US3378366A - Method of inspection and control of the reaction performance during the oxygen blowing process - Google Patents
Method of inspection and control of the reaction performance during the oxygen blowing process Download PDFInfo
- Publication number
- US3378366A US3378366A US464145A US46414565A US3378366A US 3378366 A US3378366 A US 3378366A US 464145 A US464145 A US 464145A US 46414565 A US46414565 A US 46414565A US 3378366 A US3378366 A US 3378366A
- Authority
- US
- United States
- Prior art keywords
- oxygen
- blowing
- conductivity
- inspection
- converter
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000007664 blowing Methods 0.000 title description 45
- 238000000034 method Methods 0.000 title description 42
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 title description 32
- 229910052760 oxygen Inorganic materials 0.000 title description 32
- 239000001301 oxygen Substances 0.000 title description 32
- 238000006243 chemical reaction Methods 0.000 title description 14
- 238000007689 inspection Methods 0.000 title description 11
- 239000002184 metal Substances 0.000 description 25
- 229910052751 metal Inorganic materials 0.000 description 25
- 238000007670 refining Methods 0.000 description 10
- 239000002893 slag Substances 0.000 description 7
- 239000007789 gas Substances 0.000 description 4
- 238000009413 insulation Methods 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 229910052799 carbon Inorganic materials 0.000 description 3
- 238000005261 decarburization Methods 0.000 description 3
- 238000005259 measurement Methods 0.000 description 3
- 239000000155 melt Substances 0.000 description 3
- 239000000523 sample Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 229910000805 Pig iron Inorganic materials 0.000 description 2
- 239000000498 cooling water Substances 0.000 description 2
- 238000010310 metallurgical process Methods 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000010292 electrical insulation Methods 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 238000003780 insertion Methods 0.000 description 1
- 230000037431 insertion Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 239000012495 reaction gas Substances 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C5/00—Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
- C21C5/28—Manufacture of steel in the converter
- C21C5/30—Regulating or controlling the blowing
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C5/00—Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
- C21C5/28—Manufacture of steel in the converter
- C21C5/30—Regulating or controlling the blowing
- C21C5/32—Blowing from above
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C5/00—Manufacture of carbon-steel, e.g. plain mild steel, medium carbon steel or cast steel or stainless steel
- C21C5/28—Manufacture of steel in the converter
- C21C5/42—Constructional features of converters
- C21C5/46—Details or accessories
- C21C5/4673—Measuring and sampling devices
Definitions
- ABSTRACT 0F THE DISCLGSURE A method of inspection and control of the conditions prevailing in a converter during the oxygen blowing process of refining molten metal which includes the steps of positioning a single electrically conductive and insulated member in the converter spaced above the surface of the metal bath therein, passing an electric current through a closed circuit which includes the member, the atmosphere in the space between the surface of the metal bath and the member, the metal bath, and a wall of the converter, providing an electrical resistance between the member and ground of about 10 ohms to about 10,000 ohms, measuring the electric current passing through the circuit during the refining of the metal, and varying the conditions under which the refining of the metal in the converter takes place in accordance with the variations in the flow of electric current through the circuit as determined by the measurement.
- the present invention relates to a method of inspection and control of the reaction performance during the oxygen blowing process.
- the electric resistance of the insulation amounts to much less than 10,000 ohms, as for instance 10 ohms.
- the apparatus capable of performing in accordance with the method of the present invention comprises a converter 1 of conventional structure, which is equipped with an upper mouth portion 3 through which a blowing tube 2 is inserted for blowing oxygen into the converter 1.
- the blowing tube 2 is cooled and for this purpose the blowing tube 2 includes a jacket 4' forming the outer part of the blowing tube 2.
- a feeding-in tube 4 leads into the jacket 4 and a feeding-off tube 5 leads off the jacket 4', so that cooling water is continuously fed through the jacket 4'.
- An oxygen feeding tube 6 is disposed on top of the blowing tube 2 and communicates with the latter.
- a moving slide 7 surrounds the blowing tube 2, which moving slide 7 is adapted to lift and lower, respectively, the blowing tube 2.
- An electrical insulation ring 8 is disposed between the blowing tube 2 and the moving slide 7 for a purpose more clearly disclosed below.
- An electric source 9 feeds electric current into a circuit comprising an electrical conduit 10 which has one terminal at the oxygen feeding tube 6 and another terminal at the outer face of the converter 1, so that the oxygen blowing tube 2 and the converter 1 are disposed in series in the electrical circuit.
- the circuit includes a conductivity measuring device 11 which is disposed in series in said circuit and which conductivity measuring device is operatively connected with an indicating device 11' in order to indicate on a diagram the conductivity of the current through the metal bath to be processed.
- the oxygen-blowing tube 2 used in the method of the present invention is electrically insulated from the remaining parts of the entire unit by means of the insulating ring 8.
- the oxygen blowing tube 2 can also be grounded.
- the electrical resistance should amount less than 10,000 ohms and may assume values of about 10 ohms.
- the resistance of the cooling water and oxygen feeding tubes amounts to a multiple of this value in case non-n1etallic tubes are used.
- the insulation of the oxygen blowing tube towards its supporting device and moving slide 7, respectively, or any other carrying means can be obtained by insertion of insulating layers between the blowing tube and its mounting, as for instance, by means of the insulation ring 8.
- the present invention is not only applicable to a method performed in a LED-converter, but also in such decarburization methods in which the blowing of oxygen takes place on a rotating converter, for instance, in a Kaldoconverter rotating in an oblique position.
- the conductivity between the blowing tube and the metal bath and the inner wall of the reaction vessel, which is connected for a good electrical conducting with a converter jacket as well as with the other parts of the unit is continuously determined and recorded.
- two or more resistance measuring ranges capable of switching over, can be used, whereby the switching over from one range to another range-can be obtained automatically by any 3 -24 conventional means upon reaching a predetermined value.
- the oxygen feeding tube Prior to the start of the blowing operation, by lowering the oxygen feeding tube to engagement with the bath surface, its height can be determined and, thereby, the distance between the blowing nozzle and the bath surface required for the process can be set exactly with distances required for the process, whereby the time of engagement is indicated by a strong change of the electric conductivity. If the oxygen feeding tube cannot be lowered as far or if an immersion of the tube should be avoided, the latter can be extended for a predetermined length by means of an electrically conducting extension member (not shown), which is electrically conducting with the oxygen feeding tube.
- the conductivity between the blowing tube and the bath is determined during the blowing process in dependency of a series of influences.
- An appreciable influence has the conductivity of the reaction gases rising from the bath and of the oxygen stream burning at a certain distance from the blower nozzle in which temperatures between 20003000 C. occur.
- This conductivity is, for instance, a function of the quantity of reaction gases formed in the bath within a given time unit, which reaction gas quantity is proportional to the carbon loss.
- the loading or" the gases with iron smoke and squirters, as well as the formation of a froth slag have their effect on the conductivity.
- a voltage iscreated between the blowing tube and the bath depending upon the prevailing conditions, which voltage, for instance, varies strongly within the range of +0.1 to -0.1 volt.
- the conductivity is also influenced by the metallurgical processes, by the apparatus, by the particular process and by the measuring method.
- the presence of accompanying elements, for instance Si, which binds preferably the oxygen the carbon residue remains low as long as the accompanying elements are mostly slag. The more or less steep rise of the conductivity indicates clearly this metallurgical process.
- the froth height can be measured also by a short-time lowering of the blowing tube before the slag reaches the blowing tube. From the changes of the conductivity capacity the formation of a froth slag can be early recognized, and metallurgical measures can be timely instituted in order to avoid an overfrothing and, thereby, a discharge bringing about losses for the process.
- the resistance changes in metallurgically equal melts conform to a great extent and offer the possibility for an automatic inspection or control of the reaction procedure.
- the method in accordance with the present invention can be performed also such that the conductivity between a particular probe and the bath surface is determined.
- the probe must, of course, be electrically insulated and water cooled.
- a method of inspection and control of the conditions prevailing in a converter during the oxygen blowing process of refining molten metal comprising the steps of positioning a single electrically conductive and insulated member in said converter spaced above the surface of the metal bath therein, passing an electric current through a closed circuit which includes said member, the atmosphere in the space between the surface of said metal bath and said member, said metal bath, and a wall of said converter, providing an electrical resistance between said member and ground of about 10 ohms to about 10,000 ohms,
- a method of inspection and control of the conditions prevailing in a converter during the oxygen blowing process of refining molten metal comprising the steps of positioning a single electrically conductive and insulated member in said converter spaced above the surface of the metal bath therein,
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Refinement Of Pig-Iron, Manufacture Of Cast Iron, And Steel Manufacture Other Than In Revolving Furnaces (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Carbon Steel Or Casting Steel Manufacturing (AREA)
- Vertical, Hearth, Or Arc Furnaces (AREA)
- Treatment Of Steel In Its Molten State (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEB76045A DE1290557B (de) | 1964-03-23 | 1964-03-23 | Verfahren zur UEberwachung und Steuerung des Reaktionsablaufes bei Sauerstoffaufblaseverfahren |
DEB77404A DE1299671B (de) | 1964-03-23 | 1964-06-25 | Verfahren zur UEberwachung und Steuerung des Reaktionsablaufes beim Sauerstoffaufblaseverfahren |
Publications (1)
Publication Number | Publication Date |
---|---|
US3378366A true US3378366A (en) | 1968-04-16 |
Family
ID=25966997
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US464145A Expired - Lifetime US3378366A (en) | 1964-03-23 | 1965-06-15 | Method of inspection and control of the reaction performance during the oxygen blowing process |
Country Status (9)
Country | Link |
---|---|
US (1) | US3378366A (enrdf_load_stackoverflow) |
AT (1) | AT266891B (enrdf_load_stackoverflow) |
BE (1) | BE661460A (enrdf_load_stackoverflow) |
DE (2) | DE1290557B (enrdf_load_stackoverflow) |
ES (1) | ES310759A1 (enrdf_load_stackoverflow) |
FR (1) | FR1426777A (enrdf_load_stackoverflow) |
GB (1) | GB1044644A (enrdf_load_stackoverflow) |
LU (1) | LU48232A1 (enrdf_load_stackoverflow) |
NL (1) | NL6503611A (enrdf_load_stackoverflow) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3505062A (en) * | 1965-10-24 | 1970-04-07 | Allegheny Ludlum Steel | Method for positioning an oxygen lance |
US3610601A (en) * | 1969-10-01 | 1971-10-05 | Allegheny Ludlum Steel | Apparatus for positioning a consumable lance |
US3663204A (en) * | 1969-04-15 | 1972-05-16 | Voest Ag | Method of measuring the thickness of a slag layer on metal baths |
US3701518A (en) * | 1969-10-03 | 1972-10-31 | Berry Metal Co | Oxygen lance control arrangement for basic oxygen furnace |
FR2443509A1 (fr) * | 1978-12-05 | 1980-07-04 | Kawasaki Steel Co | Procedes de reglage de soufflage d'oxygene, de reglage de la formation de laitier et de prediction des projections lors de la mise en oeuvre du procede l-d |
US5310166A (en) * | 1991-08-23 | 1994-05-10 | Noranda, Inc. | Self-cooling lance or tuyere |
US10126286B2 (en) | 2013-03-25 | 2018-11-13 | Voestalpine Stahl Gmbh | Lance and method for determining reaction data of the course of a reaction |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU8108175A (en) * | 1974-05-13 | 1976-11-18 | Broken Hill Pty Co Ltd | Receptacles |
DE2924791C2 (de) * | 1979-06-20 | 1982-09-30 | Ferrotron Elektronik Gmbh, 4030 Ratingen | Verfahren und Vorrichtung zur Ermittlung der Gehaltean Schwermetalloxiden in flüssigen Schlacken |
DE2937353C2 (de) * | 1979-09-13 | 1983-04-07 | Gustav 5870 Hemer Kolb | Vorrichtung zur Teufenmessung der Oberfläche eines Metallbades in Schmelzgefäßen |
DE3110569A1 (de) * | 1981-03-18 | 1982-12-30 | Skw Trostberg Ag, 8223 Trostberg | Verfahren zur verhinderung des ueberschaeumens beim frischen von roheisen sowie zur erniedrigung des phosphorgehaltes, mittel und vorrichtung zur durchfuehrung des verfahrens |
USD608647S1 (en) | 2008-06-05 | 2010-01-26 | Colgate-Palmolive Co. | Container |
USD615869S1 (en) | 2009-06-09 | 2010-05-18 | Colgate-Palmolive Company | Container |
USD630517S1 (en) | 2009-06-09 | 2011-01-11 | Colgate-Palmolive Company | Container |
USD616308S1 (en) | 2009-06-09 | 2010-05-25 | Colgate-Palmolive Company | Container |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE635307A (enrdf_load_stackoverflow) * | ||||
GB900061A (en) * | 1959-11-25 | 1962-07-04 | Salzgitter Huettenwerk Ag | Lance for blowing gases, particularly gaseous oxygen and mixtures of gas and solids on or into metal baths |
GB933414A (en) * | 1961-06-02 | 1963-08-08 | Richard Thomas & Baldwins Ltd | Improvements relating to the production of steel |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE376363C (de) * | 1923-05-28 | Ernst Herbert Kuehne | Anzeigevorrichtung fuer Schmelzoefen | |
AT183095B (de) * | 1953-03-25 | 1955-09-10 | Voest Ag | Vorrichtung zum Verblasen von Roheisen mit Sauerstoff |
US2803534A (en) * | 1954-08-07 | 1957-08-20 | Oesterr Alpine Montan | Process for the production of steel |
FR1133958A (fr) * | 1955-06-17 | 1957-04-04 | Mannesmann Ag | Procédé de fabrication d'acier |
AT201088B (de) * | 1956-08-30 | 1958-12-10 | Huettenwerk Oberhausen Ag | Verfahren zum Frischen von Metallbädern in einem sich drehenden Trommelofen |
AT234127B (de) * | 1962-07-25 | 1964-06-10 | Bot Brassert Oxygen Technik Ag | Verfahren zur Betriebsregelung von Blasverfahren in Abhängigkeit vom Schäumungsgrad der Schlacke |
FR1345757A (fr) * | 1962-11-02 | 1963-12-13 | Siderurgie Fse Inst Rech | Procédé et dispositif de réglage de la hauteur d'une lance d'affinage |
-
1964
- 1964-03-23 DE DEB76045A patent/DE1290557B/de not_active Withdrawn
- 1964-06-25 DE DEB77404A patent/DE1299671B/de not_active Withdrawn
-
1965
- 1965-03-17 AT AT241065A patent/AT266891B/de active
- 1965-03-20 ES ES0310759A patent/ES310759A1/es not_active Expired
- 1965-03-20 LU LU48232A patent/LU48232A1/xx unknown
- 1965-03-22 FR FR10138A patent/FR1426777A/fr not_active Expired
- 1965-03-22 BE BE661460D patent/BE661460A/xx unknown
- 1965-03-22 NL NL6503611A patent/NL6503611A/xx unknown
- 1965-03-22 GB GB12084/65A patent/GB1044644A/en not_active Expired
- 1965-06-15 US US464145A patent/US3378366A/en not_active Expired - Lifetime
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
BE635307A (enrdf_load_stackoverflow) * | ||||
GB900061A (en) * | 1959-11-25 | 1962-07-04 | Salzgitter Huettenwerk Ag | Lance for blowing gases, particularly gaseous oxygen and mixtures of gas and solids on or into metal baths |
GB933414A (en) * | 1961-06-02 | 1963-08-08 | Richard Thomas & Baldwins Ltd | Improvements relating to the production of steel |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3505062A (en) * | 1965-10-24 | 1970-04-07 | Allegheny Ludlum Steel | Method for positioning an oxygen lance |
US3663204A (en) * | 1969-04-15 | 1972-05-16 | Voest Ag | Method of measuring the thickness of a slag layer on metal baths |
US3610601A (en) * | 1969-10-01 | 1971-10-05 | Allegheny Ludlum Steel | Apparatus for positioning a consumable lance |
US3701518A (en) * | 1969-10-03 | 1972-10-31 | Berry Metal Co | Oxygen lance control arrangement for basic oxygen furnace |
FR2443509A1 (fr) * | 1978-12-05 | 1980-07-04 | Kawasaki Steel Co | Procedes de reglage de soufflage d'oxygene, de reglage de la formation de laitier et de prediction des projections lors de la mise en oeuvre du procede l-d |
US5310166A (en) * | 1991-08-23 | 1994-05-10 | Noranda, Inc. | Self-cooling lance or tuyere |
US10126286B2 (en) | 2013-03-25 | 2018-11-13 | Voestalpine Stahl Gmbh | Lance and method for determining reaction data of the course of a reaction |
Also Published As
Publication number | Publication date |
---|---|
AT266891B (de) | 1968-12-10 |
ES310759A1 (es) | 1965-06-01 |
LU48232A1 (enrdf_load_stackoverflow) | 1965-05-20 |
GB1044644A (en) | 1966-10-05 |
BE661460A (enrdf_load_stackoverflow) | 1965-07-16 |
FR1426777A (fr) | 1966-01-28 |
NL6503611A (enrdf_load_stackoverflow) | 1965-09-24 |
DE1290557B (de) | 1969-03-13 |
DE1299671B (de) | 1969-07-24 |
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