US2920972A - Glass and the method of making it - Google Patents

Glass and the method of making it Download PDF

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Publication number
US2920972A
US2920972A US513914A US51391455A US2920972A US 2920972 A US2920972 A US 2920972A US 513914 A US513914 A US 513914A US 51391455 A US51391455 A US 51391455A US 2920972 A US2920972 A US 2920972A
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weight
bao
oxide
glass
pbo
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Expired - Lifetime
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US513914A
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English (en)
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Godron Yves
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Compagnie de Saint Gobain SA
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Manufactures De Glaces Et Prod
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M103/00—Lubricating compositions characterised by the base-material being an inorganic material
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/12—Silica-free oxide glass compositions
    • C03C3/16—Silica-free oxide glass compositions containing phosphorus
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/12—Silica-free oxide glass compositions
    • C03C3/16—Silica-free oxide glass compositions containing phosphorus
    • C03C3/17—Silica-free oxide glass compositions containing phosphorus containing aluminium or beryllium
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/12—Silica-free oxide glass compositions
    • C03C3/16—Silica-free oxide glass compositions containing phosphorus
    • C03C3/19—Silica-free oxide glass compositions containing phosphorus containing boron
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/12—Esters of monohydric alcohols or phenols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/02—Monocarboxylic acids having less than ten carbon atoms, Derivatives thereof
    • C08F20/10—Esters
    • C08F20/40—Esters of unsaturated alcohols, e.g. allyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F20/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide or nitrile thereof
    • C08F20/62—Monocarboxylic acids having ten or more carbon atoms; Derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/20—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds unconjugated
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2201/00—Inorganic compounds or elements as ingredients in lubricant compositions
    • C10M2201/12—Glass
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/24—Metal working without essential removal of material, e.g. forming, gorging, drawing, pressing, stamping, rolling or extruding; Punching metal
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/241—Manufacturing joint-less pipes
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/242—Hot working
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/243—Cold working
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/245—Soft metals, e.g. aluminum
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/246—Iron or steel
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2040/00—Specified use or application for which the lubricating composition is intended
    • C10N2040/20—Metal working
    • C10N2040/244—Metal working of specific metals
    • C10N2040/247—Stainless steel
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S71/00—Chemistry: fertilizers
    • Y10S71/903—Soil conditioner
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T29/00—Metal working
    • Y10T29/49—Method of mechanical manufacture
    • Y10T29/4981—Utilizing transitory attached element or associated separate material
    • Y10T29/49812—Temporary protective coating, impregnation, or cast layer

Definitions

  • This invention comprises a discovery that the glass compositions hereinafter described maintain a lubricating viscosity in the temperature range from about 300 C. to about 550 C. and may be used as lubricants for drawing metals and alloys having low melting points, especially aluminum and its alloys, for which the temperature reached by the lubricant during working or drawing falls in this range.
  • the fritting temperature of the novel glasses described herein is between about 280 C. and 440 c.
  • the speed of drawing may be increased to the order of 15 to 50 m. per minute, in particular in the drawing of aluminum and its alloys.
  • the gross peripheral grains are not produced after subsequent thermal treatment.
  • the axial recess is eliminated.
  • An especial advantage is that .theseglasses can be removed from the surface to increase its chemical and weather resistance.
  • the P 0 B 0 and Alumina may or may not contain A1 0 but if it is present the total amount of P 0 B 0 and Alumina should not materially exceed 66%. Thus the P 0 may attain about 66% when B 0 and A1 0 are lacking.
  • the A1 0 ranges from O to a maximum of 16 percent.
  • PbO and/or BaO contain 9-13% of the group composed of PbO, BaO, and the other alkaline-earth oxides, PbO and/or BaO always being in preponderant amount.
  • PbO and/or BaO are preferred but a small percentage of them may be replaced by at least one other alkaline earth oxide, e.g. lime or magnesia.
  • alkali metal oxides for example, potassium oxide or lithium oxide.
  • a small amount of the alkali metal oxide eg. 5% calculated as Na O, may be replaced by ZnO.
  • the ratio of the total weight of alkali metal oxide (calculated as Na O) and ZnO to the total weight of PhD and BaO and other alkaline earth oxide is from 3 minimum to maximum.
  • the lead oxide may be kept below 5% if it isnecessary or desired.
  • Example 1 A mixture of 109.5 parts by weight of hydrated trisodium phosphate, 64 parts of monoammonium phosphate, 5.15 parts of red lead oxide, and 10.7 parts of barium carbonate are melted at about 900 C. in a silica crucible and pouredon'a table, producing a slightly opalescent glass without any tendency to devitrify. Its composition by weight analysis is:
  • composition of the vitrifiable mixture, and the analysis of the finished glass are given in the following table:
  • composition of the Vitrifiable Material Chemical Composition of the Corresponding Glass P B10; A120: PbO BaO ZnO N810 81.3 parts by weight of hydrated trisodium phosphate containing 22.1% by weight of P10 and 31.8% by weight of Nero.
  • the glass is pulverized by being ground, and it is then passed to a 55 screen, which has the openings between the wires measuring from .299 to .331 mm. on a side.
  • the glass which passes through the 55 screen is then passed to a 100 screen, which has the openings between the wires lying between .152 and .168 mm. on a side.
  • the material which remains upon the 100 screen is that employed in making the disc.
  • a stainless steel mold having a cavity 145 mm. in diameter and 3 mm. in depth was filled with such material.
  • the mold and its contents were introduced into an electric resistance furnace, where it was held at a temperature of 285 C. for minutes. Atthe end of that time the mold was withdrawn from the furnace.
  • the product thus treated in the mold was a disc made up of fritted grains, that is, the grains were bonded to each other but remaine distinct.
  • Example 2 The following batch is vitrified as in Example 1 but at 920 0.:
  • Example 1 Parts by weight After pulverizing to .l5-.30 mm. a disk 145 x 3 mm. was made and molded as in Example 1. Said disc was sintered at 440 C. in 25 minutes.
  • Example 3 g It being desired to extrude an aluminum alloy containing Cu 1.6 parts by weight,'Mn 0.2, Mg 2.5, Cr 0.3, Zn 5.6, a disk was made with a granulated glass containing by weight:
  • the disc After pulverizing to .15-30 mm. the disc was made and molded as in Example 1. Said disc was fritted at 370 C. in 25 minutes. The speed of drawing the alloy through the die, the plate made by fritting having been placed between die and ingot before the drawing, was 18 meters per minute. The product had no axial recess at the end and later thermal treatments showed no peripheral gross grains.
  • the alumina confers on glasses in accordance with the invention a hygroscopicity which decreases as the proportion of alumina increases.
  • the alumina raises the temperature of fritting and improves resistance to chemicals. and weather.
  • the lead oxide and baryta increase the fusibility.
  • alkali lowers the fritting temperature but we have found that an increase in alkali beyond the range indicated may produce products that tend to devitrify on cooling and even to produce pro-ductsthat vitrify with difiiculty.
  • P205+B20 50% minimum to 66% maximum.
  • PbO BaO other alkaline earth oxide Alkali metal oxide (calculated as NazO) ZnO Alkali metal oxide (calcu lated as N-a20) +Zn0--- Alkali metal oxide (calculated as NaeO) ZnO/ Pb0+BaO+other alkaline earth oxides 2/1 minimum to 3.5/1 maximum.
  • PbO+BaO are preponderant over other alkaline earth oxides, said other alkaline earth oxides may be 0.
  • a glass according to claim 11 in which a relatively small part of the percentage of BaO and PbO is replaced by magnesium oxide, and the ratio of weight of alkali oxide, calculated as Na O, to the total weight of BaO and PbO and MgO being between 2 and 3.5.
  • I 17 A glass according to claim 10 in which a relatively small part of the percentage of BaO is replaced by magnesium oxide, and the ratio of the weight of alkali oxide, calculated as Na O, to the total weight of BaO and MgO being between 2 and 3.5.
  • a glass according to claim 11 in which a small amount of alkali oxide calculated as Na O,- at most 5%, is replaced by ZnO, and the ratio of the total weight of alkali oxide, calculated as Na O, and ZnO to the total weight of BaO and PbO being between 2-and 3.5.
  • a glass according to claim 9 in which a small amount of alkali oxide calculated as Na O, at most 5%, is replaced by ZnO, and the ratio of the total weight of alkali oxide, calculated as Na O, and ZnO to the weight of PbO beingbetween 2 and 3.5.
  • a glass according to claim 10 in which a small amount of alkali oxidecalculated as Na O, at most 5 is replaced by ZnO, and the ratio of the total weight of alkali oxide, calculated as Na O, and ZnO to the weight of BaO being between 2 and 3.5.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Glass Compositions (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
US513914A 1954-05-26 1955-06-07 Glass and the method of making it Expired - Lifetime US2920972A (en)

Applications Claiming Priority (1)

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FR1100960X 1954-05-26

Publications (1)

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US2920972A true US2920972A (en) 1960-01-12

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US513914A Expired - Lifetime US2920972A (en) 1954-05-26 1955-06-07 Glass and the method of making it

Country Status (7)

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US (1) US2920972A (ja)
BE (2) BE538888A (ja)
CH (2) CH334653A (ja)
DE (2) DE1100960B (ja)
FR (4) FR1105938A (ja)
GB (2) GB786381A (ja)
NL (2) NL197538A (ja)

Cited By (23)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3067135A (en) * 1959-03-04 1962-12-04 Sulzer Frers S A Bearing comprising polytetrafluoroethylene and phosphate glass
US3067655A (en) * 1959-09-08 1962-12-11 Benjamin S Miller Artificial ice and snow and methods of making the same
US3215543A (en) * 1960-12-08 1965-11-02 Saint Gobain Vitreous body including mica in finely divided state
US3218255A (en) * 1960-01-08 1965-11-16 Glacier Co Ltd Bearing composition containing polytetrafluoroethylene and ammonium manganese orthophosphate
US3248234A (en) * 1955-02-12 1966-04-26 Saint Gobain Glass compositions
US3253934A (en) * 1956-05-25 1966-05-31 Saint Gobain Vitreous compositions of matter
US3253933A (en) * 1955-02-12 1966-05-31 Saint Gobain Glass compositions
US3300670A (en) * 1962-02-28 1967-01-24 Table xiv
US3464248A (en) * 1966-08-19 1969-09-02 Mannesmann Meer Ag Method and apparatus for producing extrusions
US3485646A (en) * 1965-10-21 1969-12-23 Ppg Industries Inc Glass compositions
US3885973A (en) * 1972-06-08 1975-05-27 Ici Ltd Li{hd 2{b O-ZnO-P{HD 2{B O{HD 5{B -glass
US3926649A (en) * 1971-10-15 1975-12-16 Ici Ltd Borosphosphate glass compositions with high water resistance and low softening point
US3930833A (en) * 1973-10-18 1976-01-06 Ferro Corporation Micronutrient metal-containing phosphate glasses
US3935018A (en) * 1972-04-27 1976-01-27 Imperial Chemical Industries Limited Glasses
US3958973A (en) * 1973-10-18 1976-05-25 Ferro Corporation Micronutrient metal-containing phosphate glasses
US3964919A (en) * 1972-02-14 1976-06-22 Imperial Chemical Industries Limited Glass compositions
US3979322A (en) * 1973-04-09 1976-09-07 Nikolai Efimovich Alexeev Phosphate glass for laser use
US3989532A (en) * 1973-02-21 1976-11-02 Imperial Chemical Industries Limited Anti-misting inorganic oxide glass compositions
US4026714A (en) * 1975-09-19 1977-05-31 Imperial Chemical Industries Limited Phosphate glass compositions
US4076541A (en) * 1976-03-22 1978-02-28 Owens-Illinois, Inc. Glasses suitable for laser application, glass lasers, and method for making same
US4110002A (en) * 1977-03-02 1978-08-29 Gte Laboratories Incorporated Optical fibers formed of aluminum borophosphate glass compositions
US4202700A (en) * 1979-05-02 1980-05-13 The United States Of America As Represented By The United States Department Of Energy Glassy composition for hermetic seals
EP0024891A1 (en) * 1979-08-30 1981-03-11 International Standard Electric Corporation Process for liberating metal ions from a water soluble glass at a controlled rate

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1002612A (en) * 1960-12-09 1965-08-25 Ian Griffith Slater Lubricant for use in the hot extrusion of metals and metal alloys
DE1257334B (de) * 1961-05-05 1967-12-28 Hydraulik Gmbh Schmiermittel-Plattenvorlage zum Auspressen von Kohlenstoff-Stahlbloecken aus Strangpressen
US3255139A (en) * 1962-03-21 1966-06-07 Bayer Ag Preparation of n-(alkenyloxymethylene) acrylamide copolymers and products thereof
NL8104778A (nl) * 1981-10-22 1983-05-16 Philips Nv Met precisie geperste optische onderdelen uit glas en daarvoor geschikt glas.
FR2542228B1 (fr) * 1983-03-10 1985-08-02 Cegedur Procede de frittage sous pression de poudres d'alliages d'aluminium

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1016352A (en) * 1908-07-09 1912-02-06 Charles Nicholas Meriwether Phosphate and the method of making same.
US1654404A (en) * 1924-12-23 1927-12-27 Stockholders Syndicate Acid metal phosphate and process of making same
US2192939A (en) * 1937-05-17 1940-03-12 Owens Corning Fiberglass Corp Agricultural application of glass wool

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2273891A (en) * 1939-02-18 1942-02-24 Pittsburgh Plate Glass Co Method of polymerizing polymerizable materials containing more than one polymerizable grouping
GB658426A (en) * 1947-09-04 1951-10-10 Borden Co Improvements in or relating to a polymerisation process and products resulting therefrom

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1016352A (en) * 1908-07-09 1912-02-06 Charles Nicholas Meriwether Phosphate and the method of making same.
US1654404A (en) * 1924-12-23 1927-12-27 Stockholders Syndicate Acid metal phosphate and process of making same
US2192939A (en) * 1937-05-17 1940-03-12 Owens Corning Fiberglass Corp Agricultural application of glass wool

Cited By (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3248234A (en) * 1955-02-12 1966-04-26 Saint Gobain Glass compositions
US3253933A (en) * 1955-02-12 1966-05-31 Saint Gobain Glass compositions
US3253934A (en) * 1956-05-25 1966-05-31 Saint Gobain Vitreous compositions of matter
US3481749A (en) * 1956-05-25 1969-12-02 Saint Gobain Vitreous compositions of matter
US3067135A (en) * 1959-03-04 1962-12-04 Sulzer Frers S A Bearing comprising polytetrafluoroethylene and phosphate glass
US3067655A (en) * 1959-09-08 1962-12-11 Benjamin S Miller Artificial ice and snow and methods of making the same
US3218255A (en) * 1960-01-08 1965-11-16 Glacier Co Ltd Bearing composition containing polytetrafluoroethylene and ammonium manganese orthophosphate
US3215543A (en) * 1960-12-08 1965-11-02 Saint Gobain Vitreous body including mica in finely divided state
US3300670A (en) * 1962-02-28 1967-01-24 Table xiv
US3485646A (en) * 1965-10-21 1969-12-23 Ppg Industries Inc Glass compositions
US3464248A (en) * 1966-08-19 1969-09-02 Mannesmann Meer Ag Method and apparatus for producing extrusions
US3926649A (en) * 1971-10-15 1975-12-16 Ici Ltd Borosphosphate glass compositions with high water resistance and low softening point
US3964919A (en) * 1972-02-14 1976-06-22 Imperial Chemical Industries Limited Glass compositions
US3935018A (en) * 1972-04-27 1976-01-27 Imperial Chemical Industries Limited Glasses
US3885973A (en) * 1972-06-08 1975-05-27 Ici Ltd Li{hd 2{b O-ZnO-P{HD 2{B O{HD 5{B -glass
US3989532A (en) * 1973-02-21 1976-11-02 Imperial Chemical Industries Limited Anti-misting inorganic oxide glass compositions
US3979322A (en) * 1973-04-09 1976-09-07 Nikolai Efimovich Alexeev Phosphate glass for laser use
US3930833A (en) * 1973-10-18 1976-01-06 Ferro Corporation Micronutrient metal-containing phosphate glasses
US3958973A (en) * 1973-10-18 1976-05-25 Ferro Corporation Micronutrient metal-containing phosphate glasses
US4026714A (en) * 1975-09-19 1977-05-31 Imperial Chemical Industries Limited Phosphate glass compositions
US4076541A (en) * 1976-03-22 1978-02-28 Owens-Illinois, Inc. Glasses suitable for laser application, glass lasers, and method for making same
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US4202700A (en) * 1979-05-02 1980-05-13 The United States Of America As Represented By The United States Department Of Energy Glassy composition for hermetic seals
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Also Published As

Publication number Publication date
FR1107913A (fr) 1956-01-06
BE538888A (ja)
DE1100960B (de) 1961-03-02
BE538225A (ja)
DE1102351B (de) 1961-03-16
FR67841E (fr) 1958-03-24
NL197538A (ja)
CH337996A (fr) 1959-04-30
FR67846E (fr) 1958-03-24
NL91245C (ja)
CH334653A (fr) 1958-12-15
GB786381A (en) 1957-11-20
GB774248A (en) 1957-05-08
FR1105938A (fr) 1955-12-09

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