US2999004A - Treating filamentary material - Google Patents
Treating filamentary material Download PDFInfo
- Publication number
- US2999004A US2999004A US691180A US69118057A US2999004A US 2999004 A US2999004 A US 2999004A US 691180 A US691180 A US 691180A US 69118057 A US69118057 A US 69118057A US 2999004 A US2999004 A US 2999004A
- Authority
- US
- United States
- Prior art keywords
- cellulose triacetate
- bath
- filaments
- methylene chloride
- treating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/06—Wet spinning methods
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F2/00—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof
- D01F2/24—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from cellulose derivatives
- D01F2/28—Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof from cellulose derivatives from organic cellulose esters or ethers, e.g. cellulose acetate
Definitions
- This invention relates to the wet spinning of cellulose triacetate to form filamentary materials.
- Textile materials of cellulose triacetate have recently attained considerable commercial importance. On suitable after-treatment, these textile materials have superior heat resistance,- high safe-ironing temperatures, excellent wash-fastness even when dyed in heavy shades, crease resistance and resistance to glazing and to shrinkage on pressing with moist steam.
- cellulose triacetate filamentary materials of greater strength and high elongation can be prepared by wet spinning of the cellulose triacetate, i.e. by extrusion of a solution of the cellulose triacetate into a-coagulating or spin bath which exerts a swelling action on the filamentary material.
- a solution of the cellulose triacetate into a-coagulating or spin bath which exerts a swelling action on the filamentary material.
- the filaments tend to coalesce to an appreciable extent, i.e. they bond laterally to one another.
- a solution of cellulose'triacetate. in a solvent comprising methylene chloride is extruded through 'a spinnerette, preferably provided with a plurality of orifices, into a spin bath containing methylene chloride and preferably a lower aliphatic alcohol such as methanol.
- methylene chloride preferably a lower aliphatic alcohol
- the resulting swollen cellulose triacetate filaments are then treated with a liquid organic non-solvent for cellulose triacetate. It is found that upon drying the filaments are uncoalesced.
- the use of certain critical proportions of methylene chloride in the spin bath results in the production of filamentary materials of outstanding physical properties (e.g. tenacity of at least 1.8 grams per denier and elongation of at least 18%).
- proportions of methylene chloride within the scope of the Riley application.
- the stretching force is most conveniently applied by means of a positively driven feed roll, such as a godet roll, over which the filaments pass, as a bundle, after they leave the spinbath.
- the liquid organic non-solvent for cellulose triacetate which can be employed to treat the bundle of cellulose triacetate filaments from the spin bath is preferably miscible with methylene chloride and boils below C.
- Representative substances include hydrocarbons such as aliphatic compounds and mixtures thereof, cycloaliphatic compounds such as cyclohexane, aromatic compounds such as benzene and its lower alkyl substitution products such as toluene and xylene, others such as isopropyl ether, and the like.
- xylene is particularly satisfactory since it permits a marked reduction in coalescence in a short time of contact, and the filaments have desirable physical properties such as high strength and satisfactory elongation.
- the bundle of filaments can be immersed freely in the treating bath after leaving the spin-bath without being taken up on a bobbin.
- the bundle of filaments leaving the spinbath is passed about a positively driven feed roller, through a second bath containing the treating liquid and is taken up on a bobbin. the second bath to maintain the yarn submerged therein. It is generally advantageous to maintain a low tension on the yarn during the treatment of this invention, so as to produce a final product of desirable high elongation with a low degree of coalescence.
- the take-up bobbin may be run at a somewhat lower linear 1 velocity than the feed roller.
- the percent coalescence can be reduced by me chanically assisting the treatment, as by the use of suitable wiping devices in the treating bath, e.g. an aluminum magnesium silicate device having a satin-finished rounded wiping edge which will flatten the filament bun- It can conveniently be elfected on the bobbin or it can be I elfected with the filaments relaxed, i.e. filamentary material merely passes about a roller and is collected in a can where it is free to contract. a r
- the cellulose triacetate employed in accordance with this invention has an acetyl value of at least about 60%, preferably above 61%, calculated as acetic acid. Its concentnation in the spinning solution can range between about 18 to 26% by weight.
- the spinning solution solvent can contain up to about 15% by weight of methanol while the methanol content of the spin-bath is about 50%by weight.
- the percent coalescence as employed in the examples is that percentage ofthe total'nuniber of' filaments in a yarn bundle which participate in coalescence. t is found as follows: A piece of piano wire of 0.097 mm. diameter is looped through a hole of 1.02 diameter in a metal plate 0.62 mm. thick. A 10 cm. length of uncolored yarn to be examined is bundled with a blue yarn and the bundle is inserted through the loop of the wire. The wire loop is pulled through the hole in the plate, thereby doubling the filament bundle and draw.-
- the blue yarn serves to fill the hole and ensures a snug fit.
- the yarn is cut flush with the surfaces of the plate using a razor blade, thereby forming a thin section-
- a drop of decane is placed on c section to improve filament boundary definition, a cover glass is placed over the section and it is examined under a microscope at a magnification of 440.
- the number of filaments which are fused or bonded together is determined and the test repeated 8 times for each yarn.
- the percent coalescence is 100 times the average number of filaments of a section involved in coalescence vided by the total number of uncolored filaments in the section.
- the yarn After. emerging from the bath, the yarn is passed over a ball-bearing pulley and 3 meters downward to a driven feed roll and idler operating at a surface speed of 60 meters/minute. From the feed roll, the yarn passes through a 1.7 meter horizontal bath of xylene at room temperature to a take-up bobbin rotated at a peripheral. speed of 57-60 meters/minute. The yarn is dried on the bobbin by standing in air for 17 hours, then standing for 17 hours at 50 C. and an absolute pressure of 200 mm. of mercury, and finally standing for 20 hours at 50 C. and an absolute pressure-of 5 mm. of mercury. The percent coalescence of the yarn is 5.0%.
- EXAMPLE II Solutions of cellulose triacetate as described in Example I are spun vertically upwardly through a 1.0 meter height of spinning hath made up of a mixture of methylene chloride and methanol. The filaments pass about a godet and idler assembly, through a horizontal treating bath 95 cm. long, and then to a take-up roll, fixed guides being employed to submerge the yarn in the bath.
- the results using a variety of conditions and solvents are given in the following table:
- Process for the production of filamentary cellulose triacetate which comprises extruding a solution. of cellulose triacetate in a solvent therefor comprising methylene chloride into a spin bath comprising about 25 to of methylene chloride and a lower aliphatic alcohol to form filamentary cellulose triacetate, and. treating said filamentary cellulose triacetate with a liquid organic nonsolvent for cellulose triacetate which is miscible with methylene chloride and boils below about C.
- the spinbath comprises a mixture of. methylene chloride and methanol containing at least about 50% by weight of methanol.
- liquid organic non-solvent for cellulose triacetate comprises isopropyl ether.
- liquid organic non-solvent for cellulose triacetate comprises a cyclic hydrocarbon.
- liquid organic-non-solvent for cellulose triacetate comprises cyclohexane
- liquid organic non-solvent for cellulose triacetate comprises a monocyclic aromatic hydrocarbon.
- liquid organic non-solvent for cellulose triacetate comprises xylene.
- liquid organic non-solvent for cellulose tn'acetate comprises benzene.
- treating is efiected by continuously introducing said filamentary cellulose triacetate into a treating bath and removing it from said treating bath at a lower linear velocity than it is introduced, treating thereby being effected with said filamentary cellulose tn'acetate under low tension.
Description
States Patent 2,999,004 TREATING FILAMENTARY MATERIAL Stewart W. Morse, Jr., Chatham, N.J., assignor to Celanese Corporation of America, New York, N. a corp'oration of Delaware No Drawing. Filed Oct. 21, 1957, Ser. No. 691,180 12 Claims. (Cl. 18-.54)
This invention relates to the wet spinning of cellulose triacetate to form filamentary materials.
Textile materials of cellulose triacetate have recently attained considerable commercial importance. On suitable after-treatment, these textile materials have superior heat resistance,- high safe-ironing temperatures, excellent wash-fastness even when dyed in heavy shades, crease resistance and resistance to glazing and to shrinkage on pressing with moist steam.
It has recently been found that cellulose triacetate filamentary materials of greater strength and high elongation can be prepared by wet spinning of the cellulose triacetate, i.e. by extrusion of a solution of the cellulose triacetate into a-coagulating or spin bath which exerts a swelling action on the filamentary material. Upon contacting a plurality of such filaments while wet and swollen with the spin bath and then drying, it has been found that the filaments tend to coalesce to an appreciable extent, i.e. they bond laterally to one another.
It is accordingly an object'of this invention to provide a process for reducing the coalescence of wet spun cel' lulose triacetate filamentary material.
It is another object of the invention to provide a continuous process for wet spinning cellulose triacetate and recovering filaments thereof in substantially uncoalesced condition.
Other objects of this invention will be apparent fromthefollowing detailed description and claims. In this description and claims all proportions are by weight unless otherwise indicated.
In accordance with one aspect of this invention, a solution of cellulose'triacetate. in a solvent comprising methylene chloride is extruded through 'a spinnerette, preferably provided with a plurality of orifices, into a spin bath containing methylene chloride and preferably a lower aliphatic alcohol such as methanol. The resulting swollen cellulose triacetate filaments are then treated with a liquid organic non-solvent for cellulose triacetate. It is found that upon drying the filaments are uncoalesced.
The formation of the swollen cellulose triacetate filaments is preferably carried out in the manner described in detail in the copending application of Jesse L. Riley, entitled Spinning, Serial No. 638,414, filed February 5, 1957, and the entire disclosure of said Riley application is hereby incorporated into the present application.
As taught in the copending application of Riley, referred to above, the use of certain critical proportions of methylene chloride in the spin bath results in the production of filamentary materials of outstanding physical properties (e.g. tenacity of at least 1.8 grams per denier and elongation of at least 18%). In the practice of the present invention it is preferable to use proportions of methylene chloride within the scope of the Riley application. Preferably the proportions of methylene chloride in the spin bath are within the range defined by the formula C=%-T:L5, where C is the concentration in percent and T is the temperature in degrees centigrade, the balance of the solvent comprising a lower Since the temperature of As disclosed in said Riley application, the
ice
has a considerable swelling power for the cellulose triacetate, the stretching being etfected by taking up the swollen filaments at a higher linear speed than the linear speed at which they are extruded. The stretching force is most conveniently applied by means of a positively driven feed roll, such as a godet roll, over which the filaments pass, as a bundle, after they leave the spinbath.
The liquid organic non-solvent for cellulose triacetate which can be employed to treat the bundle of cellulose triacetate filaments from the spin bath is preferably miscible with methylene chloride and boils below C. Representative substances include hydrocarbons such as aliphatic compounds and mixtures thereof, cycloaliphatic compounds such as cyclohexane, aromatic compounds such as benzene and its lower alkyl substitution products such as toluene and xylene, others such as isopropyl ether, and the like. The use of xylene is particularly satisfactory since it permits a marked reduction in coalescence in a short time of contact, and the filaments have desirable physical properties such as high strength and satisfactory elongation. The bundle of filaments can be immersed freely in the treating bath after leaving the spin-bath without being taken up on a bobbin. Preferably, however, the bundle of filaments leaving the spinbath is passed about a positively driven feed roller, through a second bath containing the treating liquid and is taken up on a bobbin. the second bath to maintain the yarn submerged therein. It is generally advantageous to maintain a low tension on the yarn during the treatment of this invention, so as to produce a final product of desirable high elongation with a low degree of coalescence. To this end the take-up bobbin may be run at a somewhat lower linear 1 velocity than the feed roller.
With certain of the treating liquids, such as cyclo-. hexane, the percent coalescence can be reduced by me chanically assisting the treatment, as by the use of suitable wiping devices in the treating bath, e.g. an aluminum magnesium silicate device having a satin-finished rounded wiping edge which will flatten the filament bun- It can conveniently be elfected on the bobbin or it can be I elfected with the filaments relaxed, i.e. filamentary material merely passes about a roller and is collected in a can where it is free to contract. a r
The cellulose triacetate employed in accordance with this invention has an acetyl value of at least about 60%, preferably above 61%, calculated as acetic acid. Its concentnation in the spinning solution can range between about 18 to 26% by weight. The spinning solution solvent can contain up to about 15% by weight of methanol while the methanol content of the spin-bath is about 50%by weight.-
p The following examples are given to illustrate this invention further. The percent coalescence as employed in the examples is that percentage ofthe total'nuniber of' filaments in a yarn bundle which participate in coalescence. t is found as follows: A piece of piano wire of 0.097 mm. diameter is looped through a hole of 1.02 diameter in a metal plate 0.62 mm. thick. A 10 cm. length of uncolored yarn to be examined is bundled with a blue yarn and the bundle is inserted through the loop of the wire. The wire loop is pulled through the hole in the plate, thereby doubling the filament bundle and draw.-
Guides can be provided in ass-e004 ing it through the hole. The blue yarn serves to fill the hole and ensures a snug fit. The yarn is cut flush with the surfaces of the plate using a razor blade, thereby forming a thin section- A drop of decane is placed on c section to improve filament boundary definition, a cover glass is placed over the section and it is examined under a microscope at a magnification of 440. The number of filaments which are fused or bonded together is determined and the test repeated 8 times for each yarn. The percent coalescence is 100 times the average number of filaments of a section involved in coalescence vided by the total number of uncolored filaments in the section.
EXAMPLE I Cellulose triacetate of 61.5% acetyl value, calculated as acetic acid, and of intrinsic viscosity 2.0 (measured in cupricthylene diamine at C. on cellulose regenerated from said cellulose triacetate) is dissolved in a solvent comprising 91 parts by weight of methylene chloride and 9 parts by weight of methanol to form a 22% by weight solution having a viscosity of 1800 poises at 25 C. The solution is spun upwardly through a spinning jet having 40 holes each 0.10 mm. in diameter, the filaments passing upwardly through. 1.7 meters of a spin-bath composed by weight of 42.2/57.8 methylene chloride/methanol. The spin-bath is maintained at C. and is circulated upwardly at the rate of 4.0 liters/minute through a vertical column of 2 inches internal diameter. After. emerging from the bath, the yarn is passed over a ball-bearing pulley and 3 meters downward to a driven feed roll and idler operating at a surface speed of 60 meters/minute. From the feed roll, the yarn passes through a 1.7 meter horizontal bath of xylene at room temperature to a take-up bobbin rotated at a peripheral. speed of 57-60 meters/minute. The yarn is dried on the bobbin by standing in air for 17 hours, then standing for 17 hours at 50 C. and an absolute pressure of 200 mm. of mercury, and finally standing for 20 hours at 50 C. and an absolute pressure-of 5 mm. of mercury. The percent coalescence of the yarn is 5.0%.
EXAMPLE II Solutions of cellulose triacetate as described in Example I are spun vertically upwardly through a 1.0 meter height of spinning hath made up of a mixture of methylene chloride and methanol. The filaments pass about a godet and idler assembly, through a horizontal treating bath 95 cm. long, and then to a take-up roll, fixed guides being employed to submerge the yarn in the bath. The results using a variety of conditions and solvents are given in the following table:
Table Yarn: filaments.
Spinning Speed: 40 m. min. (3.75 denier); 23.5 m./min. (6.38 denier). Spin Bath: 1 meter 0 iCh/CH OH.
Treating Bath: 95 em.
When water is used in the treating bath not only are the filaments almost fully coalesced as indicated in the table, but the yarn is also exceedingly weak and shatters rather than breaking cleanly.
It is to be understood that the foregoing detailed description is merely given by way of illustration and that many variations may be made therein without departing from the spirit of my invention.
Having described my invention, what I desire to secure by Letters Patent is:
1. Process for the production of filamentary cellulose triacetate which comprises extruding a solution. of cellulose triacetate in a solvent therefor comprising methylene chloride into a spin bath comprising about 25 to of methylene chloride and a lower aliphatic alcohol to form filamentary cellulose triacetate, and. treating said filamentary cellulose triacetate with a liquid organic nonsolvent for cellulose triacetate which is miscible with methylene chloride and boils below about C.
2. The process set forth in claim 1, wherein. the filamentary cellulose triacetate upon leaving said spin bath passes continuously through a treating bath containing. said liquid organic non-solvent for cellulose triacetate.
3. The process set forth inclairn 1, wherein the solvent from which the cellulose triacetate is spun comprises methylene chloride and up to about 15% by weight. of a lower alkanol, and the treatment with said. liquid. or ganic non-solvent for cellulose triacetate is eifected with the filamentary cellulose triacetate under low tension.
4. The process set forth in claim 1, wherein. the spinbath comprises a mixture of. methylene chloride and methanol containing at least about 50% by weight of methanol.
5. The process set forth in claim. 1, wherein the: filamentary cellulose acetate upon leaving said spin bath is taken up on a bobbin, and said bobbin is thereafter immersed in a treating bath containing said liquid organic non-solvent for cellulose triacetate.
6'. The process set forth in claim 1, wherein said liquid organic non-solvent for cellulose triacetate comprises isopropyl ether.
7. The process set forth in claim 1, wherein said liquid organic non-solvent for cellulose triacetate comprises a cyclic hydrocarbon.
8. The process set forth in claim 1, wherein said liquid organic-non-solvent for cellulose triacetate comprises cyclohexane.
9. The process set forth in claim 1, wherein said liquid organic non-solvent for cellulose triacetate comprises a monocyclic aromatic hydrocarbon.
CHiOli pinning Content of Treating Bath Im- Takeup Cooles- Treating Liquid Speed, 011 01;] Temp, mersion Tensio ence,
m./m1n C H OH C. Time, sec. gm. percent Spin bath, Wt. percent 5 1.4 .5. Xylene 5 1.4........ 10 1 Benzene 40 so 25 17hours 0 16.2. i3 28 i8 i:i:::::::: 2 5.
40 50 25 l.4 9 11.2. Graeme i8 28 ii iii: 8 5:2:
23. 5 41 35 2.5 .0. 6 12.5. Water 40 5O 25 1.4 -3 Alllalist mersed freely.
1 After travelling filaments treated in bath and. taken up on bobbin, bobbin immersed in treatment bath.
10. The process set forth in claim 1, wherein said liquid organic non-solvent for cellulose triacetate comprises xylene.
11. The process set forth in claim 1, wherein said liquid organic non-solvent for cellulose tn'acetate comprises benzene.
12. The process set forth in claim 1, wherein treating is efiected by continuously introducing said filamentary cellulose triacetate into a treating bath and removing it from said treating bath at a lower linear velocity than it is introduced, treating thereby being effected with said filamentary cellulose tn'acetate under low tension.
References Cited in the file of this patent UNITED STATES PATENTS Eichengrun Oct. 13, Dreyfus Mar. 30, Dickie Feb. 21, Johnson et a1 Nov. 3, Bradshaw et al. Jan. 31,
FOREIGN PATENTS Great Britain Aug. 3, Great Britain July 3,
Claims (1)
1. PROCESS FOR THE PRODUCTION OF FILAMENTARY CELLULOSE TRIACETATE WHICH COMPRISES EXTRUDING A SOLUTION OF CELLULOSE TRIACETATE IN A SOLVENT THEREFOR COMPRISING METHYLENE CHLORIDE INTO A SPIN BATH COMPRISING ABOUT 25 TO 65% OF METHYLENE CHLORIDE AND A LOWER ALIPHATIC ALCOHOL TO FORM FILAMENTARY CELLULOSE TRIACETATE, AND TREATING SAID FILAMENTARY CELLULOSE TRIACETATE WITH A LIQUID ORGANIC NONSOLVENT FOR CELLULOSE TRIACETATE WHICH IS MISCIBLE WITH METHYLENE CHLORIDE AND BOILS BELOW ABOUT 150*C.
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US691180A US2999004A (en) | 1957-10-21 | 1957-10-21 | Treating filamentary material |
GB1854/58A GB826098A (en) | 1957-10-21 | 1958-01-20 | Wet spinning cellulose triacetate |
FR1200188A FR1200188A (en) | 1957-10-21 | 1958-02-05 | Process and apparatus for spinning cellulose traicetate and resulting products |
DEC16243A DE1276289B (en) | 1957-10-21 | 1958-02-05 | Method and device for producing threads or fibers from cellulose triacetate |
GB16378/59A GB915623A (en) | 1957-10-21 | 1959-05-13 | Artificial filamentary material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US691180A US2999004A (en) | 1957-10-21 | 1957-10-21 | Treating filamentary material |
Publications (1)
Publication Number | Publication Date |
---|---|
US2999004A true US2999004A (en) | 1961-09-05 |
Family
ID=24775473
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US691180A Expired - Lifetime US2999004A (en) | 1957-10-21 | 1957-10-21 | Treating filamentary material |
Country Status (4)
Country | Link |
---|---|
US (1) | US2999004A (en) |
DE (1) | DE1276289B (en) |
FR (1) | FR1200188A (en) |
GB (2) | GB826098A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3201505A (en) * | 1962-05-24 | 1965-08-17 | Eastman Kodak Co | Process for molding rod-like cigarette filter tip of cellulose ester flake |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103757720B (en) * | 2014-01-15 | 2017-08-25 | 中国纺织科学研究院 | Coagulating bath and the method for preparing fiber for cellulose solution spinning technique |
CN104213211B (en) * | 2014-09-18 | 2016-06-08 | 东华大学 | A kind of method preparing doughnut artificial blood vessel for raw material with polycaprolactone |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2057141A (en) * | 1928-02-08 | 1936-10-13 | Celanese Corp | Production of filaments, threads, bands, ribbons and the like, from cellulose derivatives |
US2075027A (en) * | 1931-10-21 | 1937-03-30 | Dreyfus Henry | Manufacture and treatment of artificial silk and like products |
US2147640A (en) * | 1928-11-05 | 1939-02-21 | Celanese Corp | Production of artificial materials |
US2657973A (en) * | 1949-10-28 | 1953-11-03 | British Celanese | Process for wet-spinning cellulose triacetate |
GB734736A (en) * | 1952-08-26 | 1955-08-03 | Textile & Chemical Res Company | Improvements in or relating to the production of artificial filaments and the like |
US2732586A (en) * | 1952-04-30 | 1956-01-31 | Spinning of | |
GB778395A (en) * | 1954-05-26 | 1957-07-03 | British Celanese | Improvements in the manufacture of cellulose triacetate yarns |
Family Cites Families (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE643863C (en) * | 1930-03-22 | 1937-04-19 | Boehringer & Soehne Gmbh | Process for the representation of rayon and other artificial products made of acetyl cellulose |
CH175036A (en) * | 1933-02-15 | 1935-02-15 | Boehringer & Soehne Gmbh | Process for the production of artificial structures from cellulose esters. |
-
1957
- 1957-10-21 US US691180A patent/US2999004A/en not_active Expired - Lifetime
-
1958
- 1958-01-20 GB GB1854/58A patent/GB826098A/en not_active Expired
- 1958-02-05 DE DEC16243A patent/DE1276289B/en active Pending
- 1958-02-05 FR FR1200188A patent/FR1200188A/en not_active Expired
-
1959
- 1959-05-13 GB GB16378/59A patent/GB915623A/en not_active Expired
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2057141A (en) * | 1928-02-08 | 1936-10-13 | Celanese Corp | Production of filaments, threads, bands, ribbons and the like, from cellulose derivatives |
US2147640A (en) * | 1928-11-05 | 1939-02-21 | Celanese Corp | Production of artificial materials |
US2075027A (en) * | 1931-10-21 | 1937-03-30 | Dreyfus Henry | Manufacture and treatment of artificial silk and like products |
US2657973A (en) * | 1949-10-28 | 1953-11-03 | British Celanese | Process for wet-spinning cellulose triacetate |
US2732586A (en) * | 1952-04-30 | 1956-01-31 | Spinning of | |
GB734736A (en) * | 1952-08-26 | 1955-08-03 | Textile & Chemical Res Company | Improvements in or relating to the production of artificial filaments and the like |
GB778395A (en) * | 1954-05-26 | 1957-07-03 | British Celanese | Improvements in the manufacture of cellulose triacetate yarns |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3201505A (en) * | 1962-05-24 | 1965-08-17 | Eastman Kodak Co | Process for molding rod-like cigarette filter tip of cellulose ester flake |
Also Published As
Publication number | Publication date |
---|---|
DE1276289B (en) | 1968-08-29 |
GB826098A (en) | 1959-12-23 |
FR1200188A (en) | 1959-12-18 |
GB915623A (en) | 1963-01-16 |
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