US3277000A - Lubricating compositions for segmented elastomeric copolymer filaments - Google Patents

Lubricating compositions for segmented elastomeric copolymer filaments Download PDF

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Publication number
US3277000A
US3277000A US454181A US45418165A US3277000A US 3277000 A US3277000 A US 3277000A US 454181 A US454181 A US 454181A US 45418165 A US45418165 A US 45418165A US 3277000 A US3277000 A US 3277000A
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United States
Prior art keywords
finish
fatty acid
filaments
weight
oil
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Expired - Lifetime
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US454181A
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English (en)
Inventor
Carroll F Chandler
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EIDP Inc
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EI Du Pont de Nemours and Co
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Publication date
Priority to NL298620D priority Critical patent/NL298620A/xx
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Priority to US454181A priority patent/US3277000A/en
Application granted granted Critical
Publication of US3277000A publication Critical patent/US3277000A/en
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Expired - Lifetime legal-status Critical Current

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Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M7/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made of other substances with subsequent freeing of the treated goods from the treating medium, e.g. swelling, e.g. polyolefins
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
    • D06M2200/40—Reduced friction resistance, lubricant properties; Sizing compositions

Definitions

  • This invention relates to lubricated elastic structures and in particular to filaments of synthetic segmented elastomeric copolym'ers having an oil-based lubricant thereon.
  • an elastic filament made of rubber or of a segmented elastomer, e.g., of the spandex type cannot be processed if free of a lubricating finish.
  • Such elastic fibers have a greater tendency than do relatively inelastic fibers for cohesion of adjacent filaments of the yarn to one another and for sticking of the yarn to other surfaces which causes erratic running tensions.
  • Talc has been the classic lubricant for filaments made of rubber, and it may also be used to lubricate spandex filaments. Talc, however, has many disadvantages as a lubricant. It presents a housekeeping nuisance as Well as a dust hazard, since it is spattered around the area in which the yarn is finished and processed.
  • a talc-coated filament presents serious abrasion problems both in spinning machines and on processing equipment.
  • Oils would appear to be attractive substitutes for talc for the purpose of overcoming these disadvantages.
  • oils cannot be used to lubricate rubber filaments because of the harmful effect of such oils on physical properties.
  • the problem of using oils with spandex filaments was solved by Yuk in US. Patent No. 3,039,895, wherein it is taught that a textile oil, such as mineral oil, makes a satisfactory finish for filaments of synthetic segmented elastomeric copolymers when at least 2% by weight of finely divided particles of certain metal soaps are dispersed therein.
  • an object of this invention to provide an elastic filament having the property of uniform tension in over-end takeoff from a wound bobbin and having thereon an oil-based finish containing less than 2% of dispersed solids. Another object is to provide an elastic filament with a lubricating finish which may be processed without ditficulty.
  • an oiled elastic structure comprising a filament of a synthetic segmented elastomeric copolymer having a substantially anhydrous lubricating finish comp-rising a mixture of a textile oil and a polyethylene oxide ester of a higher fatty acid, said mixture having dispersed therein finely divided particles of a Group I, II, or III metal salt of a higher fatty acid.
  • ethylene oxide adducts are referred to herein as ethylene oxide adducts. These adducts may be prepared by condensing ethylene oxide with higher fatty acids, i.e., the saturated carboxylic acids containing at least 12 carbon atoms in the molecule. Suitable acids include lauric, myristic, palmitic, margaric, stearic, alrachidic, behenic, and cerotic acid. The preferred acids contain no more than 22 carbon atoms.
  • the ethylene oxide adducts useful in the present invention must be soluble in the textile oil at a temperature above the melting point of the adduct. These adducts contain from 2 to about 20 rn-ols of ethylene oxide per mol of acid. Many of these adducts are known in the art and are commercially available.
  • the preferred adducts are waxy solids at room temperature and melt above about 25 C.
  • a preferred group, i.e., those having 6 to 12 mols of ethylene oxide per mol of acid, melt between about 25 C. and 50 C., are selfdispers-ing in water, and are soluble in mineral oil above their melting points.
  • a preferred adduct is Myrj 45, a polyethylene oxide ester of stearic acid, sold by Atlas Chemical Industries, which is reported to contain 8 mols of ethylene oxide per mol of stearic acid.
  • polyethylene oxide esters hereinabove mentioned are used in minor amounts in the finishes of this invention. Mixtures of these esters may be used if desired. Generally, they constitute less than 20% by weight of the finish. Preferably, the finishes do not contain more than about 5% of these esters. Ordinarily, the benefits of the present invention are achieved by the use of as little as about 0.5% by weight of the ester in the finish.
  • the major ingredient in the lubricating finish is a textile oil.
  • textile oil is meant the organic liquids with which textile fibers are normally treated during processing, such liquids being in general oils of low volatility that serve to lubricate the fibers, for instance, tallows, naphthenic oil, sulfated or sulfonated oils, aromatic oils, parafiinic oils, and synthetic oils such as the silicones.
  • the preferred textile oil for the purpose of this invention is a white mineral oil of low to medium viscosity (40 to Saybolt viscosity at about 38 C.). Mixtures of oils may be used if desired.
  • the soaps used in dispersion in the aforementioned Yuk finishes are suitable for use in the present invention. These are the essentially colorless, finely divided soaps of certain metals of Groups I, II, and III of the Periodic Table.
  • Metals of Group In of the well-known Mendeleevs Periodic Table are useful and include those having atomic weights between about 7 and 133, i.e., lithium, sodium, potassium, rubidium, and cesium.
  • Metals of Group II include those having atomic weights between about 24 and 137, i.e., magnesium, calcium, strontium, barium, zinc, and cadmium. From Group III, aluminum which has an atomic weight of about 27 may be used.
  • the higher fatty acid component of the suitable soaps comprise the C to C saturated and unsaturated fatty acids.
  • the soap which is the salt of these fatty acids, may be prepared, of course, from substituted acids such as ketoand hydroxy-acids, for example, 4-ketostearic acid or 12-hydroxystearic acid, instead of fatty acids, or in admixture therewith, if desired.
  • substituted acids such as ketoand hydroxy-acids, for example, 4-ketostearic acid or 12-hydroxystearic acid, instead of fatty acids, or in admixture therewith, if desired.
  • a fatty acid-metal combination is suitable if the resulting soap is essentially colorless and may be obtained in a finely divided state.
  • any of the acids described above may be used, since these soaps are obtainable as finely divided particles.
  • suitable soaps include sodium caprate, sodium laurate, sodium behenate, potassium oleate, potassium myristate, lithium stearate, lithium palmitate, zinc stearate, calcium oleate, magnesium laurate, aluminum trioctoate, and aluminum distearate.
  • the preferred soaps are water-insoluble soaps and are those of the Group II metals, especially those of zinc, calcium and magnesium. Magnesium stearate is particularly preferred.
  • the average radius of the dispersed particle as determined by standard light scattering methods should fall in the range 0.05 to 5 microns.
  • the dispersed particles fall within the range 0.2 to 1.5 microns.
  • the finishes of the present invention contain less than about 2% of dispersed soap particles. A minimum 7 amount of dispersed soap, however, is necessary to achieve the.benefits of the present invention. It has now been found that as little as about 0.5% by weight of soap may be used in the practice of this invention. Accordingly, the oil finish of this invention contains from about 0.5% to about 2% by weight of dispersed solids.
  • the finishes are readily prepared by dissolving the ethylene oxide adduct in mineral oil at a temperature above the melting point of the adduct. The soap is then added and a satisfactorily stable dispersion is obtained by heating to about 8085 C. with good agitation.
  • the finishes of this invention may also contain color inhibitors, anti-static agents, and other additives as desired.
  • a lubricated elastic filament will contain at least 3.5% by weight andless than about 25% by weight of the finish.
  • the amount of finish on a lubricated elastic filament of this invention is in the range from about 12% to about 15%.
  • the finishes of this invention maybe applied to elastic fibers in any convenient manner.
  • the finish may be applied by any of the standard procedures such as by dipping, padding, or spraying.
  • Running yarns may be treated, for example, by spraying, or by passing them through baths or over wicks or other similar devices from which they pick up the finish. Passing the filaments over a roller which dips into a trough containing the finish is a convenient method of application.
  • the trough-roller apparatus is preferably located at a point on the threadline just beyond the first driven feed roll which the elastic filaments contact after leaving the spinneret.
  • the segmented copolymer which makes up the elastic filament of this invention consists of segments of a high-melting, crystalline polymer alternating with segments of a low-melting, amorphous polymer.
  • the crystalline, high-melting segment may be derived from, for example, a polyurea, polyurethane, polyamide, bisureylene polymer, or polyester.
  • the low-melting, amorphous segment may be derived from, for example, a polyester, a polyether, or a hydrocarbon polymer. Polymers of the spandex type are illustrative of such a segmented copolymer.
  • segmented copolymers described in several patents are useful in the practice of this invention.
  • segmented copolymers when in filament form display elongations at the break in excess of 200%, elastic recovery (or tensile recovery) above about 90%, and stress decays below about 20%.
  • elastic recovery and stress decay are defined inU.S. 2,957,852.
  • Example I N,N-dimethylacetan1ide is added at 6.8 pounds per hour.
  • the mixture (57.5% solids) is thoroughly agitated for 15 minutes and then passes to a chamber in which a mixture of hydrazine (35% in water) and diethylamine.
  • the mixture passes to a reaction chamber held at a temperature of 20 to 70 C., the contents having a residence time of about 2-3 minutes.
  • the emerging polymer solution contains approximately 30.0% solids and has a viscosity of 1400 poises at 30 C.
  • the polymer has an intrinsic viscosity of 1.2.
  • the spandex filament so treated shows substantially no tendency to stick to adjacent filaments.
  • Example II A finish having the following composition is applied to the as-spun, untreated spandex yarn of Example 1:
  • Example III A finish having the following composition is applied to the as-spun, untreated spandex yarn of Example I:
  • Example IV A finish having the following composition is applied to a sample of the polyester-based spandex fiber described in US. Patent 2,953,839:
  • the finish is applied to continuous filament elastomeric yarns.
  • individual fine denier filaments for example, 6 denier or less, may first be treated with the finish of this invention, then collected into a continuous filament tow, which may be cut into staple.
  • the lubricated elastic filaments of staple length may be blended with inelastic staple as taught in US. 3,007,227, which blends are useful in the formation of elastic yarn. Staple blends may also be formed by proper blending of the lubricated continuous filament tow with -a tow of inelastic continuous filaments and then cut- Exam le V p t1ng the blend of tows to staple length.
  • the average frictional force in the table above refers to the average force required to overcome the friction between yarn and guide in measurements on a running end of lubricated yarn and is measured at a 70 angle on a dual strain gauge recording yarn frictometer at 100 yards per minute with a 1 0 gram input load using a dull Cr O pin. Where the maximum deviation from the average frictional measurement exceeds 0.75 gram, it is found that the unwinding tension in over-end takeoff is unacceptably erratic. From these data, it is evident that acceptable over-end takeoff tensions are obtainable with dispersed soap contents of less than 2% by weight, when the polyethylene oxide esters of the higher fatty acids are present in the finish.
  • the physical properties of the elastomeric yarn are not adversely affected by the finish used. Tenacity, elongation, modulus, stress decay, and tensile recovery are measured and found to be essentially equal to the same properties of the identical elastic filament having no finish.
  • the finishes of this invention contain a substantially lower content of dispersed soap than do the aforementioned finishes described in Yuk in US. 3,039,895.
  • the advantages of lower soap content are many.
  • reduction in soap content provides improved stability of the dispersion of the soap particles in the textile oil. This results in less settling of solids in the finish troughs with attendant advantages of less frequent need for cleaning the troughs and/or an easier trough-cleaning operation.
  • the lubricated elastic filaments of this invention essentially eliminate the problem of solid deposits building up on yarn guides and knitting needles, which problem has been associated with the use of the Yuk finishes.
  • the staple blends are useful for making a wide variety of elastic or stretchy products including woven, knitted and non-woven fabrics for use in universal fitting apparel, form-fittiug upholstery, surgical stockings, and splint tapes.
  • a lubricant composition for application to a filament of a synthetic segmented elastomeric copolymer consisting essentially of a textile oil; at least about 0.5% by weight of a normally solid polyethylene oxide monoester of a higher fatty acid having 6 to 1-2 mols of ethylene oxide per mol of fatty acid containing 12 to 22 carbon atoms, said ester being soluble in said textile oil at a temperature above its melting point of at least 25 C.; and from about 0.5 to less than about 2% by weight of finely divided particles of a metal salt of a fatty acid containing from about 8 to 22 carbon atoms dispersed in the ester-oil solution, said metal being selected from the class consisting of Group Ia metals having an atomic weight between about 7 and 133, Group II metals having an atomic weight between about 24 and 137, and a Group III metal having an atomic weight of about 27, said particles having an average radius in the range between 0.05 to 5 microns.
  • composition of claim 1 wherein said fatty acid is stearic acid and said ester contains 8 mols of ethylene oxide per mol of acid.

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  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Artificial Filaments (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
US454181A 1965-05-07 1965-05-07 Lubricating compositions for segmented elastomeric copolymer filaments Expired - Lifetime US3277000A (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
NL298620D NL298620A (enrdf_load_stackoverflow) 1965-05-07
US454181A US3277000A (en) 1965-05-07 1965-05-07 Lubricating compositions for segmented elastomeric copolymer filaments

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3421935A (en) * 1965-08-12 1969-01-14 Du Pont Bulkable nylon yarn
US3482010A (en) * 1963-09-30 1969-12-02 Kuraray Co Process for the production of polyurethane elastic fiber having less adhesivity
US3549475A (en) * 1967-05-24 1970-12-22 Fiber Industries Inc Method for increasing the flex life of synthetic leather and product produced thereby
US3953339A (en) * 1973-09-14 1976-04-27 Diamond Shamrock Corporation Coning oil
WO1993017170A1 (en) * 1992-02-19 1993-09-02 E.I. Du Pont De Nemours And Company Oil finish with high lubricant content
US6664299B2 (en) * 2002-02-14 2003-12-16 Dow Corning Corporation Masterbatch method for economically and efficiently producing soap dispersions in textile fluids for synthetic fiber treatment

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2025435A (en) * 1933-07-01 1935-12-24 American Enka Corp Treating natural and artificial fibers
US2682486A (en) * 1948-12-17 1954-06-29 Celanese Corp Lubrication treatment of textile materials
US2690426A (en) * 1950-03-07 1954-09-28 Atlas Powder Co Lubricating compositions
US3039895A (en) * 1960-03-29 1962-06-19 Du Pont Textile

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2025435A (en) * 1933-07-01 1935-12-24 American Enka Corp Treating natural and artificial fibers
US2682486A (en) * 1948-12-17 1954-06-29 Celanese Corp Lubrication treatment of textile materials
US2690426A (en) * 1950-03-07 1954-09-28 Atlas Powder Co Lubricating compositions
US3039895A (en) * 1960-03-29 1962-06-19 Du Pont Textile

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3482010A (en) * 1963-09-30 1969-12-02 Kuraray Co Process for the production of polyurethane elastic fiber having less adhesivity
US3421935A (en) * 1965-08-12 1969-01-14 Du Pont Bulkable nylon yarn
US3549475A (en) * 1967-05-24 1970-12-22 Fiber Industries Inc Method for increasing the flex life of synthetic leather and product produced thereby
US3953339A (en) * 1973-09-14 1976-04-27 Diamond Shamrock Corporation Coning oil
WO1993017170A1 (en) * 1992-02-19 1993-09-02 E.I. Du Pont De Nemours And Company Oil finish with high lubricant content
US5370804A (en) * 1992-02-19 1994-12-06 E. I. Du Pont De Nemours And Company Neat oil finish with high lubricant content
TR28934A (tr) * 1992-02-19 1997-07-21 Du Pont Kayganlastirici madde muhtevasi yüksek olan saf yag apre maddesi.
CN1307338C (zh) * 1992-02-19 2007-03-28 因维斯塔技术有限公司 润滑整理剂组合物，其使用方法以及用其涂敷的合成纤维
US6664299B2 (en) * 2002-02-14 2003-12-16 Dow Corning Corporation Masterbatch method for economically and efficiently producing soap dispersions in textile fluids for synthetic fiber treatment

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