US3478809A - Process of producing continuous castings of square or circular cross-section - Google Patents
Process of producing continuous castings of square or circular cross-section Download PDFInfo
- Publication number
- US3478809A US3478809A US462042A US46204265A US3478809A US 3478809 A US3478809 A US 3478809A US 462042 A US462042 A US 462042A US 46204265 A US46204265 A US 46204265A US 3478809 A US3478809 A US 3478809A
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- United States
- Prior art keywords
- casting
- section
- cross
- rolls
- castings
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/46—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling metal immediately subsequent to continuous casting
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B13/00—Metal-rolling stands, i.e. an assembly composed of a stand frame, rolls, and accessories
- B21B13/22—Metal-rolling stands, i.e. an assembly composed of a stand frame, rolls, and accessories for rolling metal immediately subsequent to continuous casting, i.e. in-line rolling of steel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/12—Accessories for subsequent treating or working cast stock in situ
- B22D11/1206—Accessories for subsequent treating or working cast stock in situ for plastic shaping of strands
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/12—Accessories for subsequent treating or working cast stock in situ
- B22D11/128—Accessories for subsequent treating or working cast stock in situ for removing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22D—CASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
- B22D11/00—Continuous casting of metals, i.e. casting in indefinite lengths
- B22D11/12—Accessories for subsequent treating or working cast stock in situ
- B22D11/128—Accessories for subsequent treating or working cast stock in situ for removing
- B22D11/1287—Rolls; Lubricating, cooling or heating rolls while in use
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B1/00—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations
- B21B1/08—Metal-rolling methods or mills for making semi-finished products of solid or profiled cross-section; Sequence of operations in milling trains; Layout of rolling-mill plant, e.g. grouping of stands; Succession of passes or of sectional pass alternations for rolling structural sections, i.e. work of special cross-section, e.g. angle steel
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49972—Method of mechanical manufacture with separating, localizing, or eliminating of as-cast defects from a metal casting [e.g., anti-pipe]
- Y10T29/49973—Compressing ingot while still partially molten
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/4998—Combined manufacture including applying or shaping of fluent material
- Y10T29/49988—Metal casting
- Y10T29/49991—Combined with rolling
Definitions
- This invention relates to a process of producing continuous castings of square or circular cross-section, particularly of steel.
- the continuous casting emerging from a mold is moved along a straight or curved path through the so-called after-cooling region and then passes between feeding and straightening rollers, after which it is cut into the desired lengths. Only the skin of the casting solidifies in the mold. The interior of the casting solidifies in the after-cooling region. Contraction causes the solidified skin of the casting to lift from the mold wall. This lifting is highly irregular so that the resulting castings do not have exactly the same cross-sectional shape as the mold.
- the square-section castings are usually diamond-shaped and the circular-section castings depart from a circular form at various points of their periphery.
- FIG. 1 is a diagrammatic view illustrating the casting leaving the mold
- FIG. 2 is a diagrammatic view illustrating the crosssection of the casting upon entering the gauged rollers.
- a continuous casting 1 emerging from a mold 2 has core 3 thereof in a liquid state and the casting is of diamond cross-sectional shape.
- the casting 1 is shaped in a closed pass defined by a pair of grooved rolls 4 and the profile of the coacting roll provides a closed pass denoted 5.
- the cross-section of the casting 1 as it enters the grooved rolls is diamond shaped as indicated by the broken lines and when the casting leaves the rolls it is square in cross-section.
- the invention provides a process of manufacturing continuous castings of square or circular crosssection, especially of steel, in which the continuous casting emerging from the mold is shaped in a closed pass defined by a pair of grooved rolls with the utilization of the residual heat of the casting and is characterized in that the shaping changes the cross-sectional shape of the casting from oval to circular or from diamond to square in a manner known from individual rods.
- the feeding means comprise usually one or more pairs of rolls. For this reason, it is a development of the invention to shape with the aid of one of the pairs of rolls which act also as straightening or feeding rolls.
- the shaping of the crosssection may be combined with a substantial reduction of the cross-section of the casting and the substantial reduction in cross-section may be assisted by maintaining the casting under tensile stress by succeeding feeding rolls while the casting is being shaped in the closed pass defined by the pair of grooved rollers.
- a pair of grooved rolls may form a plurality of closed passes disposed one beside the other and shaping the casting to different cross-sections.
- the casting may be fed to a selected one of these closed passes so that castings differing in cross-section may be made without the need of changing the mold.
- the casting is preferably guided between the mold and the shaping rolls by grooved guiding rolls, which conform to the crosssection of the casting and these guiding rolls are, or part of them is, displaced or pivotally moved to guide the casting to a selected pass of the shaping rolls.
- a process of manufacturing continuous castings comprising providing a mold having an oval shaped cross-section; withdrawing from the mold a continuous casting having an oval cross-section, and the longer axis of the cross-section remaining in the same direction as the longer axis of the mold, and then hotforming said continuous casting in a closed pass between and by a pair of cooperating grooved rolls to a circular cross-section, with said hot-forming being effected while said casting still contains sufiicient residual heat from the casting operation to enable said hot-forming.
- a process of manufacturing continuous castings comprising providing a mold having a diamond shaped cross-section; withdrawing from said mold a continuous casting having a diamond cross-section, and the longer diagonal line of the cross-section remaining in the same direction as the longer diagonal line of the mold, and then hot-forming said continuous casting in a closed pass between and by a pair of cooperating grooved rolls to a square cross-section, with said hot-forming being effected While said casting still contains sufficient residual heat from the casting operation to enable said hot-forming.
- a process as set forth in claim 10 in which said casting is guided between said mold and said grooved pair of grooved rolls by grooved guiding rolls, which conform to the cross-section of the continuous casting as it is withdrawn from the mold; and at least part of said guiding rolls is adjusted to guide said continuous casting to a selected pass of said grooved rolls for hot-forming.
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Continuous Casting (AREA)
- Metal Rolling (AREA)
Description
Nov. 18, 1969 TARMANN ET AL 3,478,809
PROCESS OF PRODUCING CONTINUOUS CASTINGS OF SQUARE OR CIRCULAR CROSS-SECTION Filed June '7, 1965 Casfz'ng alien in; 292g lQ/ZS 1% Z 524/50 Erma/m United States Patent US. Cl. 164-82 12 Claims ABSTRACT OF THE DISCLOSURE This disclosure relates to a method of obtaining square or circular cross-sectioned continuous castings by firstly utilizing a mold having a diamond or oval cross-sectional shape, then hot-forming the resultant casting into a respectively square or circular cross-sectional shape by commensurately shaped rolls.
This invention relates to a process of producing continuous castings of square or circular cross-section, particularly of steel.
In this process, the continuous casting emerging from a mold is moved along a straight or curved path through the so-called after-cooling region and then passes between feeding and straightening rollers, after which it is cut into the desired lengths. Only the skin of the casting solidifies in the mold. The interior of the casting solidifies in the after-cooling region. Contraction causes the solidified skin of the casting to lift from the mold wall. This lifting is highly irregular so that the resulting castings do not have exactly the same cross-sectional shape as the mold. The square-section castings are usually diamond-shaped and the circular-section castings depart from a circular form at various points of their periphery. Small irregularities during teeming are inevitable and give rise to one or more changes of said irregularities in the cross-sectional shape of the resulting castings obtained by one and the same teeming. This results in difiiculties during the conveying of the casting in the feeding or straightening apparatus, particularly if grooved rolls are used therein. In certain subsequent processes, e.g., during piercing to produce tubes, it is desirable to use castings which have exactly uniform crosssectional shapes.
For this reason, it is proposed according to the invention to use molds having a diamond or oval cross-sectional shape for continuous casting in such cases and to shape these diamond or oval castings to squareor circular-section castings, respectively, in a pair of grooved rolls defining a closed pass with the utilization of the residual heat of the casting.
It has been found that the cross-section of castings obtained from molds having "a diamond or oval cross-sectional shape remains extremely uniform throughout the teeming so that it is easy to provide grooved rolls defining such a pass whereby castings having an exactly square.
or circular cross-section are obtained.
Continuous casting installations, in which the resulting castings are shaped by the feed rolls or by additional rolling mills with the utilization of the residual heat of the casting, are known per so. For instance, it has been suggested to roll down flat-section castings to sheet metal gauge, e.g., with the aid of cluster mills, or to divide fiatsection castings having fiat or pro-profiled side faces into a plurality of part castings with the aid of suitably grooved rolls. Contrary to these known proposals, however, the invention is concerned with the shaping of individual castlugs.
I CC.
Referring to the drawings, FIG. 1 is a diagrammatic view illustrating the casting leaving the mold, and
FIG. 2 is a diagrammatic view illustrating the crosssection of the casting upon entering the gauged rollers.
In FIG. 1 it will be noted that a continuous casting 1 emerging from a mold 2 has core 3 thereof in a liquid state and the casting is of diamond cross-sectional shape. The casting 1 is shaped in a closed pass defined by a pair of grooved rolls 4 and the profile of the coacting roll provides a closed pass denoted 5. The cross-section of the casting 1 as it enters the grooved rolls is diamond shaped as indicated by the broken lines and when the casting leaves the rolls it is square in cross-section.
Thus, the invention provides a process of manufacturing continuous castings of square or circular crosssection, especially of steel, in which the continuous casting emerging from the mold is shaped in a closed pass defined by a pair of grooved rolls with the utilization of the residual heat of the casting and is characterized in that the shaping changes the cross-sectional shape of the casting from oval to circular or from diamond to square in a manner known from individual rods.
In continuous casting installations, the feeding means comprise usually one or more pairs of rolls. For this reason, it is a development of the invention to shape with the aid of one of the pairs of rolls which act also as straightening or feeding rolls.
According to the invention, the shaping of the crosssection may be combined with a substantial reduction of the cross-section of the casting and the substantial reduction in cross-section may be assisted by maintaining the casting under tensile stress by succeeding feeding rolls while the casting is being shaped in the closed pass defined by the pair of grooved rollers.
It is another advantage afforded by the invention that a pair of grooved rolls may form a plurality of closed passes disposed one beside the other and shaping the casting to different cross-sections. In this case, the casting may be fed to a selected one of these closed passes so that castings differing in cross-section may be made without the need of changing the mold. The casting is preferably guided between the mold and the shaping rolls by grooved guiding rolls, which conform to the crosssection of the casting and these guiding rolls are, or part of them is, displaced or pivotally moved to guide the casting to a selected pass of the shaping rolls.
What is claimed is:
1. A process of manufacturing continuous castings, said process comprising providing a mold having an oval shaped cross-section; withdrawing from the mold a continuous casting having an oval cross-section, and the longer axis of the cross-section remaining in the same direction as the longer axis of the mold, and then hotforming said continuous casting in a closed pass between and by a pair of cooperating grooved rolls to a circular cross-section, with said hot-forming being effected while said casting still contains sufiicient residual heat from the casting operation to enable said hot-forming.
2. A process as set forth in claim 1, in which said continuous casting consists of steel.
3. A process as set forth in claim 1, in which the crosssectional area of said continuous casting is substantially reduced by said hot-forming; and imparting tensile stress to the said casting by suceeding pairs of feeding rolls while the said casting is being hot-formed.
4. A process as set forth in claim 1, in which said pair of grooved rolls employed for said hot-forming has a plurality of closed passes adapted to impart different cross-sections to said continuous casting, and which crosssections have uniform dimensions in any two directions which are at right angles to each other.
5. A process as set forth in claim 4, in which said casting is guided between said mold and said grooved pair of grooved rolls by grooved guiding rolls, which conform to the cross-section of the continuous casting as it is withdrawn from the mold; and at least part of said guiding rolls is adjusted to guide said continuous casting to a selected pass of said grooved rolls for hot-forming.
6. A process as set forth in claim 5, in which said part of said guiding rolls is pivotally adjusted.
7. A process of manufacturing continuous castings, said process comprising providing a mold having a diamond shaped cross-section; withdrawing from said mold a continuous casting having a diamond cross-section, and the longer diagonal line of the cross-section remaining in the same direction as the longer diagonal line of the mold, and then hot-forming said continuous casting in a closed pass between and by a pair of cooperating grooved rolls to a square cross-section, with said hot-forming being effected While said casting still contains sufficient residual heat from the casting operation to enable said hot-forming.
8. A process as set forth in claim 7 in which said continuous casting consists of steel.
9. A process as set forth in claim 7 in which the crosssectional area of the said continuous casting is substantially reduced by said hot-forming; and imparting tensile stress to said casting by succeeding pairs of feeding rolls while said casting is being hot-formed.
10. A process as set forth in claim 7 in which said pair of grooved rolls employed for said hot-forming has a plurality of closed passes adapted to impart different cross-sections to said continuous casting, and which cross-sections have uniform dimensions in any two directions which are at right angles to each other.
11. A process as set forth in claim 10 in which said casting is guided between said mold and said grooved pair of grooved rolls by grooved guiding rolls, which conform to the cross-section of the continuous casting as it is withdrawn from the mold; and at least part of said guiding rolls is adjusted to guide said continuous casting to a selected pass of said grooved rolls for hot-forming.
12. A process as set forth in claim 11 in which said part of said guiding rolls is pivotally adjusted.
References Cited UNITED STATES PATENTS 2,057,580 10/1936 Layton 72-224 2,008,626 7/1935 Murakami 2257 3,147,521 9/1964 Boehm 2257 3,209,452 10/1965 Schneckenburger 2257 3,374,826 3/1968 Black 164-282 X FOREIGN PATENTS 517,838 3/1955 Italy. 1,323,948 3/1963 France. 1,335,289 7/1963 France.
I. SPENCER OVERHOLSER, Primary Examiner ROBERT D. BALDWIN, Assistant Examiner US. Cl. X.R.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
AT571664A AT251213B (en) | 1964-07-03 | 1964-07-03 | Process for the production of square or round strands |
Publications (1)
Publication Number | Publication Date |
---|---|
US3478809A true US3478809A (en) | 1969-11-18 |
Family
ID=3578874
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US462042A Expired - Lifetime US3478809A (en) | 1964-07-03 | 1965-06-07 | Process of producing continuous castings of square or circular cross-section |
Country Status (7)
Country | Link |
---|---|
US (1) | US3478809A (en) |
AT (1) | AT251213B (en) |
BE (1) | BE666333A (en) |
DE (1) | DE1296749B (en) |
GB (1) | GB1048403A (en) |
NL (1) | NL6508272A (en) |
SE (1) | SE301365B (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4493363A (en) * | 1976-07-30 | 1985-01-15 | Jernkontoret | Method at continuous casting of steels and metal alloys with segregation tendency and apparatus for carrying out the method |
WO1993004802A1 (en) * | 1991-09-12 | 1993-03-18 | Giovanni Arvedi | A process and apparatus for the manufacture of billets and blooms from a continuously last steel showing high or excellent quality |
EP0545510A1 (en) * | 1991-11-26 | 1993-06-09 | MANNESMANN Aktiengesellschaft | Process for manufacture of steel long products |
AU658451B2 (en) * | 1991-09-12 | 1995-04-13 | Giovanni Arvedi | A process and an apparatus for the manufacture of billets and blooms from a continuously cast steel showing high or excellent quality |
WO2003039789A2 (en) * | 2001-11-06 | 2003-05-15 | Sms Demag Aktiengesellschaft | Method and casting machine for production of casting bars in the shape of billets or blocks |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3403388C2 (en) * | 1984-02-01 | 1986-08-07 | Benteler-Werke Ag Werk Neuhaus, 4790 Paderborn | Support device for a polygonal cast strand of a continuous casting plant |
GB2279595A (en) * | 1993-07-06 | 1995-01-11 | British Steel Plc | Continuous casting using rollers having varying radii across their width |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2008626A (en) * | 1932-02-04 | 1935-07-16 | Murakami Yoshimichi | Method for manufacturing metallic materials by rotating rolls or wheels containing a molten metal between them |
US2057580A (en) * | 1934-02-15 | 1936-10-13 | Lansdowne Steel & Iron Company | Method for working standard steel billets |
FR1323948A (en) * | 1962-05-16 | 1963-04-12 | Boehler & Co Ag Geb | Device for guiding the casting bar in continuous casting systems |
FR1335289A (en) * | 1962-09-13 | 1963-08-16 | Verwaltungs Ges Moeller & Neum | Plant for continuous casting of billets |
US3147521A (en) * | 1961-08-10 | 1964-09-08 | Boehm Arnold Henry | Continuous casting and forming process |
US3209452A (en) * | 1961-05-05 | 1965-10-05 | Moossche Eisenwerke Ag | Method of producing bars or sections by continuous casting |
US3374826A (en) * | 1965-03-01 | 1968-03-26 | Porter Co Inc H K | Process for continuously casting elongated metal bodies |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE902304C (en) * | 1950-05-10 | 1954-04-05 | Martin Roeckner Dipl Ing | Process for continuous casting and device for practicing the process |
GB820582A (en) * | 1957-02-05 | 1959-09-23 | British Iron Steel Research | Improvements in or relating to the continuous casting of metals |
-
1964
- 1964-07-03 AT AT571664A patent/AT251213B/en active
-
1965
- 1965-06-02 DE DEB82219A patent/DE1296749B/en active Pending
- 1965-06-07 US US462042A patent/US3478809A/en not_active Expired - Lifetime
- 1965-06-09 GB GB24453/65A patent/GB1048403A/en not_active Expired
- 1965-06-28 NL NL6508272A patent/NL6508272A/xx unknown
- 1965-07-02 SE SE8770/65A patent/SE301365B/xx unknown
- 1965-07-02 BE BE666333A patent/BE666333A/xx unknown
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2008626A (en) * | 1932-02-04 | 1935-07-16 | Murakami Yoshimichi | Method for manufacturing metallic materials by rotating rolls or wheels containing a molten metal between them |
US2057580A (en) * | 1934-02-15 | 1936-10-13 | Lansdowne Steel & Iron Company | Method for working standard steel billets |
US3209452A (en) * | 1961-05-05 | 1965-10-05 | Moossche Eisenwerke Ag | Method of producing bars or sections by continuous casting |
US3147521A (en) * | 1961-08-10 | 1964-09-08 | Boehm Arnold Henry | Continuous casting and forming process |
FR1323948A (en) * | 1962-05-16 | 1963-04-12 | Boehler & Co Ag Geb | Device for guiding the casting bar in continuous casting systems |
FR1335289A (en) * | 1962-09-13 | 1963-08-16 | Verwaltungs Ges Moeller & Neum | Plant for continuous casting of billets |
US3374826A (en) * | 1965-03-01 | 1968-03-26 | Porter Co Inc H K | Process for continuously casting elongated metal bodies |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4493363A (en) * | 1976-07-30 | 1985-01-15 | Jernkontoret | Method at continuous casting of steels and metal alloys with segregation tendency and apparatus for carrying out the method |
WO1993004802A1 (en) * | 1991-09-12 | 1993-03-18 | Giovanni Arvedi | A process and apparatus for the manufacture of billets and blooms from a continuously last steel showing high or excellent quality |
AU658451B2 (en) * | 1991-09-12 | 1995-04-13 | Giovanni Arvedi | A process and an apparatus for the manufacture of billets and blooms from a continuously cast steel showing high or excellent quality |
US5497821A (en) * | 1991-09-12 | 1996-03-12 | Giovanni Arvedi | Manufacture of billets and blooms from a continuously cast steel |
EP0545510A1 (en) * | 1991-11-26 | 1993-06-09 | MANNESMANN Aktiengesellschaft | Process for manufacture of steel long products |
KR100295954B1 (en) * | 1991-11-26 | 2001-10-24 | 마리오 파텍 | Manufacturing method of long steel |
WO2003039789A2 (en) * | 2001-11-06 | 2003-05-15 | Sms Demag Aktiengesellschaft | Method and casting machine for production of casting bars in the shape of billets or blocks |
WO2003039789A3 (en) * | 2001-11-06 | 2003-12-24 | Sms Demag Ag | Method and casting machine for production of casting bars in the shape of billets or blocks |
US20050067135A1 (en) * | 2001-11-06 | 2005-03-31 | Hans Streubel | Method and casting machine for production of casting bars in the shape of billets or blocks |
Also Published As
Publication number | Publication date |
---|---|
NL6508272A (en) | 1966-01-04 |
SE301365B (en) | 1968-06-04 |
AT251213B (en) | 1966-12-27 |
GB1048403A (en) | 1966-11-16 |
DE1296749B (en) | 1969-06-04 |
BE666333A (en) | 1965-11-03 |
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