water-soluble thickening agents.
  • water-soluble thickening agents include, for instance, salts of polyacrylic acid or polyrnethacrylic acid.
  • compositions of this invention can also contain phosphates such as pyroand tripolyphosphates.
  • phosphates such as pyroand tripolyphosphates.
  • These phosphates can be replaced in whole or in part by other coingexing agents, such as the salts of nitrilotriacetic acid or e ylene diaminotetra-acetic acid.
  • coingexing agents such as the salts of nitrilotriacetic acid or e ylene diaminotetra-acetic acid.
  • the quantity of these phosphates and/ or complexing agents depends on the field of use; cleaning agents for surfaces of solid materia s, particularly for dishwashing agents, frequently contain only such quantities of phosphates and/or other complexing agents as dissolve in the aqueous phase. In the case of fine washing agents or other textile washing agents on the other hand, it is advisable to incorporate larger quantities of phosphates and/or other complexing atogethers which are then to be sure suspended as undissolved
  • skin-protecting surfactants there are recommended, in addition to the indicated nononics, the'sulfation products of non-ionics and, in particular, the sulfated addition products of about 1 to 20, and preferably about 6 to 18, mols of ethylene oxide to fatty alcohols.
  • fatty alcohols as well as other water-insoluble fatty substances which contain hydroxyl groups such as, for instance, fatty acid mono-glycerides, fatty acid monoethylene glycol esters, etc. These substances are present in dispersed condition in the liquid washing agents and thus cause such compositions to appear to be cloudy. If desired, one can also of course incorporate other clouding agents such as polystyrene dispersions.
  • liquid washing agents present on the market are differently colored, for instance red, orange, yellow, green, blue or violet. These colors may be very soft pastel shades or stronger colors as desired.
  • red, orange, yellow, green, blue or violet may be very soft pastel shades or stronger colors as desired.
  • the changes in color by the action of sun make themselves unpleasantly perceptible.
  • These discolorations can be observed both in the case of glass, or plastic containers. Such discoloration is particularly noticeable with uncolored glass or plastic or with transparent containers. Colored containers make the discoloration less apparent but do not prevent the composition from discoloring.
  • compositions in accordance with the invention are in the form of aqueous solutions which contain:
  • solubilizers Up to about 20% by weight and preferably about 10 to by weight of solubilizers;
  • 0t clouding agents such as polystyrene, ethylene glycol distearate, etc.
  • buffer substances such as fragrances, preservatives, coloring substances, etc.
  • the disinfectants present in the dishwashing agents in accordance with the invention show their action not only in the washing solution and on materials washed, particularly' dishes, but also on the dishcloths used for the washing. Since these dishcloths frequently lie moist after the washing, they develop a musty odor which in all probability is due to the development of microorganisms. With use of the washing agents in accordance with the invention, this undesired development of odor is avoided.
  • a composition consisting essentially of about to 40 weight-percent of at least one surfactant selected from the group consisting of natural and synthetic anionic and synthetic non-ionic surfactants, about 0.1 to 5 weightpercent of at least one halogenated organic disinfectant selected from the group consisting of halogenated phenols, halogenated bisphenols, halogenated diarylureas, halogenated N-aryl-salicylamides, halogenated carbanilides and halogenated salicylanilides and about 0.01 to 5 weightpercent of at least one water soluble inorganic reducing agent selected from the group consisting of hydrazine sulfate, hydroxylamine hydrochloride, sodium dithionite.
  • surfactant selected from the group consisting of natural and synthetic anionic and synthetic non-ionic surfactants
  • halogenated organic disinfectant selected from the group consisting of halogenated phenols, halogenated bisphenols, halogenated diarylureas, hal
  • a composition according to claim 1 wherein said disinfectant is at least one selected from the group consisting of 4-bromo-3,5-xylenol; bis-(2-hydroxy- 3,5,6-trichlorophenyl)-methane; bis-(2-hydroxy-4,S-dichlorophenyl)-methane; bis-(2-hydroxy-3,4-dichlorophenyl) methane; bis-(2-hydroxy-5-chlorophenyl)-methane; bis-(2-hydroxy-S-bromophenyl)-methane; bis (2-hydroxy-3,5-dichlorophenyl)-sulfide; bi (2-hydroxy-5-chlorophenyl)- sulfide; 2-chlorophenyl dichloro carbanilide; 3-chlorophenyl dichloro carbanilide; 4 bromophenyl dichloro carbanilide; 2,4-dichlorophenyl-dichloro carbanilide; 2,3- dichlor
  • composition according to claim 1 wherein said composition additionally contains up to about 20 weightpercent of a water-soluble organic solvent, up to 35 weight-percent of at least one complexing agent selected from the group consisting of water soluble anhydous'phosphate and up to about 3 weight-percent of at least one clouding agent selected from the group consisting of polystyrene and ethylene glycol distearate.
  • a water-soluble organic solvent up to 35 weight-percent of at least one complexing agent selected from the group consisting of water soluble anhydous'phosphate and up to about 3 weight-percent of at least one clouding agent selected from the group consisting of polystyrene and ethylene glycol distearate.
  • composition according to claim 1 consisting essentially of:
  • composition according to claim 1 consisting essentially of;
  • a composition according to claim 1 consisting essentially of Percent Ethanolamine salt of an a-sulfo fatty acid ethylester with 12 to 18 carbon atoms in the fatty acid radical 5
  • coconut fatty acid diethanolamide 5
  • Ethylene glycol distearate 1
  • Ethylene diamine tetra-acetate 1
  • O-phenyl phenol 0.8
  • Potassium pyrophosphate 10 Water Balance (References on following page) 9
US594409A 1965-11-27 1966-11-15 Color stable washing,rinsing and cleaning composition Expired - Lifetime US3503885A (en)

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DEH0057793 1965-11-27

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US (1) US3503885A (de)
BE (1) BE690213A (de)
CH (1) CH484268A (de)
DE (1) DE1467619A1 (de)
ES (1) ES333834A1 (de)
FR (1) FR1501612A (de)
NL (1) NL6615294A (de)
SE (1) SE317765B (de)

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3897357A (en) * 1972-12-06 1975-07-29 American Home Prod Bacteriostatic toilet bowl cleaner compositions
US3925227A (en) * 1972-05-31 1975-12-09 American Home Prod Novel laundering compositions
US3933671A (en) * 1974-02-27 1976-01-20 The Procter & Gamble Company Germicidal cleaning composition and method
US3968250A (en) * 1971-06-21 1976-07-06 Wave Energy Systems, Inc. Method and sporicidal compositions for synergistic disinfection or sterilization
US4048336A (en) * 1974-04-22 1977-09-13 West Chemical Products, Incorporated Means for killing bacterial spores with glutaraldehyde sporicidal compositions
US4093744A (en) * 1971-06-28 1978-06-06 West Laboratories, Inc. Killing bacterial spores with glutaraldehyde sporicidal compositions
US4140649A (en) * 1976-09-27 1979-02-20 Eduard Bossert Method and composition for cleaning the surfaces of foods and fodder
US4329247A (en) * 1980-11-06 1982-05-11 Pdi, Inc. Stain remover for vinyl materials
US4446043A (en) * 1981-09-01 1984-05-01 Lever Brothers Company Built liquid detergent compositions
US4468338A (en) * 1983-06-13 1984-08-28 Purex Corporation Transparent soap composition
US4803008A (en) * 1987-09-23 1989-02-07 The Drackett Company Cleaning composition containing a colorant stabilized against fading
US4822854A (en) * 1987-09-23 1989-04-18 The Drackett Company Cleaning compositions containing a colorant stabilized against fading
US5726142A (en) * 1995-11-17 1998-03-10 The Dial Corp Detergent having improved properties and method of preparing the detergent
US6362152B1 (en) 2000-04-07 2002-03-26 The Dow Chemical Company Low color and low haze formulations of sodium o-phenylphenate
WO2002048298A1 (en) * 2000-12-14 2002-06-20 Ciba Specialty Chemicals Holding Inc. Surface-active compositions
US6451748B1 (en) 1999-06-23 2002-09-17 The Dial Corporation Compositions containing a high percent saturation concentration of antibacterial agent
US20030125224A1 (en) * 1999-06-23 2003-07-03 Seitz Earl P. Compositions having enhanced deposition of a topically active compound on a surface
EP2258820B1 (de) 2009-06-02 2019-12-18 The Procter and Gamble Company Wasserlöslicher Beutel

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2136913B1 (de) * 1971-05-07 1973-05-11 Colgate Palmolive Co
US4797225A (en) * 1986-09-08 1989-01-10 Colgate-Palmolive Company Nonaqueous liquid nonionic laundry detergent composition containing an alkali metal dithionite or sulfite reduction bleaching agent and method of use
CA2196771A1 (en) * 1994-08-25 1996-02-29 Laszlo Moldovanyi Surface-active formulations
SK24597A3 (en) * 1994-08-25 1997-08-06 Ciba Geigy Ag Surface-active formulations

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US2906711A (en) * 1958-04-25 1959-09-29 Herbert C Stecker Toilet detergent composition containing synergistic di- and tri-halo salicylanilide mixtures
US3111358A (en) * 1961-04-14 1963-11-19 Olin Mathieson Hydrazine salt for activation and stabilization of chlorite bleach for cellulosic textiles
US3276955A (en) * 1962-07-30 1966-10-04 Armour & Co Bacteriostatic compositions
US3326808A (en) * 1965-08-25 1967-06-20 Pfizer & Co C Antiseptic detergent composition
US3326807A (en) * 1963-02-15 1967-06-20 Ici Ltd Detergent compositions
US3346503A (en) * 1963-10-11 1967-10-10 Monsanto Co Heavy-duty liquid detergent emulsion compositions and processes for preparing the same

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2906711A (en) * 1958-04-25 1959-09-29 Herbert C Stecker Toilet detergent composition containing synergistic di- and tri-halo salicylanilide mixtures
US3111358A (en) * 1961-04-14 1963-11-19 Olin Mathieson Hydrazine salt for activation and stabilization of chlorite bleach for cellulosic textiles
US3276955A (en) * 1962-07-30 1966-10-04 Armour & Co Bacteriostatic compositions
US3326807A (en) * 1963-02-15 1967-06-20 Ici Ltd Detergent compositions
US3346503A (en) * 1963-10-11 1967-10-10 Monsanto Co Heavy-duty liquid detergent emulsion compositions and processes for preparing the same
US3326808A (en) * 1965-08-25 1967-06-20 Pfizer & Co C Antiseptic detergent composition

Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3968250A (en) * 1971-06-21 1976-07-06 Wave Energy Systems, Inc. Method and sporicidal compositions for synergistic disinfection or sterilization
US3968248A (en) * 1971-06-21 1976-07-06 Wave Energy Systems, Inc. Method and sporicidal compositions for synergistic disinfection or sterilization
US4093744A (en) * 1971-06-28 1978-06-06 West Laboratories, Inc. Killing bacterial spores with glutaraldehyde sporicidal compositions
US3925227A (en) * 1972-05-31 1975-12-09 American Home Prod Novel laundering compositions
US3897357A (en) * 1972-12-06 1975-07-29 American Home Prod Bacteriostatic toilet bowl cleaner compositions
US3933671A (en) * 1974-02-27 1976-01-20 The Procter & Gamble Company Germicidal cleaning composition and method
US4048336A (en) * 1974-04-22 1977-09-13 West Chemical Products, Incorporated Means for killing bacterial spores with glutaraldehyde sporicidal compositions
US4140649A (en) * 1976-09-27 1979-02-20 Eduard Bossert Method and composition for cleaning the surfaces of foods and fodder
US4329247A (en) * 1980-11-06 1982-05-11 Pdi, Inc. Stain remover for vinyl materials
US4446043A (en) * 1981-09-01 1984-05-01 Lever Brothers Company Built liquid detergent compositions
US4468338A (en) * 1983-06-13 1984-08-28 Purex Corporation Transparent soap composition
US4803008A (en) * 1987-09-23 1989-02-07 The Drackett Company Cleaning composition containing a colorant stabilized against fading
US4822854A (en) * 1987-09-23 1989-04-18 The Drackett Company Cleaning compositions containing a colorant stabilized against fading
US5726142A (en) * 1995-11-17 1998-03-10 The Dial Corp Detergent having improved properties and method of preparing the detergent
US6451748B1 (en) 1999-06-23 2002-09-17 The Dial Corporation Compositions containing a high percent saturation concentration of antibacterial agent
US20030125224A1 (en) * 1999-06-23 2003-07-03 Seitz Earl P. Compositions having enhanced deposition of a topically active compound on a surface
US6861397B2 (en) 1999-06-23 2005-03-01 The Dial Corporation Compositions having enhanced deposition of a topically active compound on a surface
US6362152B1 (en) 2000-04-07 2002-03-26 The Dow Chemical Company Low color and low haze formulations of sodium o-phenylphenate
WO2002048298A1 (en) * 2000-12-14 2002-06-20 Ciba Specialty Chemicals Holding Inc. Surface-active compositions
US20040023822A1 (en) * 2000-12-14 2004-02-05 Dietmar Ochs Surface-active compositions
US20050003994A1 (en) * 2000-12-14 2005-01-06 Dietmar Ochs Surface-active compositions
US7041631B2 (en) 2000-12-14 2006-05-09 Ciba Specialty Chemicals Corporation Surface-active compositions comprising a mixture of diphenyl ether and o-phenyl pheno
EP2258820B1 (de) 2009-06-02 2019-12-18 The Procter and Gamble Company Wasserlöslicher Beutel

Also Published As

Publication number Publication date
SE317765B (de) 1969-11-24
FR1501612A (fr) 1967-11-10
BE690213A (de) 1967-05-25
NL6615294A (de) 1967-05-29
ES333834A1 (es) 1967-12-16
CH484268A (de) 1970-01-15
DE1467619A1 (de) 1969-02-13

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