Classifications

• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M1/00—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
  • C10M1/08—Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
• • C—CHEMISTRY; METALLURGY
  • C07—ORGANIC CHEMISTRY
  • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
  • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
  • C07F9/02—Phosphorus compounds
  • C07F9/28—Phosphorus compounds with one or more P—C bonds
  • C07F9/30—Phosphinic acids [R2P(=O)(OH)]; Thiophosphinic acids ; [R2P(=X1)(X2H) (X1, X2 are each independently O, S or Se)]
  • C07F9/32—Esters thereof
  • C07F9/3205—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
  • C07F9/3211—Esters of acyclic saturated acids which can have further substituents on alkyl
• • C—CHEMISTRY; METALLURGY
  • C07—ORGANIC CHEMISTRY
  • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
  • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
  • C07F9/02—Phosphorus compounds
  • C07F9/28—Phosphorus compounds with one or more P—C bonds
  • C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
  • C07F9/40—Esters thereof
  • C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
  • C07F9/4006—Esters of acyclic acids which can have further substituents on alkyl
• • C—CHEMISTRY; METALLURGY
  • C07—ORGANIC CHEMISTRY
  • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
  • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
  • C07F9/02—Phosphorus compounds
  • C07F9/28—Phosphorus compounds with one or more P—C bonds
  • C07F9/50—Organo-phosphines
  • C07F9/53—Organo-phosphine oxides; Organo-phosphine thioxides
  • C07F9/5304—Acyclic saturated phosphine oxides or thioxides
• • C—CHEMISTRY; METALLURGY
  • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
  • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
  • C08K5/00—Use of organic ingredients
  • C08K5/49—Phosphorus-containing compounds
  • C08K5/51—Phosphorus bound to oxygen
  • C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
  • C10M2223/06—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
  • C10M2223/06—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
  • C10M2223/061—Metal salts
• • C—CHEMISTRY; METALLURGY
  • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
  • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
  • C10M2223/00—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions
  • C10M2223/06—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds
  • C10M2223/065—Organic non-macromolecular compounds containing phosphorus as ingredients in lubricant compositions having phosphorus-to-carbon bonds containing sulfur

Definitions

• Polyolefins are stabilized against thermal degradation by inclusion of an effective stabilizing amount of a phosphorus-containing carbonamide, e.g., N,N-dihydrocarbylomega(dihydrocarbylphosphono)carbonamides, N,N dihydrocarbyl omega (dihydrocarbylphosphenyl) carbonamides and N,N dihydrocarbyl omega(dihydrocarbylphosphinyl) carbonamides, optionally in combination with phenolic antioxidants.
• a phosphorus-containing carbonamide e.g., N,N-dihydrocarbylomega(dihydrocarbylphosphono)carbonamides, N,N dihydrocarbyl omega (dihydrocarbylphosphenyl) carbonamides and N,N dihydrocarbyl omega(dihydrocarbylphosphinyl) carbonamides, optionally in combination with phenolic antioxidants.
• the invention relates to the stabilization of polymers and copolymers of olefinically unsaturated compounds, or, in other words, to the preparation of stable compositions mainly consisting of polymers or copolymers of olefinically unsaturated compounds.
• the invention is of special importance for the stabilization of polymers and copolymers of alpha-olefins containing from two to four carbon atoms in the molecule.
• the stabilization referred to here is in particular the prevention or inhibition of decomposition during treatments requiring elevated temperatures, as in molding at temperatures around 250 C. and higher.
• the invention furthermore, relates to the molding of the compositions in question at elevated temperature, in particular molding by processes of extrusion, injection-molding and meltspinning.
• R is a monovalent hydrocarbon radical or an OR group
• R is a monovalent hydrocarbon radical or an OR group
• R R and R are similar or dissimilar monovalent hydrocarbon radicals
• R is hydrogen or a monovalent hydrocarbon radical, with R and R possibly forming, with the nitrogen atom, a heterocyclic ring which may also contain other heteroatoms besides N
• R is a bivalent hydrocarbon radical, and where one or more of the hydrogen atoms in the various hydrocarbon radicals are possibly replaced by other atoms or groups.
• phosphonocarbonamides if R is an OR group and R an OR group; as phosphenylcarbonann'des, if only one of the symbols R and R represents an OR or OR group and the other a monovalent hydrocarbon radical; and as phosphinylcarbonamides, if the symbols R and R each represent a monovalent hydrocarbon radical.
• R is a monovalent hydrocarbon radical which may possibly contain one or more substituents, the symbols R R R R and R having the aforementioned significance.
• the various hydrocarbon radicals in the phosphoruscontaining carbonamides may be aliphatic or aromatic, or of a mixed aliphatic-aromatic character.
• the aliphatic radicals or parts of the radicals may be branched or unbranched or cyclic, saturated or unsaturated.
• the aromatic radicals may be single or condensed nuclei.
• the various monovalent hydrocarbon radicals will usually contain from 1 to 12 carbon atoms, but may also contain more than 12 carbon atoms.
• the bivalent hydrocarbon radical R will preferably be a polymethylene radical with at least 3 carbon atoms, and usually not more than 20 carbon atoms. Possible substituents in the hydrocarbon radicals include, for example, halogen atoms and hydroxyl groups.
• Preferred representative phosphorus-containing carbon-amides for use according to this invention are those listed in Table I, below. Those include the N,N-dialkylomega-(dialkylphosphono)alkanoamides, and as a preferred group the N,N-dialkyl-'y(dialkylphosphono)butyramides, in which the alkyl groups attached to the N-atom are identical and the alkyl groups bridged to the P-atom by oxygen are identical, but not necessarily the same as those attached to N, and in which all alkyl groups have from 2 to 4 carbon atoms and are preferably branched. Another group are the corresponding N-heterocyclic compounds, such as N piperidyl (dialkylphosphono) butyramides.
• N,N-dialkylomega-(dialkylphosphenyl)allcanoamides and N,N dialkyl-omega-(dial'kylphosphinyl) alkanoamides vand their corresponding N-heterocyclic compounds; in these compounds, also, the y-butyramides are preferred, and the alkyl groups, when present, preferably have from 2 to 4 carbon atoms and are preferably branched.
• the phosphorus-containing carbonamides employed in this invention are believed to be novel compounds. They can be readily prepared by the above-indicated reactions, which are illustrated by the following typical preparation.
• the compound prepared is N,N-diisopropyl-'y-(diisopropylphosphono)butyramide, i.e., the compound of the In terms of Formula 1, above, R is 0R where OR is an isopropoxy group; R is 0R where GR is an isopropoxy group; R is a trimethylene radical, and R and R are isopropyl groups.
• the phosphorus-containing carbonamides do not give rise to any discoloration in the mixtures with polymers and copolymers. In many cases their stabilizing effect may be still considerably enhanced by introducing into the compositions to be prepared according to the invention one or more phenols having secondary and/ or tertiary hydrocarbon radical substituents in one or more orthopositions.
• phenols the so-called sterically-hindered phenols, are, for example, compounds having the formula:
• Ar is an aryl nucleus which may contain substituent groups; R represents similar or dissimilar secondary and/or tertiary hydrocarbon radicals; R represents a member of the group consisting of hydrogen atoms and hydrocarbon radicals; and n is a whole number from 1 to 3 inclusive.
• Ar may also contain a phenolic hydroxyl group.
• Ar is a polyalkyl phenyl group containing (6-n) alkyl substituents, particularly lower alkyl, such as methyl or ethyl.
• Preferred polyphenolic antioxidants of this type are described in more detail in US. 3,026,264 to Rocklin et a1. and US. 3,062,895 to Martin et a1.
• R represent similar or dissimilar secondary and/ or tertiary alkyl groups each containing not more than 8 carbon atoms, e.g., tert-butyl, and the letters R similar or dissimilar alkyl groups each containing not more than 4 carbon atoms, e. g., methyl.
• R10 (VIII) where Ar, R R and n have the same meaning as above, the R 'radicals being branched in the alpha-position and containing from 3 to not more than 8 carbon atoms;
• the hydrogen atom of the NH group may be replaced by Very serviceable phenolic antioxidants also are those in which there are two arylol nuclei linked together by an oxygen atom, a sulfur atom, an imine group, a methylene or a polymethylene group, and having in the or-tho-position relative to the hydroxyl groups present in the aryl nuclei one or more alkyl groups which are branched in the alpha-position.
• the substituents in the phenols which substituents may cause the steric hindrance, are, for example, isopropyl, tert-butyl, tert-phenyl, cyclohexyl, norbornyl and isobornyl.
• novel stabilizers of this invention are used together with phenolic antioxidants, as just described, still further desirable results may be obtained by including as third stabilizing component one of certain sulfur-containing non-phenolic antioxidant compounds having a sulfide or polysulfide linkage. These compounds are not very effective antioxidants when used by themselves, but often enhance the etfectiveness of phenolic antioxidants.
• a widely used compound of this type is dilauryl thiodipropionate.
• Other higher dialkyl thiodipropionates, e.g., the distearyl salt are also very suitable.
• Another useful group of such sulfur are the dialkyl sulfides and disulfides, e.g., di-n-cetyl sulfide or di-n-hexadecyl disulfide.
• These sulfur-containing additives are now known as antioxidant stabilizers for polyolefins. They are described in more detail in US. application Ser. No. 300,096, filed Aug. 5, 1963, now abandoned. Said application also contains added disclosures with respect to the above-referred-to phenolic antioxidants and with respect to polyolefin substrates to be stabilized. Said application may be referred to for such details if desired, and the pertinent disclosures of said application are incorporated herein by reference.
• the polymers which can be stabilized according to this invention are polymers of alpha-monoolefins prepared at low temperatures and pressures in the presence of certain catalyst compositions which are commonly referred to as Ziegler-type catalysts, low-pressure catalysts, or coordination catalysts.
• a particularly useful low-pressure polymer is highly crystalline or crystallizable isotactic polypropylene. It is of such catalysts are characregularity of their molecules crystalline,
• the inhibitor systems of this invention are useful in linear polymers of olefins of from 2 to 8 or more carbon atoms per molecule, including polymers of ethylene, butene-l, 4-methyl-pentene-1 and hexene-l, and the like, in crystalline copolymers of propylene with ethylene, butene-l and the like, and block copolymers of alphaolefins. While this invention thus applies to polymers of various alpha-monoolefins, the description is directed mainly to polypropylene. Inhibitor systems satisfactory in polypropylene will usually also be satisfactory in other low-pressure polymers. The invention will therefore be explained by reference to stabilization of polypropylene.
• the polymer powder was mixed with stabilizer and milled for five minutes at 180 C. Plates of the milled sheet, 1 mm. thick, were then kept in a press for 10 minutes at 300 C. under a pressure of 50 kg./cm.
• LVN limiting viscosity number
• the stabilizer was a phosphonoor a phosphonylcarbonamide or a combination thereof with a stericallyhindered phenol.
• the phosphorus-containing amides used were compounds having the general formula:
• R R R -N C2H5 R H N (CH3): iSO-CaH' R 0 H N(CH 7 11-CaH7 R 0 H N(CH )2 ISO-C3111 R 0 H N(C H n-C3H7 R 0 H N(C2H )z C2H R 0 H N (iS0-C H )g n-CaH1 R 0 H N(iS0-C3H7)2 1so-CaH1 R 0 H N -C3H7)2 11-C3H7 R 0 H N -C H 1so-CaH1 R H N (iso-C3H 2 ISO-C3117 R 0 H N(iSO-C4Ho)a 11-CaH1 R 0 H N Use-04H): C2H5 R 0 H N(11-C4Hg)g Il-C3H7 R 0 H N(I1-C4Hg)
• a polyolefin composition stabilized against degradation at elevated temperatures comprising (a) solid polymer of an alpha-monoolefin of 2 to 8 carbon atoms per molecule combined with (b) an efiective amount of a phosphorus-containing carbonamide having the general formula l R1P-R7(3N wherein R is a radical selected from the group consisting of monovalent hydrocarbon radicals and groups of the formula -OR R is selected from the group consisting of monovalent hydrocarbon radicals and groups having the formula -OR R R and R are monovalent hydrocarbon radicals; R is selected from the group consisting of hydrogen and monovalent hydrocarbon radicals; and R is a divalent hydrocarbon radical; provided that R and R may further be selected from the group consisting of divalent radicals which, together with the N atom, form a heterocyclic ring.
• a composition according to claim 3 containing from 0.01 to 5 percent by weight of said phosphorus-containing carbonamide and from 0.01 to 1 percent by weight of a hindered phenolic polyolefin antioxidant.
• Polypropylene stabilized against degradation at elevated temperatures comprising solid polypropylene and a stabilizing amount of an N,N-dialkyl-'y(dialkylphosphono)butyramide wherein each alkyl group has from 1 to 12 carbon atoms.
• composition according to claim 5 wherein said alkyl groups have from 2 to 4 carbon atoms.
• Polypropylene stabilized against degradation at elevated temperatures comprising solid polypropylene and a stabilizing amount of an N,N-dialkyl- (dialkylphosphenyl)butyratnide wherein each alkyl group has from 1 to 12 carbon atoms.
• Polypropylene stabilized against degradation at elevated temperatures comprising solid polypropylene and a stabilizing amount of an N,N-dialkyl-' (dialkylphosphinyl)butyramide wherein each alkyl group has from 1 to 12 carbon atoms.
• Polypropylene stabilized against degradation at elevated temperatures comprising solid polypropylene and from 0.05 to 1 percent by weight of N,N-dipropyl-'y(dipropylphosphouo butyramide.
• a composition according to claim 10 which contains from 0.05 to 0.5 percent by Weight of 1,3,5-trimethyl-2,4, 6-tri (3 5 -di-tert-butyl-4-hydroxybenzyl benzene.
• composition according to claim 10 which contains from 0.05 to 0.5 percent by Weight of 2,2'-methylene-bis(4-methyl-6-tert-butyl-phenol).
• composition according to claim 10 wherein each of said propyl groups is an isopropyl group.

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• 1963
  • 1963-10-30 NL NL299936D patent/NL299936A/de unknown
  • 1963-10-30 NL NL299935D patent/NL299935A/xx unknown
• 1964
  • 1964-10-09 US US402924A patent/US3361784A/en not_active Expired - Lifetime
  • 1964-10-28 GB GB43962/64A patent/GB1028616A/en not_active Expired
  • 1964-10-28 BE BE654960D patent/BE654960A/xx not_active Expired
  • 1964-10-28 DE DES93951A patent/DE1232143B/de active Pending
  • 1964-10-28 DE DES93952A patent/DE1223545B/de active Pending
  • 1964-10-28 FR FR992962A patent/FR1435815A/fr not_active Expired

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