US3492463A - Electrical resistance heater - Google Patents
Electrical resistance heater Download PDFInfo
- Publication number
- US3492463A US3492463A US676595A US3492463DA US3492463A US 3492463 A US3492463 A US 3492463A US 676595 A US676595 A US 676595A US 3492463D A US3492463D A US 3492463DA US 3492463 A US3492463 A US 3492463A
- Authority
- US
- United States
- Prior art keywords
- molybdenum
- tantalum
- insulating material
- cylinder
- resistance conductor
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000010438 heat treatment Methods 0.000 abstract description 28
- 239000004020 conductor Substances 0.000 abstract description 18
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 abstract description 12
- 229910052750 molybdenum Inorganic materials 0.000 abstract description 12
- 239000011733 molybdenum Substances 0.000 abstract description 12
- 229910045601 alloy Inorganic materials 0.000 abstract description 11
- 239000000956 alloy Substances 0.000 abstract description 11
- 229910052715 tantalum Inorganic materials 0.000 abstract description 11
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 abstract description 11
- 229910052582 BN Inorganic materials 0.000 abstract description 10
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 abstract description 10
- FRWYFWZENXDZMU-UHFFFAOYSA-N 2-iodoquinoline Chemical compound C1=CC=CC2=NC(I)=CC=C21 FRWYFWZENXDZMU-UHFFFAOYSA-N 0.000 abstract description 6
- LTPBRCUWZOMYOC-UHFFFAOYSA-N beryllium oxide Inorganic materials O=[Be] LTPBRCUWZOMYOC-UHFFFAOYSA-N 0.000 abstract description 6
- 239000010955 niobium Substances 0.000 abstract description 6
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 abstract description 6
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract description 3
- 229910052708 sodium Inorganic materials 0.000 abstract description 3
- 239000011734 sodium Substances 0.000 abstract description 3
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 abstract description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract description 2
- 239000012530 fluid Substances 0.000 abstract description 2
- 239000007788 liquid Substances 0.000 abstract description 2
- 229910052744 lithium Inorganic materials 0.000 abstract description 2
- 229910052700 potassium Inorganic materials 0.000 abstract description 2
- 239000011591 potassium Substances 0.000 abstract description 2
- 229910052758 niobium Inorganic materials 0.000 abstract 2
- 239000012777 electrically insulating material Substances 0.000 abstract 1
- 230000008602 contraction Effects 0.000 description 18
- 239000011810 insulating material Substances 0.000 description 13
- 229910052751 metal Inorganic materials 0.000 description 10
- 239000002184 metal Substances 0.000 description 10
- 239000000463 material Substances 0.000 description 6
- 150000002739 metals Chemical class 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 2
- 229910001338 liquidmetal Inorganic materials 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 230000002411 adverse Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/40—Heating elements having the shape of rods or tubes
- H05B3/42—Heating elements having the shape of rods or tubes non-flexible
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B3/00—Ohmic-resistance heating
- H05B3/10—Heating elements characterised by the composition or nature of the materials or by the arrangement of the conductor
Definitions
- heating elements of the conductor-insulation-jacket type often suffer from the disadvantage that the thermal loading capacity as expressed in watts/cm. is not sufficiently high for a variety of applications.
- the thermal load actually a thermal load of the order of about 500 watts/cmF, at a temperature of about 600 C., because the heating element is constructed in such a way that even at the working temperature of the element there is maintained a contraction joint or shrink fit, and hence a surface pressure, between the outer jacket and the insulating layer. This surface pressure at the working temperature is of great importance, as it constitutes the only way in which the emission of the heat produced is ensured.
- This pressure furthermore ensures, in conjunction with the close fit of the contraction joint, that the basic geometry of the heating body is maintained. This is an important improvement as compared with electrical heating elements of prior art, which often showed local cavities due to deficient surface contact, or asymmetrical geometry, as a result of the swaging process to which the element had been subjected. Such asymmetrical configurations and local cavities invariably gave rise in practice to local overheating (hot spots), which adversely affected the loading level.
- the insulating layer is made of boron nitride, while both the resistance conductor and the metal outer jacket are made of molybdenum, tantalum or columhium, or of alloys of these metals.
- the advantageous effect that is obtained in this Way, especially with the preferred materials boron nitride and molybdenum, is enhanced by the fact that the coeificients of thermal expansion of boron nitride and molybdenum are of approximately the same magnitude. The result is that, when the heating element has heated up, its temperature gradient gives rise to such an expansion of the component materials that a mutual surface pressure is maintained.
- beryllium oxide may be used to advantage as an electrical insulating material.
- the most efficacious way of obtaining the said contraction joint in a heating element is by first selecting a tube of molybdenum, tantalum or columhium or of alloys of these metals, after which this tube is firmly shrunk around a solid cylinder of the electrical insulating material consisting essentially of boron nitride or beryllium oxide. Owing to the fact that this cylinder is solid, the required contraction joint or shrink fit may 'be elfected so as to have a firm contraction fit at about 700 to 800 C., without there being any need to fear that the boron nitride or the beryllium oxide might show dislocations.
- the central part of the cylinder made of the electrical insulating material is drilled out, with consequent formation of a cylindrical jacket of the electrical insulating material which is surrounded, via a contraction joint, by a cylindrical jacket of molybdenum, tantalum, columhium or alloys of these metals.
- this structure of coaxial cylinder and jacket is shrunk at a temperature of C. with a light contraction fit around a resistance conductor which is likewise composed of molybdenum, tantalum, columhium or an alloy of these metals.
- the heating element made in this way proves capable of emitting a very high heating current, resulting in a thermal load up to about 500 watts/cm. at temperatures in the neighborhood of 600 C.
- This heating element is very well adapted for heating liquid metals such as sodium, potassium, lithium or alloys thereof.
- the heating elements according to the invention will have an external diameter of about mm. or slightly higher. With this diameter it is possible to obtain a length of such a heating body of about 50 cm.
- FIGURE 1 is a transverse cross-sectional view of one form of a heating element embodying the principles of the present invention.
- FIGURE 2 is a similar view of a modified form of heating element.
- FIGURE 1 there is shown a heating element constructed of a central rod-shaped resistance conductor 1, a surrounding layer of insulating material 2, such as boron nitride or beryllium oxide and an outer metal jacket 3 of molybdenum, tantalum, columbium or alloys thereof.
- the heating element is fabricated by the steps previously described.
- FIGURE 2 differs from the embodiment represented in FIGURE 1 only insofar as the central resistance conductor 1 possesses the form of a cylindrical jacket having inside it a cylinder 4 in which other possible components (not shown in the drawing) may be incorporated.
- this cylinder 4 may be fitted, for instance, channels for electrical conductors or for a fluid.
- Cylinder 4 may be made of a material having qualities suitable for this purpose.
- An electrical resistance heating element comprising: an elongated resistance conductor having a closed cylindrical outer layer and constructed of a metal selected from the group consisting of molybdenum, tantalum and columbium and alloys thereof, a solid tube of solid insulating material concentrically surrounding said resistance conductor and being shrink-fitted in tight engagement therewith so as to establish a contraction joint at room temperature, said insulating material being selected from the group consisting of boron nitride and beryllium oxide, and an outer tubular jacket concentrically surrounding said layer of insulating material and shrink-fitted in tight engagement therewith so as to establish a contraction joint at the working temperature of said heating element in the range of 700 to 800 C., said jacket being constructed of a metal selected from the group consisting of molybdenum, tantalum and columbium and alloys thereof.
Landscapes
- Resistance Heating (AREA)
- Physical Or Chemical Processes And Apparatus (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL666614751A NL153755C (nl) | 1966-10-20 | 1966-10-20 | Werkwijze voor het vervaardigen van een elektrisch verwarmingselement, alsmede verwarmingselement vervaardigd met toepassing van deze werkwijze. |
Publications (1)
Publication Number | Publication Date |
---|---|
US3492463A true US3492463A (en) | 1970-01-27 |
Family
ID=19797967
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US676595A Expired - Lifetime US3492463A (en) | 1966-10-20 | 1967-10-19 | Electrical resistance heater |
Country Status (5)
Country | Link |
---|---|
US (1) | US3492463A (enrdf_load_stackoverflow) |
BE (1) | BE705286A (enrdf_load_stackoverflow) |
DE (1) | DE1690665C2 (enrdf_load_stackoverflow) |
GB (1) | GB1136368A (enrdf_load_stackoverflow) |
NL (1) | NL153755C (enrdf_load_stackoverflow) |
Cited By (41)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3665598A (en) * | 1970-12-17 | 1972-05-30 | Meindert Willem Brieko | Method of making a heating body |
EP0057172A3 (en) * | 1981-01-26 | 1982-09-01 | Walther Dr. Menhardt | Self-regulating heating element |
US4998006A (en) * | 1990-02-23 | 1991-03-05 | Brandeis University | Electric heating elements free of electromagnetic fields |
US5976333A (en) * | 1998-01-06 | 1999-11-02 | Pate; Ray H. | Collector bar |
EP1145842A3 (fr) * | 2000-04-13 | 2002-05-02 | Saint-Gobain Glass France | Vitre feuilletée |
WO2005103445A1 (en) | 2004-04-23 | 2005-11-03 | Shell Oil Company | Subsurface electrical heaters using nitride insulation |
US20070137857A1 (en) * | 2005-04-22 | 2007-06-21 | Vinegar Harold J | Low temperature monitoring system for subsurface barriers |
US20080035347A1 (en) * | 2006-04-21 | 2008-02-14 | Brady Michael P | Adjusting alloy compositions for selected properties in temperature limited heaters |
US20090090158A1 (en) * | 2007-04-20 | 2009-04-09 | Ian Alexander Davidson | Wellbore manufacturing processes for in situ heat treatment processes |
US7559367B2 (en) | 2005-10-24 | 2009-07-14 | Shell Oil Company | Temperature limited heater with a conduit substantially electrically isolated from the formation |
US20090194286A1 (en) * | 2007-10-19 | 2009-08-06 | Stanley Leroy Mason | Multi-step heater deployment in a subsurface formation |
US20090272526A1 (en) * | 2008-04-18 | 2009-11-05 | David Booth Burns | Electrical current flow between tunnels for use in heating subsurface hydrocarbon containing formations |
US7640980B2 (en) | 2003-04-24 | 2010-01-05 | Shell Oil Company | Thermal processes for subsurface formations |
US20100126727A1 (en) * | 2001-10-24 | 2010-05-27 | Shell Oil Company | In situ recovery from a hydrocarbon containing formation |
US7735935B2 (en) | 2001-04-24 | 2010-06-15 | Shell Oil Company | In situ thermal processing of an oil shale formation containing carbonate minerals |
US7831133B2 (en) | 2005-04-22 | 2010-11-09 | Shell Oil Company | Insulated conductor temperature limited heater for subsurface heating coupled in a three-phase WYE configuration |
US20110124223A1 (en) * | 2009-10-09 | 2011-05-26 | David Jon Tilley | Press-fit coupling joint for joining insulated conductors |
US20110132661A1 (en) * | 2009-10-09 | 2011-06-09 | Patrick Silas Harmason | Parallelogram coupling joint for coupling insulated conductors |
US20110134958A1 (en) * | 2009-10-09 | 2011-06-09 | Dhruv Arora | Methods for assessing a temperature in a subsurface formation |
US8224163B2 (en) | 2002-10-24 | 2012-07-17 | Shell Oil Company | Variable frequency temperature limited heaters |
US8220539B2 (en) | 2008-10-13 | 2012-07-17 | Shell Oil Company | Controlling hydrogen pressure in self-regulating nuclear reactors used to treat a subsurface formation |
US8225866B2 (en) | 2000-04-24 | 2012-07-24 | Shell Oil Company | In situ recovery from a hydrocarbon containing formation |
US8327932B2 (en) | 2009-04-10 | 2012-12-11 | Shell Oil Company | Recovering energy from a subsurface formation |
US8485256B2 (en) | 2010-04-09 | 2013-07-16 | Shell Oil Company | Variable thickness insulated conductors |
US8586866B2 (en) | 2010-10-08 | 2013-11-19 | Shell Oil Company | Hydroformed splice for insulated conductors |
US8631866B2 (en) | 2010-04-09 | 2014-01-21 | Shell Oil Company | Leak detection in circulated fluid systems for heating subsurface formations |
US8701768B2 (en) | 2010-04-09 | 2014-04-22 | Shell Oil Company | Methods for treating hydrocarbon formations |
US8820406B2 (en) | 2010-04-09 | 2014-09-02 | Shell Oil Company | Electrodes for electrical current flow heating of subsurface formations with conductive material in wellbore |
US8857051B2 (en) | 2010-10-08 | 2014-10-14 | Shell Oil Company | System and method for coupling lead-in conductor to insulated conductor |
US8939207B2 (en) | 2010-04-09 | 2015-01-27 | Shell Oil Company | Insulated conductor heaters with semiconductor layers |
US8943686B2 (en) | 2010-10-08 | 2015-02-03 | Shell Oil Company | Compaction of electrical insulation for joining insulated conductors |
US9016370B2 (en) | 2011-04-08 | 2015-04-28 | Shell Oil Company | Partial solution mining of hydrocarbon containing layers prior to in situ heat treatment |
US9033042B2 (en) | 2010-04-09 | 2015-05-19 | Shell Oil Company | Forming bitumen barriers in subsurface hydrocarbon formations |
US9048653B2 (en) | 2011-04-08 | 2015-06-02 | Shell Oil Company | Systems for joining insulated conductors |
US9080409B2 (en) | 2011-10-07 | 2015-07-14 | Shell Oil Company | Integral splice for insulated conductors |
US9080917B2 (en) | 2011-10-07 | 2015-07-14 | Shell Oil Company | System and methods for using dielectric properties of an insulated conductor in a subsurface formation to assess properties of the insulated conductor |
US9226341B2 (en) | 2011-10-07 | 2015-12-29 | Shell Oil Company | Forming insulated conductors using a final reduction step after heat treating |
US9309755B2 (en) | 2011-10-07 | 2016-04-12 | Shell Oil Company | Thermal expansion accommodation for circulated fluid systems used to heat subsurface formations |
US20180176991A1 (en) * | 2015-12-08 | 2018-06-21 | Temp4 Inc. | Efficient Assembled Heating Elements of Large Sizes and of Metallic Tubular Designs for Electric Radiant Heaters |
US10047594B2 (en) | 2012-01-23 | 2018-08-14 | Genie Ip B.V. | Heater pattern for in situ thermal processing of a subsurface hydrocarbon containing formation |
WO2023046943A1 (de) | 2021-09-27 | 2023-03-30 | Basf Se | Mehrfachzylinder |
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EP0811303A4 (en) * | 1995-02-21 | 1998-09-02 | Hoskins Mfg Co | PIPE RADIATOR WITH INSULATED CORE |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1981878A (en) * | 1929-09-23 | 1934-11-27 | Sirian Lamp Co | Lamp, filament, and process of making the same |
US3121154A (en) * | 1959-10-30 | 1964-02-11 | Babcock & Wilcox Ltd | Electric heaters |
US3205467A (en) * | 1962-07-27 | 1965-09-07 | Ward Leonard Electric Co | Plastic encapsulated resistor |
US3217280A (en) * | 1962-11-29 | 1965-11-09 | Thermel Inc | Heating element |
US3254320A (en) * | 1963-08-15 | 1966-05-31 | Babcock & Wilcox Co | Electric heaters |
US3356834A (en) * | 1964-05-11 | 1967-12-05 | Hooker Chemical Corp | Process and apparatus for storing heat |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB775522A (enrdf_load_stackoverflow) * | 1954-07-07 | 1900-01-01 | ||
DE1079238B (de) * | 1956-05-30 | 1960-04-07 | Manfried Steinmetz | Elektrischer Hochtemperatur-Heizkoerper |
DE1090790B (de) * | 1957-12-11 | 1960-10-13 | Max Planck Inst Eisenforschung | Keramischer, Chromoxyd enthaltender Heizleiter, insbesondere fuer Hochtemperaturoefen |
-
1966
- 1966-10-20 NL NL666614751A patent/NL153755C/nl active
-
1967
- 1967-10-17 GB GB47286/67A patent/GB1136368A/en not_active Expired
- 1967-10-18 BE BE705286D patent/BE705286A/xx unknown
- 1967-10-19 US US676595A patent/US3492463A/en not_active Expired - Lifetime
- 1967-10-20 DE DE1690665A patent/DE1690665C2/de not_active Expired
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1981878A (en) * | 1929-09-23 | 1934-11-27 | Sirian Lamp Co | Lamp, filament, and process of making the same |
US3121154A (en) * | 1959-10-30 | 1964-02-11 | Babcock & Wilcox Ltd | Electric heaters |
US3205467A (en) * | 1962-07-27 | 1965-09-07 | Ward Leonard Electric Co | Plastic encapsulated resistor |
US3217280A (en) * | 1962-11-29 | 1965-11-09 | Thermel Inc | Heating element |
US3254320A (en) * | 1963-08-15 | 1966-05-31 | Babcock & Wilcox Co | Electric heaters |
US3356834A (en) * | 1964-05-11 | 1967-12-05 | Hooker Chemical Corp | Process and apparatus for storing heat |
Cited By (133)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3665598A (en) * | 1970-12-17 | 1972-05-30 | Meindert Willem Brieko | Method of making a heating body |
EP0057172A3 (en) * | 1981-01-26 | 1982-09-01 | Walther Dr. Menhardt | Self-regulating heating element |
US4998006A (en) * | 1990-02-23 | 1991-03-05 | Brandeis University | Electric heating elements free of electromagnetic fields |
US5976333A (en) * | 1998-01-06 | 1999-11-02 | Pate; Ray H. | Collector bar |
EP1145842A3 (fr) * | 2000-04-13 | 2002-05-02 | Saint-Gobain Glass France | Vitre feuilletée |
US8485252B2 (en) | 2000-04-24 | 2013-07-16 | Shell Oil Company | In situ recovery from a hydrocarbon containing formation |
US8225866B2 (en) | 2000-04-24 | 2012-07-24 | Shell Oil Company | In situ recovery from a hydrocarbon containing formation |
US8789586B2 (en) | 2000-04-24 | 2014-07-29 | Shell Oil Company | In situ recovery from a hydrocarbon containing formation |
US7735935B2 (en) | 2001-04-24 | 2010-06-15 | Shell Oil Company | In situ thermal processing of an oil shale formation containing carbonate minerals |
US20100126727A1 (en) * | 2001-10-24 | 2010-05-27 | Shell Oil Company | In situ recovery from a hydrocarbon containing formation |
US8627887B2 (en) | 2001-10-24 | 2014-01-14 | Shell Oil Company | In situ recovery from a hydrocarbon containing formation |
US8238730B2 (en) | 2002-10-24 | 2012-08-07 | Shell Oil Company | High voltage temperature limited heaters |
US8224164B2 (en) | 2002-10-24 | 2012-07-17 | Shell Oil Company | Insulated conductor temperature limited heaters |
US8224163B2 (en) | 2002-10-24 | 2012-07-17 | Shell Oil Company | Variable frequency temperature limited heaters |
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AU2005236490B2 (en) * | 2004-04-23 | 2009-01-29 | Shell Internationale Research Maatschappij B.V. | Subsurface electrical heaters using nitride insulation |
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US20060289536A1 (en) * | 2004-04-23 | 2006-12-28 | Vinegar Harold J | Subsurface electrical heaters using nitride insulation |
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Also Published As
Publication number | Publication date |
---|---|
NL153755C (nl) | 1977-11-15 |
GB1136368A (en) | 1968-12-11 |
DE1690665C2 (de) | 1975-12-04 |
DE1690665B1 (de) | 1971-07-29 |
BE705286A (enrdf_load_stackoverflow) | 1968-03-01 |
NL6614751A (enrdf_load_stackoverflow) | 1968-04-22 |
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