US3377232A - Nonwoven fabrics and the method of manufacture thereof - Google Patents
Nonwoven fabrics and the method of manufacture thereof Download PDFInfo
- Publication number
- US3377232A US3377232A US39502064A US3377232A US 3377232 A US3377232 A US 3377232A US 39502064 A US39502064 A US 39502064A US 3377232 A US3377232 A US 3377232A
- Authority
- US
- United States
- Prior art keywords
- fibres
- web
- flock
- fabric
- crimp
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/04—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres having existing or potential cohesive properties, e.g. natural fibres, prestretched or fibrillated artificial fibres
- D04H1/06—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres having existing or potential cohesive properties, e.g. natural fibres, prestretched or fibrillated artificial fibres by treatment to produce shrinking, swelling, crimping or curling of fibres
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/42—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties characterised by the use of certain kinds of fibres insofar as this use has no preponderant influence on the consolidation of the fleece
- D04H1/4326—Condensation or reaction polymers
- D04H1/4334—Polyamides
-
- D—TEXTILES; PAPER
- D04—BRAIDING; LACE-MAKING; KNITTING; TRIMMINGS; NON-WOVEN FABRICS
- D04H—MAKING TEXTILE FABRICS, e.g. FROM FIBRES OR FILAMENTARY MATERIAL; FABRICS MADE BY SUCH PROCESSES OR APPARATUS, e.g. FELTS, NON-WOVEN FABRICS; COTTON-WOOL; WADDING ; NON-WOVEN FABRICS FROM STAPLE FIBRES, FILAMENTS OR YARNS, BONDED WITH AT LEAST ONE WEB-LIKE MATERIAL DURING THEIR CONSOLIDATION
- D04H1/00—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres
- D04H1/40—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties
- D04H1/54—Non-woven fabrics formed wholly or mainly of staple fibres or like relatively short fibres from fleeces or layers composed of fibres without existing or potential cohesive properties by welding together the fibres, e.g. by partially melting or dissolving
- D04H1/542—Adhesive fibres
- D04H1/549—Polyamides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/23907—Pile or nap type surface or component
- Y10T428/23943—Flock surface
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/26—Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
- Y10T428/268—Monolayer with structurally defined element
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/29—Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof
- Y10T428/2904—Staple length fiber
- Y10T428/2909—Nonlinear [e.g., crimped, coiled, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/608—Including strand or fiber material which is of specific structural definition
- Y10T442/627—Strand or fiber material is specified as non-linear [e.g., crimped, coiled, etc.]
- Y10T442/635—Synthetic polymeric strand or fiber material
Definitions
- a nonwoven fabric is made by forming an open, nonwoven web of staple fibres or continuous filaments, electrostatically projecting potentially crimpable flock fibres into the web and developing the crimp in the flock fibres to entangle them with the web fibres.
- Either the flock fibres or web fibres or both may be heterofilaments having a potentially adhesive component which is bonded to the neighboring fibres at the cross-over points.
- This invention relates to nonwoven fabrics and, in particular, to nonwoven fabrics comprising an open web the fibres in which are bonded together by short length textile fibres, the fibres being projected into the web by the action of an electrostatic field.
- fibres in webs may be bonded together by applying an adhesive to the whole or selected parts of the web, by needle punching or, where the web contain potentially adhesive fibres, by causing the potentially adhesive fibres to become tacky and bond themselves to other fibres in the web at points of contact.
- a nonwoven fabric comprising a web the fibres in which are bonded together by crimped flock, the fibres of the flock having an uncrimped length no greater than 4 inch.
- bonded includes bonding by fibre entanglement, bonding by fusion and bonding by chemical adhesion brought about by rendering one component of the fabric tacky by the addition of some substance, e.g., a solvent, which can subsequently be removed to cause that compenent to revert to the nontacky state, but does not include bonding which is the result of the deliberate addition of an adhesive to the web.
- some substance e.g., a solvent
- the fabrics of this invention can be manufactured by projecting flock, com-prising potentially crimpable fibres, which may contain a potentially adhesive component into an open fibrous web, by the action of electrostatic forces.
- the web may be composed of staple length fibres or of continuous filament components and may also contain a significant proportion of a potentially adhesive component.
- the fibres in the web are then bonded together by causing the flock to crimp and thus become entangled with the web fibres to give a nonwoven fabric of some strength.
- the fabric may be further strengthened by causing the po- 3,377,232 Patented Apr. 9, 1968 tentially adhesive component of the flock to become tacky and bond the fibres in the web and flock together at their crossover points.
- the flock employed may be composed of heterofilament fibres in which one component of the heterofilament is potentialy adhesive, in which case particularly good bonding of the flock onto the web is obtained.
- the web may also be composed of heterofilaments, in staple fibre form if required, in which one component is potentially adhesive.
- Suitable heterofilaments for flock or web fibres may be in the form where the components exist in a side-by-side or sheath and core relationship, in the latter instance of course the potentially adhesive component will be the sheath components.
- the present invention provides a process for the manufacture of fabrics wherein flock composed of potentially crimpable fibres is projected into fibrous web by the action of electrostatic forces and the structure obtained treated to cause the flock fibres to crimp and thereby bond together fibres inthe fibrous web, by entanglement of the fibres of the flock with fibres of the web.
- the flock fibres When the flock fibres contain a potentially adhesive component, it may be rendered tacky, thereby further strengthening the fabric, in the same treatment by which the flock fibres are crimped or in a subsequent treatment.
- the flock may be forced further into the web by mechanical means, for-example, by rolling, preferably whilst still subject to the action of the electrostatic forces. Any of the flock fibres which have not penetrated sufficiently into the web may then be removed by a vacuum extractor before the fabric is further treated.
- flock may be projected into both faces of the web before treating the fabric to crimp the fibres in the flock.
- EXAMPLE 1 A carded open web of 1% inch staple fibres of polyhexamethylene adipamide having a weight of 4 ounces per square yard is laid on the earthed working top of a conventional flocking unit and below a flock container, comprising a sieve and a brush, which is charged by a high tension source at 110 kv. The unit is also provided with a roller and vacuum extractor. Flock for this experiment consists of 3 mm. staple fibres cut from heterofilaments composed of 66 nylon and 66/6 (/20) nylon copolymer components existing in a side-by-side relationship.
- the flock is fed to the sieve, distributed uniformly by the brushes, allowed to fall into the electric field maintained between the charged container and the earthed working top, and projected into the staple fibre web.
- the web is then rolled using an insulated roller whilst under the influence of the electric field, to press the fibres further into the web. Flock which has not penetrated into the web is removed by the vacuum extractor. Examination of the web at this stage shows that the flock fibres in the web are oriented within the web in a direction substantially perpendicular to the plane of the web.
- the web is immersed in boiling water for 3 minutes to cause the flock fibres to crimp and entangle themselves into the web.
- the crimped flock possesses a crimp frequency of approximately 25 per inch.
- the fabric has some strength owing to the mechanical bonding effect of the crimped flock in the web, but on handling tends to shed flock.
- Example 2 The process of Example 1 was repeated to give fabrics containing various percentages of flock. The percentage fiock in the fabric and'the tenacity of the fabric are given in Table 1.
- Fabrics containing more than about 45% of flock tend to have a harsh handle and relatively poor drape.
- the heterofilament flock may be crimped by means other than immersion in boiling water, thus it may be subjected to a steam treatment, or dry heated, or to a chemical treatment. If superheated steam is used and the potentially adhesive component of the heterofilament has a sufficiently low melting, then the crimping and bonding steps can be carried out simultaneously.
- Variations in the handle and surface effect of flocked web can be obtained by applying other processes, e.g. needle punching to the flocked web before the bonding operation.
- the invention is not limited to the use of webs or flock based only on polyamides; any suitable materials may be employed provided that effective bonding between the flock and the web can be attained, i.e. the potentially adhesive component where employed should be compatible with the other components of the fabric.
- a process for enhancing the strength of nonwoven fabrics comprising: substantially completelyembedding potentially crirnpable fiock fibres into a preformed, nonwoven web by projecting the flock-fibres into said web by the action of electrostatic forces and subsequently entangling the flock fibres with the web fibres by developing crimp in the flock fibres, thereby bonding the Web fibres in the nonwoven fabric and enhancing the strength of the nonwoven fabric.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3744163A GB1034207A (en) | 1963-09-24 | 1963-09-24 | Improvements in or relating to nonwoven fabrics and the method of manufacture thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
US3377232A true US3377232A (en) | 1968-04-09 |
Family
ID=10396498
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US39502064 Expired - Lifetime US3377232A (en) | 1963-09-24 | 1964-09-08 | Nonwoven fabrics and the method of manufacture thereof |
Country Status (6)
Country | Link |
---|---|
US (1) | US3377232A (nl) |
BE (1) | BE653203A (nl) |
DE (1) | DE1560662C3 (nl) |
GB (1) | GB1034207A (nl) |
LU (1) | LU46984A1 (nl) |
NL (1) | NL146232B (nl) |
Cited By (35)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4187343A (en) * | 1975-10-08 | 1980-02-05 | Toyobo Co., Ltd. | Process for producing non-woven fabric |
US5336552A (en) * | 1992-08-26 | 1994-08-09 | Kimberly-Clark Corporation | Nonwoven fabric made with multicomponent polymeric strands including a blend of polyolefin and ethylene alkyl acrylate copolymer |
US5382400A (en) * | 1992-08-21 | 1995-01-17 | Kimberly-Clark Corporation | Nonwoven multicomponent polymeric fabric and method for making same |
US5405682A (en) * | 1992-08-26 | 1995-04-11 | Kimberly Clark Corporation | Nonwoven fabric made with multicomponent polymeric strands including a blend of polyolefin and elastomeric thermoplastic material |
US5643662A (en) * | 1992-11-12 | 1997-07-01 | Kimberly-Clark Corporation | Hydrophilic, multicomponent polymeric strands and nonwoven fabrics made therewith |
US20020009571A1 (en) * | 2000-07-24 | 2002-01-24 | Abrams Louis Brown | Flocked transfer and article of manufacture including the application of the transfer by thermoplastic polymer film |
US6500538B1 (en) | 1992-12-28 | 2002-12-31 | Kimberly-Clark Worldwide, Inc. | Polymeric strands including a propylene polymer composition and nonwoven fabric and articles made therewith |
US20030098529A1 (en) * | 2000-07-21 | 2003-05-29 | Robert Drumm | Nanoscale corundum powders, sintered compacts produced from these powders and method for producing the same |
US20030186019A1 (en) * | 2000-07-24 | 2003-10-02 | High Voltage Graphics, Inc. | Flocked transfer and article of manufacture including the application of the transfer by thermoplastic polymer film |
US20030207072A1 (en) * | 2000-07-24 | 2003-11-06 | Abrams Louis Brown | Co-molded direct flock and flock transfer and methods of making same |
US20040053001A1 (en) * | 2002-07-03 | 2004-03-18 | Abrams Louis Brown | Process for printing and molding a flocked article |
US20040077247A1 (en) * | 2002-10-22 | 2004-04-22 | Schmidt Richard J. | Lofty spunbond nonwoven laminate |
US20040081791A1 (en) * | 2002-07-03 | 2004-04-29 | Abrams Louis Brown | Flocked articles and methods of making same |
US20050266204A1 (en) * | 2004-01-16 | 2005-12-01 | Abrams Louis B | Process for printing and molding a flocked article |
US20050268407A1 (en) * | 2004-05-26 | 2005-12-08 | Abrams Louis B | Process for high and medium energy dye printing a flocked article |
US20070022548A1 (en) * | 2005-08-01 | 2007-02-01 | High Voltage Graphics, Inc. | Process for heat setting polyester fibers for sublimation printing |
US20070102093A1 (en) * | 2005-09-20 | 2007-05-10 | High Voltage Graphics, Inc. | Flocked elastomeric articles |
US20070289688A1 (en) * | 2000-07-24 | 2007-12-20 | High Voltage Graphics, Inc. | Processes for precutting laminated flocked articles |
US20080006968A1 (en) * | 2000-07-24 | 2008-01-10 | High Voltage Graphics, Inc. | Heat moldable flock transfer with heat resistant, reusable release sheet and methods of making same |
US20080111047A1 (en) * | 2006-11-14 | 2008-05-15 | High Voltage Graphics, Inc. | Rigid mouse pad |
US20080124503A1 (en) * | 2006-11-02 | 2008-05-29 | High Voltage Graphics, Inc. | Flocked adhesive article having multi-component adhesive film |
US20080150186A1 (en) * | 2000-07-24 | 2008-06-26 | High Voltage Graphics, Inc. | Co-molded direct flock and flock transfer and methods of making same |
US7410682B2 (en) | 2002-07-03 | 2008-08-12 | High Voltage Graphics, Inc. | Flocked stretchable design or transfer |
US7465485B2 (en) | 2003-12-23 | 2008-12-16 | High Voltage Graphics, Inc. | Process for dimensionalizing flocked articles or wear, wash and abrasion resistant flocked articles |
US20090239025A1 (en) * | 2008-03-04 | 2009-09-24 | High Voltage Graphics, Inc. | Flocked articles having a woven graphic design insert and methods of making the same |
US20100068447A1 (en) * | 2006-12-15 | 2010-03-18 | High Voltage Graphics, Inc. | Flocked slurried thermosetting adhesive article |
US20100143669A1 (en) * | 2008-12-04 | 2010-06-10 | High Voltage Graphics, Inc. | Sublimation dye printed textile design having metallic appearance and article of manufacture thereof |
US20100209654A1 (en) * | 2009-02-16 | 2010-08-19 | High Voltage Graphics, Inc. | Flocked stretchable design or transfer including thermoplastic film and method for making the same |
US20100233410A1 (en) * | 2005-12-07 | 2010-09-16 | High Voltage Graphics, Inc. | Wet-on-wet method for forming flocked adhesive article |
US7799164B2 (en) | 2005-07-28 | 2010-09-21 | High Voltage Graphics, Inc. | Flocked articles having noncompatible insert and porous film |
US20100316832A1 (en) * | 2009-04-10 | 2010-12-16 | High Voltage Graphics, Inc. | Flocked article having a woven insert and method for making the same |
US8007889B2 (en) | 2005-04-28 | 2011-08-30 | High Voltage Graphics, Inc. | Flocked multi-colored adhesive article with bright lustered flock and methods for making the same |
US20110223373A1 (en) * | 2010-03-12 | 2011-09-15 | High Voltage Graphics, Inc. | Flocked articles having a resistance to splitting and methods for making the same |
US8475905B2 (en) | 2007-02-14 | 2013-07-02 | High Voltage Graphics, Inc | Sublimation dye printed textile |
US9193214B2 (en) | 2012-10-12 | 2015-11-24 | High Voltage Graphics, Inc. | Flexible heat sealable decorative articles and method for making the same |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3038236A (en) * | 1954-02-26 | 1962-06-12 | Du Pont | Crimped textile products |
US3314845A (en) * | 1964-07-23 | 1967-04-18 | Du Pont | Method of flocking and subsequently developing latently crimpable fibers and article produced thereby |
-
1963
- 1963-09-24 GB GB3744163A patent/GB1034207A/en not_active Expired
-
1964
- 1964-09-08 US US39502064 patent/US3377232A/en not_active Expired - Lifetime
- 1964-09-16 NL NL6410771A patent/NL146232B/nl unknown
- 1964-09-17 BE BE653203A patent/BE653203A/xx unknown
- 1964-09-19 LU LU46984D patent/LU46984A1/xx unknown
- 1964-09-23 DE DE1560662A patent/DE1560662C3/de not_active Expired
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3038236A (en) * | 1954-02-26 | 1962-06-12 | Du Pont | Crimped textile products |
US3314845A (en) * | 1964-07-23 | 1967-04-18 | Du Pont | Method of flocking and subsequently developing latently crimpable fibers and article produced thereby |
Cited By (57)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4187343A (en) * | 1975-10-08 | 1980-02-05 | Toyobo Co., Ltd. | Process for producing non-woven fabric |
US5382400A (en) * | 1992-08-21 | 1995-01-17 | Kimberly-Clark Corporation | Nonwoven multicomponent polymeric fabric and method for making same |
US5418045A (en) * | 1992-08-21 | 1995-05-23 | Kimberly-Clark Corporation | Nonwoven multicomponent polymeric fabric |
US5336552A (en) * | 1992-08-26 | 1994-08-09 | Kimberly-Clark Corporation | Nonwoven fabric made with multicomponent polymeric strands including a blend of polyolefin and ethylene alkyl acrylate copolymer |
US5405682A (en) * | 1992-08-26 | 1995-04-11 | Kimberly Clark Corporation | Nonwoven fabric made with multicomponent polymeric strands including a blend of polyolefin and elastomeric thermoplastic material |
US5425987A (en) * | 1992-08-26 | 1995-06-20 | Kimberly-Clark Corporation | Nonwoven fabric made with multicomponent polymeric strands including a blend of polyolefin and elastomeric thermoplastic material |
US5643662A (en) * | 1992-11-12 | 1997-07-01 | Kimberly-Clark Corporation | Hydrophilic, multicomponent polymeric strands and nonwoven fabrics made therewith |
US6500538B1 (en) | 1992-12-28 | 2002-12-31 | Kimberly-Clark Worldwide, Inc. | Polymeric strands including a propylene polymer composition and nonwoven fabric and articles made therewith |
US20030098529A1 (en) * | 2000-07-21 | 2003-05-29 | Robert Drumm | Nanoscale corundum powders, sintered compacts produced from these powders and method for producing the same |
US7338697B2 (en) | 2000-07-24 | 2008-03-04 | High Voltage Graphics, Inc. | Co-molded direct flock and flock transfer and methods of making same |
US20080006968A1 (en) * | 2000-07-24 | 2008-01-10 | High Voltage Graphics, Inc. | Heat moldable flock transfer with heat resistant, reusable release sheet and methods of making same |
US20030207072A1 (en) * | 2000-07-24 | 2003-11-06 | Abrams Louis Brown | Co-molded direct flock and flock transfer and methods of making same |
US20080150186A1 (en) * | 2000-07-24 | 2008-06-26 | High Voltage Graphics, Inc. | Co-molded direct flock and flock transfer and methods of making same |
US20020009571A1 (en) * | 2000-07-24 | 2002-01-24 | Abrams Louis Brown | Flocked transfer and article of manufacture including the application of the transfer by thermoplastic polymer film |
US7390552B2 (en) | 2000-07-24 | 2008-06-24 | High Voltage Graphics, Inc. | Flocked transfer and article of manufacturing including the flocked transfer |
US8354050B2 (en) | 2000-07-24 | 2013-01-15 | High Voltage Graphics, Inc. | Co-molded direct flock and flock transfer and methods of making same |
US20110052859A1 (en) * | 2000-07-24 | 2011-03-03 | High Voltage Graphics, Inc. | Processes for precutting laminated flocked articles |
US20100092719A1 (en) * | 2000-07-24 | 2010-04-15 | High Voltage Graphics, Inc. | Flocked transfer and article of manufacture including the application of the transfer by thermoplastic polymer film |
US7632371B2 (en) | 2000-07-24 | 2009-12-15 | High Voltage Graphics, Inc. | Flocked transfer and article of manufacture including the application of the transfer by thermoplastic polymer film |
US20070289688A1 (en) * | 2000-07-24 | 2007-12-20 | High Voltage Graphics, Inc. | Processes for precutting laminated flocked articles |
US20030186019A1 (en) * | 2000-07-24 | 2003-10-02 | High Voltage Graphics, Inc. | Flocked transfer and article of manufacture including the application of the transfer by thermoplastic polymer film |
US7402222B2 (en) | 2000-07-24 | 2008-07-22 | High Voltage Graphics, Inc. | Flocked transfer and article of manufacture including the flocked transfer |
US7344769B1 (en) | 2000-07-24 | 2008-03-18 | High Voltage Graphics, Inc. | Flocked transfer and article of manufacture including the flocked transfer |
US7381284B2 (en) | 2000-07-24 | 2008-06-03 | High Voltage Graphics, Inc. | Flocked transfer and article of manufacture including the application of the transfer by thermoplastic polymer film |
US7364782B2 (en) | 2000-07-24 | 2008-04-29 | High Voltage Graphics, Inc. | Flocked transfer and article of manufacture including the application of the transfer by thermoplastic polymer film |
US7413581B2 (en) | 2002-07-03 | 2008-08-19 | High Voltage Graphics, Inc. | Process for printing and molding a flocked article |
US7410682B2 (en) | 2002-07-03 | 2008-08-12 | High Voltage Graphics, Inc. | Flocked stretchable design or transfer |
US7351368B2 (en) | 2002-07-03 | 2008-04-01 | High Voltage Graphics, Inc. | Flocked articles and methods of making same |
US20040081791A1 (en) * | 2002-07-03 | 2004-04-29 | Abrams Louis Brown | Flocked articles and methods of making same |
US20040053001A1 (en) * | 2002-07-03 | 2004-03-18 | Abrams Louis Brown | Process for printing and molding a flocked article |
US20040077247A1 (en) * | 2002-10-22 | 2004-04-22 | Schmidt Richard J. | Lofty spunbond nonwoven laminate |
US7465485B2 (en) | 2003-12-23 | 2008-12-16 | High Voltage Graphics, Inc. | Process for dimensionalizing flocked articles or wear, wash and abrasion resistant flocked articles |
US20050266204A1 (en) * | 2004-01-16 | 2005-12-01 | Abrams Louis B | Process for printing and molding a flocked article |
US7393576B2 (en) * | 2004-01-16 | 2008-07-01 | High Voltage Graphics, Inc. | Process for printing and molding a flocked article |
US20050268407A1 (en) * | 2004-05-26 | 2005-12-08 | Abrams Louis B | Process for high and medium energy dye printing a flocked article |
US8007889B2 (en) | 2005-04-28 | 2011-08-30 | High Voltage Graphics, Inc. | Flocked multi-colored adhesive article with bright lustered flock and methods for making the same |
US7799164B2 (en) | 2005-07-28 | 2010-09-21 | High Voltage Graphics, Inc. | Flocked articles having noncompatible insert and porous film |
USRE45802E1 (en) | 2005-07-28 | 2015-11-17 | High Voltage Graphics, Inc. | Flocked articles having noncompatible insert and porous film |
US20070022548A1 (en) * | 2005-08-01 | 2007-02-01 | High Voltage Graphics, Inc. | Process for heat setting polyester fibers for sublimation printing |
US8168262B2 (en) | 2005-09-20 | 2012-05-01 | High Voltage Graphics, Inc. | Flocked elastomeric articles |
US7749589B2 (en) | 2005-09-20 | 2010-07-06 | High Voltage Graphics, Inc. | Flocked elastomeric articles |
US20100276060A1 (en) * | 2005-09-20 | 2010-11-04 | High Voltage Graphics, Inc. | Flocked elastomeric articles |
US20070102093A1 (en) * | 2005-09-20 | 2007-05-10 | High Voltage Graphics, Inc. | Flocked elastomeric articles |
US20100233410A1 (en) * | 2005-12-07 | 2010-09-16 | High Voltage Graphics, Inc. | Wet-on-wet method for forming flocked adhesive article |
US8206800B2 (en) | 2006-11-02 | 2012-06-26 | Louis Brown Abrams | Flocked adhesive article having multi-component adhesive film |
US20080124503A1 (en) * | 2006-11-02 | 2008-05-29 | High Voltage Graphics, Inc. | Flocked adhesive article having multi-component adhesive film |
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US20100068447A1 (en) * | 2006-12-15 | 2010-03-18 | High Voltage Graphics, Inc. | Flocked slurried thermosetting adhesive article |
US8475905B2 (en) | 2007-02-14 | 2013-07-02 | High Voltage Graphics, Inc | Sublimation dye printed textile |
US20090239025A1 (en) * | 2008-03-04 | 2009-09-24 | High Voltage Graphics, Inc. | Flocked articles having a woven graphic design insert and methods of making the same |
US20100143669A1 (en) * | 2008-12-04 | 2010-06-10 | High Voltage Graphics, Inc. | Sublimation dye printed textile design having metallic appearance and article of manufacture thereof |
US9012005B2 (en) | 2009-02-16 | 2015-04-21 | High Voltage Graphics, Inc. | Flocked stretchable design or transfer including thermoplastic film and method for making the same |
US20100209654A1 (en) * | 2009-02-16 | 2010-08-19 | High Voltage Graphics, Inc. | Flocked stretchable design or transfer including thermoplastic film and method for making the same |
US20100316832A1 (en) * | 2009-04-10 | 2010-12-16 | High Voltage Graphics, Inc. | Flocked article having a woven insert and method for making the same |
US20110223373A1 (en) * | 2010-03-12 | 2011-09-15 | High Voltage Graphics, Inc. | Flocked articles having a resistance to splitting and methods for making the same |
US9175436B2 (en) | 2010-03-12 | 2015-11-03 | High Voltage Graphics, Inc. | Flocked articles having a resistance to splitting and methods for making the same |
US9193214B2 (en) | 2012-10-12 | 2015-11-24 | High Voltage Graphics, Inc. | Flexible heat sealable decorative articles and method for making the same |
Also Published As
Publication number | Publication date |
---|---|
LU46984A1 (nl) | 1964-11-19 |
DE1560662C3 (de) | 1974-08-22 |
BE653203A (nl) | 1965-03-17 |
DE1560662B2 (de) | 1974-01-24 |
NL6410771A (nl) | 1965-03-25 |
GB1034207A (en) | 1966-06-29 |
NL146232B (nl) | 1975-06-16 |
DE1560662A1 (de) | 1969-10-02 |
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