US3158532A - Tapered pore filter elements - Google Patents
Tapered pore filter elements Download PDFInfo
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- US3158532A US3158532A US74130A US7413060A US3158532A US 3158532 A US3158532 A US 3158532A US 74130 A US74130 A US 74130A US 7413060 A US7413060 A US 7413060A US 3158532 A US3158532 A US 3158532A
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
- B01D39/14—Other self-supporting filtering material ; Other filtering material
- B01D39/20—Other self-supporting filtering material ; Other filtering material of inorganic material, e.g. asbestos paper, metallic filtering material of non-woven wires
- B01D39/2003—Glass or glassy material
- B01D39/2006—Glass or glassy material the material being particulate
- B01D39/2013—Glass or glassy material the material being particulate otherwise bonded, e.g. by resins
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
- B01D39/14—Other self-supporting filtering material ; Other filtering material
- B01D39/20—Other self-supporting filtering material ; Other filtering material of inorganic material, e.g. asbestos paper, metallic filtering material of non-woven wires
- B01D39/2003—Glass or glassy material
- B01D39/2017—Glass or glassy material the material being filamentary or fibrous
- B01D39/2024—Glass or glassy material the material being filamentary or fibrous otherwise bonded, e.g. by resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
- B01D39/14—Other self-supporting filtering material ; Other filtering material
- B01D39/20—Other self-supporting filtering material ; Other filtering material of inorganic material, e.g. asbestos paper, metallic filtering material of non-woven wires
- B01D39/2068—Other inorganic materials, e.g. ceramics
- B01D39/2072—Other inorganic materials, e.g. ceramics the material being particulate or granular
- B01D39/2079—Other inorganic materials, e.g. ceramics the material being particulate or granular otherwise bonded, e.g. by resins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D39/00—Filtering material for liquid or gaseous fluids
- B01D39/14—Other self-supporting filtering material ; Other filtering material
- B01D39/20—Other self-supporting filtering material ; Other filtering material of inorganic material, e.g. asbestos paper, metallic filtering material of non-woven wires
- B01D39/2068—Other inorganic materials, e.g. ceramics
- B01D39/2082—Other inorganic materials, e.g. ceramics the material being filamentary or fibrous
- B01D39/2089—Other inorganic materials, e.g. ceramics the material being filamentary or fibrous otherwise bonded, e.g. by resins
Definitions
- This invention relates to porous materials, and particularly nonwoven fibrous materials, especially adapted for use as filter media, and to a process for preparing such materials.
- the materials comprise mixed particles of different sizes, and are characterized by tapered pores defined by varying the proportion of particles of different sizes from surface to surface of the material.
- Filter media can generally be classified as being of one of two typesdepth filters and surface filters.
- a surface filter removes suspended material from the fluid passed through the filter by collecting such material on its surface, and the material thus removed forms a filter cake or bed upon the filter. This material naturally obstructs the openings in the surface of the filter, because the fluid must flow through this material, which thus effectively reduces the diameter of the filter openings to the size of the pores in the filter cake. This reduction in effective diameter of pore openings in the filter increases the pressure differential required to mmntain flow through the filter. As this process continues, the filter eventually becomes clogged, and must be cleaned or replaced. This is a necessary task which occurs with burdensome frequency when large amounts of suspended material must be removed.
- inert materials have been added to the fluid which serve to maintain a greater proportion of open area in the filter cake.
- Such materials are called filter aids, and diatomaceous earth is a typical example.
- Coarser filters capable of removing the coarsest of the suspended material have also been inserted earlier in the fluid line, to remove some of the suspended material before the'main fine pore filter is reached. Neither of these expedients is always practical, and consequently surface filters because of their low dirt capacity are not always practical to meet large scale commercial filtration needs.
- the filter element In depth filtration, the filter element is designed to remove contaminants not only on the surface of the element but also as the fluid passes through the element, which has a considerable thickness and which has a plurality of pores of distinct length. The length of the pores increases the dirt capacity, because there is more room for dirt along the pores.
- Most depth filters are made of masses of fibers or other particulate material, held together by mechanical means or by bonding. One or several layers of such materials can be employed, and these layers can vary in porosity, with the coarsest layer usually arranged to first contact the suspended material, thereby removing from the fluid medium first the coarser and then the finer material as it passes through the filter, thus obtaining some distribution of the contaminants through the filter, and obtaining an extended life as compared to a surface filter.
- porous materials in the form of bats or sheets of any desired thickness having pores which are tapered and capable of continuous variation in diameter and configuration from one surface of the medium to the other.
- the surface dirt retention eifect characteristic of surface filters and multi-layered depth filters is avoided in the porous materials of the invention, and the entire open volume of the porous material is available to its maximum extent, for a higher dirt capacity, before clogging.
- particulate material which can be in the form, for example, of fibers or granules of the material of which the porous material is to be composed, is suspended in a fluid and deposited therefrom in the form of a porous layer on and/ or into a base.
- Particulate material of at least two sizes, each size suspended in fluid systems, separately, are blended together in the desired proportions before laydown on the base, and the desired configmration in pore diameter from surface to surface of the material is obtained by varying the proportion of the multi-size materials in the layer during deposition.
- the different size particles can be deposited in any proportions and in any order at any point in the layer, so that a porous material can be obtained in which the pores are of any configuration and have a constantly varying diameter.
- the pore diameter at the surfaces can be large or small, and can increase or decrease in any portion or throughout, as desired.
- the configuration of the pores depends not only on the choice and concentration of the materials deposited but also on the base or substratum on which the particulate materials are deposited. In general, one or more of three types of bases will be used:
- a base which remains a part of the porous layer during its useful application and whose filtration characteristics are modified by the penetration and impregnation thereof by particulate material to form an impreg nated ultra-fine filter medium.
- Exemplary of such bases are a reinforcing screen or supplemental filter, say, of greater strength, or having a greater or lesser porosity, such as a filter paper or plastic membrane, the porous layer furnishing depth-type filtration in conjunction with said supplemental element.
- a reinforcing screen or supplemental filter say, of greater strength, or having a greater or lesser porosity, such as a filter paper or plastic membrane, the porous layer furnishing depth-type filtration in conjunction with said supplemental element.
- the process of the invention is applicable to particulate material or any type or size, the only requirement being that the material be capable of being suspended in a fluid, so that the fluid systems can be blended and the blend brought to the base upon which the particulate material is to be deposited.
- Fibrous material is particularly desirable, because of its versatility. A great variety of diameters of fibers are available, thus making it pos sible to achieve a very large assortment of mixtures of different diameter fibers for making fibrous material of any porosity, arid such fibers can be made of any length, so as to take advantage of the greater cohesiveness of a layer of long fibers, as compared to granular material layers.
- Typical fibrous materials include glass, asbestos, potassium titanate, aluminum silicate, mineral wool, regenerated cellulose, polyvinyl chloride, polyvinylidene chloride, polyacrylonitrile, polyethylene, polypropylene, rubber, polymers of *terephthalic acid and ethylene glycol, polyamides, casein fibers, zein fibers, cellulose acetate, viscose rayon, hemp, jute, linen, cot-ten, silk, wool, mohair, paper, and metallic fibers.
- Particulate materials such as diatomaceous earth, fullers earth, silicon, magnesia, silica, talc, silica gel, alumina, quartz, carbon, activated carbon, clays, synthetic resins and cellulose derivatives, such as polyethylene, polystyrene, olypropylene, urea-formaldehyde, phenol-formaldehyde, polytetra fiuorethylene, polytrifluorochloroethylene, polymers of terephthalic acid and ethylene glycol, polyacrylonitrile, ethyl cellulose, polyamides, and cellulose acetate-propionate, and metal particles such as aluminum, iron, copper, nickel, chromium, and titanium and metal alloys of all kinds, such as monel, brass, stainless steel, bronze, Inconel, cupronickel, Hastelloy, beryllium, and copper can also be employed. Combinations of fibers and particles are also useful, such as combinations of diatornaceous earth and glass fibers.
- the fluid medium used for the suspension is preferably inert to the particulate material. It should not dissolve a substantial amount thereof, although if the fluid is reused, the fact that some material is in solution is not a disadvantage, since a saturated solution is quickly formed ab initio.
- the fluid should be volatile at a reasonably elevated temperature below the melting point of the material to facilitate removal after the suspension is laid down. However, nonvolatile fluids may be desirable under certain conditions, and those can be removed, as is more fully described later, by washing out with a volatile solvent that is a solvent for the fluid but not for the particulate material.
- the fiuid can be the liquid to be filtered by the layer.
- Typical fluids are water, polyalkylene glycols, such as polyethylene glycols, poly 1,2-propylene glycols, and mono and di alkyl others thereof, such as the methyl,
- ethyl, butyl and propyl mono and di ethers ethyl, butyl and propyl mono and di ethers, mineral lubricating oils, vegetable oils, and organic solvents such as xylene and petroleum ethers. Since the layer is potentially useful to filter any liquid, depending upon the choice of particulate material, obviously a wide selection of fluids is available, and such would be known to one skilled in this art.
- a dispersing agent can be incorporated therein.
- the compression and hence bulk density of the layer can be varied by varying the differential pressure across the layer during laydown.
- the diilerential pressure is in turn dependent upon fluid velocity and viscosity, and the permeability of the layer.
- the layers density can be decreased by including a small amount of bulked or crimped coarse particles which can support the finer particles, and space them better, to avoid reducing the average pore size of the layer.
- pore size and pore configuration are best adjusted by appropriate adjustment in the proportions of multi-size particles and their mean diameter.
- mean diameter is given to particulate materials consistent in diameter, having only a slight variation each side of the mean, or having a considerable spread, usually, however, not in excess of a factor of 1 to 10, between maximum and minimum diameters above and below the mean diameter.
- the mean diameter of the particles (2) The shape of the particles (3) The length of the particles (particularly fibers) (4) The distance between adjacent particles Unless an arbitrary external force is applied during laydown, the last depends upon the first three, so that these can be said generally to control mean pore size under any given laydown conditions.
- fine and coarse fibers may be combined and blended to produce a layer having an intermediate mean pore diameter dependent on the proportions of these fibers.
- the ratio of mean fiber diameter and length should not exceed a certain value, to ensure that the finer fibers are held in place by the more rigid matrix of coarser fibers during a flow of fiuid through the layer.
- a layer formed by blending fibers A and B is produced by varying the proportions of fibers A and B at various points in the mat.
- one side of the mat consists of 100% A fibers, and the other side of 100% B fibers.
- the mean pore would in effect he tapered. If the mean pore is envisioned as being straight, with straight tapered sides, the variation in mean pore diameter is said to be linear. It the sides of the taper are curved, the variation in mean pore diameter is nonlinear. It will be appreciated that an infinite number of linear and nonlinear configurations are available, by using various combinations of different size and length fibers.
- FIGURE 1 is a flow chart showing the various steps of the process of the invention.
- Slurries or suspensions of particulate material of diiferent sizes to be blended are held in separate reservoirs of which only two, A and B, are shown, as exemplary.
- the slurries are blended together in varying proportions by the pump P, according to the size pores desired at any particular point in the deposited layer.
- the suspended particulate material in the reservoirs can be held constant but not necessarily alike, in which event the proportions of material are varied at the point of blending quite simply, by varying the rate of introduction of the slurries in the blend.
- the rate of introduction of the slurries can be kept constant, and the concentrations of suspended material in each reservoir varied as required, but this is more difiicult to do. It is practical to do this when the particulate material can be handled by a solids feeder.
- the combined mixture of particulate material is then fed to the base upon or into which the layer is to be.
- This base necessarily has .a porous structure which should be fine enough to retain the smallest particles first deposited, so that these particles are separated from the fluid as it passes through. Normally, the base support much finer particles than its pore diameter. Hence, bases as coarse as a 200 mesh screen may be used to support glass fibers of the order of 1 micron in diameter. If the base is to form an integral part of the porous layer, it is of course removed with the layer when deposition is complete. Any base can be employed, such as :a metal screen, or perforated sheet, or cloth, paper or membrane. Also, the base can be itself a laid-down structure formed upon a base.
- the base can be in any physical form or configuration, such as a flat sheet, a convoluted or corrugated sheet, or a cylinder of either of these, such as a filter unit or assembly including any of these as a filter element.
- a bonding agent or binder for bonding the particulate material in the deposited layer.
- binders are called beater addition binders in the paper industry.
- the bonding agent or binder may be flowed through the deposited layer as a final operation.
- the binder can also be incorporated in the layer after lay-down, if it has a deleterious efiect upon the slurry. It can for example be washed through the layer after the fluid has been drawn oil.
- Any type of adhesive or binder can be employed; it must, of course, be dispersible in the fluid.
- Many useful binders are known in nonwoven fabric art. Thermosetting binders requiring heating or ageing to effeet a cure can be incorporated, and in this case provision is made for curing the binder in situ after deposition.
- thermoplastic binders include polyethylene, polypropylene, polymethylene, polyisobutylene, cellulose acetate, ethyl cellulose, copolymers of vinyl chloride and vinyl acetate, polyvinyl chloride, polyvinylidiene chloride, polyvinyl butyral, polyacrylic resins, such as polymethyl methacrylate, alkyd resins, and synthetic rubbers such as butadienestyrene polymers.
- Thermosetting binders that can be used include phenoldormaldehyde resins, urea-formaldehyde resins, melamine-formaldehyde resins, polyester resins, and epoxy resins, such as polymers of ethylene chlorohydrin and bisphenol A.
- Binders which are used in solution form to apply them to the layer include any of the above and also polytetrafluoroethylene, polytrifluorochloroethylene, lignin sulionate resins, starch binders, casein binders, and terpene resins.
- the percentage of large particles may vary uniformly from 0 to 100 from one surface to the other of the layer, and the percentage of small particles varies inversely from 100 to O.
- the percentages may vary nonuniformly from 0 to 100 and 100 to 0, so that an increased percentage of fine or coarse particles is ob tained in a given part of the layer.
- FIGURE 2 shows the distribution of particles, for
- fibers in terms of the ratio of fine fibers to total fibers, when the rates of feed of the two fiber slurries are varied uniformly and continuously from 0 to for fine fibers and from 100 to 0 for coarse fibers.
- the family of curves show the distribution of fibers when the percentage of fine fibers ranges from 50% to 20%, i.e., when R ranges from 0.5 to 0.2.
- FIGURE 3 shows the distribution offibers when the rates of feed of the two fiber s-lurries are varied in an arbitrary and nonuniform manner but continuously from O to 100 for fine fibers and from 100 to 0 for coarse fibers, and for percentages of fine fibers ranging from 50% to 26% i.e., when R ranges from 0.5 to 0.2.
- FIGURE 4 shows a further variation, the principle of which may be applied to linear or nonlinear distribution of fibers.
- a nonlinear pore is formed having a very large ratio of maximum to minimum mean pore diameter. This is obtained by using three dispersions of three sizes of fibers A, B and C, so that A, fine asbestos fibers, is blended during deposition with fiber B, 1.2 micron mean diameter glass fibers. During deposition the percentage of A in the blend decreases until the deposited slurry consists entirely of B fibers. At or even before this point, the largest fibers C are introduced in a gradually increasing percentage. The resultant eifect is a medium ranging from fine fiber A to coarse fiber C, having an intermediate fiber B to bridge the great dilterence between the diameters of A and C.
- FIGURE 5 illustrates an apparatus for depositing either linear or nonlinear layers as desired.
- the apparatus comprises two reservoirs, 1 and 2, one for each size of particle to be blended.
- 1 is employed for the slurry of small particles, such as fine fibers
- 2 for the slurry of large particles, such as coarse fibers.
- the slurries are maintained uniform by the stirrers 3 and 4.
- a line 5 is provided for delivering slurry from reservoir l to a pump 6, and a similar line 7 is provided in conjunction with reservoir 2 for delivery of slurry to pump 8.
- the pumps 6 and 8 respectively, deliver the slurries through lines 9 and lit to blending point 11, whence the blend is delivered through line 12 to the base to be covered.
- the rate of feed of the slurries from the reservoirs 1 and 2 and through pumps 6 and 8 is controlled by regulating thespeed of these pumps. This is accomplished by a pair of earns 15 and 16.
- the rise and fall of these cams causes the output of these pumps to vary in relation to each other.
- the shape of the cams controls the rate of change of proportioning of the blend, and determines whether it is uniform or nonuniform.
- the cams are rotated by the cam input motor 17 via the variable speed gear 18, and the motion of the cams is transmitted by the cam followers 19 and Eli and the speed control shafts 21 and 22 through the variable speed gears 23 and 24 to the pumps 6 and 8.
- the variable speed gears 23 and 24 are operated by the pump motors 25 and 26.
- the layer After the layer has been completely formed, it may be desirable to remove therefrom substantially all or a part of the fluid medium of the slurry. This is indicated, for example, if the layer is to be impregnated with a binder.
- the fluid is sufiiciently volatile, it can be removed by drawing warm or hot air through the layer by application of a differential pressure across the layer, in the same manner as that by which the layer is formed.
- a nonvolatile liquid can be removed by washing it out with a volatile solvent and then removing the solvent in this Way.
- a curing oven can be provided, through which the base is passed after the layer is laid down. The layer is then also dried in this oven.
- wash fluid such as Water, if necessary.
- Test flow rate 8 gallons per minute per square foot of area.
- Contaminant Standardized AC fine test dust having the following particle size distribution:
- EXAMPLE 1 Two separate dispersions of glass fibers were prepared in Mil-H4606 hydraulic flu d, a petroleum base hydraulic fluid, one fiber having a mean diameter of 0.35 micron, the other having a mean diameter of 3.5 microns. These were deposited on a 3 micron nitrocellulose membrane to form a porous layer so that the fibers adjacent to the membrane were composed entirely of 0.35 micron mean diameter fibers while the top surface was composed entirely of 3.2 micron fibers. The fiber distribution in between was as shown in FIGURE 2, so that the overall ratio R of fine fibers to total fibers (by weight) was 0.25, and the deposition weight was 34 grams per square foot.
- Example 1 was repeated, substituting two fibers Whose average diameters were 1.2 and 10 microns, respectively. These were deposited on the same base as in Example 1 with a fiber distribution as shown in FIGURE 3, so that the overall ratio R of fine fibers to total fibers (by Weight) was 0.33 and the deposition weight was grams per square foot.
- EXAMPLE 3 Three dispersions were prepared using MlLH-5606 hydraulic fluid, one containing 1.2 micron mean diameter glass fibers, another containing 3.5 micron mean diameter glass fibers and the third containing diatomaceous earth. These materials were deposited on the same base as in Example 1 with a fiber distribution as shown in FIGURE 2, so that the overall ratio R of weight of 1.2 micron fibers to total fiber weight was 0.25 and the fiber deposition weight was 46 grams per square foot. The diatornaceous earth was deposited in direct proportion and simultaneously with the 1.2 micron fibers, so that the ratio R of diatomaceous earth to combined total weight of diatomaceous earth plus weight of 1.2 micron fibers was 0.33.
- Example 1 was repeated substituting the fibers named in the table which follows. These were deposited on the same base as Example 1, so that the Rratio was as in-.
- EXAMPLE 18 Two separate dispersions of asbestos fibers were prepared in water, one fiber having a Quebec test value (Manual of Testing Procedures for Chrysotile Asbestos Fibre, Asbestos Textile Institute, pp. 36-40) of O D-0 16, the other having a Quebec test value of 00-12-4. These were deposited on a cotton fiber filter paper to form a porous layer'so that the fibers laid down first were composed entirely of 0-0-12-4 fibers while the top was composed entirely of 00016 fibers. The fiber distribution in between was of the type shown in FIGURE 2, so that the overall ratio R of coarse fibers to total fibers (by weight) was 0.062, and the deposition weight was 9 grams per square foot.
- the porous layers of the invention are useful as filters for separating solid particles from liquids and gases, as coalescers for separating suspended droplets in fluid media, as agglomerators for separating fluids entrained in gases, as gas diffusers, as dialyzing membranes, and as porous separators in all types of apparatus employing fluids for any purpose, such as separators in batteries and diaphragm cells. They can be made to have a wide range of porosities, to meet any need. The pores can for example be made small enough to remove bacteria and like minute organisms. They can be used as shock absorbers, molded cushioning, acoustical absorbers, and in heat and sound insulation.
- a process for preparing porous depth filters having pores which vary in diameter and configuration from surface to surface of the material comprising blending continuously at least two separate suspensions comprising particulate material suspended in a fluid, the separate different sizes while varying the proportions blended of particulate material of each size sequentially, and depositing the mixture thus produced upon a base to form a porous material, thereby producing a material having a pore diameter and pore configuration varying from surface to surface thereof.
- one of the particulate materials is a fibrous material, and another of the particulate materials a granular material.
- a porous depth filter prepared in accordance with the process of claim 1 and comprising particulate material of at least two sizes blended together in varying proportions from surface to surface, thereby defining pores varying in diameter and configuration and extending from surface to surface of the material.
- a porous depth filter in accordancewith claim 14 having a base of porous material attached thereto.
- a porous depth filter in accordance with claim 14 having a base of porous material imbedded therein.
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Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
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GB1000038D GB1000038A (enrdf_load_stackoverflow) | 1960-12-06 | ||
US74130A US3158532A (en) | 1960-12-06 | 1960-12-06 | Tapered pore filter elements |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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US74130A US3158532A (en) | 1960-12-06 | 1960-12-06 | Tapered pore filter elements |
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US3158532A true US3158532A (en) | 1964-11-24 |
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US74130A Expired - Lifetime US3158532A (en) | 1960-12-06 | 1960-12-06 | Tapered pore filter elements |
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US (1) | US3158532A (enrdf_load_stackoverflow) |
GB (1) | GB1000038A (enrdf_load_stackoverflow) |
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