US2815299A - Method of producing an adherent molybdenum coating on a metal substrate - Google Patents
Method of producing an adherent molybdenum coating on a metal substrate Download PDFInfo
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- US2815299A US2815299A US542498A US54249855A US2815299A US 2815299 A US2815299 A US 2815299A US 542498 A US542498 A US 542498A US 54249855 A US54249855 A US 54249855A US 2815299 A US2815299 A US 2815299A
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- Prior art keywords
- molybdenum
- coating
- adherent
- metal substrate
- hydrogen
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- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 title claims description 32
- 229910052750 molybdenum Inorganic materials 0.000 title claims description 32
- 239000011733 molybdenum Substances 0.000 title claims description 32
- 238000000576 coating method Methods 0.000 title claims description 24
- 239000011248 coating agent Substances 0.000 title claims description 22
- 229910052751 metal Inorganic materials 0.000 title claims description 19
- 239000002184 metal Substances 0.000 title claims description 19
- 239000000758 substrate Substances 0.000 title claims description 18
- 238000000034 method Methods 0.000 title claims description 15
- 230000001464 adherent effect Effects 0.000 title claims description 12
- 239000001257 hydrogen Substances 0.000 claims description 19
- 229910052739 hydrogen Inorganic materials 0.000 claims description 19
- 229910017052 cobalt Inorganic materials 0.000 claims description 14
- 239000010941 cobalt Substances 0.000 claims description 14
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 claims description 14
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical class [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 12
- PDKHNCYLMVRIFV-UHFFFAOYSA-H molybdenum;hexachloride Chemical compound [Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Mo] PDKHNCYLMVRIFV-UHFFFAOYSA-H 0.000 claims description 10
- GICWIDZXWJGTCI-UHFFFAOYSA-I molybdenum pentachloride Chemical compound Cl[Mo](Cl)(Cl)(Cl)Cl GICWIDZXWJGTCI-UHFFFAOYSA-I 0.000 claims description 8
- 238000009792 diffusion process Methods 0.000 claims description 7
- 230000005587 bubbling Effects 0.000 claims description 4
- 238000000151 deposition Methods 0.000 claims description 4
- 239000011261 inert gas Substances 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 14
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 10
- 229910000831 Steel Inorganic materials 0.000 description 7
- 229910052759 nickel Inorganic materials 0.000 description 7
- 239000010959 steel Substances 0.000 description 7
- 238000006722 reduction reaction Methods 0.000 description 6
- 229910052786 argon Inorganic materials 0.000 description 5
- 150000001805 chlorine compounds Chemical class 0.000 description 5
- 239000007789 gas Substances 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 4
- OHZZTXYKLXZFSZ-UHFFFAOYSA-I manganese(3+) 5,10,15-tris(1-methylpyridin-1-ium-4-yl)-20-(1-methylpyridin-4-ylidene)porphyrin-22-ide pentachloride Chemical compound [Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[Mn+3].C1=CN(C)C=CC1=C1C(C=C2)=NC2=C(C=2C=C[N+](C)=CC=2)C([N-]2)=CC=C2C(C=2C=C[N+](C)=CC=2)=C(C=C2)N=C2C(C=2C=C[N+](C)=CC=2)=C2N=C1C=C2 OHZZTXYKLXZFSZ-UHFFFAOYSA-I 0.000 description 3
- 239000012159 carrier gas Substances 0.000 description 2
- 238000007747 plating Methods 0.000 description 2
- 241001156002 Anthonomus pomorum Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000282320 Panthera leo Species 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 230000001419 dependent effect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000001627 detrimental effect Effects 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 238000007323 disproportionation reaction Methods 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000006698 induction Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 239000005078 molybdenum compound Substances 0.000 description 1
- 150000002752 molybdenum compounds Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/06—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of metallic material
- C23C16/08—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes characterised by the deposition of metallic material from metal halides
- C23C16/14—Deposition of only one other metal element
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C16/00—Chemical coating by decomposition of gaseous compounds, without leaving reaction products of surface material in the coating, i.e. chemical vapour deposition [CVD] processes
- C23C16/02—Pretreatment of the material to be coated
- C23C16/0272—Deposition of sub-layers, e.g. to promote the adhesion of the main coating
- C23C16/0281—Deposition of sub-layers, e.g. to promote the adhesion of the main coating of metallic sub-layers
Definitions
- This invention relates to coating and in particular to the coating of metal substrates with molybdenum.
- One object of the present invention is to produce adherent coatings of molybdenum on metal substrates.
- Another object of the invention is to provide uniform, adherent molybdenum coatings on the interior surfaces of hollow objects.
- the invention accordingly comprises the process involving the several steps and the relation and the order of one or more of such steps with respect to each of the others which are exemplified in the following detailed disclosure, and the scope of the application of which will be indicated in the claims.
- a uniform, adherent coating of molybdenum may be obtained on a metal substrate, particularly steel, by coating the metal substrate, prior to depositing molybdenum thereon, with a layer of cobalt or nickel which is capable of forming a diffusion bond with both the metal substrate and the molybdenum.
- a coating of molybdenum is then deposited on the thin cobalt or nickel layer by reducing a molybdenum compound with hydrogen at a temperature between about 800 C. and 1100 C.
- this is accomplished by bubbling an inert gas, such as argon or helium, through a bath of molten molybdenum pentachloride and diluting the resultant vapors to the desired concentration with a separate stream of heated hydrogen.
- an inert gas such as argon or helium
- the partial pressure of molybdenum pentachloride in the molten state is much more constant than the partial pressure of the solid due to a more uniform temperature distribution throughout the liquid and a substantially constant surface area during the run, these factors producing a more even flow of vapor than was previously possible.
- This vapor is composed primarily of molybdenum pentachloride, although, due to disproportionation (and/ or reduction if hydrogen is used as the carrier gas), small quantities of the lower chlorides are also present.
- These atent lower chlorides are particularly detrimental to the process in that they deposit on the walls of the article being coated and prevent the molybdenum from forming a strong, adherent bond with the cobalt or nickel layer. The formation of these undesired lower chlorides may be largely prevented by the use of argon as a carrier gas for the vapor.
- the concentration of the molybdenum pentachloride was so erratic that effective control over the pentachloride vapor-hydrogen ratio, which is preferably about 1:10 on the basis of partial pressure ratio, was virtually impossible. It is definitely preferred that the ratio of MoCl vapor to H be equal to 1:10 or slightly less.
- a partial pressure ratio of 1:9 will cause incomplete reduction of the chlorides, resulting in the deposition of lower chlorides of molybdenum on the Walls of the object being coated.
- a partial pressure ratio of 1:11 or higher will cause the operation to go at less than the maximum possible rate, the increase in ratio directly causing a decrease in the plating speed.
- the limiting ratios for the successful operation of the instant invention are 1:9 as a lower limit and 1:15 as a practical upper limit.
- "addition of an inert gas, such as argon, as a carrier stabilizes the fiow of pentachloride vapor to the point where the molybdenum pentachloride vapor-hydrogen vapor partial pressure ratio can be effectively controlled.
- Example 1 A piece of steel pipe, thoroughly cleaned internally of all foreign substances, was coated with a layer of cobalt to a depth of about 0.0004 inch, employing the chemical reduction method described by Brenner and Riddell in the Journal of Research, National Bureau of Standards 39, 388 (1947). Although the cobalt coating produced by employing this method will contain traces of combined phosphides, they will in no way afiect the adherence of the subsequent molybdenum coating.
- the steel pipe (internally coated with cobalt) was placed in a vacuum system and then heated to about 950 C. by means of an external heater, and a mixture of molybdenum chloride vapors, argon and hydrogen was passed through the pipe.
- This mixture was obtained by bubbling 0.2 liter per minute of argon through molten molybdenum pentachloride, the molten bath being maintained at a temperature of about 228 C., and then introducing into the vapor, after reduction of the pressure from 760 mm. to 17 mm., 9 liters per minute of heated (about C.) hydrogen, the molybdenum chloride-hydrogen vapor partial pressure ratio being 1:10.
- the preferred metal substrates for the present invention are those which are cap-able of forming a satisfactory diffusion bond with cobalt or nickel.
- Suitable substrates may consist of steel, nickel, cobalt or other metals whose may be obtained when the pentachloride is reduced at a 7 temperature between about 800 C. and 1100 C., preferably above about 900 C., and at a total pressure between about 10 and 25 mm.
- Hg abs. A preferred pressure range is 15 to 20 mm.
- Hg abs. the median pressure of 17.5 mm. Hg abs. being optimum.
- the cobalt or nickel in the intermediate bonding layer will difiuse to some extent into the metal substrate and molybdenum during the coating operations, it may occasionally be necessary to reheat the coated article so as to promote a further diffusion of said bonding layer. This additional treatment may be desirable only where the coated article requires an exceptionally adherent coating of molybdenum or where the surface is desired to be an alloy of the bonding metal and molybdenum.
- the heating may be accomplished either by a gas burner, induction heating or resistance heating, the heating being over as large an area as possible so that the reaction can proceed more smoothly and rapidly.
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- Chemical & Material Sciences (AREA)
- General Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physical Vapour Deposition (AREA)
Description
Dec. 3, 1957 P. RAYMOND 2,815,299
METHOD OF PRODUCING AN ADHERENT MOLYBDENUM COATING ON A METAL SUBSTRATE Filed Oct. 24, 1955 ineri' Gas pp y MoH'en MoCl Bubbler Inerf Gas Scri'urcrl'ed wH'h MOCI5 Ccabul'P Layer Reqcl'ion Zone Effluen+- Gases K Forming Molybdenum /Film Deposi+ I a Z A e K Hea'l'er A i isle +o be Coa+ed A Tempered-are 800 HOO C Reddio" PcrHal Pressure Rcrl'io of- MoCl +0 H [:9- ms Condi'lions v Hydrogen Pressure: [0-25 min. Hg.'Abs. pp y INVENTOR. PAUL L. RAYMOND GM (J, Mz m AT TO RN EY METHOD OF PRODUCING AN ADHERENT MOLYBDENUM COATING ON A METAL SUBSTRATE Paul L. Raymond, Natick, Mass., .ass ignor to National Research Corporation, Cambridge, Mass., :1 corporahorn of Massachusetts Application October 24, 1955, Serial No. 542,498
4 Claims. (Cl. 117-71) This invention relates to coating and in particular to the coating of metal substrates with molybdenum.
One object of the present invention is to produce adherent coatings of molybdenum on metal substrates.
Another object of the invention is to provide uniform, adherent molybdenum coatings on the interior surfaces of hollow objects.
Other objects of the invention will in part be obvious and will in part appear hereinafter.
The invention accordingly comprises the process involving the several steps and the relation and the order of one or more of such steps with respect to each of the others which are exemplified in the following detailed disclosure, and the scope of the application of which will be indicated in the claims.
For a fuller understanding of the nature and objects of the invention, reference should be had to the following detailed description.
The numerous applications to which molybdenumcoated articles may be adapted are dependent to a great extent on the adherence of the molybdenum to the metal substrate, as fully explained in copending application Serial No. 380,846, filed September 17, 1953, now Patent 2,783,164. The above invention is, therefore, directed to a process for coating metal substrates, and in particular the interior surf-aces of hollow objects, with a uniform, adherent deposit of molybdenum. This may be accomplished by forming a suitable diffusion bond between the metal substrate and the molybdenum, eliminating powdery material deposits on the metal surfaces which are about to be coated, and precisely controlling the reducible molybdenum compound-hydrogen ratio.
In the present invention, a uniform, adherent coating of molybdenum may be obtained on a metal substrate, particularly steel, by coating the metal substrate, prior to depositing molybdenum thereon, with a layer of cobalt or nickel which is capable of forming a diffusion bond with both the metal substrate and the molybdenum. A coating of molybdenum is then deposited on the thin cobalt or nickel layer by reducing a molybdenum compound with hydrogen at a temperature between about 800 C. and 1100 C. In a preferred embodiment of the invention, this is accomplished by bubbling an inert gas, such as argon or helium, through a bath of molten molybdenum pentachloride and diluting the resultant vapors to the desired concentration with a separate stream of heated hydrogen.
The partial pressure of molybdenum pentachloride in the molten state is much more constant than the partial pressure of the solid due to a more uniform temperature distribution throughout the liquid and a substantially constant surface area during the run, these factors producing a more even flow of vapor than was previously possible. This vapor is composed primarily of molybdenum pentachloride, although, due to disproportionation (and/ or reduction if hydrogen is used as the carrier gas), small quantities of the lower chlorides are also present. These atent lower chlorides are particularly detrimental to the process in that they deposit on the walls of the article being coated and prevent the molybdenum from forming a strong, adherent bond with the cobalt or nickel layer. The formation of these undesired lower chlorides may be largely prevented by the use of argon as a carrier gas for the vapor.
Heretofore, the concentration of the molybdenum pentachloride was so erratic that effective control over the pentachloride vapor-hydrogen ratio, which is preferably about 1:10 on the basis of partial pressure ratio, was virtually impossible. It is definitely preferred that the ratio of MoCl vapor to H be equal to 1:10 or slightly less. A partial pressure ratio of 1:9 will cause incomplete reduction of the chlorides, resulting in the deposition of lower chlorides of molybdenum on the Walls of the object being coated. A partial pressure ratio of 1:11 or higher will cause the operation to go at less than the maximum possible rate, the increase in ratio directly causing a decrease in the plating speed. The limiting ratios for the successful operation of the instant invention are 1:9 as a lower limit and 1:15 as a practical upper limit. However, in the present invention, "addition of an inert gas, such as argon, as a carrier stabilizes the fiow of pentachloride vapor to the point where the molybdenum pentachloride vapor-hydrogen vapor partial pressure ratio can be effectively controlled.
The invention is clearly set forth in the self-explanatory drawing and will be more fully described in the following example in connection with the plating of molybdenum on steel, it being understood that the example is illustrative and is not to be construed as limiting the invention in any way.
Example 1 A piece of steel pipe, thoroughly cleaned internally of all foreign substances, was coated with a layer of cobalt to a depth of about 0.0004 inch, employing the chemical reduction method described by Brenner and Riddell in the Journal of Research, National Bureau of Standards 39, 388 (1947). Although the cobalt coating produced by employing this method will contain traces of combined phosphides, they will in no way afiect the adherence of the subsequent molybdenum coating. The steel pipe (internally coated with cobalt) was placed in a vacuum system and then heated to about 950 C. by means of an external heater, and a mixture of molybdenum chloride vapors, argon and hydrogen was passed through the pipe. This mixture was obtained by bubbling 0.2 liter per minute of argon through molten molybdenum pentachloride, the molten bath being maintained at a temperature of about 228 C., and then introducing into the vapor, after reduction of the pressure from 760 mm. to 17 mm., 9 liters per minute of heated (about C.) hydrogen, the molybdenum chloride-hydrogen vapor partial pressure ratio being 1:10.
Hydrogen reduction of the molybdenum chloride took place in the heated portion, depositing thereon a coating of molybdenum. The heater was then moved in the opposite direction to the flow of hydrogen and molybdenum chloride vapors so as to heat a new portion of the cobalt-coated surface to be coated with molybdenum. Under these conditions, an adherent coating of molybdenum was deposited on the cobalt along the entire interior surface of the pipe. The cobalt, during this latter coating operation, diffused to a small extent into both the molybdenum and the steel of the pipe and prevented diffusion of carbon from the steel to the molybdenum.
The preferred metal substrates for the present invention are those which are cap-able of forming a satisfactory diffusion bond with cobalt or nickel. Suitable substrates may consist of steel, nickel, cobalt or other metals whose may be obtained when the pentachloride is reduced at a 7 temperature between about 800 C. and 1100 C., preferably above about 900 C., and at a total pressure between about 10 and 25 mm. Hg abs. A preferred pressure range is 15 to 20 mm. Hg abs., the median pressure of 17.5 mm. Hg abs. being optimum.
It should also be mentioned that, although the cobalt or nickel in the intermediate bonding layer will difiuse to some extent into the metal substrate and molybdenum during the coating operations, it may occasionally be necessary to reheat the coated article so as to promote a further diffusion of said bonding layer. This additional treatment may be desirable only where the coated article requires an exceptionally adherent coating of molybdenum or where the surface is desired to be an alloy of the bonding metal and molybdenum.
The heating may be accomplished either by a gas burner, induction heating or resistance heating, the heating being over as large an area as possible so that the reaction can proceed more smoothly and rapidly.
Since certain changes may be made in the above process without departing from the scope of the invention herein involved, it is intended that all matter contained in the above description shall be interpreted as illustrative and not in a limiting sense.
What is claimed is:
1. In a method of producing an adherent molybdenum coating on ametal substrate capable'of forming a diffusion bond with ametal selected from the group consisting of cobalt and nickel wherein the process comprises coating a thin layer of the bonding metal on the metal substrate anddepositing a coating of molybdenum on said thin layer by the hydrogen reduction of molybdenum chloride vapors, the improvement which comprises generating the molybdenum chloride vapors by bubbling an inert gas through a. molten molybdenum pentachloride bath and thereafter reacting the resulting mixture of vapors with a stream of hydrogen.
2., The method of claim 1 wherein the molybdenum chloride vapor-hydrogen vapor partial pressure ratio is between 1:9 and 1:15.
3. Themethod of claim 1 wherein the molybdenum chloride vapor-hydrogen vapor partial pressure ratio is about 1:10.
4. The method of claim 1 wherein said molybdenum chloride vapors are reduced with hydrogen at a temperature between about 800 C. and 1100 C.
References Cited in the file of this patent UNITED STATES PATENTS 2,689,807 Kempe et al Sept. 21, 1954 2,753,800 Pewlyk et al. July 10, 1956 2,759,855 Medcalf et al Aug. 21, 1956 OTHER REFERENCES
Claims (1)
1. IN A METHOD OF PRODUCING AN ADHERENT MOLYBDENUM COATING ON A METAL SUBSTRATE CAPABLE OF FORMING A DIFFUSION BOND WITH A METAL SELECTED FROM THE GROUP CONSISTING OF COBALT AND NICKEL WHEREIN THE PROCESS COMPRISES COATING A THIN LAYER OF THE BONDING METAL ON THE METAL SUBSTRATE AND DEPOSITING A COATING OF MOLYBDENUM ON SAID THIN LAYER BY THE HYDROGEN REDUCTION OF MOLYBDENUM CHLORIDE VAPORS, THE IMPROVEMENT WHICH COMPRISES GENERATING THE MOLYBDENUM CHLORIDE VAPORS BY BUBBLING AN INERT GAS THROUGH A MOLTEN MOLYBDENUM PENTACHLORIDE BATH AND THEREAFTER REACTING THE RESULTING MIXTURE OF VAPORS WITH A STREAM OF HYDROGEN.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US542498A US2815299A (en) | 1955-10-24 | 1955-10-24 | Method of producing an adherent molybdenum coating on a metal substrate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US542498A US2815299A (en) | 1955-10-24 | 1955-10-24 | Method of producing an adherent molybdenum coating on a metal substrate |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2815299A true US2815299A (en) | 1957-12-03 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US542498A Expired - Lifetime US2815299A (en) | 1955-10-24 | 1955-10-24 | Method of producing an adherent molybdenum coating on a metal substrate |
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| Country | Link |
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| US (1) | US2815299A (en) |
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3055089A (en) * | 1958-08-06 | 1962-09-25 | Union Carbide Corp | Gaseous metal product and processes |
| US3108014A (en) * | 1961-03-13 | 1963-10-22 | Alloyd Corp | Paper metallizing process utilizing iron dodecacarbonyl |
| US3265521A (en) * | 1963-01-02 | 1966-08-09 | Gen Electric | Method of forming a composite member with a metallic coating |
| US3767456A (en) * | 1971-09-07 | 1973-10-23 | Fansteel Inc | Chemical vapor deposition of steel with tantalum and columbium |
| US3996400A (en) * | 1973-04-25 | 1976-12-07 | Centre Stephanois De Recherches Mecaniques Hydromecanique Et Frottement | Method for surface coating ferrous alloy parts |
| US4138512A (en) * | 1977-10-17 | 1979-02-06 | The United States Of America As Represented By The Secretary Of The Army | Process for chemical vapor deposition of a homogeneous alloy of refractory metals |
| US4190493A (en) * | 1975-02-26 | 1980-02-26 | Sulzer Brothers Limited | Coated structural component for a high temperature nuclear reactor |
| WO1991005743A1 (en) * | 1989-10-17 | 1991-05-02 | Libbey-Owens-Ford Co. | Method for preparing vaporized reactants for chemical vapor deposition |
| US5224998A (en) * | 1988-08-17 | 1993-07-06 | Tadahiro Ohmi | Apparatus for oxidation treatment of metal |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2689807A (en) * | 1950-06-16 | 1954-09-21 | Thompson Prod Inc | Method of coating refractory metal articles |
| US2753800A (en) * | 1952-03-24 | 1956-07-10 | Ohio Commw Eng Co | Production of printing plates |
| US2759855A (en) * | 1953-08-24 | 1956-08-21 | Eagle Picher Co | Coated electronic device and method of making same |
-
1955
- 1955-10-24 US US542498A patent/US2815299A/en not_active Expired - Lifetime
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2689807A (en) * | 1950-06-16 | 1954-09-21 | Thompson Prod Inc | Method of coating refractory metal articles |
| US2753800A (en) * | 1952-03-24 | 1956-07-10 | Ohio Commw Eng Co | Production of printing plates |
| US2759855A (en) * | 1953-08-24 | 1956-08-21 | Eagle Picher Co | Coated electronic device and method of making same |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3055089A (en) * | 1958-08-06 | 1962-09-25 | Union Carbide Corp | Gaseous metal product and processes |
| US3108014A (en) * | 1961-03-13 | 1963-10-22 | Alloyd Corp | Paper metallizing process utilizing iron dodecacarbonyl |
| US3265521A (en) * | 1963-01-02 | 1966-08-09 | Gen Electric | Method of forming a composite member with a metallic coating |
| US3767456A (en) * | 1971-09-07 | 1973-10-23 | Fansteel Inc | Chemical vapor deposition of steel with tantalum and columbium |
| US3996400A (en) * | 1973-04-25 | 1976-12-07 | Centre Stephanois De Recherches Mecaniques Hydromecanique Et Frottement | Method for surface coating ferrous alloy parts |
| US4190493A (en) * | 1975-02-26 | 1980-02-26 | Sulzer Brothers Limited | Coated structural component for a high temperature nuclear reactor |
| US4138512A (en) * | 1977-10-17 | 1979-02-06 | The United States Of America As Represented By The Secretary Of The Army | Process for chemical vapor deposition of a homogeneous alloy of refractory metals |
| US5224998A (en) * | 1988-08-17 | 1993-07-06 | Tadahiro Ohmi | Apparatus for oxidation treatment of metal |
| WO1991005743A1 (en) * | 1989-10-17 | 1991-05-02 | Libbey-Owens-Ford Co. | Method for preparing vaporized reactants for chemical vapor deposition |
| US5090985A (en) * | 1989-10-17 | 1992-02-25 | Libbey-Owens-Ford Co. | Method for preparing vaporized reactants for chemical vapor deposition |
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