US3463310A - Separation method - Google Patents
Separation method Download PDFInfo
- Publication number
- US3463310A US3463310A US708627A US3463310DA US3463310A US 3463310 A US3463310 A US 3463310A US 708627 A US708627 A US 708627A US 3463310D A US3463310D A US 3463310DA US 3463310 A US3463310 A US 3463310A
- Authority
- US
- United States
- Prior art keywords
- coal
- pyrite
- heating
- mixture
- tunnel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000000926 separation method Methods 0.000 title description 6
- 239000003245 coal Substances 0.000 description 39
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 35
- 229910052683 pyrite Inorganic materials 0.000 description 34
- 239000011028 pyrite Substances 0.000 description 34
- 238000000034 method Methods 0.000 description 26
- 230000008569 process Effects 0.000 description 25
- 238000010438 heat treatment Methods 0.000 description 22
- 239000000203 mixture Substances 0.000 description 13
- 230000005291 magnetic effect Effects 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 9
- 229910052500 inorganic mineral Inorganic materials 0.000 description 9
- 239000011707 mineral Substances 0.000 description 9
- 239000002245 particle Substances 0.000 description 9
- 238000011282 treatment Methods 0.000 description 9
- 230000005670 electromagnetic radiation Effects 0.000 description 7
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 5
- 230000005294 ferromagnetic effect Effects 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 239000011593 sulfur Substances 0.000 description 5
- 229910052717 sulfur Inorganic materials 0.000 description 5
- 230000008859 change Effects 0.000 description 4
- 229910052595 hematite Inorganic materials 0.000 description 4
- 239000011019 hematite Substances 0.000 description 4
- 238000007885 magnetic separation Methods 0.000 description 4
- 230000001419 dependent effect Effects 0.000 description 3
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 3
- 229910052952 pyrrhotite Inorganic materials 0.000 description 3
- 239000003039 volatile agent Substances 0.000 description 3
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 230000005298 paramagnetic effect Effects 0.000 description 2
- 239000011236 particulate material Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 239000004809 Teflon Substances 0.000 description 1
- 229920006362 Teflon® Polymers 0.000 description 1
- 230000004075 alteration Effects 0.000 description 1
- 229910052964 arsenopyrite Inorganic materials 0.000 description 1
- MJLGNAGLHAQFHV-UHFFFAOYSA-N arsenopyrite Chemical compound [S-2].[Fe+3].[As-] MJLGNAGLHAQFHV-UHFFFAOYSA-N 0.000 description 1
- 229910052948 bornite Inorganic materials 0.000 description 1
- 229910052951 chalcopyrite Inorganic materials 0.000 description 1
- DVRDHUBQLOKMHZ-UHFFFAOYSA-N chalcopyrite Chemical compound [S-2].[S-2].[Fe+2].[Cu+2] DVRDHUBQLOKMHZ-UHFFFAOYSA-N 0.000 description 1
- 239000000571 coke Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000005115 demineralization Methods 0.000 description 1
- 230000002328 demineralizing effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000005292 diamagnetic effect Effects 0.000 description 1
- 239000003989 dielectric material Substances 0.000 description 1
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 1
- 235000013980 iron oxide Nutrition 0.000 description 1
- VBMVTYDPPZVILR-UHFFFAOYSA-N iron(2+);oxygen(2-) Chemical class [O-2].[Fe+2] VBMVTYDPPZVILR-UHFFFAOYSA-N 0.000 description 1
- 230000001678 irradiating effect Effects 0.000 description 1
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Inorganic materials O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052960 marcasite Inorganic materials 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000006069 physical mixture Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 229910021646 siderite Inorganic materials 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000002344 surface layer Substances 0.000 description 1
- 238000007669 thermal treatment Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10B—DESTRUCTIVE DISTILLATION OF CARBONACEOUS MATERIALS FOR PRODUCTION OF GAS, COKE, TAR, OR SIMILAR MATERIALS
- C10B57/00—Other carbonising or coking processes; Features of destructive distillation processes in general
- C10B57/08—Non-mechanical pretreatment of the charge, e.g. desulfurization
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C—MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03C1/00—Magnetic separation
- B03C1/005—Pretreatment specially adapted for magnetic separation
- B03C1/015—Pretreatment specially adapted for magnetic separation by chemical treatment imparting magnetic properties to the material to be separated, e.g. roasting, reduction, oxidation
Definitions
- Some of the minerals which are known to display increased magnetic activity after heat treatment include pyrite, hematite, marcasite, siderite, chalcopyrite, arsenopyrite, bornite, pyrolusite and many others. Temperatures used in the heat treatment generally range from about 300 to 1000 C. for a contact time of few seconds to an hour or more. Treatment conditions used include oxidizing, inert and reducing atmospheres depending upon the mineral. Heat treatment followed by magnetic separation now finds its greatest use in ore concentration.
- Finely divided coal can be subjected t a thermal treatment, usually in the presence of steam and air, to effect at least a partial conversion of the contained pyrite particles to pyrrhotite, magnetite and gamma-hematite. Because these minerals are all ferromagnetic while the original pyrite is paramagnetic, the treatment allows an elficient magnetic separation of the altered pyrite from the coal.
- the pyrite-pyrrhotite transition takes place very rapidly at temperatures on the order of 600 C. and the pyrite to magnetite or hematite oxidation reaction also requires relatively high temperatures. Coal treatment temperatures as high as 360 C. have been used and alteration of the surfaces of pyrite grains to magnetic forms has been reported at these conditions.
- the process of this invention takes advantage of the conductivity differences to electromagnetic radiation between pyrite and coal in order to selectively heat the surface of pyrite particles contained within the coal.
- C011- version of at least the surface of pyrite particles to ferromagnetic forms is accomplished without substantial heating of the coal.
- Another object of this invention is to alter at least the surface of a diamagnetic or paramagnetic mineral to ferromagnetic forms by selectively heating that mineral while it is in physical admixture with other components.
- a specific object of this invention is to remove pyrite from coal.
- the figure is a schematic flow diagram of a preferred embodiment of the separation process.
- Tunnel irratiator 15 is of rectangular cross-section with electrically conducting walls. End sections 16 and 17 terminate the tunnel section and function to suppress the escape of electromagnetic energy. Coal is carried through tunnel 15 by continuous belt conveyor 12 formed of a dielectric material such as a reinforced Teflon. Conveyor 12 may be mounted on rotating drums 18 and 19 disposed one at each end of the tunnel as is conventional in the art. A driving force is applied to at least one of the drums in the direction indicated by arrow 20.
- Electromagnetic energy produced by a suitable conventional source 21, is introduced into tunnel 15 by means of energy conduit 22.
- conduit 22 comprises a waveguide of rectangular cross section having a series of openings spaced along the wall facing the interior of tunnel 15. Microwave energy is thus directed downwardly into the interior of the tunnel where it interacts with the pyrite and coal.
- coaxial cables, striplines and the like may be utilized as the energy conduit rather than the waveguide.
- Treatment time of the coal within the irradiating cavity or tunnel 15 is dependent upon the moisture content of the coal, the frequency of the electromagnetic radiation and the effective voltage gradient within the tunnel. Treatment times in the range of 1 to about 100 seconds are satisfactory for most coals over the frequency range investigated. At 10 ghz, exposure times of about 2 to 10 seconds were found satisfactory.
- Optimum process efliicenies are obtained when only surface modilication of the individual pyrite particels to ferromagnetic forms has been achieved. Continued exposure results in more complete reaction of the pyrite but also results in undue heating of the coal. It is preferred that exposure time be limited to a pyrite conversion level of less than 10% and most preferably to a pyrite conversion level of less than 5%.
- the treating gas may be introduced via conduit 23 at one end of tunnel 15 and removed via conduit 24.
- the treating gas preferably is air.
- Use of air as the treating gas performs two functions; it sweeps out water vapor released from the coal and it provides a EXAMPLE
- Samples of finely divided coal containing pyrite were subjected to electromagnetic radiation at frequencies ranging from 400 khz to ghz. Throughout this frequency range, preferential heating of the contained pyrite was observed. As the frequency increased, the preferential heating of pyrite relative to coal become more pronounced. Pyrite in the mixture thus treated was strongly attracted to a magnet and no losses of coal volatiles were observed.
- the electromagnetic treatment may be performed using any other applicable type of high frequency heating equipment.
- a coaxial tube arrangement having an annular treatment chamber with the electromagnetic radiation facilities arranged within the inner tube may also be used to advantage
- the process has been illustrated as being particularly applicable to the removal of pyrite from coal.
- separations may be performed on other mineral mixtures.
- any mineral mixture having at least one member which is susceptible to being altered to a more highly magnetic form upon heating can be treated by this process.
- a pyrite-chalcopyrite-silicate ore which may be treated to produce a copper concentrate.
- a process for the separation of a mixture of particulate materials, at least one of said materials being susceptible to a change in its magnetic properties upon heating which comprises subjecting said mixture to electromagnetic radiation having a frequency whereat said material susceptible to a change in magnetic properties absorbs electromagnetic energy ⁇ more strongly than does the other components in said mixture and is thereby preferentially heated, continuing the irradiation for a time sufficient t0 cause conversion of at least a surface layer of said particulate material being susceptible to such a change to a more highly magnetic form, terminating the irradiation before substantial heating of the other components of the mixture occurs, subjecting said irradiated mixture to a magnetic separation step and recovering a portion enriched in said magnetically altered material.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US70862768A | 1968-02-27 | 1968-02-27 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3463310A true US3463310A (en) | 1969-08-26 |
Family
ID=24846562
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US708627A Expired - Lifetime US3463310A (en) | 1968-02-27 | 1968-02-27 | Separation method |
Country Status (2)
Country | Link |
---|---|
US (1) | US3463310A (de) |
DE (1) | DE1758135B2 (de) |
Cited By (38)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3969225A (en) * | 1974-04-04 | 1976-07-13 | I. Jordan Kunik | Differential separation of particulates by combined electro-static and radio frequency means |
US3976557A (en) * | 1974-11-29 | 1976-08-24 | Hydrocarbon Research, Inc. | Pretreatment of coal-derived liquid to improve magnetic separation of solids |
US4052170A (en) * | 1976-07-09 | 1977-10-04 | Mobil Oil Corporation | Magnetic desulfurization of airborne pulverized coal |
US4077871A (en) * | 1975-04-14 | 1978-03-07 | Occidental Petroleum Corporation | Separation of colored particulate glass |
US4193767A (en) * | 1977-06-08 | 1980-03-18 | Fipke Charles E | Particulate mineral separation process |
WO1980002220A1 (en) * | 1979-04-09 | 1980-10-16 | D Brandon | An apparatus and method for thawing materials stored in gondola-type containers |
US4252638A (en) * | 1977-12-07 | 1981-02-24 | Klockner-Humboldt-Deutz Ag | Method for the desulfurization of coal |
US4259560A (en) * | 1977-09-21 | 1981-03-31 | Rhodes George W | Process for drying coal and other conductive materials using microwaves |
US4342640A (en) * | 1980-11-24 | 1982-08-03 | Chevron Research Company | Magnetic separation of mineral particles from shale oil |
US4359379A (en) * | 1979-12-21 | 1982-11-16 | Nippon Oil Company, Ltd. | Process for fluid catalytic cracking of distillation residual oils |
US4388179A (en) * | 1980-11-24 | 1983-06-14 | Chevron Research Company | Magnetic separation of mineral particles from shale oil |
US4406773A (en) * | 1981-05-13 | 1983-09-27 | Ashland Oil, Inc. | Magnetic separation of high activity catalyst from low activity catalyst |
US4466362A (en) * | 1982-03-03 | 1984-08-21 | Massachusetts Institute Of Technology | Method of removing sulfur and other contaminants from the coal in coal-oil slurries |
US4661118A (en) * | 1985-04-15 | 1987-04-28 | The United States Of America, As Represented By The Secretary Of The Interior | Method for oxidation of pyrite in coal to magnetite and low field magnetic separation thereof |
EP0431965A2 (de) * | 1989-12-07 | 1991-06-12 | De Beers Industrial Diamond Division (Proprietary) Limited | Magnettrennung von Material mit Wirbelströmen |
US5096066A (en) * | 1987-11-30 | 1992-03-17 | Genesis Research Corporation | Process for beneficiating particulate solids |
US5153838A (en) * | 1987-11-30 | 1992-10-06 | Genesis Research Corporation | Process for beneficiating particulate solids |
US5161695A (en) * | 1989-12-07 | 1992-11-10 | Roos Edwin H | Method and apparatus for separating particulate material according to conductivity |
US5171424A (en) * | 1990-10-22 | 1992-12-15 | Ashland Oil, Inc. | Magnetic separation of old from new cracking catalyst by means of heavy rare earth "magnetic hooks" |
US5190635A (en) * | 1989-04-03 | 1993-03-02 | Ashland Oil, Inc. | Superparamagnetic formation of FCC catalyst provides means of separation of old equilibrium fluid cracking catalyst |
US5262962A (en) * | 1987-11-30 | 1993-11-16 | Genesis Research Corporation | Process for beneficiating particulate solids |
US5538624A (en) * | 1994-10-21 | 1996-07-23 | Ashland Inc. | Process, apparatus and compositions for recycle of cracking catalyst additives |
WO2003072835A1 (en) * | 2002-02-22 | 2003-09-04 | Wave Separation Technologies Llc | Method and apparatus for separating metal values |
US7318528B1 (en) * | 2004-07-26 | 2008-01-15 | Iradj Hessabi | Precious metal recovery |
US7571814B2 (en) | 2002-02-22 | 2009-08-11 | Wave Separation Technologies Llc | Method for separating metal values by exposing to microwave/millimeter wave energy |
US20100038288A1 (en) * | 2008-08-12 | 2010-02-18 | MR&E, Ltd. | Refining coal-derived liquid from coal gasification, coking, and other coal processing operations |
US20110011720A1 (en) * | 2009-07-14 | 2011-01-20 | Rinker Franklin G | Process for treating agglomerating coal by removing volatile components |
US20110011722A1 (en) * | 2009-07-14 | 2011-01-20 | Rinker Franklin G | Process for treating coal by removing volatile components |
CN103447148A (zh) * | 2013-08-08 | 2013-12-18 | 内蒙古科技大学 | 利用微波还原含赤铁矿物料的磁选装置及磁选方法 |
US8968520B2 (en) | 2011-06-03 | 2015-03-03 | National Institute Of Clean And Low-Carbon Energy (Nice) | Coal processing to upgrade low rank coal having low oil content |
US9005322B2 (en) | 2011-07-12 | 2015-04-14 | National Institute Of Clean And Low-Carbon Energy (Nice) | Upgrading coal and other carbonaceous fuels using a lean fuel gas stream from a pyrolysis step |
US9074138B2 (en) | 2011-09-13 | 2015-07-07 | C2O Technologies, Llc | Process for treating coal using multiple dual zone steps |
US9163192B2 (en) | 2010-09-16 | 2015-10-20 | C2O Technologies, Llc | Coal processing with added biomass and volatile control |
US9327320B1 (en) | 2015-01-29 | 2016-05-03 | Green Search, LLC | Apparatus and method for coal dedusting |
JP2016164285A (ja) * | 2015-03-06 | 2016-09-08 | 国立大学法人九州大学 | 選鉱方法 |
JP2016164286A (ja) * | 2015-03-06 | 2016-09-08 | 国立大学法人九州大学 | 選鉱方法 |
US9598646B2 (en) | 2013-01-09 | 2017-03-21 | C20 Technologies, Llc | Process for treating coal to improve recovery of condensable coal derived liquids |
CN111298953A (zh) * | 2020-03-13 | 2020-06-19 | 中国矿业大学 | 一种发电厂燃前粉煤高梯度磁选脱硫方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1478295A (en) * | 1920-10-06 | 1923-12-18 | Metals Production Company Of N | Treatment of complex sulphide ores |
US1512870A (en) * | 1920-09-02 | 1924-10-21 | Krupp Ag Grusonwerk | Method of recovering fuel from residues |
US2907456A (en) * | 1957-05-21 | 1959-10-06 | Int Salt Co | Separation of materials |
US3097160A (en) * | 1959-11-30 | 1963-07-09 | Rosen Alfred H | Method of separating differentially heated particles |
-
1968
- 1968-02-27 US US708627A patent/US3463310A/en not_active Expired - Lifetime
- 1968-04-08 DE DE19681758135 patent/DE1758135B2/de not_active Withdrawn
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1512870A (en) * | 1920-09-02 | 1924-10-21 | Krupp Ag Grusonwerk | Method of recovering fuel from residues |
US1478295A (en) * | 1920-10-06 | 1923-12-18 | Metals Production Company Of N | Treatment of complex sulphide ores |
US2907456A (en) * | 1957-05-21 | 1959-10-06 | Int Salt Co | Separation of materials |
US3097160A (en) * | 1959-11-30 | 1963-07-09 | Rosen Alfred H | Method of separating differentially heated particles |
Cited By (55)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3969225A (en) * | 1974-04-04 | 1976-07-13 | I. Jordan Kunik | Differential separation of particulates by combined electro-static and radio frequency means |
US3976557A (en) * | 1974-11-29 | 1976-08-24 | Hydrocarbon Research, Inc. | Pretreatment of coal-derived liquid to improve magnetic separation of solids |
US4077871A (en) * | 1975-04-14 | 1978-03-07 | Occidental Petroleum Corporation | Separation of colored particulate glass |
US4052170A (en) * | 1976-07-09 | 1977-10-04 | Mobil Oil Corporation | Magnetic desulfurization of airborne pulverized coal |
US4193767A (en) * | 1977-06-08 | 1980-03-18 | Fipke Charles E | Particulate mineral separation process |
US4259560A (en) * | 1977-09-21 | 1981-03-31 | Rhodes George W | Process for drying coal and other conductive materials using microwaves |
US4252638A (en) * | 1977-12-07 | 1981-02-24 | Klockner-Humboldt-Deutz Ag | Method for the desulfurization of coal |
WO1980002220A1 (en) * | 1979-04-09 | 1980-10-16 | D Brandon | An apparatus and method for thawing materials stored in gondola-type containers |
US4359379A (en) * | 1979-12-21 | 1982-11-16 | Nippon Oil Company, Ltd. | Process for fluid catalytic cracking of distillation residual oils |
US4342640A (en) * | 1980-11-24 | 1982-08-03 | Chevron Research Company | Magnetic separation of mineral particles from shale oil |
US4388179A (en) * | 1980-11-24 | 1983-06-14 | Chevron Research Company | Magnetic separation of mineral particles from shale oil |
US4406773A (en) * | 1981-05-13 | 1983-09-27 | Ashland Oil, Inc. | Magnetic separation of high activity catalyst from low activity catalyst |
US4466362A (en) * | 1982-03-03 | 1984-08-21 | Massachusetts Institute Of Technology | Method of removing sulfur and other contaminants from the coal in coal-oil slurries |
US4661118A (en) * | 1985-04-15 | 1987-04-28 | The United States Of America, As Represented By The Secretary Of The Interior | Method for oxidation of pyrite in coal to magnetite and low field magnetic separation thereof |
US5096066A (en) * | 1987-11-30 | 1992-03-17 | Genesis Research Corporation | Process for beneficiating particulate solids |
US5153838A (en) * | 1987-11-30 | 1992-10-06 | Genesis Research Corporation | Process for beneficiating particulate solids |
US5262962A (en) * | 1987-11-30 | 1993-11-16 | Genesis Research Corporation | Process for beneficiating particulate solids |
US5280836A (en) * | 1987-11-30 | 1994-01-25 | Genesis Research Corporation | Process for beneficiating particulate solids |
US5190635A (en) * | 1989-04-03 | 1993-03-02 | Ashland Oil, Inc. | Superparamagnetic formation of FCC catalyst provides means of separation of old equilibrium fluid cracking catalyst |
EP0431965A2 (de) * | 1989-12-07 | 1991-06-12 | De Beers Industrial Diamond Division (Proprietary) Limited | Magnettrennung von Material mit Wirbelströmen |
EP0431965A3 (en) * | 1989-12-07 | 1991-08-21 | De Beers Industrial Diamond Division (Proprietary) Limited | Magnetic separation of material using eddy currents |
AU629073B2 (en) * | 1989-12-07 | 1992-09-24 | De Beers Industrial Diamond Division (Proprietary) Limited | Material separation |
US5161695A (en) * | 1989-12-07 | 1992-11-10 | Roos Edwin H | Method and apparatus for separating particulate material according to conductivity |
US5171424A (en) * | 1990-10-22 | 1992-12-15 | Ashland Oil, Inc. | Magnetic separation of old from new cracking catalyst by means of heavy rare earth "magnetic hooks" |
US5538624A (en) * | 1994-10-21 | 1996-07-23 | Ashland Inc. | Process, apparatus and compositions for recycle of cracking catalyst additives |
AU2003216298A1 (en) * | 2002-02-22 | 2003-09-09 | Wave Separation Technologies Llc | Method and apparatus for separating metal values |
US20040258591A1 (en) * | 2002-02-22 | 2004-12-23 | Birken Stephen M. | Method and apparatus for separating metal values |
US6923328B2 (en) | 2002-02-22 | 2005-08-02 | Wave Separation Technologies Llc | Method and apparatus for separating metal values |
US7571814B2 (en) | 2002-02-22 | 2009-08-11 | Wave Separation Technologies Llc | Method for separating metal values by exposing to microwave/millimeter wave energy |
CN100532592C (zh) * | 2002-02-22 | 2009-08-26 | 波分离技术有限责任公司 | 分离有价值的金属用的方法和设备 |
US20090267275A1 (en) * | 2002-02-22 | 2009-10-29 | Wave Separation Technologies Llc | Method and Apparatus for Separating Metal Values |
US8469196B2 (en) | 2002-02-22 | 2013-06-25 | Wave Separation Technologies, Llc | Method and apparatus for separating metal values |
WO2003072835A1 (en) * | 2002-02-22 | 2003-09-04 | Wave Separation Technologies Llc | Method and apparatus for separating metal values |
US7318528B1 (en) * | 2004-07-26 | 2008-01-15 | Iradj Hessabi | Precious metal recovery |
US20110168541A1 (en) * | 2008-08-12 | 2011-07-14 | Warwick James S | Refining Coal-Derived Liquid From Coal Gasification, Coking and Other Coal Processing Operations |
US20100038288A1 (en) * | 2008-08-12 | 2010-02-18 | MR&E, Ltd. | Refining coal-derived liquid from coal gasification, coking, and other coal processing operations |
US8197678B2 (en) | 2008-08-12 | 2012-06-12 | MR & E, Ltd. | Refining coal-derived liquid from coal gasification, coking and other coal processing operations |
US8394240B2 (en) | 2009-07-14 | 2013-03-12 | C2O Technologies, Llc | Process for treating bituminous coal by removing volatile components |
US8366882B2 (en) | 2009-07-14 | 2013-02-05 | C20 Technologies, Llc | Process for treating agglomerating coal by removing volatile components |
US20110011722A1 (en) * | 2009-07-14 | 2011-01-20 | Rinker Franklin G | Process for treating coal by removing volatile components |
US8470134B2 (en) | 2009-07-14 | 2013-06-25 | C2O Technologies, Llc | Process for treating coal by removing volatile components |
US20110011720A1 (en) * | 2009-07-14 | 2011-01-20 | Rinker Franklin G | Process for treating agglomerating coal by removing volatile components |
US20110011719A1 (en) * | 2009-07-14 | 2011-01-20 | Rinker Franklin G | Process for treating bituminous coal by removing volatile components |
US9163192B2 (en) | 2010-09-16 | 2015-10-20 | C2O Technologies, Llc | Coal processing with added biomass and volatile control |
US8968520B2 (en) | 2011-06-03 | 2015-03-03 | National Institute Of Clean And Low-Carbon Energy (Nice) | Coal processing to upgrade low rank coal having low oil content |
US9523039B2 (en) | 2011-07-12 | 2016-12-20 | Shenhua Group Corporation Limited | Upgrading coal and other carbonaceous fuels using a lean fuel gas stream from a pyrolysis step |
US9005322B2 (en) | 2011-07-12 | 2015-04-14 | National Institute Of Clean And Low-Carbon Energy (Nice) | Upgrading coal and other carbonaceous fuels using a lean fuel gas stream from a pyrolysis step |
US9074138B2 (en) | 2011-09-13 | 2015-07-07 | C2O Technologies, Llc | Process for treating coal using multiple dual zone steps |
US9598646B2 (en) | 2013-01-09 | 2017-03-21 | C20 Technologies, Llc | Process for treating coal to improve recovery of condensable coal derived liquids |
CN103447148B (zh) * | 2013-08-08 | 2016-02-17 | 内蒙古科技大学 | 利用微波还原含赤铁矿物料的磁选装置及磁选方法 |
CN103447148A (zh) * | 2013-08-08 | 2013-12-18 | 内蒙古科技大学 | 利用微波还原含赤铁矿物料的磁选装置及磁选方法 |
US9327320B1 (en) | 2015-01-29 | 2016-05-03 | Green Search, LLC | Apparatus and method for coal dedusting |
JP2016164285A (ja) * | 2015-03-06 | 2016-09-08 | 国立大学法人九州大学 | 選鉱方法 |
JP2016164286A (ja) * | 2015-03-06 | 2016-09-08 | 国立大学法人九州大学 | 選鉱方法 |
CN111298953A (zh) * | 2020-03-13 | 2020-06-19 | 中国矿业大学 | 一种发电厂燃前粉煤高梯度磁选脱硫方法 |
Also Published As
Publication number | Publication date |
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DE1758135A1 (de) | 1971-03-04 |
DE1758135B2 (de) | 1972-04-06 |
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