US3479022A - Apparatus for vacuum treating liquid steel according to the circulation method - Google Patents
Apparatus for vacuum treating liquid steel according to the circulation method Download PDFInfo
- Publication number
- US3479022A US3479022A US560651A US3479022DA US3479022A US 3479022 A US3479022 A US 3479022A US 560651 A US560651 A US 560651A US 3479022D A US3479022D A US 3479022DA US 3479022 A US3479022 A US 3479022A
- Authority
- US
- United States
- Prior art keywords
- vessel
- degasifying
- gas
- vacuum
- treating liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910000831 Steel Inorganic materials 0.000 title description 17
- 239000010959 steel Substances 0.000 title description 17
- 238000000034 method Methods 0.000 title description 9
- 239000007788 liquid Substances 0.000 title description 7
- 239000007789 gas Substances 0.000 description 25
- 238000006243 chemical reaction Methods 0.000 description 7
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- 239000000460 chlorine Substances 0.000 description 4
- 230000002349 favourable effect Effects 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 239000011261 inert gas Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 239000000161 steel melt Substances 0.000 description 3
- 229910052786 argon Inorganic materials 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 238000010494 dissociation reaction Methods 0.000 description 2
- 230000005593 dissociations Effects 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- 238000009489 vacuum treatment Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- -1 as for instance Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 230000002452 interceptive effect Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/10—Handling in a vacuum
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/10—Reduction of greenhouse gas [GHG] emissions
- Y02P10/143—Reduction of greenhouse gas [GHG] emissions of methane [CH4]
Definitions
- Heat energy of multi-atom inert gases is extremely high since the specific heat due to the increase in temperature is increased by dissociation and ionization energy; due to high temperatures at the phase borders, an intensive and quick reaction of the metal droplets is obtained. Heat losses occurring during the vacuum treatment are simultaneously obviated by radiation of the high temperatures, very favorable in a vacuum.
- the present invention relates to an apparatus for vacuum treating liquid steel according to the circulating method, in which a degasifying vessel with two pipes extends into the steel melt.
- Devices of this general type for carrying out the circulating degasifying method are known.
- conveyor gas In order to induce the chemical reaction, it is known instead of conveyor gas to convey inert or reactive gases into the riser.
- Plasma burners are operated by means of inert gas, such as argon, or a reactive gas, as for instance, hydrogen, oxygen, methane, carbon tetrachloride, chlorine, sodium vapor, or the like, or mixtures thereof.
- inert gas such as argon
- a reactive gas such as hydrogen, oxygen, methane, carbon tetrachloride, chlorine, sodium vapor, or the like, or mixtures thereof.
- the heat losses occuring during the vacuum treatment are at the same time obviated according to the present invention, namely by the radiation of the high temperatures, which radiation is very favorable in a vacuum.
- the degasifying vessel 1 is in a manner known per se with its two pipes 2 and 3 immersed into a ladle (not illustrated) which is filled with liquid steel.
- a conduit 4 communicating with the riser 2 argon or any other suitable gas is blown into the vessel 1 whereby in a manner known per se a circulation will be obtained.
- the steel is pulled upwardly and torn into droplets.
- Vessel 1 communicates with the vacuum pump through a connection 5 and a hose (not illustrated) which is connected to connection 5.
- the degasifying vessel 1 is equipped with controllable plasma burners 6 arranged in the upper portion of vessel 1.
- Burners 6 are operated by an inert gas, or a reactive gas, so that the highly heated gas will be able to flow around the steel droplets. With a ton melt to be degasified, burners with a power of from 1000 to 2000 kilowatts will suflice.
- high gas temperatures are selected so that a high heat supply with a relatively small quantity of gas with a temperature of approximately 25,000 C. will be obtained.
- the supplied quantity of gas should not exceed 10% of the output of the vacuum pumps.
- Plasma burners are generally Well known and have been described, for instance, in French Patent 1,311,252 which issued on Oct. 29, 1962.
- the power output of such plasma burners may be controlled in any convenient manner, for instance, by alternating current or three-phase current. This is particularly favorable when a plurality of such burners are employed since" with superposition of three-phase current the power of the burners may be increased to a maximum in a very simple manner, which is practicallynot possible with methods not employing superposition of three-phase current.
- a control circuit of this type is diagrammatically illustrated in the present drawing in which reference numerals 7 and 8 designate direct current generators respectively conductively connected to the electrodes 9, 10 and 11, 12 of the two burners 6 shown in the drawing. There is, furthermore, provided a source 13 of threephase current, the three-phase 14, 15, and 16 of which are respectively connected to electrodes 10 12 and a further electrode of a further burner (not shown).
- An apparatus for vacuum treating liquid steel according to the circulation method for degasifying the steel comprising a degasifying vessel, pipe means connected to the lower portion of said vessel and communicating with the interior thereof, said pipe means being immersed in a steel melt, conduit means communicating with said pipe means through which gas is admitted for withdrawing steel from the steel meltand throwingtthe same in form of droplets into said degasifying vessel, adjustable plasma burner means arranged at the upper portion of said vessel and operable by inert or reactive gas to convey highly heated gases into the interior of said vessel and around steel droplets thrown up into the flow of said highly heated gases, and vacuum creating means connected to and communicating with said degasifying vessel.
- An apparatus in which a plurality of plasma burner means are associated with said degasifying vessel and arranged to supply hot gas flow around the droplets for intensive metallurgical treatment.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Treatment Of Steel In Its Molten State (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEST024067 | 1965-07-01 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US3479022A true US3479022A (en) | 1969-11-18 |
Family
ID=7459958
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US560651A Expired - Lifetime US3479022A (en) | 1965-07-01 | 1966-06-27 | Apparatus for vacuum treating liquid steel according to the circulation method |
Country Status (4)
| Country | Link |
|---|---|
| US (1) | US3479022A (cs) |
| JP (1) | JPS4912B1 (cs) |
| DE (1) | DE1458936A1 (cs) |
| GB (1) | GB1129298A (cs) |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3607228A (en) * | 1969-01-13 | 1971-09-21 | Armco Steel Corp | Method of operating a vacuum degasser to equalize erosion of refractory leg liners |
| US3711615A (en) * | 1969-09-30 | 1973-01-16 | Advanced Technology Center Inc | Plasma heating method |
| US3813469A (en) * | 1973-04-09 | 1974-05-28 | Daido Steel Co Ltd | Method for heating vacuum degassing container |
| US3971875A (en) * | 1974-01-04 | 1976-07-27 | General Dynamics Corporation | Apparatus and method for vacuum hot press joining, compacting and treating of materials |
| US4049248A (en) * | 1971-07-16 | 1977-09-20 | A/S Ardal Og Sunndal Verk | Dynamic vacuum treatment |
| DE2933466A1 (de) * | 1978-08-18 | 1980-03-06 | Nippon Steel Corp | Gefaess fuer die behandlung von geschmolzenem metall |
| US4718477A (en) * | 1986-07-30 | 1988-01-12 | Plasma Energy Corporation | Apparatus and method for processing reactive metals |
| US4734551A (en) * | 1986-01-10 | 1988-03-29 | Plasma Energy Corporation | Method and apparatus for heating molten steel utilizing a plasma arc torch |
| WO1989007499A1 (en) * | 1988-02-09 | 1989-08-24 | The Broken Hill Proprietary Company Limited | Superheating and microalloying of molten metal by contact with a plasma arc |
| US4918282A (en) * | 1986-01-10 | 1990-04-17 | Plasma Energy Corporation | Method and apparatus for heating molten steel utilizing a plasma arc torch |
| US5203910A (en) * | 1991-11-27 | 1993-04-20 | Premelt Pump, Inc. | Molten metal conveying means and method of conveying molten metal from one place to another in a metal-melting furnace |
| RU2823106C2 (ru) * | 2021-06-23 | 2024-07-18 | ДжФЕ СТИЛ КОРПОРЕЙШН | Способ рафинирования расплавленной стали |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2022270225A1 (ja) * | 2021-06-23 | 2022-12-29 | Jfeスチール株式会社 | 溶鋼の精錬方法 |
| EP4339303B1 (en) * | 2021-06-23 | 2025-10-29 | JFE Steel Corporation | Molten steel refining method |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3147330A (en) * | 1962-09-24 | 1964-09-01 | Union Carbide Corp | Method for furnacing conductive materials |
| US3320053A (en) * | 1964-09-25 | 1967-05-16 | Bethlehem Steel Corp | Method of injecting gases into steel melts |
| US3342250A (en) * | 1963-11-08 | 1967-09-19 | Suedwestfalen Ag Stahlwerke | Method of and apparatus for vacuum melting and teeming steel and steellike alloys |
-
1965
- 1965-07-01 DE DE19651458936 patent/DE1458936A1/de active Pending
- 1965-12-16 GB GB53531/65A patent/GB1129298A/en not_active Expired
-
1966
- 1966-01-20 JP JP41002861A patent/JPS4912B1/ja active Pending
- 1966-06-27 US US560651A patent/US3479022A/en not_active Expired - Lifetime
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3147330A (en) * | 1962-09-24 | 1964-09-01 | Union Carbide Corp | Method for furnacing conductive materials |
| US3342250A (en) * | 1963-11-08 | 1967-09-19 | Suedwestfalen Ag Stahlwerke | Method of and apparatus for vacuum melting and teeming steel and steellike alloys |
| US3320053A (en) * | 1964-09-25 | 1967-05-16 | Bethlehem Steel Corp | Method of injecting gases into steel melts |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3607228A (en) * | 1969-01-13 | 1971-09-21 | Armco Steel Corp | Method of operating a vacuum degasser to equalize erosion of refractory leg liners |
| US3711615A (en) * | 1969-09-30 | 1973-01-16 | Advanced Technology Center Inc | Plasma heating method |
| US4049248A (en) * | 1971-07-16 | 1977-09-20 | A/S Ardal Og Sunndal Verk | Dynamic vacuum treatment |
| US3813469A (en) * | 1973-04-09 | 1974-05-28 | Daido Steel Co Ltd | Method for heating vacuum degassing container |
| US3971875A (en) * | 1974-01-04 | 1976-07-27 | General Dynamics Corporation | Apparatus and method for vacuum hot press joining, compacting and treating of materials |
| US4241904A (en) * | 1978-08-18 | 1980-12-30 | Nippon Steel Corporation | Molten-metal treating vessel |
| DE2933466A1 (de) * | 1978-08-18 | 1980-03-06 | Nippon Steel Corp | Gefaess fuer die behandlung von geschmolzenem metall |
| US4734551A (en) * | 1986-01-10 | 1988-03-29 | Plasma Energy Corporation | Method and apparatus for heating molten steel utilizing a plasma arc torch |
| US4918282A (en) * | 1986-01-10 | 1990-04-17 | Plasma Energy Corporation | Method and apparatus for heating molten steel utilizing a plasma arc torch |
| US4718477A (en) * | 1986-07-30 | 1988-01-12 | Plasma Energy Corporation | Apparatus and method for processing reactive metals |
| WO1989007499A1 (en) * | 1988-02-09 | 1989-08-24 | The Broken Hill Proprietary Company Limited | Superheating and microalloying of molten metal by contact with a plasma arc |
| US5203910A (en) * | 1991-11-27 | 1993-04-20 | Premelt Pump, Inc. | Molten metal conveying means and method of conveying molten metal from one place to another in a metal-melting furnace |
| US5395094A (en) * | 1991-11-27 | 1995-03-07 | Premelt Pump, Inc. | Means of conveying molten metal from one place to another in a metal-melting furnace with simultaneous alloying of the melt |
| US5403381A (en) * | 1991-11-27 | 1995-04-04 | Premelt Pump, Inc. | Molten metal conveying means and method of conveying molten metal from one place to another in a metal-melting furnace with simultaneous degassing of the melt |
| RU2823106C2 (ru) * | 2021-06-23 | 2024-07-18 | ДжФЕ СТИЛ КОРПОРЕЙШН | Способ рафинирования расплавленной стали |
Also Published As
| Publication number | Publication date |
|---|---|
| GB1129298A (en) | 1968-10-02 |
| JPS4912B1 (cs) | 1974-01-05 |
| DE1458936A1 (cs) | 1970-07-30 |
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