US3301663A - Steel making processes - Google Patents
Steel making processes Download PDFInfo
- Publication number
- US3301663A US3301663A US362172A US36217264A US3301663A US 3301663 A US3301663 A US 3301663A US 362172 A US362172 A US 362172A US 36217264 A US36217264 A US 36217264A US 3301663 A US3301663 A US 3301663A
- Authority
- US
- United States
- Prior art keywords
- steel
- cutting
- inclusions
- steels
- alloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000009628 steelmaking Methods 0.000 title description 2
- 238000005520 cutting process Methods 0.000 claims description 22
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 9
- 229910052782 aluminium Inorganic materials 0.000 claims description 9
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 8
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 6
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
- 229910052791 calcium Inorganic materials 0.000 claims description 6
- 239000011575 calcium Substances 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- 229910001021 Ferroalloy Inorganic materials 0.000 claims description 5
- 229910052710 silicon Inorganic materials 0.000 claims description 5
- 239000010703 silicon Substances 0.000 claims description 5
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 229910052748 manganese Inorganic materials 0.000 claims description 4
- 239000011572 manganese Substances 0.000 claims description 4
- 238000000034 method Methods 0.000 claims description 4
- 239000012535 impurity Substances 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 2
- 239000011241 protective layer Substances 0.000 claims description 2
- 229910000831 Steel Inorganic materials 0.000 description 24
- 239000010959 steel Substances 0.000 description 24
- 239000004411 aluminium Substances 0.000 description 8
- 239000010410 layer Substances 0.000 description 7
- 229910045601 alloy Inorganic materials 0.000 description 6
- 239000000956 alloy Substances 0.000 description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 3
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 3
- 239000000292 calcium oxide Substances 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 2
- AMWRITDGCCNYAT-UHFFFAOYSA-L manganese oxide Inorganic materials [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 2
- PPNAOCWZXJOHFK-UHFFFAOYSA-N manganese(2+);oxygen(2-) Chemical class [O-2].[Mn+2] PPNAOCWZXJOHFK-UHFFFAOYSA-N 0.000 description 2
- 239000000161 steel melt Substances 0.000 description 2
- 229910000676 Si alloy Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- OSMSIOKMMFKNIL-UHFFFAOYSA-N calcium;silicon Chemical compound [Ca]=[Si] OSMSIOKMMFKNIL-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000008094 contradictory effect Effects 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 201000007450 intrahepatic cholangiocarcinoma Diseases 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C35/00—Master alloys for iron or steel
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21C—PROCESSING OF PIG-IRON, e.g. REFINING, MANUFACTURE OF WROUGHT-IRON OR STEEL; TREATMENT IN MOLTEN STATE OF FERROUS ALLOYS
- C21C7/00—Treating molten ferrous alloys, e.g. steel, not covered by groups C21C1/00 - C21C5/00
- C21C7/04—Removing impurities by adding a treating agent
- C21C7/06—Deoxidising, e.g. killing
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C28/00—Alloys based on a metal not provided for in groups C22C5/00 - C22C27/00
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
Definitions
- a welded layer forms on the tools in the case of steels having good cutting properties, and this welded layer prevents cratering and wear of the front rake of the tool.
- the formation of such a welded layer is due to non-metallic inclusions in the steel, such inclusions consisting of oxides or oxide compounds formed during deoxidation of the steel. It was not hitherto possible to find out accurately which oxides or oxide compounds have the greatest influence on the welded layers. In this connection it was proposed to improve the steel cutting properties by deoxidising the liquid melts with a calcium-silicon alloy.
- the object of the invention is to improve the behaviour of steels which are to be cut at high cutting speeds, so that the steels give a long tool life over the entire range of practical cutting speeds.
- the steel is deoxidised with a ferro-alloy which contains silicon, calcium, manganese and iron in the following proportions: 45-90% of silicon, 0.5-40% of calcium, 0.5-8% of manganese and remainder iron together with impurities.
- a deoxidation alloy containing up to 4% of aluminium as well is particularly advantageous.
- the oxygen content of the steel melt plays an important part in the cutting of steels over different cutting speed ranges and varying temperatures. It should be 0.004 minimum and 0.1% maximum. These conditions can be readily obtained, for example by degasification ited States Patent Patented Jan. 31, 1967 ICC treatment of the steel. Also, the aluminium contained in the deoxidation alloy must not be such as to fix the quantity of free oxygen present in the steel. The proportion of aluminium in the deoxidation alloy must be such that the A1 0 content of the isolated residue after deoxidation is 45% maximum. The SiO content of the residue should be more than 50%, While the C210 content should be between 0.5 and 25%.
- the deoxidation agent used was a ferro-alloy having an aluminium content of 1.2%. It may range from 1 to 1.5%.
- the silicon content of the ferro-alloy was about and its calcium content was approximately 7%.
- the residue analysis was as follows:
- the melting point of the inclusions can be varied by variation of the aluminium and calcium content of the deoxidation alloy. This also influences the extent of the welded layer, because it depends on the composition and the melting points of the inclusions.
- the inclusions melt at higher temperatures for increasing aluminium oxide and calcium oxide contents. Higher cutting speeds then have to be used.
- a process for the manufacture of steels containing a fine distribution of nonmetallic inclusions and having good cutting properties over a wide range of cutting speeds which comprises providing the steel with an oxygen content of 0.004 to 0.1%, deoxidizing the steel in the molten state with a ferro-alloy containing 45 to of silicon, 0.5 to 40% of calcium, up to 4% of aluminium, 0.5 to 8% of manganese and remainder iron in addition to impurities whereby a protective layer of oxidized inclusions will be formed on a tool cutting the steel.
- a process according to claim 1 characterised in that the aluminium content of the deoxidation alloy is between 1 and 1.5%.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Treatment Of Steel In Its Molten State (AREA)
- Cutting Tools, Boring Holders, And Turrets (AREA)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DED0041446 | 1963-04-27 | ||
DED43024A DE1258433B (de) | 1963-04-27 | 1963-11-26 | Verwendung einer Ferrolegierung beim Herstellen von Staehlen mit guter Zerspanbarkeit |
Publications (1)
Publication Number | Publication Date |
---|---|
US3301663A true US3301663A (en) | 1967-01-31 |
Family
ID=25971623
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US362172A Expired - Lifetime US3301663A (en) | 1963-04-27 | 1964-04-23 | Steel making processes |
Country Status (6)
Country | Link |
---|---|
US (1) | US3301663A (enrdf_load_stackoverflow) |
AT (1) | AT270727B (enrdf_load_stackoverflow) |
BE (1) | BE646672A (enrdf_load_stackoverflow) |
DE (2) | DE1258433B (enrdf_load_stackoverflow) |
GB (1) | GB1049917A (enrdf_load_stackoverflow) |
LU (1) | LU45808A1 (enrdf_load_stackoverflow) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3765875A (en) * | 1970-07-23 | 1973-10-16 | L Septier | Inoculating alloy for cast irons |
US3767380A (en) * | 1970-05-29 | 1973-10-23 | Lenin Kohaszati Muvek | Process for the production of free-cutting carbon steels with special deoxidation |
US3933480A (en) * | 1972-09-18 | 1976-01-20 | Republic Steel Corporation | Method of making stainless steel having improved machinability |
US4127407A (en) * | 1976-04-07 | 1978-11-28 | Eitel Hans J | Method of making a casting powder |
US4795491A (en) * | 1987-04-13 | 1989-01-03 | Quigley Joseph R | Premelted synthetic slag for ladle desulfurizing molten steel |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5115487B1 (enrdf_load_stackoverflow) * | 1971-08-04 | 1976-05-17 | ||
US4115111A (en) * | 1973-11-13 | 1978-09-19 | Daido Tokushuko Kabushiki Kaisha | Free-cutting structural steel for machines |
IT1026168B (it) * | 1974-12-27 | 1978-09-20 | Centro Speriment Metallurg | Procedimento per la produzione di acciai ad elevata lavorabilita ed acciai cosi ottenuti |
FR2414560A1 (fr) * | 1978-01-13 | 1979-08-10 | Metal Research Corp | Ferrosilicium de haute purete pour ameliorer les qualites de l'acier et de la fonte |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US660846A (en) * | 1896-06-10 | 1900-10-30 | Krupp Gmbh | Process of deoxidating metals. |
US3000731A (en) * | 1958-02-03 | 1961-09-19 | Res Inst Iron Steel | Fine-grained steels |
US3137570A (en) * | 1962-08-10 | 1964-06-16 | Vanadium Corp Of America | Inoculating alloy |
US3215525A (en) * | 1962-10-12 | 1965-11-02 | Vanadium Corp Of America | Deoxidation alloy |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE904181C (de) * | 1943-05-05 | 1954-02-15 | Neunkircher Eisenwerk Ag | Verfahren zum Herstellen von Automatenstahl |
-
0
- DE DENDAT1248690D patent/DE1248690B/de active Pending
-
1963
- 1963-11-26 DE DED43024A patent/DE1258433B/de active Pending
-
1964
- 1964-04-02 GB GB13651/64A patent/GB1049917A/en not_active Expired
- 1964-04-03 LU LU45808D patent/LU45808A1/xx unknown
- 1964-04-15 AT AT327964A patent/AT270727B/de active
- 1964-04-17 BE BE646672D patent/BE646672A/xx unknown
- 1964-04-23 US US362172A patent/US3301663A/en not_active Expired - Lifetime
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US660846A (en) * | 1896-06-10 | 1900-10-30 | Krupp Gmbh | Process of deoxidating metals. |
US3000731A (en) * | 1958-02-03 | 1961-09-19 | Res Inst Iron Steel | Fine-grained steels |
US3137570A (en) * | 1962-08-10 | 1964-06-16 | Vanadium Corp Of America | Inoculating alloy |
US3215525A (en) * | 1962-10-12 | 1965-11-02 | Vanadium Corp Of America | Deoxidation alloy |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3767380A (en) * | 1970-05-29 | 1973-10-23 | Lenin Kohaszati Muvek | Process for the production of free-cutting carbon steels with special deoxidation |
US3765875A (en) * | 1970-07-23 | 1973-10-16 | L Septier | Inoculating alloy for cast irons |
US3933480A (en) * | 1972-09-18 | 1976-01-20 | Republic Steel Corporation | Method of making stainless steel having improved machinability |
US4127407A (en) * | 1976-04-07 | 1978-11-28 | Eitel Hans J | Method of making a casting powder |
US4795491A (en) * | 1987-04-13 | 1989-01-03 | Quigley Joseph R | Premelted synthetic slag for ladle desulfurizing molten steel |
Also Published As
Publication number | Publication date |
---|---|
BE646672A (enrdf_load_stackoverflow) | 1964-08-17 |
LU45808A1 (enrdf_load_stackoverflow) | 1964-06-03 |
DE1258433B (de) | 1968-01-11 |
GB1049917A (en) | 1966-11-30 |
AT270727B (de) | 1969-05-12 |
DE1248690B (enrdf_load_stackoverflow) | 1967-08-31 |
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