US3127353A - Lubricating compositions - Google Patents
Lubricating compositions Download PDFInfo
- Publication number
- US3127353A US3127353A US3127353DA US3127353A US 3127353 A US3127353 A US 3127353A US 3127353D A US3127353D A US 3127353DA US 3127353 A US3127353 A US 3127353A
- Authority
- US
- United States
- Prior art keywords
- aryl
- lubricating compositions
- glycide
- oxide
- lubricant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D303/00—Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
- C07D303/02—Compounds containing oxirane rings
- C07D303/12—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms
- C07D303/18—Compounds containing oxirane rings with hydrocarbon radicals, substituted by singly or doubly bound oxygen atoms by etherified hydroxyl radicals
- C07D303/20—Ethers with hydroxy compounds containing no oxirane rings
- C07D303/22—Ethers with hydroxy compounds containing no oxirane rings with monohydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
- C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
- C10M129/16—Ethers
- C10M129/18—Epoxides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
- C10M2201/08—Inorganic acids or salts thereof
- C10M2201/082—Inorganic acids or salts thereof containing nitrogen
- C10M2201/083—Inorganic acids or salts thereof containing nitrogen nitrites
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
- C10M2207/04—Ethers; Acetals; Ortho-esters; Ortho-carbonates
- C10M2207/042—Epoxides
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2215/00—Organic non-macromolecular compounds containing nitrogen as ingredients in lubricant compositions
- C10M2215/02—Amines, e.g. polyalkylene polyamines; Quaternary amines
- C10M2215/06—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings
- C10M2215/062—Amines, e.g. polyalkylene polyamines; Quaternary amines having amino groups bound to carbon atoms of six-membered aromatic rings containing hydroxy groups bound to the aromatic ring
Definitions
- the present invention relates to lubricating compositions; more particularly it concerns lubricating composi- CH B tions containing a lubricant, especially a lubricant based on minenal oils, and an aryl-glycide ether of the general fl- 2 63 formula (311E R on: on,
- R stands for an alkyl radial containing at least E7 58 12 carbon atoms.
- Suitable aryl-glycide ethers are for instance 4-dodecylphenoxy-p-ropene oxide, 4-is0dodecyl-phenoxy-propene 12 iso @-O-GH1-CH OH; 31 oxide, 3-pentadecyl-phenoxy-propene oxide, 4-octadecylphenoxy-propene oxide and 4-isooctadecyl-phenoxy-prm 25 P6116 oxide.
- 4-dodecylphenoxy-p-ropene oxide 4-is0dodecyl-phenoxy-propene 12 iso @-O-GH1-CH OH; 31 oxide, 3-pentadecyl-phenoxy-propene oxide, 4-octadecylphenoxy-propene oxide and 4-isooctadecyl-phenoxy-prm 25 P6116 oxide.
- Aryl-glycide ethers of this type are obtainable by various methods, e.g. by reacting epichorohydrin with phe- 1101s which are substituted by an alkyl radical containing at least 12 carbon atoms, or by epoxylating the corre- 76 sponding arylallyl ethers; in general, they are viscous, colourless or slightly coloured, odourless liquids.
- the aryl-glycide ethers present in the lubricating compositions of the invention increase mainly the thermal We claim: stability of the lubricants to which they impart good 35 A lubflcatlPg composltlon comprlsm'g mal0T high-pressure properties as well as detergent action; morep of a lubncant and 014% by Welght of an n over, it is remarkable that they are compatible with glyclde ether of the general formula other lubricant additives such as antioxidants or anti- 3 corrosion agents.
- the requisite quantities of aryl-glycide ethers may readily be established by preliminary 40 gexperiments; in general, an addition of 0.1 to 5 percent by weight, referred to the lubricant, is sufiicient.
- a lubricating composition comprising a major Ar-0-oH, oHoH, amount of a mineral oil lubricant and 0. 1-5 by weight of 4-isododecyl-phenoxy-propene oxide.
- a lubricatin com osition com risin a ma'or Wher.em Ar Stanqs ⁇ or a phenyl. radwal which amount of a miner al oil liibricant and (51-57%; by weight substituted or which 15 only substituted by alkyl radicals of a 3 pentadecyl henox m ens oxide containing on the Whole at most 4 carbon atoms.
- Com- 5O 4 A Lubricating g g com risin a mabr pared with such additives the aryl-glycide others of the amo'unt of a miner al on lubricant and 5 5 wellht present invention are surprisingly more active.
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Lubricants (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Epoxy Compounds (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DEF0026177 | 1958-07-15 |
Publications (1)
Publication Number | Publication Date |
---|---|
US3127353A true US3127353A (en) | 1964-03-31 |
Family
ID=7091915
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US3127353D Expired - Lifetime US3127353A (en) | 1958-07-15 | Lubricating compositions |
Country Status (7)
Country | Link |
---|---|
US (1) | US3127353A (fr) |
BE (1) | BE580739A (fr) |
CH (1) | CH375817A (fr) |
DE (1) | DE1074185B (fr) |
FR (1) | FR1230201A (fr) |
GB (1) | GB851845A (fr) |
NL (1) | NL110202C (fr) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6121211A (en) * | 1998-07-17 | 2000-09-19 | The Lubrizol Corporation | Engine oil having dithiocarbamate and aldehyde/epoxide for improved seal performance, sludge and deposit performance |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3637507A (en) * | 1968-02-12 | 1972-01-25 | Stauffer Chemical Co | Aircraft hydraulic fluid and method of controlling acid buildup therein with acid acceptor |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2665254A (en) * | 1950-06-23 | 1954-01-05 | Sun Oil Co | Oxidation inhibited mineral oil |
Family Cites Families (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2734032A (en) * | 1956-02-07 | Lubricants | ||
FR966140A (fr) * | 1947-05-13 | 1950-09-30 | ||
US2655254A (en) * | 1948-01-26 | 1953-10-13 | Joy Mfg Co | Swivel for conveyer troughs |
-
0
- US US3127353D patent/US3127353A/en not_active Expired - Lifetime
- BE BE580739D patent/BE580739A/xx unknown
- NL NL110202D patent/NL110202C/xx active
- DE DENDAT1074185D patent/DE1074185B/de active Pending
-
1959
- 1959-07-06 CH CH7538159A patent/CH375817A/de unknown
- 1959-07-09 GB GB23673/59A patent/GB851845A/en not_active Expired
- 1959-07-15 FR FR800102A patent/FR1230201A/fr not_active Expired
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2665254A (en) * | 1950-06-23 | 1954-01-05 | Sun Oil Co | Oxidation inhibited mineral oil |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6121211A (en) * | 1998-07-17 | 2000-09-19 | The Lubrizol Corporation | Engine oil having dithiocarbamate and aldehyde/epoxide for improved seal performance, sludge and deposit performance |
Also Published As
Publication number | Publication date |
---|---|
BE580739A (fr) | |
FR1230201A (fr) | 1960-09-14 |
DE1074185B (fr) | 1960-01-28 |
GB851845A (en) | 1960-10-19 |
NL110202C (fr) | |
CH375817A (de) | 1964-03-15 |
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