US2924518A - Zirconium alloys - Google Patents
Zirconium alloys Download PDFInfo
- Publication number
- US2924518A US2924518A US746605A US74660558A US2924518A US 2924518 A US2924518 A US 2924518A US 746605 A US746605 A US 746605A US 74660558 A US74660558 A US 74660558A US 2924518 A US2924518 A US 2924518A
- Authority
- US
- United States
- Prior art keywords
- zirconium
- alloy
- alloys
- weight
- zircaloy
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910001093 Zr alloy Inorganic materials 0.000 title description 7
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 14
- 229910052726 zirconium Inorganic materials 0.000 claims description 13
- 239000012535 impurity Substances 0.000 claims description 9
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 6
- 229910052750 molybdenum Inorganic materials 0.000 claims description 6
- 239000011733 molybdenum Substances 0.000 claims description 6
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 5
- 229910052804 chromium Inorganic materials 0.000 claims description 5
- 239000011651 chromium Substances 0.000 claims description 5
- 229910045601 alloy Inorganic materials 0.000 description 25
- 239000000956 alloy Substances 0.000 description 25
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 12
- 238000012360 testing method Methods 0.000 description 7
- 229910002092 carbon dioxide Inorganic materials 0.000 description 6
- 239000001569 carbon dioxide Substances 0.000 description 6
- 238000005260 corrosion Methods 0.000 description 6
- 230000007797 corrosion Effects 0.000 description 6
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 5
- 229910052802 copper Inorganic materials 0.000 description 5
- 239000010949 copper Substances 0.000 description 5
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 239000010936 titanium Substances 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229910000599 Cr alloy Inorganic materials 0.000 description 1
- 241001676573 Minium Species 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- PRVKLYVQRIDKIC-UHFFFAOYSA-N [Mo].[Cu].[Zr] Chemical compound [Mo].[Cu].[Zr] PRVKLYVQRIDKIC-UHFFFAOYSA-N 0.000 description 1
- QZLJNVMRJXHARQ-UHFFFAOYSA-N [Zr].[Cr].[Cu] Chemical compound [Zr].[Cr].[Cu] QZLJNVMRJXHARQ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000000788 chromium alloy Substances 0.000 description 1
- 239000012612 commercial material Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 230000000266 injurious effect Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 238000010791 quenching Methods 0.000 description 1
- 230000000171 quenching effect Effects 0.000 description 1
- 238000003303 reheating Methods 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000005496 tempering Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C16/00—Alloys based on zirconium
Definitions
- Zirconium alloys in accordance with the present invention contain 0.51.5% by weight of copper, and from 0.25-1.5% by weight of molybdenum or chromium, the
- Example 2Cu, 1.0%; M0, 1.5%; remainder Zr The following mechanical properties of the improved alloys in comparison with zirconium and Zircaloy-2 are as follows:
- V.P.N. Vickers Pyramid Number
- Alloy 3 30 300 3,000 secs. secs. secs. secs.
- Example 1 alloy was slightlyhardcr for the longest-period of load application, and slightly less hard for the shorter periods of 5 load application than Zircalo'y-Z.”
- Specimens of Example 1 alloy were about 20% better, and of Example 2 alloy about better than those of Zircaloy-2," the percentage elongation of specimens of Example l was about the same as that of Zircaloy-Z, while that of Example 2 was about two-thirds that of Zircaloy 2. This improvement was increased when the specimens were tested at 375 C.
- Example 1 and Example 2 are 0.012386 cm.- and 0.015126 cm.- respectively.
- the high temperature mechanical properties of zirconium-copper-molybdenum and zirconium-copper-chromium alloys mentioned above can be further improved by heat treatment, which consists of heating the alloy to a temperature of 850 C. to 950" C. and maintaining the temperature for a specified time before quenching to reduce the temperature of the alloy rapidly. This treatment may then be followed by a tempering treatment which consists of reheating the alloy for a specified time at a temperature below 850 C.
- the constituents of the alloy should be melted in a vacuum arc furnace.
- the alloys of the invention can be readily fabricated by conventional methods.
- Impurities in the base zirconium sponge should be kept to a minimum.
- the most deleterious impurities from the corrosion resistance point of view are. aluminium, silicon, hydrogen, xygenr i s n. a it ni m. l minium should be kept below 150 parts per million, whilst nitrogen and'titanium are not so injurious, and in the latter case, and titanium content may be as high as 1,000
- An alloy consisting of 0.5 to 1.5% by weight of copper, 0.25 to 1.5% by weight of a metal selected from the group consisting of chromium and molybdenum, and the remainder zirconium except for unavoidable impurities.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
- Furnace Charging Or Discharging (AREA)
- Conductive Materials (AREA)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB23758/57A GB829668A (en) | 1957-07-26 | 1957-07-26 | Improvements relating to zirconium alloys |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2924518A true US2924518A (en) | 1960-02-09 |
Family
ID=10200849
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US746605A Expired - Lifetime US2924518A (en) | 1957-07-26 | 1958-07-07 | Zirconium alloys |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US2924518A (sk) |
| BE (1) | BE568934A (sk) |
| DE (1) | DE1118976B (sk) |
| FR (1) | FR1199996A (sk) |
| GB (1) | GB829668A (sk) |
| IT (1) | IT594672A (sk) |
| NO (1) | NO95039A (sk) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3072478A (en) * | 1958-10-16 | 1963-01-08 | Associated Electrical Ind Rugb | Zirconium alloys |
| US3218162A (en) * | 1962-03-16 | 1965-11-16 | Ass Elect Ind | Process for making zirconium alloys |
| US3303025A (en) * | 1962-12-19 | 1967-02-07 | Ass Elect Ind | Zirconium alloys |
| US3645800A (en) * | 1965-12-17 | 1972-02-29 | Westinghouse Electric Corp | Method for producing wrought zirconium alloys |
| US5654993A (en) * | 1993-06-30 | 1997-08-05 | Abb Atom Ab | Fuel element for pressurized--water reactor with guide tubes finally heat-treated in two steps |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1454541A (fr) * | 1965-08-27 | 1966-02-11 | Commissariat Energie Atomique | Alliage de zirconium |
| FR2334763A1 (fr) * | 1975-12-12 | 1977-07-08 | Ugine Aciers | Procede permettant d'ameliorer la tenue a chaud du zirconium et de ses alliages |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2705674A (en) * | 1954-02-18 | 1955-04-05 | Chubb Walston | Ternary zirconium alloys |
-
0
- NO NO95039D patent/NO95039A/no unknown
- IT IT594672D patent/IT594672A/it unknown
- BE BE568934D patent/BE568934A/xx unknown
-
1957
- 1957-07-26 GB GB23758/57A patent/GB829668A/en not_active Expired
-
1958
- 1958-07-07 US US746605A patent/US2924518A/en not_active Expired - Lifetime
- 1958-07-21 DE DEM38334A patent/DE1118976B/de active Pending
- 1958-07-24 FR FR1199996D patent/FR1199996A/fr not_active Expired
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2705674A (en) * | 1954-02-18 | 1955-04-05 | Chubb Walston | Ternary zirconium alloys |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3072478A (en) * | 1958-10-16 | 1963-01-08 | Associated Electrical Ind Rugb | Zirconium alloys |
| US3218162A (en) * | 1962-03-16 | 1965-11-16 | Ass Elect Ind | Process for making zirconium alloys |
| US3303025A (en) * | 1962-12-19 | 1967-02-07 | Ass Elect Ind | Zirconium alloys |
| US3645800A (en) * | 1965-12-17 | 1972-02-29 | Westinghouse Electric Corp | Method for producing wrought zirconium alloys |
| US5654993A (en) * | 1993-06-30 | 1997-08-05 | Abb Atom Ab | Fuel element for pressurized--water reactor with guide tubes finally heat-treated in two steps |
| US5677937A (en) * | 1993-06-30 | 1997-10-14 | Abb Atom Ab | Fuel element for pressurized-water reactor with guide tubes finally heat-treated in two steps |
Also Published As
| Publication number | Publication date |
|---|---|
| DE1118976B (de) | 1961-12-07 |
| GB829668A (en) | 1960-03-02 |
| IT594672A (sk) | |
| FR1199996A (fr) | 1959-12-17 |
| BE568934A (sk) | |
| NO95039A (sk) |
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