US2932084A - Method of making spinnerets - Google Patents
Method of making spinnerets Download PDFInfo
- Publication number
- US2932084A US2932084A US646098A US64609857A US2932084A US 2932084 A US2932084 A US 2932084A US 646098 A US646098 A US 646098A US 64609857 A US64609857 A US 64609857A US 2932084 A US2932084 A US 2932084A
- Authority
- US
- United States
- Prior art keywords
- spinneret
- fluid
- walls
- making
- porous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Images
Classifications
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D4/00—Spinnerette packs; Cleaning thereof
- D01D4/02—Spinnerettes
- D01D4/022—Processes or materials for the preparation of spinnerettes
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/10—Sintering only
- B22F3/11—Making porous workpieces or articles
- B22F3/1103—Making porous workpieces or articles with particular physical characteristics
- B22F3/1109—Inhomogenous pore distribution
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S264/00—Plastic and nonmetallic article shaping or treating: processes
- Y10S264/63—Processes of molding porous blocks
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S425/00—Plastic article or earthenware shaping or treating: apparatus
- Y10S425/115—Lubricator
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S425/00—Plastic article or earthenware shaping or treating: apparatus
- Y10S425/217—Spinnerette forming conjugate, composite or hollow filaments
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/496—Multiperforated metal article making
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49826—Assembling or joining
- Y10T29/49888—Subsequently coating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/4998—Combined manufacture including applying or shaping of fluent material
- Y10T29/49982—Coating
Definitions
- the invention relates to the method of making spinnerets. Particularly, the inventionis concernedwith the method of making self-cleaning spinnerets which are adapted to apply various finishing, colorant or additive solutions to the material extruded through the capillaries or openings of the spinnerets.
- This application is a flitcd mates .Pat h D division of my United States Patent application 509,349 .5
- these additives and colorants are incorporated into the mixer in which the filament-formingsolution is first formed, or are intermixed with the filament-forming solution after its formation and before its extrusion through the spinneret.
- these known methods of imparting desirable properties to the filamentary strand render it difiicult to maintain control over the quality of the particular characteristic imparted to the filament and also lack flexibility, as for example when filamentary strands having treated sections of relatively short length are desired. It is therefore an object of the invention to provide a generally new or improved and more satisfactory method for making spinnerets having greater utility than those heretofore known.
- Another object is to provide a method of making a spinneret having capillaries which may be flushed clean without removal of the spinneret from its operating position.
- Still another object is the provision of the method of forming a spinneret having a porous internal structure through which flushing, colorant, and additive fluids may be forced to and through the capillary walls.
- a further object is the provision of a method of making a spinneret having an integral fluid supply chamber from which various flushing, colorant, or additive solutions may be forced through the porous interior structure of the spinneret to the spinneret capillaries.
- Fig. 1 is a top view of a spinneret made in accordance with the present invention
- Fig. 2 is a central vertical section taken on the lin II--II of Fig. l;
- Fig. 3 is a fragmentary horizontal section, on an enlarged scale, taken through the wall of the spinneret along the line III-III of Fig. 2;
- Fig. 4 is a section similar to Fig. 3 taken along the line I VIV ofFig. 2;
- Fig. 5 is a fragmentary vertical section, on an enlarged scale, taken-through the face of the spinneret along the line V-V of Fig. 2.
- p H A spinneret made bythe method of the present invention resembles a conventional spinneret in shape, with the addition of a fluid receiving chamber or trough extend ing around its exterior periphery.
- the exposed surfaces of the. annular wall and face of the spinneret, and walls of the'fluid receiving chamber are coated with a thin layer of impervious material, while the internal structure of the assembly is porous so as to permit the flow of I fluid therethrough.
- the spinneret openings or capillaries are formed after the exposed surfaces have been coated,
- Fluid under pressure is adapted to flow freely from the chamber through the porous internal structure of the spinneret to the capillary walls to flush the same of any foreign matter, or to be applied to the filament-forming material extruded therethrough.
- the spinneret has a conventional cup-shaped body including an annular ortubular wall 11 and a face 13 integrally formedby sintering a powdered material, as for example stainless steel particles, under high temperature and pressure in a suitably shaped mold.
- a powdered material as for example stainless steel particles
- Any suitable means as for example external threads, may be provided on the collar 23 to facilitate attachment of fluid conduit means thereto.
- the walls 17 and '19 are also fabricated by sintering, under high temperature -and pressure, a powdered material of the same type as employed in the spinneret body, and may be formed either integrally with the spinneret body or as a separate unit, with the first'mentioned procedure being preferable.
- the sintering procedure employed provides the spinneret body'and chamber Walls with a strong but porous structure, as shown at 25, through which fluids, under pressure, are able to flow. The strength of these members and the rate at which they conduct fluids may be readily controlled by the particle size of the powdered material and sintering temperatures and pressures.
- the top of the chamber 15 is formed by an annular plate 27 fastened, in a fluid-tight manner, to the walls 11 and 17 of the spinneret assembly.
- the plate 27 need not be of porous construction and is preferably formed of a material, for example stainless steel, not readily attacked by the solutions normally employed. All of the exposed surfaces of the spinneret assembly are then coated or plated with a thin layer 29 of impervious material, as for example stainless steel, while the inlet opening 21 is temporarily sealed with a suitable stopper, after which the openings or apertures or capillaries 31 are formed in the spinneret face 13. By punching the capillaries 31 after the assembly has been coated, it will be evident that the major portion of the capillary walls are defined by the internal porous structure of the face 13.
- fluid forced into the chamber 15, after its temporary seal is removed is adapted to flow along the porous internal *sfiucture ofthe"annulaflwall 11 and face/13 to the capillaries--31, asshown-by the-arrows 33 and 35 in Figs. 4 and 5, and is confined to its path by the impervious exposed surfaces 29 on either side of the porous internal str uc'tu're.
- the walls 17-and 19 of the chamber are preferably' sinteredsimultaneously with the wall and face of the spinneret since forming these elements as a unit separate-fro'm the 'spinneretbody requires extreme care *to' prevent blocking -of theporous structure of the wall 11 at the point of connection of the-walls 11 and 19.
- the fluid is forced by any suitable manner, not shown, through" the inlet opening 21 in'to the'chamb'er 15.
- Sufiic'ient pressure ' is 'employedto' force the fluid as above "-described to the capillary walls so -as;to"flu'sh the sameof anyforeign matter.
- otherflu'ids' may be forced into the chamber 15 and-caused to flow along the wall-11 and the face 13 to-the capillaries, and impart-to the filament-forming solutions extruded therethrough, any desirable finish or color.
- the additive fiu id can be changed whendesired without in any way stopping or altering the extrusion of the filament-forming material-through the spinneret'capillaries, andthus the spinneret provides excellent flexibility when filaments of various characteristics are-desired.
- I claim: 1 A method of producing a spi'nn'eret for usein-making'filaments including the steps'of forming a cup-shaped 'member having a porous fluid permeable structure, cover- :ing an exposed portion of the fluid permeable structure, "applying a fluid impermeable coating on the remaining "exposed surfaces of the member to confine the" fluid permeable structure of said member betweenapair of lessees-1.
- tion of said member may permeate through the confined portion of the porousstructure and at least surface-treat securing an annular coverto the trough over its open end, applying a fluid impermeable coating on exposed surfaces of the member toconfine.
- the porous structure of said member between a pair of fluid impermeable surfaces, and perforating a coated portion of the member with a plurality'of apertures extending in adirection approximately parallel to its axis whereby liquidfrom sa'id channel-shaped -trough' may permeate through the confined porous Structure of said member and pass through the walls ofthe apertures to flush the same.
- porous fluid permeable structure is formed by sintering metal powders under pressure.
- a method of producing a. self-cleaning spinneret for use in making filaments including the steps of form- .ing a-cup-likemembcr having a porous fluid permeable structure, applying an impermeable coating on exposed surfaces ofihe .member to confine the fluid permeable structure of-said member between a pair of fluid impermeable surfaces and perforating the coated member 'with' a pluralityof extrusion aperturesextending in'a direction approximatelyparallel to its axis whereby liquid fluid impermeable surfaces, and perforating acoated portion of the member with a plurality of apertures extending in a dir'ectionapproximately parallel to its axis whereby liquid delivered through the uncoated por- -delivercd tothe confined fluid permeable structure of said member flows therethrough to the walls of the apertures for atleast surface-treating filament-forming material 'as it is extruded.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Textile Engineering (AREA)
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
Description
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US509349A US3056163A (en) | 1955-05-18 | 1955-05-18 | Spinneret |
US646098A US2932084A (en) | 1955-05-18 | 1957-03-14 | Method of making spinnerets |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US509349A US3056163A (en) | 1955-05-18 | 1955-05-18 | Spinneret |
US646098A US2932084A (en) | 1955-05-18 | 1957-03-14 | Method of making spinnerets |
Publications (1)
Publication Number | Publication Date |
---|---|
US2932084A true US2932084A (en) | 1960-04-12 |
Family
ID=27056515
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US509349A Expired - Lifetime US3056163A (en) | 1955-05-18 | 1955-05-18 | Spinneret |
US646098A Expired - Lifetime US2932084A (en) | 1955-05-18 | 1957-03-14 | Method of making spinnerets |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US509349A Expired - Lifetime US3056163A (en) | 1955-05-18 | 1955-05-18 | Spinneret |
Country Status (1)
Country | Link |
---|---|
US (2) | US3056163A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3285631A (en) * | 1963-06-05 | 1966-11-15 | James R Stolpmann | Indium coated o-ring seal |
US3670069A (en) * | 1969-09-15 | 1972-06-13 | Itt | Process for forming hydroxyethyl cellulose fibers having high water absorption and high water retention properties |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3215760A (en) * | 1962-11-27 | 1965-11-02 | Du Pont | Process of a voiding gel particles during extrusion by removal of air from the filter pack prior to spinning |
US3304577A (en) * | 1965-06-18 | 1967-02-21 | Lambert H Mott | Spinnerette disk for extrusion of synthetic polymer fibers |
GB1193314A (en) * | 1966-10-24 | 1970-05-28 | Asahi Chemical Ind | Funnel Spinning of Viscose Rayon Filaments |
US3994654A (en) * | 1975-01-02 | 1976-11-30 | Monsanto Company | Die for extruding thermoplastic sheets |
DE2713601C2 (en) * | 1977-03-28 | 1983-09-01 | Akzo Gmbh, 5600 Wuppertal | Device for preparing the exit surface of spinnerets |
DE2919331C2 (en) * | 1979-05-14 | 1986-02-13 | Akzo Gmbh, 5600 Wuppertal | Spinneret with device for the continuous application of spin finish oil to the exit surface |
DE3163504D1 (en) * | 1980-08-18 | 1984-06-14 | Teijin Ltd | Process and molding apparatus for producing a fibrous assembly by melt extrusion |
JPS59163422A (en) * | 1983-03-09 | 1984-09-14 | Kashima Sekiyu Kk | Spinning of petroleum mesophase |
US5882690A (en) * | 1996-04-24 | 1999-03-16 | Mitsubishi Rayon Co., Ltd. | Resin forming nozzle device and resin forming method using same |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1604216A (en) * | 1925-04-02 | 1926-10-26 | Clement S Brainin | Method of making spinnerets |
US2093800A (en) * | 1934-08-08 | 1937-09-21 | Speer Carbon Company | Bearing and method of manufacturing same |
US2307034A (en) * | 1939-08-23 | 1943-01-05 | Armstrong Cork Co | Method and apparatus for the extrusion of cork compositions |
Family Cites Families (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1654936A (en) * | 1926-03-23 | 1928-01-03 | Baker & Co Inc | Method of making spinnerets |
DE637212C (en) * | 1934-05-27 | 1936-10-24 | I G Farbenindustrie Akt Ges | Spinneret for making twisted artificial threads |
US2233987A (en) * | 1938-03-17 | 1941-03-04 | Nixon Nitration Works | Machine and method for making striped plastic bodies |
US2324397A (en) * | 1941-06-04 | 1943-07-13 | Du Pont | Method for production of continuous structures |
US2377810A (en) * | 1942-10-30 | 1945-06-05 | Dow Chemical Co | Crinkled polymeric vinylidene chloride fibers |
US2450457A (en) * | 1945-11-09 | 1948-10-05 | Gen Tire & Rubber Co | Process and apparatus for coagulating a coagulable fluid |
BE477016A (en) * | 1946-12-02 | |||
US2597553A (en) * | 1948-09-17 | 1952-05-20 | Donald J Weber | Apparatus for lubricating plastic materials undergoing extrusion |
DE809230C (en) * | 1948-12-03 | 1951-07-26 | Degussa | Spinneret for the production of rayon, especially according to the viscose process |
GB673654A (en) * | 1949-02-23 | 1952-06-11 | British Celanese | Improvements in the manufacture of water-soluble filaments, films and the like from cellulose ethers |
US2588584A (en) * | 1949-11-12 | 1952-03-11 | Celanese Corp | Spinning artificial filamentary materials |
US2677148A (en) * | 1950-06-02 | 1954-05-04 | American Viscose Corp | Spinneret |
US2702230A (en) * | 1950-11-24 | 1955-02-15 | Celanese Corp | Cellulose acetate spinning process |
-
1955
- 1955-05-18 US US509349A patent/US3056163A/en not_active Expired - Lifetime
-
1957
- 1957-03-14 US US646098A patent/US2932084A/en not_active Expired - Lifetime
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US1604216A (en) * | 1925-04-02 | 1926-10-26 | Clement S Brainin | Method of making spinnerets |
US2093800A (en) * | 1934-08-08 | 1937-09-21 | Speer Carbon Company | Bearing and method of manufacturing same |
US2307034A (en) * | 1939-08-23 | 1943-01-05 | Armstrong Cork Co | Method and apparatus for the extrusion of cork compositions |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3285631A (en) * | 1963-06-05 | 1966-11-15 | James R Stolpmann | Indium coated o-ring seal |
US3670069A (en) * | 1969-09-15 | 1972-06-13 | Itt | Process for forming hydroxyethyl cellulose fibers having high water absorption and high water retention properties |
Also Published As
Publication number | Publication date |
---|---|
US3056163A (en) | 1962-10-02 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
AS | Assignment |
Owner name: JOHN HANCOCK MUTUAL LIFE INSURANCE COMPANY JOHN HA Free format text: AS SECURITY FOR INDEBTEDNESS RECITED ASSIGNOR GRANTS , BARGAINS, MORTGAGES, PLEDGES, SELLS AND CREATES A SECURITY INTEREST WITH A LIEN UNDER SAID PATENTS, SUBJECT TO CONDITIONS RECITED.;ASSIGNOR:AVTEX FIBERS INC. A NY CORP.;REEL/FRAME:003959/0219 Effective date: 19810301 Owner name: PAUL REVERE LIFE INSURANCE COMPANY THE C/O THE PAU Free format text: AS SECURITY FOR INDEBTEDNESS RECITED ASSIGNOR GRANTS , BARGAINS, MORTGAGES, PLEDGES, SELLS AND CREATES A SECURITY INTEREST WITH A LIEN UNDER SAID PATENTS, SUBJECT TO CONDITIONS RECITED.;ASSIGNOR:AVTEX FIBERS INC. A NY CORP.;REEL/FRAME:003959/0219 Effective date: 19810301 Owner name: BALBOA INSURANCE COMPANY C/O THE PAUL REVERE EQUIT Free format text: AS SECURITY FOR INDEBTEDNESS RECITED ASSIGNOR GRANTS , BARGAINS, MORTGAGES, PLEDGES, SELLS AND CREATES A SECURITY INTEREST WITH A LIEN UNDER SAID PATENTS, SUBJECT TO CONDITIONS RECITED.;ASSIGNOR:AVTEX FIBERS INC. A NY CORP.;REEL/FRAME:003959/0219 Effective date: 19810301 Owner name: NEW ENGLAND MUTUAL LIFE INSURANCE COMPANY 501 BOYL Free format text: AS SECURITY FOR INDEBTEDNESS RECITED ASSIGNOR GRANTS , BARGAINS, MORTGAGES, PLEDGES, SELLS AND CREATES A SECURITY INTEREST WITH A LIEN UNDER SAID PATENTS, SUBJECT TO CONDITIONS RECITED.;ASSIGNOR:AVTEX FIBERS INC. A NY CORP.;REEL/FRAME:003959/0219 Effective date: 19810301 Owner name: PROVIDENT ALLIANCE LIFE INSURANCE COMPANY C/O THE Free format text: AS SECURITY FOR INDEBTEDNESS RECITED ASSIGNOR GRANTS , BARGAINS, MORTGAGES, PLEDGES, SELLS AND CREATES A SECURITY INTEREST WITH A LIEN UNDER SAID PATENTS, SUBJECT TO CONDITIONS RECITED.;ASSIGNOR:AVTEX FIBERS INC. A NY CORP.;REEL/FRAME:003959/0219 Effective date: 19810301 Owner name: KELLOGG CREDIT CORPORATION A DE CORP. Free format text: AGREEMENT WHEREBY SAID HELLER AND RAYONIER RELEASES ALL MORTGAGES AND SECURITY INTERESTS HELD BY AVTEX ON APRIL 28, 1978, AND JAN. 11, 1979, RESPECTIVELY AND ASSIGNS ITS ENTIRE INTEREST IN SAID MORT-AGAGE AGREEMENT TO ASSIGNEE;ASSIGNORS:WALTER E. HELLER & COMPANY, INC. A NY CORP.;ITT RAYONIER INCORPORATED, A DE CORP.;AVTEX FIBERS INC., A NY CORP.;REEL/FRAME:003959/0350 Effective date: 19800326 Owner name: WALTER E. HELLER & COMPANY, INC., A CORP. OF DEL. Free format text: AGREEMENT WHEREBY AETNA RELEASES AVTEX FROM ALL MORTAGES AND SECURITY INTERESTS IN SAID INVENTIONS AS OF JANUARY 11,1979, AND ASSIGNS TO ASSIGNEE THE ENTIRE INTEREST IN SAID MORTAGE AGREEMENT TO ASSIGNEE;ASSIGNORS:AETNA BUSINESS CREDIT, INC., A CORP. OF N.Y.;AVTEX FIBERS, INC, A CORP. OF NY;KELLOGG CREDIT CORP., A CORP. OF DEL.;REEL/FRAME:003959/0250 Effective date: 19800326 Owner name: WESTERN AND SOUTHERN LIFE INSURANCE COMPANY THE C/ Free format text: AS SECURITY FOR INDEBTEDNESS RECITED ASSIGNOR GRANTS , BARGAINS, MORTGAGES, PLEDGES, SELLS AND CREATES A SECURITY INTEREST WITH A LIEN UNDER SAID PATENTS, SUBJECT TO CONDITIONS RECITED.;ASSIGNOR:AVTEX FIBERS INC. A NY CORP.;REEL/FRAME:003959/0219 Effective date: 19810301 |