US3435592A - Process and apparatus for the purification of the gases generated in the chlorinating treatment of aluminous melts - Google Patents
Process and apparatus for the purification of the gases generated in the chlorinating treatment of aluminous melts Download PDFInfo
- Publication number
- US3435592A US3435592A US568584A US56858466A US3435592A US 3435592 A US3435592 A US 3435592A US 568584 A US568584 A US 568584A US 56858466 A US56858466 A US 56858466A US 3435592 A US3435592 A US 3435592A
- Authority
- US
- United States
- Prior art keywords
- liquid
- gas
- aluminum chloride
- melt
- waste gas
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/46—Removing components of defined structure
- B01D53/68—Halogens or halogen compounds
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B21/00—Obtaining aluminium
- C22B21/06—Obtaining aluminium refining
- C22B21/064—Obtaining aluminium refining using inert or reactive gases
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Definitions
- This invention relates to purifying the 'waste gases which are formed in the removal of hydrogen from aluminous melts by introduction of chlorine, and 1s concerned with a process and apparatus for accomplishing this purpose.
- molten pure aluminum has the capacity to hold great amounts of hydrogen.
- Said hydrogen is partly dissolved in the melt as atomic hydrogen, partly it is chemically bound as aluminum hydride.
- the dissolved atomic h ydrogen changes into the molecular state and causes obnoxious bubbles in the casting.
- the melt is chlorinated by introduction of dry chlorine or carbon chloride compounds, whereby the hydrogen is converted to hydrogen chloride.
- a large stoichiometric excess of chlorine gas must be applied to produce a thorough intermixture of the melt with the chlorine and substantial removal of the hydrogen.
- said excess chlorinating gas forms aluminum chloride which at atmospheric pressure sublimes at about 180 C. from the solid state into the gaseous state.
- the reaction products leaving the melt at a temperature of about 700 C. consist essentially of gaseous aluminum chloride and a small proportion of gaseous hydrogen chloride. If said chlorination waste gases are allowed to escape into the atmosphere, dense white fumes are formed when they are cooled below the sublimation temperature of the aluminum chloride. Said fumes consist of very fine solid aluminum chloride particles, and chemically aggressive hydrochloric acid formed on contact with the moisture of the air due to the presence of hydrogen chloride gas. Therefore, said waste gases must be puried before they enter the atmosphere.
- a purification method has become known where a hood is placed above the Crucible.
- the chlorination gases leaving the nielt are mixed between crucible and hood with air, drawn off and passed into a separation station.
- the temperature of the gas mixture falls below the sublimation temperature of the aluminum chloride; thereby, the aluminum chloride precipitates in the form of very tine particles having a diameter essentially below 1/1000 mm.
- the removal of said aluminum chloride particles from the gas current is 'very difcult and requires costly apparatus. Cyclones, wash or spray towers or mechanical washing devices do not give satisfactory re- Patented Apr.
- the known separators generally comprise a wash tower in :which the coarser aluminum chloride particles and the hydrogen chloride gas are washed out, and a subsequent wet electrolter for the removal of the line aluminum chloride particles.
- Such purification methods are expensive and require much space because they must use costly electroiilters and treat large quantities ofrgases, due to the carrier air employed.
- One of the objects of this invention is to provide a process and apparatus which eliminates the drawback of the known procedure that the originally gaseous aluminum chloride is precipitated as very iine particles whose removal is diflicult.
- Another object of the invention is to provide a simple apparatus for the removal of the chlorination reaction products, particularly the aluminum chloride, from an aluminous melt.
- the waste gas of the chlorinating treatment of aluminous melts which waste gas has still a temperature above the sublimation temperature of the aluminum chloride contained therein, is contacted -with a liquid surface which has a temperature below said sublimation temperature.
- the aluminum chloride condenses on said liquid surface, is absorbed by the liquid, and can be removed therewith.
- Our new method allows of absorbing substantially the entire aluminum chloride condensed at the liquid surface immediately after it has passed into the solid phase; in contrast to the known condensation devi-ces for aluminum chloride, our method prevents the formation of solid accretions which would have to be removed periodically.
- the formation of such solid accretions has the additional drawback that with increasing thickness of the adhering chloride layer the condensation effect of the separator device decreases because said layer has a low heat conductivity and hinders the heat transfer.
- a condensation of the aluminum chloride on a liquid surface prevents the condensation products to form accretions because they are absorbed by the liquid immediately after they are formed, and are continuously discharged together with the liquid.
- a preferred liquid is water but ⁇ weakly alkaline aqueous solutions which are good absorbers for aluminum chloride and hydrogen chloride can also be used. There is no risk of any substantial evaporation of the absorption liquid on contact with the waste gases because the heat content of said gases is relatively small and because the heating of the liquid can be limited to a predetermined degree by adjusting the liquid feed per unit of time accordingly.
- the apparatus for carrying out the process comprises a gas space above the aluminum melt, which gas space is essentially or completely sealed against the entry of the atmosphere and provided with a conduit for the vwaste gas, and it comprises further a separator device for the aluminum chloride.
- the walls defining said gas space are heat insulated, and the separator device is a falling film condenser for the aluminum chloride consisting of one or more fall tubes which are Connected gastight to the waste gas conduit.
- the inner and/ or outer faces of said fall tubes presented to the gas current are covered by a liquid tilm which extends over the entire tube circumference and drains downwardlyA by gravity.
- the gas space above the aluminum melt is substantially enclosed by a hood tightly placed on the Crucible.
- our new apparatus allows of passing the waste gas without any noticeable admixture of atmospheric air into a falling lm condenser which offers a large liquid surface and ensures self-purification of the fall tubes, thereby preventing any deposits of solid matter in said fall tubes.
- Spray towers for condensing the aluminum chloride are less effective than falling film condensers because the individual dro-ps of the sprayed liquid leave, on their passage through the gas, a Zone of undercooled gas in which the aluminum Chloride precipitates in form of solid particles.
- a hermetic seal 4between the Waste gas conduit and the condenser can be readily obtained by providing therebetween a fluid seal where the liquid container, in which the end of the waste gas conduit, or a connecting piece, is immersed, serves simultaneously as supply Wessel for the liquid for the fall tubes.
- the waste gas leaving the falling film condenser is passed through a packed scrubbing column in countercurrent to a washing liquid and then through a liquid jet aspirator which is connected to an exhaust for the purified gas over a collecting and gas Iseparating vessel.
- the gas is ⁇ washed and the residual hydrogen chloride as well as the entrained particles of the melt are removed while in the suction jet the chlorine, which may be still present in the Waste gas, is dissolved by the thorough mixing with a large amount of liquid and disc-harged therewith.
- the liquid jet suction pump acts as conveying means for the Waste gas as well as to maintain the reduced pressure in the preceding conduits and parts of the apparatus through which the waste gas ows.
- the liquid jet suction pump is operated with a large ⁇ supply of fluid so as to produce a thorough mixing of the waste gas with said operating fluid and to absorb any free chlorine therein.
- the gas can be passed repeatedly therethrough.
- the discharge of the suction jet may be connected with the suction side by a line provided with a control val-ve to return part of the ⁇ waste gas to the suction jet. In this way, contact time and contact surface ⁇ between Waste gas and jet operating liquid can be adjusted yby manipulation of the control valve.
- the drawing shows a Crucible provided with an iron shell 1 and an inner lining 3; the Crucible contains the aluminous melt 2 to be chlorinated.
- a draw device (not shown) engages ⁇ with hook 4 the Crucible to tilt it around the pivot 5 for tapping.
- a hood for the waste gasses is -placed on the Crucible.
- Said hood is detachably secured to the Crucible by means of screws 7, with interposition of a seal 8, which may consist of asbestos.
- a seal 8 prevents entry of atmospheric air into the gas space. This prevents that the chlorination waste gas leaving the melt is mixed with cold air entering between Crucible and hool, and is cooled to such an extent that gaseous aluminum chloride precipitates in form of the solid sublimate.
- the hood 6 is provided with an outer heat insulation 10 to prevent deposits of solid aluminum chloride on cold areas of the walls.
- the heat insulation is so dimensioned as to maintain, due to the heat radiation of the 'aluminous melt, which has a temperature of about 700 C., a Wall temperature of the hood above the sublimitation temperature of the AlCl3 ⁇ of about 180 C.
- a chlorine distributing pipe 12 is passed through a connecting nipple 11 in the center of the hood 6 and immersed in the aluminous melt 2.
- the chlorine is supplied to pipe 12 from a pressure vessel through a line 12 and a flexible admission line 13.
- a valve 14 in line 131 permits metering the amount of chlorine fed into the me t.
- the hood 6 has a flange 15a for connection to a waste gas line 16 which is provided with a heat insulation 18 and serves to draw off the gas to be purified from the gas space.
- a waste gas line 16 which is provided with a heat insulation 18 and serves to draw off the gas to be purified from the gas space.
- electric heating means in form ⁇ of a heating band 17 spirally wound around the pipe, which is connected, preferably via a thermoswitch (not shown), to an electric voltage source so as to keep the tube 16 always at a temperature above the sublimation temperature of the aluminum Chloride.
- the waste gas line 16 enters a condenser into which the waste gas is introduced for removal of the aluminum chloride and part ⁇ of the hydrogen chloride.
- Said condenser is a falling ilm condenser and com-prises a fall tube 19 whose inner face is entirely covered by a liquid iilm.
- the upper end of the fall tube which is provided with intake teeth 20, dips into a liquid distributing cup 21 which receives the liquid, e.g., water, from the supply line 22 equipped with a throttle 23.
- the distributor cup 21 is open at the top to avoid that the liquid can flow through the waste gas line 16 into the Crucible and be evaporated there explosively, when there is any obstruction in the proper drainage of the liquid from the Condenser or from the collecting vessel 26.
- the gas line 16 swings upwardly; therefore, the connection between said line and the condenser must be arranged for ready disconnection.
- the connection -of the waste gas tube 16 to the fall tube 19 is provided by a fluid seal where the distributor cup 21 for the liquid forms an immersion vessel for a short cylindrical brim 25, which is detachably secured to the electrically heated and heat insulated conically fiaring end 24 of tube 16.
- the brim 25 encloses the fall tube 19 so as to leave a free slot through which the supplied liquid passes from the distributor cup to the inner wall of the fall tube 19.
- the brim is unheated and always in contact with moist waste gas, corrosion is unavoidable.
- the brim is formed as a readily replaced wearing member and is screwed to the conically liaring tube end 24 over a flange connection for easy removal.
- a collecting vessel 26 with a connecting flange for said fall tube. Adjacent to said fall tube 19, a washer in form of a packed column 27 is secured to said collecting vessel.
- the collecting vessel 26 is filled with liquid only to a predetermined level so that the gas leaving the fall tube 19 passes over the surface of the liquid and enters the packed column 27.
- the gas then passes at a suitably high speed the packing 28 which may consist, for example, of Raschig rings, from the bottom to the top in countercurrent to the down flowing wash liquid, which is supplied from the line 22 through a throttle 30 in adjustable quantities.
- the residual hydrogen chloride of the waste gases is substantially absorbed in the liquid of column 27, where, in addition, the solidied melt particles entrained by the chlorinating gas are removed.
- the gas passes through a connecting line 44 to liquid suction jet 31 which receives the operating liquid in ⁇ amounts adjustable by the throttle valve 32 from the :pressure line 22.
- the suction jet 31 is connected through a line 33 with a collecting vessel 34, which communicates, through line 40, with vessel 26.
- the liquid is siphoned at 35 into the canalization 36, while the purified waste gas, which separates in the collecting vessel 34 from the liquid, escapes at 37 into the atmosphere.
- the jet pump In order to increase the chlorine-'absorbing effect of the jet pump, it may be overdimensioned with respect to its delivery many times, e.g., tenfold, so that, e.g., 90 percent of the delivered waste gas can be returned from line 37 through the connecting line 38 equipped with throttlevalve 41 to the suction side of the jet pump.
- the waste gas drawn loff from the packed column 27 can be passed about 10 times through the jet aspirator, thereby prolonging accordingly the residence time of the gas in the mixing chamber of the ⁇ aspirator and producing an increased absorption of the chlorine.
- the liquid consumption of the purification plant can be reduced by recycling, by means of pump 39, part of the operating liquid coming from the fall tube 19, the packed column 27, and the jet pum-p 31, into said units.
- the pump 39 is at its outlet side connected to the pressure line 22 by means of a connecting line 45 provided with a check valve 42. Said check valve 42 lprevents development of a short circuit ow from the pressure line 22 directly through pump 39 into ,the canalization.
- the pressure line 22 contains a ⁇ further check valve 43 to prevent return of the liquid through the pump 39 into the general pressure system.
- a process for the purification of the hot waste gases formed in the removal of hydrogen by the chlorination of aluminous melt comprising contacting said waste Vgases at a temperature above the sublimation temperature of the aluminum chloride contained therein with a liquid surface which completely encloses the stream of the wast gases and has a temperature below said sublimation temperatue, to condense said aluminum chloride on said liquid surface and to dissolve the same in said liquid, removing said dissolved aluminum chloride with said liquid, subsequently washing said waste gases freed from aluminum chloride to remove hydrogen chloride still contained in the gases and solid particles entrained from the melt, finally admixing to the waste gases in amount of Water suliicient to absorb free chlorine contained in said gases, separating the waste gases from said water containing-the absorbed chlorine, and discharging said purified waste gases.
- An apparatus for the purification of the waste gases which are formed in the removal of hydrogen by the chlorination of an aluminous melt comprising a crucible for an alumin-ous melt, heat insulated walls defining a gas space above said melt substantially sealed against the atmosphere, a falling film condenser comprising at least one fall tube, means for supplying liquid to said condenser for contacting said waste gases with the falling film of said liquid, a iirst collection vessel for collecting the falling film of said condenser with the aluminum chloride precipitated therein from said waste gases, a packed column in which the waste gases leaving said first collection vessel are passed in countercurrent to said wash liquid, a liquid jet suction pump receiving the gases from said :packed column, a second collecting vessel for separating the liquid and gas delivered by said jet suction pump, an outlet for said gas, and a line connecting said two collecting vessels.
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Biomedical Technology (AREA)
- Analytical Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Treating Waste Gases (AREA)
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE19651268850 DE1268850C2 (de) | 1965-07-16 | 1965-07-16 | Vorrichtung zur reinigung der abgase, die beim entfernen des wasserstoffes aus aluminiumschmelzen durch einleiten von chlor entstehen |
AT711565A AT254534B (de) | 1965-07-16 | 1965-08-02 | Verfahren und Vorrichtung zur Reinigung der Abgase, die bei der Entfernung des Wasserstoffs aus Aluminiumschmelzen durch Einleiten von Chlor entstehen |
GB31825/66A GB1095730A (en) | 1965-07-16 | 1966-07-15 | A method of and a device for purifying waste gases |
FR8662A FR1486885A (fr) | 1965-07-16 | 1966-07-15 | Procédé et installation pour l'épuration des gaz d'échappement produits par l'introduction de chlore en vue de l'enlèvement de l'hydrogène dans des bains d'aluminium fondu |
NO163942A NO115908B (de) | 1965-07-16 | 1966-07-15 | |
US568584A US3435592A (en) | 1965-07-16 | 1966-07-28 | Process and apparatus for the purification of the gases generated in the chlorinating treatment of aluminous melts |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEK0056637 | 1965-07-16 | ||
US568584A US3435592A (en) | 1965-07-16 | 1966-07-28 | Process and apparatus for the purification of the gases generated in the chlorinating treatment of aluminous melts |
Publications (1)
Publication Number | Publication Date |
---|---|
US3435592A true US3435592A (en) | 1969-04-01 |
Family
ID=25984095
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US568584A Expired - Lifetime US3435592A (en) | 1965-07-16 | 1966-07-28 | Process and apparatus for the purification of the gases generated in the chlorinating treatment of aluminous melts |
Country Status (6)
Country | Link |
---|---|
US (1) | US3435592A (de) |
AT (1) | AT254534B (de) |
DE (1) | DE1268850C2 (de) |
FR (1) | FR1486885A (de) |
GB (1) | GB1095730A (de) |
NO (1) | NO115908B (de) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3904494A (en) * | 1971-09-09 | 1975-09-09 | Aluminum Co Of America | Effluent gas recycling and recovery in electrolytic cells for production of aluminum from aluminum chloride |
US4036915A (en) * | 1973-01-02 | 1977-07-19 | Meloy Laboratories, Inc. | Temperature-controlled apparatus for fluid permeation or the like |
US4405563A (en) * | 1980-11-26 | 1983-09-20 | Irwin Fox | Scavenging natural gas streams with slurry apparatus |
CN111699028A (zh) * | 2017-12-27 | 2020-09-22 | 欧萨斯能源环境设备有限公司 | 用于除去液态盐的具有排出部的装置以及方法 |
US10941497B2 (en) | 2017-02-27 | 2021-03-09 | Honeywell International Inc. | Electrochemical carbon dioxide converter and liquid regenerator |
US11123685B2 (en) * | 2017-02-27 | 2021-09-21 | Honeywell International Inc. | Hollow fiber membrane contactor scrubber/stripper for cabin carbon dioxide and humidity control |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SE424507B (sv) * | 1977-02-03 | 1982-07-26 | Aluminum Co Of America | Forfarande for rening av avgaser erhallna vid framstellning av aluminiumklorid |
EP0040643A1 (de) * | 1980-05-24 | 1981-12-02 | AMSTED Industries Incorporated | Verfahren zum Trennen von Feststoffen in lösliche und unlösliche Bestandteile und Vorrichtung zur Durchführung des Verfahrens |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2718279A (en) * | 1952-12-18 | 1955-09-20 | Du Pont | Process for condensing vaporized metal halides |
US3073092A (en) * | 1959-12-28 | 1963-01-15 | British Titan Products | Cooling of vapour-phase oxidation products |
US3078145A (en) * | 1958-10-14 | 1963-02-19 | Nac Calvo Sotelo De Combustibl | Process and apparatus for producing anhydrous aluminum chloride |
US3152864A (en) * | 1962-03-07 | 1964-10-13 | Nat Smelting Co Ltd | Production of aluminium chloride |
US3257777A (en) * | 1961-01-31 | 1966-06-28 | Demag Elektrometallurgie Gmbh | Process for treating waste gases |
US3284992A (en) * | 1963-09-30 | 1966-11-15 | Ethyl Corp | Hydrogen chloride separation |
-
1965
- 1965-07-16 DE DE19651268850 patent/DE1268850C2/de not_active Expired
- 1965-08-02 AT AT711565A patent/AT254534B/de active
-
1966
- 1966-07-15 NO NO163942A patent/NO115908B/no unknown
- 1966-07-15 FR FR8662A patent/FR1486885A/fr not_active Expired
- 1966-07-15 GB GB31825/66A patent/GB1095730A/en not_active Expired
- 1966-07-28 US US568584A patent/US3435592A/en not_active Expired - Lifetime
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2718279A (en) * | 1952-12-18 | 1955-09-20 | Du Pont | Process for condensing vaporized metal halides |
US3078145A (en) * | 1958-10-14 | 1963-02-19 | Nac Calvo Sotelo De Combustibl | Process and apparatus for producing anhydrous aluminum chloride |
US3073092A (en) * | 1959-12-28 | 1963-01-15 | British Titan Products | Cooling of vapour-phase oxidation products |
US3257777A (en) * | 1961-01-31 | 1966-06-28 | Demag Elektrometallurgie Gmbh | Process for treating waste gases |
US3152864A (en) * | 1962-03-07 | 1964-10-13 | Nat Smelting Co Ltd | Production of aluminium chloride |
US3284992A (en) * | 1963-09-30 | 1966-11-15 | Ethyl Corp | Hydrogen chloride separation |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3904494A (en) * | 1971-09-09 | 1975-09-09 | Aluminum Co Of America | Effluent gas recycling and recovery in electrolytic cells for production of aluminum from aluminum chloride |
US4036915A (en) * | 1973-01-02 | 1977-07-19 | Meloy Laboratories, Inc. | Temperature-controlled apparatus for fluid permeation or the like |
US4405563A (en) * | 1980-11-26 | 1983-09-20 | Irwin Fox | Scavenging natural gas streams with slurry apparatus |
US10941497B2 (en) | 2017-02-27 | 2021-03-09 | Honeywell International Inc. | Electrochemical carbon dioxide converter and liquid regenerator |
US11123685B2 (en) * | 2017-02-27 | 2021-09-21 | Honeywell International Inc. | Hollow fiber membrane contactor scrubber/stripper for cabin carbon dioxide and humidity control |
US11466372B2 (en) | 2017-02-27 | 2022-10-11 | Honeywell International Inc. | Electrochemical carbon dioxide converter and liquid regenerator |
US11519080B2 (en) | 2017-02-27 | 2022-12-06 | Honeywell International Inc. | Electrochemical carbon dioxide converter and liquid regenerator |
US11519079B2 (en) | 2017-02-27 | 2022-12-06 | Honeywell International Inc. | Electrochemical carbon dioxide converter and liquid regenerator |
US11707709B2 (en) | 2017-02-27 | 2023-07-25 | Honeywell International Inc. | Hollow fiber membrane contactor scrubber/stripper for cabin carbon dioxide and humidity control |
CN111699028A (zh) * | 2017-12-27 | 2020-09-22 | 欧萨斯能源环境设备有限公司 | 用于除去液态盐的具有排出部的装置以及方法 |
CN111699028B (zh) * | 2017-12-27 | 2023-04-04 | 克里斯托夫全球影响有限公司 | 用于除去液态盐的具有排出部的装置以及方法 |
Also Published As
Publication number | Publication date |
---|---|
FR1486885A (fr) | 1967-06-30 |
DE1268850B (de) | 1974-10-03 |
NO115908B (de) | 1968-12-23 |
GB1095730A (en) | 1967-12-20 |
AT254534B (de) | 1967-05-26 |
DE1268850C2 (de) | 1974-10-03 |
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