US3227241A - Ceramic mufflers - Google Patents

Ceramic mufflers Download PDF

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US3227241A
US3227241A US351949A US35194964A US3227241A US 3227241 A US3227241 A US 3227241A US 351949 A US351949 A US 351949A US 35194964 A US35194964 A US 35194964A US 3227241 A US3227241 A US 3227241A
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inlet
ceramic
elements
portions
outlet
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US351949A
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Deo R Mattoon
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Corning Glass Works
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Corning Glass Works
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Priority to US351949A priority Critical patent/US3227241A/en
Priority to FR8261A priority patent/FR1425993A/en
Priority to FR8260A priority patent/FR1429588A/en
Priority to GB10391/65A priority patent/GB1093179A/en
Priority to DE1965C0035282 priority patent/DE1476493A1/en
Priority to GB1064465A priority patent/GB1093180A/en
Priority to NL6503259A priority patent/NL6503259A/xx
Priority to SE333065A priority patent/SE304640B/xx
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N13/00Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
    • F01N13/18Construction facilitating manufacture, assembly, or disassembly
    • F01N13/1838Construction facilitating manufacture, assembly, or disassembly characterised by the type of connection between parts of exhaust or silencing apparatus, e.g. between housing and tubes, between tubes and baffles
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63CSKATES; SKIS; ROLLER SKATES; DESIGN OR LAYOUT OF COURTS, RINKS OR THE LIKE
    • A63C11/00Accessories for skiing or snowboarding
    • A63C11/02Devices for stretching, clamping or pressing skis or snowboards for transportation or storage
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N1/00Silencing apparatus characterised by method of silencing
    • F01N1/08Silencing apparatus characterised by method of silencing by reducing exhaust energy by throttling or whirling
    • F01N1/082Silencing apparatus characterised by method of silencing by reducing exhaust energy by throttling or whirling the gases passing through porous members
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N13/00Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
    • F01N13/009Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series
    • F01N13/0097Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having two or more separate purifying devices arranged in series the purifying devices are arranged in a single housing
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N13/00Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
    • F01N13/14Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00 having thermal insulation
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N13/00Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
    • F01N13/16Selection of particular materials
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N13/00Exhaust or silencing apparatus characterised by constructional features ; Exhaust or silencing apparatus, or parts thereof, having pertinent characteristics not provided for in, or of interest apart from, groups F01N1/00 - F01N5/00, F01N9/00, F01N11/00
    • F01N13/18Construction facilitating manufacture, assembly, or disassembly
    • F01N13/1888Construction facilitating manufacture, assembly, or disassembly the housing of the assembly consisting of two or more parts, e.g. two half-shells
    • F01N13/1894Construction facilitating manufacture, assembly, or disassembly the housing of the assembly consisting of two or more parts, e.g. two half-shells the parts being assembled in longitudinal direction
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2310/00Selection of sound absorbing or insulating material
    • F01N2310/06Porous ceramics
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2330/00Structure of catalyst support or particle filter
    • F01N2330/02Metallic plates or honeycombs, e.g. superposed or rolled-up corrugated or otherwise deformed sheet metal
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2330/00Structure of catalyst support or particle filter
    • F01N2330/06Ceramic, e.g. monoliths
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2450/00Methods or apparatus for fitting, inserting or repairing different elements
    • F01N2450/28Methods or apparatus for fitting, inserting or repairing different elements by using adhesive material, e.g. cement
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2470/00Structure or shape of gas passages, pipes or tubes
    • F01N2470/10Tubes having non-circular cross section
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2490/00Structure, disposition or shape of gas-chambers
    • F01N2490/18Dimensional characteristics of gas chambers
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2530/00Selection of materials for tubes, chambers or housings
    • F01N2530/02Corrosion resistive metals
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F01MACHINES OR ENGINES IN GENERAL; ENGINE PLANTS IN GENERAL; STEAM ENGINES
    • F01NGAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL COMBUSTION ENGINES
    • F01N2530/00Selection of materials for tubes, chambers or housings
    • F01N2530/24Sintered porous material, e.g. bronze, aluminium or the like
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S55/00Gas separation
    • Y10S55/30Exhaust treatment

Definitions

  • Sound attenuation or sound deadening of the exhaust gas stream of internal combustion engines is a wellknown art.
  • Commonly structures for this purpose are of the nonresistive type (ie. relatively large tlow passages), made of metallic parts and include baffles that serve a sound attenuation function.
  • these nonresistive structures are coated r lined with conventional, well-knovvn sound absorbing materials to further improve sound attenuation performance.
  • These devices are usually subject to relatively rapid deterioration due to the severe corrosive chemical and thermal conditions encountered in use and by detrimental build-up of exhaust products on their surfaces.
  • Resistive type devices wherein the sound deadening is brought about by a multitude of irregular surfaces largely parallel to gas flow have also been proposed for this purpose. These latter devices involved passing the exhaust gases through a porous mass of material, Isuch as a loose packing of refractory granules, balls or libers, and ruptured cell teamed glass.
  • a porous mass of material Isuch as a loose packing of refractory granules, balls or libers, and ruptured cell teamed glass.
  • resistive type muiliing devices no significant success has been had with these resistive type muiliing devices.
  • the difficulties encountered include relatively rapid chemically corrosive destruction of supporting metallic parts as well as of the resistive material mass due to vibration and thermal conditions of use, and very importantly the low engine efiiency caused by the very large back pressures inherent iu these proposed structures, which problem may be further aggravated by build-up of exhaust products.
  • this resistive element is essentially characterized by: (l) regular gas passages or cells being defined and separated from one another by the thin ceramic walls so as to provide a cross-sectional area of each individual passage or cell of no more than about 0.010 square inch, preferably within the range of about 0.0002 to 0.003
  • the thinness of the cell walls being chosen so that there is at least about of aggregate open space, preferably about to 85%, provided by the collective cell crosssectional areas in a plane through the honeycomb perpendicular to the axes of the gas passages.
  • the thin walls generally are Within the range of about 0.004 to 0.010 inch thick, but can be as thick as 0.015 inch or even somewhat thinner than 0.004 inch.
  • this resistive element for a muilier used with an internal combustion engine, is that it be made of ceramic material that is highly refractory (ie. melting or softening temperature substantially exceeding maximum operating or service temperatures) and remains so indefinitely, that has good thermal shock resistance, and that is chemically resistant or inert to the highly corrosive conditions at operating ternperatures.
  • the sintered unitary construction provides a high degree of strength to resist indeiinitely destruction due to vibration or other mechanical stresses encountered under normal service conditions. Although its contribution to the successful deadening of sound in the abovedescribed ceramic honeycomb resistive element is not positively ascertained, it is believed that the normal resulting cell wall porosity adds to the sound attenuation performance.
  • the usual porosity resulting from the preferred process of construction described below has been measured at 25% to 45%.
  • Mutllers with one or several ceramic honeycomb resistive elements, as described above, have been found to give almost (but not equally) as good long term sound attenuation performance as prior commercial mutllers for a great variety of engines. Notably, such performance was accompanied by no observable mechanical nor chemical deterioration of the ceramic honeycomb elements. Furthermore, except for a very small zone adjacent the periphery of these elements, no build-up of exhaust products was found.
  • the all-ceramic noise suppressor device of this invention basically comprises a plurality of gas ilow resistive elements arranged in a series dening an irregular gas flow path within a casing and rigidly positioned within the casing by means of a bond.
  • the resistive elements, the casing and the bond are all made of sintered ceramic.
  • all the sintered ceramic must have essentially similar coeilicients of thermal expansion lso as to avoid physical destruction in service.
  • an irregular gas flow path is delined as a path configuration other than that of a straight or smooth line conguration parallel to the axis of the series of elements.
  • the axis of the series of elements within the casing can be, but is not necessarily limited to, a straight line configuration. Such axis of the series can also be made in other congurations if desired, o g. sinusoidal or even S-shaped.
  • the casing includes opposite inlet and outlet end walls. These walls are provided with inlet and outlet ports, respectively.
  • each resistive element comprises two different portions.
  • @ne portion (or portions) comprises an open passage, thin walled, sintered ceramic honeycomb having features, e.g. inlet and outlet surfaces with unobstructed gas passages extending therebetween, maximum thickness of thin walls defining the passages, maximum crosssectional areas of the gas passages, and minimum aggregate open space or cross sectional area measured in a plane perpendicular to the axes of the gas passages, all as specified above.
  • the total open area of each of these open passage portions must be not less than, and desirably greater than, the area of the inlet port in order to obtain the excellent low back pressure as the gas stream flows through them.
  • each open passage portion has a total open area of about two to three times the area of the inlet port.
  • the outlet port should have an area at least equal to the inlet port area for the same reason.
  • the arrangement of the series of elements is such that the inlet surface of the open passage portion of each succeeding element along the gas flow path is spaced from the outlet surface of the open passage portion of the preceeding element. These spaced surfaces are so constructed and arranged to provide the definition of the irregular gas flow path.
  • the other portion (or portions) of the resistive elements comprises an imperforate barrier to gas flow.
  • an imperforate barrier to gas flow For effective muflling, particularly a high intensity of the lower frequency sounds (e.g. G-315 c.p.s.), of the exhaust from the larger engines (ie. 200 or more cubic inches displacement with six or more cylinders) to, and even lower than, the low level of present day commercial mulilers, the imperforate barrier portions each should comprise a close passage, thin walled, sintered ceramic honeycomb having the same restrictive physical features as those specified above for the open passage honeycomb portions, but additionally having a sintered ceramic closure sealing off each gas passage at a point spaced from the inlet surface of the close passage honeycomb toward the outlet surface thereof.
  • the closure provides the imperforate barrier structure while at the same time forming with the honeycomb structure a plurality of dead-end passages or cul de sacs opening on the inlet surface of the close passage honeycomb.
  • An additional or alternative plurality of such cul de sacs or dead-end passages opening on the outlet surface of the close passage portion can be provided, if desired in certain cases, to further assist in absorbing sound.
  • the sound waves in the gas stream passing through the noise suppressor device of this invention containing the cul de sacs upon reaching the inlet surface of the close passage honeycomb portions, propagate into the dead-end gas passages. Sound energy is then dissipated by cancellation due to the reflectance of the Wave from the closed end surface or closure of the gas passage. Of course, it is expected that some sound energy is absorbed by the porous walls.
  • the imperforate barrier portion can be made of a plain solid ceramic wall or the like without the cul de sacs.
  • FIGURE l is a longitudinal view in cross section of one specific embodiment of the present invention.
  • FIGURE 2 is a sectional view taken along line II--II in FIGURE 1,
  • FIGURE 3 is a sectional View taken along line III-III in FIGURE l,
  • FIGURE 4 is a transverse cross sectional view of another speciiic embodiment of the present invention, v
  • FIGURE 5 is a longitudinal view in cross section of a further composite embodiment of the present invention illustrating several additional variations
  • FIGURE 6 is a longitudinal view in cross section of a still further specific embodiment of the present invention.
  • FIGURE 7 is a sectional View taken along line VII- VII in FIGURE 6, and
  • FIGURE 8 is a sectional view taken along line VIII- VIII in FIGURE 6.
  • the all-ceramic mufiler or noise suppression device includes a compatible sintered ceramic shell or casing lil and compatible sintered ceramic honeycomb resistive elements lli-I7 rigidly bonded to the casing l@ by means of a compatible sintered ceramic cement 20.
  • the sintered ceramics used have essentially similar coefficients of thermal expansion so as to avoid fractures and physical destruction of the device upon being subjected to repeated and substantial changes in temperature.
  • the sintered ceramics also should have low thermal expansion coecients (ie. -lO to ⁇ l0 l07/ C. over extended temperature range) to minimize the thermal stresses in the device.
  • thermal expansion coeiicients is not essential.
  • Casing lil includes an inlet end wall 1S and an outlet end Wall I9.
  • the inlet end wall 1S has an inlet port 21 and outlet end wall I9 has an outlet port- 22. Both ports have diameters D1.
  • the casing lil is made in two sections as shown and provided with a ships lap 23 to render the two sections separable.
  • casing lil can be made one unitary piece as desired, e.g. by forming a bond of sintered ceramic cement at ships lap 23.
  • the resistive elements are of two types, each alternating with the other along the series defining the irregular gas ilow path.
  • Each type of element comprises a central portion bounded by an outer portion with each of these portions being substantially symmetrical about the axis of the series.
  • the outer perimeter of these central and outer portions can be of various configurations as desired, e.g. circular, oval, square, rectangular, triangular, polygonal, etc.
  • the central portions having outside diameters D2, D4, D6 of the first type elements l2, 14, 16 and the outer annular portions having inside diameters D3, D5, D7 0f the second type elements I3, 15, I7 comprise the open passage, thin walled honeycombs described above.
  • the outer annular portions having inside diameters D2, D4, De of the rst type elements l2, lll, ll6 and the central portions having outside diameters D3, D5, D7 of the second type elements 13, l5, I7 comprise the imperforate barriers with cul de sacs described above.
  • the total area of the central portion of the second type element should be at least about equal to the total area of the central portion of adjacent first type elements.
  • the open cells or open gas passages of one type element are axially opposite the barrier portion of the other type element along the axis of the series.
  • he cul de sacs of elements itil-17 are formed by providing sintered ceramic coatings 32;-37 on the outlet faces or surfacesU of the elements. These coatings 32-37 seal or close off the cells or gas passages terminating at the outlet surface areas covered by the coatings.
  • Coatings 32, 34, 36 form the outer annular barrier zones or portions of elements 12, 1d, 16 that surround the central portions of open passage cells.
  • coatings 33, 35, 37 form the central circular barrier zones or portions of elements 13, 1S, 17 that are surrounded by the outer annular portions of open passage cells.
  • the number and spacing of the two-portion elements can be varied depending upon the particular type of application. A series of at least four of the elements are necessary for satisfactory muffling the exhaust from the large internal combustion engines whereas only two or three elements can be satisfactorily used for mufrling the exhaust from smaller engines, such as those commonly found on agricultural tractors and the like.
  • the ceramic honeycomb elements can be advantageously made of a ceramic material having a fairly high specific heat (eg. about 0.2 or more calories per gram at 25 C.) so as to additionally act as a flame arrestor in the hot exhaust stream.
  • the superior performance i.e. sound attenuation, low back pressure, etc.
  • the superior performance for large engines is obtained by spacing the elements a distance substantially equal to the sum of the average cell or gas passage length of the two elements forming the spacing and with an average gas passage length for each element Within the range of about 1/2 to 21/2 inches.
  • Particularly effective results have been obtained when the spacing has been kept Within i25% of the aforesaid sum of average gas passage lengths.
  • the spacing may be advantageously less than as described above relative to the sum of the average gas passage lengths for suitable results (possibly because of the lower viscosity of the ex- A muffier unit made according to the structure shown in FlGURES 1-3 was tested in the exhaust line of a 401 cubic inch, eight cylinder engine and found to give superior performance as compared with the commercial muffler customarily supplied with the engine and with a comparable back pressure of 18" of Hg.
  • the ceramic casing was made of a sintered slip cast mixture of 72% by weight petalite and 28% by weight beta spodumene in accordance with the teachings of U.S.
  • Patent r5,096,159 to H. C. Van Cott This sintered ceramic exhibits a very low coefficient of thermal expansion of about up to 900 C.
  • the casing was made with a wall thickness of about 1A", an inside diameter of about 6, a total length of about 251/2" and port diameters D1 of 2".
  • honeycomb elements were made in accordance with the teachings of U.S. Patent 3,112,184 to R. Z. Hollenbach.
  • the ceramic material used consisted of 75% by weight of petalite and 25% by weight of a glass-ceramic having the following approximate composition, by oxide analysis, in weight percent: 70% Si02, 18% AlzOs, 5% TiOg, 3% MgO, 3% Lig@ and 1% ZnO.
  • a slurry was formed of this comminuted ceramic material by ball milling it with equal parts of a solution having the following approximate composition, in volume percent:
  • Versarnid 115 is the trade name of a thermoplastic polymer supplie-d by General Mills, inc., and it is prepared by condensation of polymerized unsaturated fatty acids, such as dilinoleic acid, with aliphatic amines such as ethylene diamine.
  • Hysol 6111 is the trade name of an epoxy resin solution, supplied by Houghton Laboratories, Inc., containing 57% by weight of epoxy resin having a viscosity of about 2.5-4.0 poise at C., an epoxide equivalent (grams of resin containing l gram chemical equivalent of epoxy) of 595i50, and a melting range of 73-85 C.
  • the slurry was coated onto common 31/2 pound tea bag paper and formed into sintered ceramic honeycomb structures in the manner described in the aforementioned U.S. Patent 3,112,184.
  • the firing schedule was as follows:
  • Temperature range Firing rate Room temp. to 700 C 350 C./hr. Hold at 700 C. 1 hour. 700 C. to l220 C 30 minutes. Cool to room temp. Furnace rate. Rere to 1240o C. 300 C./hr. Hold at 1240 C 7 hours.
  • honeycornbs were furnace cooled to handling temperature.
  • honeycornbs were produced with gas passages, taken in cross-section, in the shape of isosceles triangles having a height of about 0.04 inch and a base of about 0.075 inch and with an aggregate open area of about 70% of the total cross-sectional area of the honeycombs in a plane perpendicular to the axes of the gas pasasges.
  • the average cell wall thickness was about 0.006 inch and the wall porosity was about
  • the sintered ceramic honeycombs exhibited coefficients of thermal expansion of about 0i2 107/ C. up to 300 C. or higher.
  • honeycomb elements were cut to slightly less than 6 inches in diameter.
  • Elements 12, 13, 16 and 17 were Imade l inch thick (direction parallel to gas passage axes) and elements 1d and 15 were made 13/4 inches thick. The latter two elements were spaced apart 4% inches, each equidistant from the mid-point of the casing.
  • the spacing between elements 13 and 14,1andbetween elements 15 and 16 was 21/2 inches.
  • the spacing between elements 12 and 13, and between elements i6 and 17 was 2 inches.
  • the ceramic cement for rigidly bonding the elements 12.,17 to the casing 10 had the following batch composition analytically by weight: 8.72% ZnO, 1.3% CaF2, 3.46% SiC, 1.93% S03 (from fuirned white lead), 6.81% Pb() and the remainder glass petalite.
  • a batch of this cement composition was dispersed in a solution of 75 by Weight butyl alcohol and 25% by weight toluene and the resulting dispersion coated on the peripheral surface of the honeycomb elements. The same cement dispersion was used to form coatings 32-37 on the outlet surface of the elements. After placing the elements in the abovedescribed positions, the resulting assembly was heated to ll C. at about 5 C./minute and held at 1150 C.
  • the assembly was furnace cooled to handling temperatures at a rate of about 5 C./minute.
  • the resulting sintered ceramic cement exhibited coefficients of thermal expansion of about 0-4 l0-7/ C. up to 300 C. or higher.
  • the coatings 32-37 were formed so as to provide the following diameters: D2 being 31/2 inches; D3, D5 and D7 being 41A inches; D., and D5 being 4 inches.
  • Example 2 Another unit made similiar to the structure shown in FIGURES 1-3 was tested in the exhaust line of ya 225 cubic inch, six cylinder engine and found to give satisfactory results.
  • the construction of this unit was the same as in Example 1 except for the following specific features.
  • the total casing length was about 17 inches.
  • the elements lf2-i7 were each l inch thick ⁇ and spaced apart about 11/2 inches.
  • Elements 13, l5 and f7 were made with gas passages, taken in cross-section, in the shape of isosceles triangles having a height of about 0.02 inch and a base of about 0.038 inch and with an aggregate open area of about 60%.
  • FGURE 4 shows another form of the noise suppressor device of the invention that can be made in smaller compact shapes for location in the exhaust manifold or closely to it.
  • This form of device comprises, similarly to the ones already desc-ribed, a sintered ceramic casing stl of rectangular cross-section. Sintered ceramic cement 4l rigidly holds the resistive elements in place within the casing dil.
  • sintered ceramic element 42 (analogous to element l?. in FIGURE l) shown comprises a central portion 44 of open cells or gas passages outer portions 46 of dead-end gas passages or cul de sacs formed by a sintered ceramic coating on the outlet face of the element.
  • the second type element in this unit would have the open cells in similar outer portions and the cul de sacs in a similar central portion. Of course, this unit would be made to conform to the other necessary physical restrictive features described above.
  • FIGURE 5 illustrates several other modifications that can be made within the present invention.
  • the casing can be made in several separable segments 4S, Il@ and 5b. rlhus, suitable muilling units can be readily provided for a variety of engines merely by assembling segments 43 and Sil with or without one or more segments 49. ln order to conserve space, inlet end wall 52 and outlet end wall 53 can be provided with a stubby inlet port Se and a stubby outlet port 55, respectively.
  • the element can be provided with a forwardly extending central portion 56 having its inlet surface angularly converging at a central furtherrnost forward point.
  • the sound attenuating or deadening effectiveness of the cul de sac feature can be strengthened or increased by cutting cavities or indentations 58 into the inlet surface portions of the elements opposite the outlet surface portions having the sintered ceramic coatings et) and 6l sealing shut the gas passages extending between those surfaces.
  • the cavities 5S are circular resonating chambers, but they can be made in other geometric forms as desired.
  • all the elements 62-67 can be provided with cavities Sil or only selected elements can be so provided, as desired for each particular application.
  • Example 3 FEGURES 6-8 show a still further specific embodiment of my invention tested in the exhaust line of a 3G() cubic inch, eight cylinder engine with excellent results.
  • the two part casing '70 was made like the casing in Example l, except that the total length was only about 2l".
  • Elements 1 77 were made of the sintered ceramic honeycomb structures used in Example 2.
  • the round elements 7l, 73, 75, 77 were slightly less than 5 inches in diameter and one inch thick.
  • Elements 72, 7d, '76 were made rectangular (see FIGURE 8) with dimensions 6 x 4% x l and assembled with the other elements as shown in FIG- URE 6.
  • Elements 7l, 73, 75, "i7 were then rigidly bonded to casing '76 by cement 78 in the same manner as in Example l.
  • one half of the outlet surfaces of elements 7i, '73, 75, 77 were provided with coatings 2li, 83, S5, 87 (also in the same manner as Example l) thereby forming barriers with cul de sacs opening on the inlet surfaces in an alternating pattern through the mufller unit.
  • the other halves of these elements were the open passage portions.
  • coatings S2, Sd, 86 were provided on elements 72, '74, 76 forming Outer close passage portions and defining the central open passage portions. Each of the latter can be divided in two by a central close passage portion if desired in certain cases. While coatings 84 are formed on the outlet surface of element .74 to provide cul de sacs opening on the inlet surface, coatings 32 and 86 are formed on the inlet surfaces of elements 72 and 75 to provide cul de sacs opening on the outlet surfaces thereof. This design allows the muflier unit to be positioned so that no cul de sacs open upwardly in a manner that would permit solid particles carried in the gas stream to lill up these cul de sacs and reduce their ability to absorb sound energy.
  • the present invention has been described with respect to specific details of certain embodiments thereof, it is not intended that such details be limitations upon the scope of the invention except insofar as set forth in the claims. Accordingly, it will be appreciated that a variety of ceramic materials and methods of constructing the ceramic structures can be utilized without departing from the invention.
  • the structures can be made from appropriate glass or glass-ceramic materials by known hot glass processes and, as used in this specification, including the claims, the term ceramic is used in its most generic sense as encompassthose ceramic materials that are amorphous, crystalline or mixtures of these two physical states.
  • An all-ceramic noise suppressor device comprising (A) a ceramic casing including opposite inlet and outlet end walls having inlet and outlet ports, respectively,
  • each honeycomb having: (a) an inlet surface and an opposed outlet surface, (b) a plurality of unobstructed gas passages extending between said inlet and outlet surfaces, the gas passages being dened by thin walls up to about 0.015 inch thick, the crosssectional area of each gas passage not exceeding about 0.01() square inch and the aggregate open cross-sectional area of said honeycomb measured in a plane perpendicular to the axes of the gas passages being at least 50 percent of the total cross sectional area of said honeycomb, the inlet surface of said second portions of each succeeding element along the gas flow path being spaced from the outlet surface of said second portions of the preceding element, said spaced surfaces so constructed and arranged together with said first portions to provide the definition of the irregular gas flow path, said aggregate open area of each element being not less than the area of said inlet port, and
  • the device of claim l in which the thin walls of said honeycomb are porous.
  • imperforate barriers comprise close passage, thin walled honeycombs having the same restrictive physical features as those specified for said open passage honeycombs, but additionally having ceramic closures so constructed and arranged to seal off each gas passage and to form a plurality of cul de sacs opening on at least one of said inlet and outlet surfaces of the close passage honeycombs.
  • An al1-ceramic noise suppressor device comprising (A) a ceramic casing including opposite inlet and out let end walls having inlet and outlet ports, respectively,
  • each honeycomb having; (a) an inlet surface and an opposed outlet surface, (b)
  • the gas passages being defined by thin walls up to about 0.015 inch thick, the cross-sectional area of each gas passage not exceeding about 0.010 square inch and the aggregate open cross-sectional area of said honeycomb measured in a plane perpendicular to the axes of the gas passages being at least 50 percent of the total crosssectional area of said honeycomb, the area of the central portion of said second type element being at least about equal to the area of the central portion of adjacent first type elements, the area of the central portion of said first type element and the outer portion of said second type element being greater than the area of said inlet port, and
  • the device of claim 9 including at least four of said elements.
  • each of said imperforate barriers comprise close passage, thin walled honeycombs having the same restrictive physical features as those specified for said open passage honeycombs, but additionally having ceramic closures sealing off each gas passage and spaced from the inlet surface of said close passage honeycomb toward the outlet surface thereof thereby forming a plurality of cul de sacs opening on said inlet surface.
  • the device of claim 12 including at least four of said elements.
  • An all-ceramic noise suppressor device comprising (A) a ceramic casing including opposite inlet and outlet end walls having inlet and outlet ports, respectively.
  • each honeycomb having: (a) an inlet surface and an opposed outlet surface, (b) a plurality of unobstructed gas passages extending between said inlet and outlet surfaces, the gas passages being defined by thin Walls up to about 0.015 inch thick, the cross-sectional area of each gas passage not exceeding about 0.010 square inch and the aggregate open cross-sectional area of said honeycomb measured in a plane perpendicular to the axes of the gas passages being at least 50 per cent of the total cross-sectional area of said honeycomb, said aggregate open area of each element being greater than the area of said inlet port, and
  • the device of claim 19 including at least four of said first type elements and at least three of said second type elements.
  • imperforate barriers comprise close passage, thin walled honeycombs having the same restrictive physical features as those specified for said open passage honeycombs, but additionally having ceramic closures so constructed and arranged to seal off each -gas passage and to form a plurality of cul de sacs opening on at least one of said inlet and outlet surfaces of the close passage honeycombs.
  • the device of claim 21 including at least four of said first type elements and at least three of said second type elements, said ceramic closures of all said first type elements except the one nearest the outlet end wall and said ceramic closures of every other second type element as determined from said inlet end Wall being located at the outlet surface of said close passage honeycombs thereby forming a plurality of cul de sacs opening on the inlet surface thereof, and said ceramic closures of the first type element nearest the outlet end Wall ⁇ and of the other second type elements being located at the inlet surface of said close passage honeycombs thereby forming a plurality of cul de sacs opening on the outlet surface thereof.

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Exhaust Silencers (AREA)
  • Exhaust Gas After Treatment (AREA)

Description

D. R. MATTOON CERAMIC MUFFLERS Jan. 4, 1966 5 Sheets-Sheet 1 Filed March 16, 1964 lilll Jan. 4, 1966 D. R. MATTooN 3,227,241
CERAMIC MUFFLERS Filed March 16. 1964 3 Sheets-Sheet z n E lL .X N n INVENTOR l Deo. R. Marwan BY ATTORNEY D. R. MATTOON CERAMIC MUFFLERS Jan. 4, 1966 5 Sheets-Sheet .'5
Filed March 16, 1964 INVENTOR. Deo R. Maffoon A TTORNEY United States Patent O 3,227,241 CERAMlC MUFFLERS Deo lll. Matteoli, Horseheads, NY., assigner to Corning glass Works, Corning, N.Y., a corporation of New orlr Filed Mar. 16, i964, Ser. No. 351,949 22 Claims. (Cl. lSL-S) This invention relates to the deadening or suppressing of sound by means of an acoustic lter or silencer device. la particular, it relates to a novel resistive, ceramic muffer structure for the exhaust system of internal combustion engines and the like.
Sound attenuation or sound deadening of the exhaust gas stream of internal combustion engines is a wellknown art. Commonly structures for this purpose are of the nonresistive type (ie. relatively large tlow passages), made of metallic parts and include baffles that serve a sound attenuation function. In some cases, these nonresistive structures are coated r lined with conventional, well-knovvn sound absorbing materials to further improve sound attenuation performance. These devices are usually subject to relatively rapid deterioration due to the severe corrosive chemical and thermal conditions encountered in use and by detrimental build-up of exhaust products on their surfaces.
Resistive type devices wherein the sound deadening is brought about by a multitude of irregular surfaces largely parallel to gas flow have also been proposed for this purpose. These latter devices involved passing the exhaust gases through a porous mass of material, Isuch as a loose packing of refractory granules, balls or libers, and ruptured cell teamed glass. However, as far as l am aware, no significant success has been had with these resistive type muiliing devices. The difficulties encountered include relatively rapid chemically corrosive destruction of supporting metallic parts as well as of the resistive material mass due to vibration and thermal conditions of use, and very importantly the low engine efiiency caused by the very large back pressures inherent iu these proposed structures, which problem may be further aggravated by build-up of exhaust products.
sarge back pressuresl severely cut down the engine volumetric eiliciency. rl`hus, for example, the pistons cannot expel all the exhaust gases from the cylinders due to the opposing force of the back pressure, thereby leaving some exhaust gases to mix in the chamber with the intake fuel. This results in untenable dilution of the fuel mixture in present day engine designs.
Recently, it has been found that the foregoing dithculties can be avoided by utilizing, as a resistive element or member, at least one relatively inexpensive, thin walled, ceramic cellular or honeycomb structure sintered to a rigid unitary state or condition and having a plurality cgenerally regular, unobstructed gas passages of small cross-section extending between and terminating in substantially opposed inlet and outlet surfaces. For effective sound deadening and modestly low or negligible back pressure, this resistive element is essentially characterized by: (l) regular gas passages or cells being defined and separated from one another by the thin ceramic walls so as to provide a cross-sectional area of each individual passage or cell of no more than about 0.010 square inch, preferably within the range of about 0.0002 to 0.003
square inch and (2) the thinness of the cell walls being chosen so that there is at least about of aggregate open space, preferably about to 85%, provided by the collective cell crosssectional areas in a plane through the honeycomb perpendicular to the axes of the gas passages. The thin walls generally are Within the range of about 0.004 to 0.010 inch thick, but can be as thick as 0.015 inch or even somewhat thinner than 0.004 inch.
Other important characteristics of this resistive element, for a muilier used with an internal combustion engine, are that it be made of ceramic material that is highly refractory (ie. melting or softening temperature substantially exceeding maximum operating or service temperatures) and remains so indefinitely, that has good thermal shock resistance, and that is chemically resistant or inert to the highly corrosive conditions at operating ternperatures. The sintered unitary construction provides a high degree of strength to resist indeiinitely destruction due to vibration or other mechanical stresses encountered under normal service conditions. Although its contribution to the successful deadening of sound in the abovedescribed ceramic honeycomb resistive element is not positively ascertained, it is believed that the normal resulting cell wall porosity adds to the sound attenuation performance. The usual porosity resulting from the preferred process of construction described below has been measured at 25% to 45%.
Mutllers with one or several ceramic honeycomb resistive elements, as described above, have been found to give almost (but not equally) as good long term sound attenuation performance as prior commercial mutllers for a great variety of engines. Notably, such performance was accompanied by no observable mechanical nor chemical deterioration of the ceramic honeycomb elements. Furthermore, except for a very small zone adjacent the periphery of these elements, no build-up of exhaust products was found.
l have now discovered, and it is a primary object of this invention to provide, a novel muffler or noise suppressor device utilizing a plurality of the ceramic honeycomb gas ilow resistive element described above in a unique assembly or construction arrangement that yields superior sound attenuation or deadening in service with internal combustion engines as Well as with noise-containing gas streams from other sources. Moreover, my invention provides, as another object thereof, a relatively inexpensive and unique, all-ceramic noise suppressor device capable of providing superior lifetime with excellent sound attenuation or deadening performance.
The all-ceramic noise suppressor device of this invention basically comprises a plurality of gas ilow resistive elements arranged in a series dening an irregular gas flow path within a casing and rigidly positioned within the casing by means of a bond. The resistive elements, the casing and the bond are all made of sintered ceramic. Where the device is used with hot gas stream (eg. exhaust from internal combustion engine), all the sintered ceramic must have essentially similar coeilicients of thermal expansion lso as to avoid physical destruction in service.
As used in this application, an irregular gas flow path is delined as a path configuration other than that of a straight or smooth line conguration parallel to the axis of the series of elements. The axis of the series of elements within the casing can be, but is not necessarily limited to, a straight line configuration. Such axis of the series can also be made in other congurations if desired, o g. sinusoidal or even S-shaped.
The casing includes opposite inlet and outlet end walls. These walls are provided with inlet and outlet ports, respectively.
Basically, each resistive element comprises two different portions. @ne portion (or portions) comprises an open passage, thin walled, sintered ceramic honeycomb having features, e.g. inlet and outlet surfaces with unobstructed gas passages extending therebetween, maximum thickness of thin walls defining the passages, maximum crosssectional areas of the gas passages, and minimum aggregate open space or cross sectional area measured in a plane perpendicular to the axes of the gas passages, all as specified above. The total open area of each of these open passage portions must be not less than, and desirably greater than, the area of the inlet port in order to obtain the excellent low back pressure as the gas stream flows through them. Preferably, each open passage portion has a total open area of about two to three times the area of the inlet port. Also, the outlet port should have an area at least equal to the inlet port area for the same reason.
The arrangement of the series of elements is such that the inlet surface of the open passage portion of each succeeding element along the gas flow path is spaced from the outlet surface of the open passage portion of the preceeding element. These spaced surfaces are so constructed and arranged to provide the definition of the irregular gas flow path.
The other portion (or portions) of the resistive elements comprises an imperforate barrier to gas flow. For effective muflling, particularly a high intensity of the lower frequency sounds (e.g. G-315 c.p.s.), of the exhaust from the larger engines (ie. 200 or more cubic inches displacement with six or more cylinders) to, and even lower than, the low level of present day commercial mulilers, the imperforate barrier portions each should comprise a close passage, thin walled, sintered ceramic honeycomb having the same restrictive physical features as those specified above for the open passage honeycomb portions, but additionally having a sintered ceramic closure sealing off each gas passage at a point spaced from the inlet surface of the close passage honeycomb toward the outlet surface thereof. The closure provides the imperforate barrier structure while at the same time forming with the honeycomb structure a plurality of dead-end passages or cul de sacs opening on the inlet surface of the close passage honeycomb. An additional or alternative plurality of such cul de sacs or dead-end passages opening on the outlet surface of the close passage portion can be provided, if desired in certain cases, to further assist in absorbing sound. The sound waves in the gas stream passing through the noise suppressor device of this invention containing the cul de sacs, upon reaching the inlet surface of the close passage honeycomb portions, propagate into the dead-end gas passages. Sound energy is then dissipated by cancellation due to the reflectance of the Wave from the closed end surface or closure of the gas passage. Of course, it is expected that some sound energy is absorbed by the porous walls.
In some applications where low frequency sounds are not exceedingly troublesome, the imperforate barrier portion can be made of a plain solid ceramic wall or the like without the cul de sacs.
For a better understanding of the invention, several preferred forms with illustrative specific embodiments thereof will now be described in conjunction with the attached drawings wherein:
FIGURE l is a longitudinal view in cross section of one specific embodiment of the present invention,
FIGURE 2 is a sectional view taken along line II--II in FIGURE 1,
FIGURE 3 is a sectional View taken along line III-III in FIGURE l,
FIGURE 4 is a transverse cross sectional view of another speciiic embodiment of the present invention, v
FIGURE 5 is a longitudinal view in cross section of a further composite embodiment of the present invention illustrating several additional variations,
FIGURE 6 is a longitudinal view in cross section of a still further specific embodiment of the present invention,
FIGURE 7 is a sectional View taken along line VII- VII in FIGURE 6, and
FIGURE 8 is a sectional view taken along line VIII- VIII in FIGURE 6.
Referring now to FIGURES l-3, the all-ceramic mufiler or noise suppression device includes a compatible sintered ceramic shell or casing lil and compatible sintered ceramic honeycomb resistive elements lli-I7 rigidly bonded to the casing l@ by means of a compatible sintered ceramic cement 20.
By the term compatible, I mean that the sintered ceramics used have essentially similar coefficients of thermal expansion so as to avoid fractures and physical destruction of the device upon being subjected to repeated and substantial changes in temperature. Preferably, the sintered ceramics also should have low thermal expansion coecients (ie. -lO to {l0 l07/ C. over extended temperature range) to minimize the thermal stresses in the device. Of course, when the device is used in gas streams not involving elevated temperatures, the described compatibility of thermal expansion coeiicients is not essential.
Casing lil includes an inlet end wall 1S and an outlet end Wall I9. The inlet end wall 1S has an inlet port 21 and outlet end wall I9 has an outlet port- 22. Both ports have diameters D1. Preferably, the casing lil is made in two sections as shown and provided with a ships lap 23 to render the two sections separable. Alternatively, casing lil can be made one unitary piece as desired, e.g. by forming a bond of sintered ceramic cement at ships lap 23.
In the embodiment shown in FIGURES 1-3, the resistive elements are of two types, each alternating with the other along the series defining the irregular gas ilow path. Each type of element comprises a central portion bounded by an outer portion with each of these portions being substantially symmetrical about the axis of the series. The outer perimeter of these central and outer portions can be of various configurations as desired, e.g. circular, oval, square, rectangular, triangular, polygonal, etc.
The central portions having outside diameters D2, D4, D6 of the first type elements l2, 14, 16 and the outer annular portions having inside diameters D3, D5, D7 0f the second type elements I3, 15, I7 comprise the open passage, thin walled honeycombs described above.
The outer annular portions having inside diameters D2, D4, De of the rst type elements l2, lll, ll6 and the central portions having outside diameters D3, D5, D7 of the second type elements 13, l5, I7 comprise the imperforate barriers with cul de sacs described above. In this embodiment, the total area of the central portion of the second type element should be at least about equal to the total area of the central portion of adjacent first type elements. Thus, the open cells or open gas passages of one type element are axially opposite the barrier portion of the other type element along the axis of the series. This causes the gas stream to travel a sinuate path as it progresses through the noise suppressor device and results in substantially reducing the outlet sound level below that obtained in a similar device with the open cells all opposite each other in straight-through alignment (ie. regular gas iiow path of straight line configuration).
he cul de sacs of elements itil-17 are formed by providing sintered ceramic coatings 32;-37 on the outlet faces or surfacesU of the elements. These coatings 32-37 seal or close off the cells or gas passages terminating at the outlet surface areas covered by the coatings. Coatings 32, 34, 36 form the outer annular barrier zones or portions of elements 12, 1d, 16 that surround the central portions of open passage cells. In an opposite manner, coatings 33, 35, 37 form the central circular barrier zones or portions of elements 13, 1S, 17 that are surrounded by the outer annular portions of open passage cells.
The number and spacing of the two-portion elements can be varied depending upon the particular type of application. A series of at least four of the elements are necessary for satisfactory muffling the exhaust from the large internal combustion engines whereas only two or three elements can be satisfactorily used for mufrling the exhaust from smaller engines, such as those commonly found on agricultural tractors and the like. For the latter type of application, the ceramic honeycomb elements can be advantageously made of a ceramic material having a fairly high specific heat (eg. about 0.2 or more calories per gram at 25 C.) so as to additionally act as a flame arrestor in the hot exhaust stream.
1n situations where the muffler is commonly situated along an exhaust pipe, the superior performance (i.e. sound attenuation, low back pressure, etc.) for large engines is obtained by spacing the elements a distance substantially equal to the sum of the average cell or gas passage length of the two elements forming the spacing and with an average gas passage length for each element Within the range of about 1/2 to 21/2 inches. Particularly effective results have been obtained when the spacing has been kept Within i25% of the aforesaid sum of average gas passage lengths.
Where the mufling device (see FIGURE i) is located in or near the exhaust manifold, the spacing may be advantageously less than as described above relative to the sum of the average gas passage lengths for suitable results (possibly because of the lower viscosity of the ex- A muffier unit made according to the structure shown in FlGURES 1-3 was tested in the exhaust line of a 401 cubic inch, eight cylinder engine and found to give superior performance as compared with the commercial muffler customarily supplied with the engine and with a comparable back pressure of 18" of Hg. The ceramic casing was made of a sintered slip cast mixture of 72% by weight petalite and 28% by weight beta spodumene in accordance with the teachings of U.S. Patent r5,096,159 to H. C. Van Cott. This sintered ceramic exhibits a very low coefficient of thermal expansion of about up to 900 C. The casing was made with a wall thickness of about 1A", an inside diameter of about 6, a total length of about 251/2" and port diameters D1 of 2".
The honeycomb elements were made in accordance with the teachings of U.S. Patent 3,112,184 to R. Z. Hollenbach. The ceramic material used consisted of 75% by weight of petalite and 25% by weight of a glass-ceramic having the following approximate composition, by oxide analysis, in weight percent: 70% Si02, 18% AlzOs, 5% TiOg, 3% MgO, 3% Lig@ and 1% ZnO. A slurry was formed of this comminuted ceramic material by ball milling it with equal parts of a solution having the following approximate composition, in volume percent:
29.6% isopropanol, 39.8% ethyl acetate, 8.4% Versamid 115 and 22.2% vHysol 6111. Versarnid 115 is the trade name of a thermoplastic polymer supplie-d by General Mills, inc., and it is prepared by condensation of polymerized unsaturated fatty acids, such as dilinoleic acid, with aliphatic amines such as ethylene diamine. Hysol 6111 is the trade name of an epoxy resin solution, supplied by Houghton Laboratories, Inc., containing 57% by weight of epoxy resin having a viscosity of about 2.5-4.0 poise at C., an epoxide equivalent (grams of resin containing l gram chemical equivalent of epoxy) of 595i50, and a melting range of 73-85 C. The slurry was coated onto common 31/2 pound tea bag paper and formed into sintered ceramic honeycomb structures in the manner described in the aforementioned U.S. Patent 3,112,184. The firing schedule was as follows:
Temperature range: Firing rate Room temp. to 700 C 350 C./hr. Hold at 700 C. 1 hour. 700 C. to l220 C 30 minutes. Cool to room temp. Furnace rate. Rere to 1240o C. 300 C./hr. Hold at 1240 C 7 hours.
Thereafter the honeycornbs were furnace cooled to handling temperature. These honeycornbs were produced with gas passages, taken in cross-section, in the shape of isosceles triangles having a height of about 0.04 inch and a base of about 0.075 inch and with an aggregate open area of about 70% of the total cross-sectional area of the honeycombs in a plane perpendicular to the axes of the gas pasasges. The average cell wall thickness was about 0.006 inch and the wall porosity was about The sintered ceramic honeycombs exhibited coefficients of thermal expansion of about 0i2 107/ C. up to 300 C. or higher.
The honeycomb elements were cut to slightly less than 6 inches in diameter. Elements 12, 13, 16 and 17 were Imade l inch thick (direction parallel to gas passage axes) and elements 1d and 15 were made 13/4 inches thick. The latter two elements were spaced apart 4% inches, each equidistant from the mid-point of the casing. The spacing between elements 13 and 14,1andbetween elements 15 and 16 was 21/2 inches. The spacing between elements 12 and 13, and between elements i6 and 17 was 2 inches.
The ceramic cement for rigidly bonding the elements 12.,17 to the casing 10 had the following batch composition analytically by weight: 8.72% ZnO, 1.3% CaF2, 3.46% SiC, 1.93% S03 (from fuirned white lead), 6.81% Pb() and the remainder glass petalite. A batch of this cement composition was dispersed in a solution of 75 by Weight butyl alcohol and 25% by weight toluene and the resulting dispersion coated on the peripheral surface of the honeycomb elements. The same cement dispersion was used to form coatings 32-37 on the outlet surface of the elements. After placing the elements in the abovedescribed positions, the resulting assembly was heated to ll C. at about 5 C./minute and held at 1150 C. for about l hour to permit the cement to completely foam, sinter and form strong chemical bonds with the honeycombs and the casing. Thereafter, the assembly was furnace cooled to handling temperatures at a rate of about 5 C./minute. The resulting sintered ceramic cement exhibited coefficients of thermal expansion of about 0-4 l0-7/ C. up to 300 C. or higher.
The coatings 32-37 were formed so as to provide the following diameters: D2 being 31/2 inches; D3, D5 and D7 being 41A inches; D., and D5 being 4 inches.
Example 2 Another unit made similiar to the structure shown in FIGURES 1-3 was tested in the exhaust line of ya 225 cubic inch, six cylinder engine and found to give satisfactory results. The construction of this unit was the same as in Example 1 except for the following specific features. The total casing length was about 17 inches. The elements lf2-i7 were each l inch thick `and spaced apart about 11/2 inches. Elements 13, l5 and f7 were made with gas passages, taken in cross-section, in the shape of isosceles triangles having a height of about 0.02 inch and a base of about 0.038 inch and with an aggregate open area of about 60%.
FGURE 4 shows another form of the noise suppressor device of the invention that can be made in smaller compact shapes for location in the exhaust manifold or closely to it. This form of device comprises, similarly to the ones already desc-ribed, a sintered ceramic casing stl of rectangular cross-section. Sintered ceramic cement 4l rigidly holds the resistive elements in place within the casing dil. The solen sintered ceramic element 42 (analogous to element l?. in FIGURE l) shown comprises a central portion 44 of open cells or gas passages outer portions 46 of dead-end gas passages or cul de sacs formed by a sintered ceramic coating on the outlet face of the element. The second type element in this unit would have the open cells in similar outer portions and the cul de sacs in a similar central portion. Of course, this unit would be made to conform to the other necessary physical restrictive features described above.
FIGURE 5 illustrates several other modifications that can be made within the present invention. First, the casing can be made in several separable segments 4S, Il@ and 5b. rlhus, suitable muilling units can be readily provided for a variety of engines merely by assembling segments 43 and Sil with or without one or more segments 49. ln order to conserve space, inlet end wall 52 and outlet end wall 53 can be provided with a stubby inlet port Se and a stubby outlet port 55, respectively.
As a means for better distribution of the gaseous sound stream across the inlet face of a resistive element, the element can be provided with a forwardly extending central portion 56 having its inlet surface angularly converging at a central furtherrnost forward point.
In some applications, the sound attenuating or deadening effectiveness of the cul de sac feature can be strengthened or increased by cutting cavities or indentations 58 into the inlet surface portions of the elements opposite the outlet surface portions having the sintered ceramic coatings et) and 6l sealing shut the gas passages extending between those surfaces. As shown in FIGURE 5, the cavities 5S are circular resonating chambers, but they can be made in other geometric forms as desired. Also, all the elements 62-67 can be provided with cavities Sil or only selected elements can be so provided, as desired for each particular application.
Example 3 FEGURES 6-8 show a still further specific embodiment of my invention tested in the exhaust line of a 3G() cubic inch, eight cylinder engine with excellent results. The two part casing '70 was made like the casing in Example l, except that the total length was only about 2l". Elements 1 77 were made of the sintered ceramic honeycomb structures used in Example 2. The round elements 7l, 73, 75, 77 were slightly less than 5 inches in diameter and one inch thick. Elements 72, 7d, '76 were made rectangular (see FIGURE 8) with dimensions 6 x 4% x l and assembled with the other elements as shown in FIG- URE 6. Elements 7l, 73, 75, "i7 were then rigidly bonded to casing '76 by cement 78 in the same manner as in Example l.
Prior to assembly, one half of the outlet surfaces of elements 7i, '73, 75, 77 were provided with coatings 2li, 83, S5, 87 (also in the same manner as Example l) thereby forming barriers with cul de sacs opening on the inlet surfaces in an alternating pattern through the mufller unit. The other halves of these elements were the open passage portions.
Also prior to assembly, coatings S2, Sd, 86 were provided on elements 72, '74, 76 forming Outer close passage portions and defining the central open passage portions. Each of the latter can be divided in two by a central close passage portion if desired in certain cases. While coatings 84 are formed on the outlet surface of element .74 to provide cul de sacs opening on the inlet surface, coatings 32 and 86 are formed on the inlet surfaces of elements 72 and 75 to provide cul de sacs opening on the outlet surfaces thereof. This design allows the muflier unit to be positioned so that no cul de sacs open upwardly in a manner that would permit solid particles carried in the gas stream to lill up these cul de sacs and reduce their ability to absorb sound energy.
Although the present invention has been described with respect to specific details of certain embodiments thereof, it is not intended that such details be limitations upon the scope of the invention except insofar as set forth in the claims. Accordingly, it will be appreciated that a variety of ceramic materials and methods of constructing the ceramic structures can be utilized without departing from the invention. For example, the structures can be made from appropriate glass or glass-ceramic materials by known hot glass processes and, as used in this specification, including the claims, the term ceramic is used in its most generic sense as encompassthose ceramic materials that are amorphous, crystalline or mixtures of these two physical states.
l claim:
l.. An all-ceramic noise suppressor device comprising (A) a ceramic casing including opposite inlet and outlet end walls having inlet and outlet ports, respectively,
(B) a plurality of ceramic gas flow resistive elements arranged in a series defining an irregular gas flow path within said casing intermediate said inlet and outlet end walls, each of said elements comprising two different portions,
(l) first portions comprising imperforate barriers to gas ow,
(2) second portions comprising open passage,
thin walled honeycombs, each honeycomb having: (a) an inlet surface and an opposed outlet surface, (b) a plurality of unobstructed gas passages extending between said inlet and outlet surfaces, the gas passages being dened by thin walls up to about 0.015 inch thick, the crosssectional area of each gas passage not exceeding about 0.01() square inch and the aggregate open cross-sectional area of said honeycomb measured in a plane perpendicular to the axes of the gas passages being at least 50 percent of the total cross sectional area of said honeycomb, the inlet surface of said second portions of each succeeding element along the gas flow path being spaced from the outlet surface of said second portions of the preceding element, said spaced surfaces so constructed and arranged together with said first portions to provide the definition of the irregular gas flow path, said aggregate open area of each element being not less than the area of said inlet port, and
(C) a ceramic bond rigidly positioning said elements in said casing.
2. The device of claim It wherein the ceramic of said casing, of said elements and of said bond have essentially similar coefficients of thermal expansion.
3. The device of claim l in which the aggregate open area of each element is about two to three times greater than the area of said inlet port, and in which the area of the outlet port is at least equal to the area of said inlet port.
The device of claim l in which the thin walls of said honeycomb are porous.
5. The device of claim l in which said imperforate barriers comprise close passage, thin walled honeycombs having the same restrictive physical features as those specified for said open passage honeycombs, but additionally having ceramic closures so constructed and arranged to seal off each gas passage and to form a plurality of cul de sacs opening on at least one of said inlet and outlet surfaces of the close passage honeycombs.
6. The device of claim wherein the ceramic of said casing, of said elements and of said bond have essentially low and similar coefficients of thermal expansion.
7. The device of claim 5 in which the thin walls of said honeycombs are porous.
8. The device of claim 7 wherein the porosity of said thin walls is 25 to 45 percent.
9. An al1-ceramic noise suppressor device comprising (A) a ceramic casing including opposite inlet and out let end walls having inlet and outlet ports, respectively,
(B) a plurality of spaced ceramic gas flow resistive elements arranged in a series defining an irregular gas flow path Within said casing intermediate said inlet and outlet end Walls, said elements being of a first and a second type, each type alternating with the other type along said gas fiow path and comprising a central portion bounded by an outer portion, each of said portions being substantially symmetrical about the axis of said series,
( 1) the outer portion of said first type element and the central portion of said second type element comprising imperforate barriers to gas flow,
(2) the central portion of said first type element and the outer portion of said second type element comprising open passage, thin walled honeycombs, each honeycomb having; (a) an inlet surface and an opposed outlet surface, (b)
a plurality of unobstructed gas passages extending between said inlet and outlet surfaces, the gas passages being defined by thin walls up to about 0.015 inch thick, the cross-sectional area of each gas passage not exceeding about 0.010 square inch and the aggregate open cross-sectional area of said honeycomb measured in a plane perpendicular to the axes of the gas passages being at least 50 percent of the total crosssectional area of said honeycomb, the area of the central portion of said second type element being at least about equal to the area of the central portion of adjacent first type elements, the area of the central portion of said first type element and the outer portion of said second type element being greater than the area of said inlet port, and
(C) a ceramic bond rigidly positioning said elements in said casing.
10. The device of claim 9 including at least four of said elements.
11. The device of claim 10 wherein the element ade jacent the inlet end wall is of the first type.
12. The device of claim 9 in which each of said imperforate barriers comprise close passage, thin walled honeycombs having the same restrictive physical features as those specified for said open passage honeycombs, but additionally having ceramic closures sealing off each gas passage and spaced from the inlet surface of said close passage honeycomb toward the outlet surface thereof thereby forming a plurality of cul de sacs opening on said inlet surface.
13. The device of claim 12 in which the aggregate open area of the central portion of said first type element and `of the outer portion of said second type element is about two to three times greater than the area of said inlet port, and in which the area of the outlet port is at least equal to the area of said inlet port.
1d. The device of claim 12 including at least four of said elements.
15. The device of claim 14 wherein the element adjacent the inlet end wall is of the first type.
16. The device of claim 12 wherein adjacent resistive elements are spaced a distance substantially equal to the sum of the average gas passage lengths of the two adjacent elements forming the spacing.
17. The device of claim 16 wherein the average gas passage length of each element is Within the range of about 1/2 to 21/2 inches.
18. The device of claim 12 wherein the inlet Surface of the outer portion of said first type element and the inlet surface of the central portion of said second type element include cavity forming surf-aces.
19. An all-ceramic noise suppressor device comprising (A) a ceramic casing including opposite inlet and outlet end walls having inlet and outlet ports, respectively.
(B) a plurality of ceramic gas fiow resistive elements arraned in a series within said casing intermediate said inlet and outlet end walls, first type elements comprising the element nearest the inlet end wall and every second element thereafter positioned with their largest faces substantially perpendicular to the axis of the series, a second type element positioned between every two successive first type elements with a plane within said second type element parallel to the largest faces thereof intersecting the axis of said series and said second type element abutting said two successive first type elements along substantially diametral lines of the latter elements, each of said first and second type elements comprising two different portions,
(1) substantially one half of each first type element, but on opposite sides of the diametral abutments with said second type element for each successive first type element, and the portions of said second type elements adjacent said diametral abutments constituting first portions comprising imperforate barriers to gas flow,
(2) substantially the other half of each first type element and central portion of said second type element constituting second portions comprising open passage, thin walled honeycombs, each honeycomb having: (a) an inlet surface and an opposed outlet surface, (b) a plurality of unobstructed gas passages extending between said inlet and outlet surfaces, the gas passages being defined by thin Walls up to about 0.015 inch thick, the cross-sectional area of each gas passage not exceeding about 0.010 square inch and the aggregate open cross-sectional area of said honeycomb measured in a plane perpendicular to the axes of the gas passages being at least 50 per cent of the total cross-sectional area of said honeycomb, said aggregate open area of each element being greater than the area of said inlet port, and
(C) a ceramic bond rigidly positioning said elements in said casing.
20. The device of claim 19 including at least four of said first type elements and at least three of said second type elements.
21. The device of claim 19 in which said imperforate barriers comprise close passage, thin walled honeycombs having the same restrictive physical features as those specified for said open passage honeycombs, but additionally having ceramic closures so constructed and arranged to seal off each -gas passage and to form a plurality of cul de sacs opening on at least one of said inlet and outlet surfaces of the close passage honeycombs.
22. The device of claim 21 including at least four of said first type elements and at least three of said second type elements, said ceramic closures of all said first type elements except the one nearest the outlet end wall and said ceramic closures of every other second type element as determined from said inlet end Wall being located at the outlet surface of said close passage honeycombs thereby forming a plurality of cul de sacs opening on the inlet surface thereof, and said ceramic closures of the first type element nearest the outlet end Wall `and of the other second type elements being located at the inlet surface of said close passage honeycombs thereby forming a plurality of cul de sacs opening on the outlet surface thereof.
References Cited by the Examiner UN ETED STATES PATENTS Buttler 181-62 X Gary. Johnson et al 2,2-2
Marcellus 181-56 Lanning 181-56 Slayter et al, 60-29 Johnson 60-30 X FOREIGN PATENTS France. Great Britain. Great Britain.
LEO SMILOW, Primary Examiner.

Claims (1)

1. AN ALL-CERAMIC NOISE SUPPRESSOR DEVICE COMPRISING (A) A CERAMIC CASING INCLUDING OPPOSITE INLET AND OUTLET END WALLS HAVING INLET AND OUTLET PORTS, RESPECTIVELY, (B) A PLURALITY OF CERAMIC GAS FLOW RESISTIVE ELEMENTS ARRANGED IN A SERIES DEFINING AN IRREGULAR GAS FLOW PATH WITHIN SAID CASING INTERMEDIATE SAID INLET AND OUTLET END WALLS, EACH OF SAID ELEMENTS COMPRISING TWO DIFFERENT PORTIONS, (1) FIRST PORTIONS COMPRISING IMPERFORATE BARRIERS TO GAS FLOW, (2) SECOND PORTIONS COMPRISING OPEN PASSAGE, THIN WALLED HONEYCOMBS, EACH HONEYCOMB HAVING: (A) AN INLET SURFACE AND AN OPPOSED OUTLET SURFACE, (B) A PLURALITY OF UNOBSTRUCTED GAS PASSAGES EXTENDING BETWEEN SAID INLET AND OUTLET SURFACES, THE GAS PASSAGES BEING DEFINED BY THIN WALLS UP TO ABOUT 0.015 INCH THICK, THE CROSSSECTIONAL AREA OF EACH GAS PASSAGE NOT EXCEEDING ABOUT 0.010 SQUARE INCH AND THE AGGREGATE OPEN CROSS-SECTIONAL AREA OF SAID HONEYCOMB MEASURED IN A PLANE PERPENDICULAR TO THE AXES OF THE GAS PASSAGES BEING AT LEAST 50 PERCENT OF THE TOTAL CROSS SECTIONAL AREA OF SAID HONEYCOMB, THE INLET SURFACE OF SAID SECOND PORTIONS OF EACH SUCCEEDING ELEMENT ALONG THE GAS FLOW PATH BEING SPACED FROM THE OUTLET SURFACE OF SAID SECOND PORTIONS OF THE PRECEDING ELEMENT, SAID SPACED SURFACES SO CONSTRUCTED AND ARRANGED TOGETHER WITH SAID FIST PORTIONS TO PROVIDE THE DEFINITION OF THE IRREGULAR GAS FLOW PATH, SAID AGGREGATE OPEN AREA OF EACH ELEMENT BEING NOT LESS THAN THE AREA OF SAID INLET PORT, AND (C) A CERAMIC BOND RIGIDLY POSITIONING SAID ELEMENTS IN SAID CASING.
US351949A 1964-03-16 1964-03-16 Ceramic mufflers Expired - Lifetime US3227241A (en)

Priority Applications (8)

Application Number Priority Date Filing Date Title
US351949A US3227241A (en) 1964-03-16 1964-03-16 Ceramic mufflers
FR8260A FR1429588A (en) 1964-03-16 1965-03-08 Sound damping device
FR8261A FR1425993A (en) 1964-03-16 1965-03-08 Engine muffler
DE1965C0035282 DE1476493A1 (en) 1964-03-16 1965-03-11 Acoustic device
GB10391/65A GB1093179A (en) 1964-03-16 1965-03-11 A noise suppressor device for i.c. engine exhausts or other noisecontaining gas streams
GB1064465A GB1093180A (en) 1964-03-16 1965-03-12 Acoustical device for suppressing noise in a gas stream
NL6503259A NL6503259A (en) 1964-03-16 1965-03-15
SE333065A SE304640B (en) 1964-03-16 1965-03-15

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DE (1) DE1476493A1 (en)
FR (1) FR1429588A (en)
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US3593499A (en) * 1969-04-11 1971-07-20 Richard D Myerly Exhaust muffler and purifier
US3620329A (en) * 1969-12-31 1971-11-16 Glasrock Products Jet engine noise suppressor
JPS4867136U (en) * 1971-12-06 1973-08-25
US3799196A (en) * 1971-12-03 1974-03-26 Arvin Ind Inc Exhaust gas manifold
US3891009A (en) * 1973-02-24 1975-06-24 Toyota Motor Co Ltd High-temperature heat-insulating structure
US3958582A (en) * 1973-02-26 1976-05-25 Toyota Jidosha Kogyo Kabushiki Kaisha High-temperature heat-insulating structure
US3969083A (en) * 1973-11-26 1976-07-13 Maremont Corporation Catalytic converter for purifying gases
US4125380A (en) * 1977-03-02 1978-11-14 Carmine Negola Pollution control device
EP0022063A1 (en) * 1979-06-06 1981-01-07 Schweizerische Aluminium AG Exhaust gas outlet device for internal combustion engines and method for its manufacture
US4322388A (en) * 1979-11-26 1982-03-30 Arvin Industries, Inc. Catalytic converter assembly
US4458779A (en) * 1981-07-02 1984-07-10 Antiphon Ab Silencer
EP0164155A1 (en) * 1984-05-07 1985-12-11 Pedersen, Johannes A silencer and a method of manufacturing the silencer
US4863700A (en) * 1985-04-16 1989-09-05 Stemcor Monolithic catalytic converter mounting arrangement
US4969264A (en) * 1986-06-12 1990-11-13 Tennessee Gas Pipeline Company Catalytic converter and substrate support
US4999168A (en) * 1989-05-01 1991-03-12 The Carborundum Company Crack resistant intumescent sheet material
US5032441A (en) * 1989-05-01 1991-07-16 The Carborundum Company Intumescent conforming mounting pad
US5118476A (en) * 1986-06-12 1992-06-02 Tennessee Gas Pipeline Company Catalytic converter and substrate support
US5331810A (en) * 1992-05-21 1994-07-26 Arvin Industries, Inc. Low thermal capacitance exhaust system for an internal combustion engine
US20040134172A1 (en) * 2002-09-30 2004-07-15 Unifrax Corporation Exhaust gas treatment device and method for making the same
DE10326150A1 (en) * 2003-06-06 2005-02-17 Leinemann Gmbh & Co. Durable fire barrier
US20060008395A1 (en) * 2004-06-29 2006-01-12 Unifrax Corporation Exhaust gas treatment device and method for making the same
WO2012138672A1 (en) * 2011-04-05 2012-10-11 The Regents Of The University Of California Quiet bleed valve for gas turbine engine
US8404187B1 (en) 1998-03-11 2013-03-26 Unifrax I Llc Support element for fragile structures such as catalytic converters
US20160053390A1 (en) * 2013-05-02 2016-02-25 Robert Bosch Gmbh Fluid distributor, fuel cell, or electrolyzer, and method for the function of a fluid distributor

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DE3837173B4 (en) * 1987-11-14 2005-08-25 Volkswagen Ag exhaust silencer
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Cited By (34)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3593499A (en) * 1969-04-11 1971-07-20 Richard D Myerly Exhaust muffler and purifier
US3620329A (en) * 1969-12-31 1971-11-16 Glasrock Products Jet engine noise suppressor
US3799196A (en) * 1971-12-03 1974-03-26 Arvin Ind Inc Exhaust gas manifold
JPS4867136U (en) * 1971-12-06 1973-08-25
US3891009A (en) * 1973-02-24 1975-06-24 Toyota Motor Co Ltd High-temperature heat-insulating structure
US3958582A (en) * 1973-02-26 1976-05-25 Toyota Jidosha Kogyo Kabushiki Kaisha High-temperature heat-insulating structure
US3969083A (en) * 1973-11-26 1976-07-13 Maremont Corporation Catalytic converter for purifying gases
US4125380A (en) * 1977-03-02 1978-11-14 Carmine Negola Pollution control device
EP0022063A1 (en) * 1979-06-06 1981-01-07 Schweizerische Aluminium AG Exhaust gas outlet device for internal combustion engines and method for its manufacture
US4322388A (en) * 1979-11-26 1982-03-30 Arvin Industries, Inc. Catalytic converter assembly
US4458779A (en) * 1981-07-02 1984-07-10 Antiphon Ab Silencer
EP0164155A1 (en) * 1984-05-07 1985-12-11 Pedersen, Johannes A silencer and a method of manufacturing the silencer
AU585222B2 (en) * 1984-05-07 1989-06-15 Pedersen, Johannes A silencer and a method of manufacturing the silencer
US4863700A (en) * 1985-04-16 1989-09-05 Stemcor Monolithic catalytic converter mounting arrangement
US4969264A (en) * 1986-06-12 1990-11-13 Tennessee Gas Pipeline Company Catalytic converter and substrate support
US5118476A (en) * 1986-06-12 1992-06-02 Tennessee Gas Pipeline Company Catalytic converter and substrate support
US5032441A (en) * 1989-05-01 1991-07-16 The Carborundum Company Intumescent conforming mounting pad
US4999168A (en) * 1989-05-01 1991-03-12 The Carborundum Company Crack resistant intumescent sheet material
US5331810A (en) * 1992-05-21 1994-07-26 Arvin Industries, Inc. Low thermal capacitance exhaust system for an internal combustion engine
US8404187B1 (en) 1998-03-11 2013-03-26 Unifrax I Llc Support element for fragile structures such as catalytic converters
US7033412B2 (en) 2002-09-30 2006-04-25 Unifrax Corporation Exhaust gas treatment device and method for making the same
US20040134172A1 (en) * 2002-09-30 2004-07-15 Unifrax Corporation Exhaust gas treatment device and method for making the same
US7918664B2 (en) 2003-06-06 2011-04-05 Leinemann Gmbh & Co. Kg Permanently fireproof flame guard
US20060144599A1 (en) * 2003-06-06 2006-07-06 Christoph Leinemann Permanently fireproof flame guard
DE10326150B4 (en) * 2003-06-06 2005-12-15 Leinemann Gmbh & Co. Kg Durable fire barrier
DE10326150A1 (en) * 2003-06-06 2005-02-17 Leinemann Gmbh & Co. Durable fire barrier
US20060008395A1 (en) * 2004-06-29 2006-01-12 Unifrax Corporation Exhaust gas treatment device and method for making the same
US20110123417A1 (en) * 2004-06-29 2011-05-26 Ten Eyck John D Exhaust gas treatment device
US7971357B2 (en) 2004-06-29 2011-07-05 Unifrax I Llc Exhaust gas treatment device and method for making the same
US7998422B2 (en) 2004-06-29 2011-08-16 Unifrax I Llc Exhaust gas treatment device
US8182752B2 (en) 2004-06-29 2012-05-22 Unifrax I Llc Exhaust gas treatment device
WO2012138672A1 (en) * 2011-04-05 2012-10-11 The Regents Of The University Of California Quiet bleed valve for gas turbine engine
US9175577B2 (en) 2011-04-05 2015-11-03 The Regents Of The University Of California Quiet bleed valve for gas turbine engine
US20160053390A1 (en) * 2013-05-02 2016-02-25 Robert Bosch Gmbh Fluid distributor, fuel cell, or electrolyzer, and method for the function of a fluid distributor

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NL6503259A (en) 1965-09-17
GB1093179A (en) 1967-11-29
FR1429588A (en) 1966-02-25
DE1476493A1 (en) 1969-05-29

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