US2808011A - Furnace for burning semi-liquid fuels - Google Patents

Furnace for burning semi-liquid fuels Download PDF

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US2808011A
US2808011A US305648A US30564852A US2808011A US 2808011 A US2808011 A US 2808011A US 305648 A US305648 A US 305648A US 30564852 A US30564852 A US 30564852A US 2808011 A US2808011 A US 2808011A
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furnace
chamber
liquor
liquid fuels
jets
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US305648A
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Henry C L Miller
Harry A Raddin
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Miller Hofft Inc
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Miller Hofft Inc
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/32Incineration of waste; Incinerator constructions; Details, accessories or control therefor the waste being subjected to a whirling movement, e.g. cyclonic incinerators
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/04Incinerators or other apparatus for consuming industrial waste, e.g. chemicals of waste liquors, e.g. sulfite liquors

Definitions

  • Claim. (Cl. 110-7) It is an object of this invention to provide a method and means for burning semi-liquid fuels of relatively low heat content.
  • Figurel is a vertical cross-section through one form of the improved apparatus.
  • Figure 2 is a section on the line 22 of Figure 1.
  • yield of pulp ranges from 50-60 percent of the bonedry weight of the original chips and the black liquors therefor contain as complex lignin materials from 40-50 percent of the bonedry weight of the chips.
  • the solids therefore in the black liquor have a very substantial fuel value.
  • the chips are cooked by the semi-chemical or neutral sulphite process the pulp yield runs from 75-80 percent, which means that in the black liquor solids there is only from 2025 percent of the original chips.
  • the fuel value is very much lower and the recoverable chemicals in the black liquor solids is in far higher proportion to total solids than in ordinary kraft or soda black liquors.
  • This high proportion of inorganic recoverable chemicals to organic combustible matter it becomes of the utmost importance to minimize the passage of any solids into the stack since any solids going to the stack necessarily will represent a higher percentage of recoverable chemicals.
  • the present invention contemplates a combustion chamber in the form of a cylinder with its axis vertical. While for most purposes a circular horizontal cross-section is preferred; for some purposes, the horizontal cross-section may be polygonal. In any case the cross-section should be uniform for a height at least approximately twice the mean diameter of the chamber.
  • the top or outlet is substantially restricted in diameter and the bottom preferably is frusto-conical.
  • Tangential air jets are provided at three different levels to create and maintain a vortex which will heat fine particles adjacent the periphery of the combustion chamber, thus preventing them from emerging through the restricted outlet.
  • Concentrated liquor is sprayed into the combustion chamber and against the chamber wall.
  • the spray is preferably thin and is flattened in the vertical plane.
  • the spray nozzle or a series of nozzles preferably is oscillated horizontally in order to deposit the liquor on a maximum portion of the combustion chamber wall. As the liquor is sprayed in at a concentration of from 2 50-70 percent solids and strikes the hot combustion wall it immediately sticks there and is thereby exposed to the heat of the combustion chamber.
  • FIG. 1 there is shown a cylindrical shell 10, a frusto-conical lower portion 12 and an upper gas outlet 14.
  • a lower slag outlet 16 is provided at the bottom of the frusto-conical portion and through this outlet 16 molten chemicals are removed. iust above the outlet 16 are one or more tangential air jets 18 through which roughly 30 percent of total air is supplied. Clearly enough this will maintain a reducing atmosphere within the frusto-conical portion so that the burning in this section will be to carbon monoxide.
  • the furnace is started and brought up to heat by any conventional means such, for example, as an oil burner 19.
  • Concentrated black liquor is then introduced through the nozzle 22 in the form of a flat spray which expands along the lines 28 and impinges on the wall of the chamber 10.
  • the air jets 20 are similarly expanded to create a vortex vertically coextensive with the area of the wall 10 receiving liquor from the nozzle 22. Approximately 50 percent total air is supplied in this area with the remainder supplied by the jets 24. It will be clear that with enforced swirling of the gases throughout the chamber 10 and with only a moderate central vertical velocity, it will be almost impossible for any solid particle, however fine, to emerge through the gas outlet 14. All solids therefore ultimately must find their way to the bottom where, if organic, they are burned and, if inorganic, they are smelted.
  • the nozzle or nozzles 22 should be oscillated horizontally toward and from a tangential position while for other purposes it will be more effective to oscillate the nozzles on each side of a radial median position.
  • the spray emerging from the nozzle should be flattened in a vertical plane.
  • the vortex created by the air jets 20 will distort the liquor jet emerging from nozzle 22, extending the area of the chanrber wall covered by the jet in the direction of the vortex, while shortening the area covered by the jet in the direction opposite the vortex. Only the liquor jets oscillate.
  • the air jets while in substantially the same horizontal plane as the liquor jets, are fixed within that plane.
  • a method of operating a substantially cylindrical com- Patented Oct. 1, 1957- 3 4i bustion chamber having its axis vertical and having a re- References Cited in the file of this patent stricted outlet for combustion products in its top surface UNITED STATES PATENTS comprising: introducing tangentially, approximately midway between top and bottom of the chamber, a jet of a 901,232 Eldred 1908 water slurry containing burnable and unburnable solids; 5 1530321 Pollock 1925 igniting and burning the burnable portion of saidv solids; 1779537 4 1930 introducing combustion air in a tangential jet in the same 2138278 1938 direction and in the plane of said slurry jet; introducing 2'161'110 Tofnlmson June 1939 additional combustion air in similar jets similarly directed 2357301 Bafley Sept 1944 adjacent the top and bottom of said chamber; allocating 10 2362066 Hales.

Description

Oct. 1, 1957 H. c. L. MILLER L 2,808,011
FURNACE FOR BURNING SEMI-LIQUID FUELS v Filed Aug. 21, 1952 W W ,d
1H F I6. I.
w -1 w w t 1% a i1 /9 I O 22 F l e. 2
INVENTORS HENRY O. L. MILLER HARRY A. RADDIN United States Patent FURNACE FOR BURNING SEMI-LIQUID FUELS Henry C. L. Miller and Harry A. Raddin, Richmond, Va., assignors to Miller Holft, Inc., Richmond, Va., a cor poratiou of Delaware Application August 21, 1952, Serial No. 305,648
1 Claim. (Cl. 110-7) It is an object of this invention to provide a method and means for burning semi-liquid fuels of relatively low heat content.
It is a further object of this invention to provide a method and means as aforesaid whereby the escape of solids from the furnace will be minimized.
The above and other objects will be made clear from the following detailed description taken in connection with the annexed drawings, in which:
Figurel is a vertical cross-section through one form of the improved apparatus; and
Figure 2 is a section on the line 22 of Figure 1.
This invention will be described with particular reference to the burning of black liquor resulting from the production of pulp by the semichemical or by the neutral sulphite type of cook. Either of such liquors represents a more difiicult burning problem than is presented by the black liquors from the normal kraft or soda cook. The invention, however, is applicable to all of the black liquors.
In the ordinary kraft or soda cook, yield of pulp ranges from 50-60 percent of the bonedry weight of the original chips and the black liquors therefor contain as complex lignin materials from 40-50 percent of the bonedry weight of the chips.
The solids therefore in the black liquor have a very substantial fuel value. When, however, the chips are cooked by the semi-chemical or neutral sulphite process the pulp yield runs from 75-80 percent, which means that in the black liquor solids there is only from 2025 percent of the original chips. Hence the fuel value is very much lower and the recoverable chemicals in the black liquor solids is in far higher proportion to total solids than in ordinary kraft or soda black liquors. With this high proportion of inorganic recoverable chemicals to organic combustible matter it becomes of the utmost importance to minimize the passage of any solids into the stack since any solids going to the stack necessarily will represent a higher percentage of recoverable chemicals.
The present invention contemplates a combustion chamber in the form of a cylinder with its axis vertical. While for most purposes a circular horizontal cross-section is preferred; for some purposes, the horizontal cross-section may be polygonal. In any case the cross-section should be uniform for a height at least approximately twice the mean diameter of the chamber. The top or outlet is substantially restricted in diameter and the bottom preferably is frusto-conical.
Tangential air jets are provided at three different levels to create and maintain a vortex which will heat fine particles adjacent the periphery of the combustion chamber, thus preventing them from emerging through the restricted outlet. Concentrated liquor is sprayed into the combustion chamber and against the chamber wall. The spray is preferably thin and is flattened in the vertical plane. The spray nozzle or a series of nozzles preferably is oscillated horizontally in order to deposit the liquor on a maximum portion of the combustion chamber wall. As the liquor is sprayed in at a concentration of from 2 50-70 percent solids and strikes the hot combustion wall it immediately sticks there and is thereby exposed to the heat of the combustion chamber. As the heat of the combustion chamber evaporates the moisture of the liquor, chunks are formed which detach themselves from the wall and drop to the lower frusto-conical section. The air supply is adjusted so that Within the lower section the organic material burns primarily to carbon monoxide, thus maintaining a reducing atmosphere in which the inorganic material melts to form a smelt which drops through an outlet into a dissolving tank. Additional air is supplied adjacent the liquor spray and adjacent the top of the combustion chamber in order to burn the carbon monoxide formed at the bottomof the chamber completely to carbon dioxide and to assist, at three levels, in
maintaining the circular motion of the combustion gases.
Within the chamber, due to the tangential jets, there is maintained a high circular velocity but there is only a very modest velocity in the vertical direction through the outlet.
It will be recognized that the foregoing represents an adaptation of some of the principles of our copending application Serial No. 152,294, filed March 28, 1950, now Patent No. 2,614,513.
Referring now to Figure 1 there is shown a cylindrical shell 10, a frusto-conical lower portion 12 and an upper gas outlet 14. A lower slag outlet 16 is provided at the bottom of the frusto-conical portion and through this outlet 16 molten chemicals are removed. iust above the outlet 16 are one or more tangential air jets 18 through which roughly 30 percent of total air is supplied. Clearly enough this will maintain a reducing atmosphere within the frusto-conical portion so that the burning in this section will be to carbon monoxide.
Approximately midway of the height of the cylindrical shell 10 there are one or more additional tangential air jets 20 and within this area the spray or sprays 22 of concentrated black liquor is introduced. Other air jets 24 are directed tangentially adjacent and slightly below the annular constriction 26 which defines the gas outlet 14.
The furnace is started and brought up to heat by any conventional means such, for example, as an oil burner 19. Concentrated black liquor is then introduced through the nozzle 22 in the form of a flat spray which expands along the lines 28 and impinges on the wall of the chamber 10. The air jets 20 are similarly expanded to create a vortex vertically coextensive with the area of the wall 10 receiving liquor from the nozzle 22. Approximately 50 percent total air is supplied in this area with the remainder supplied by the jets 24. It will be clear that with enforced swirling of the gases throughout the chamber 10 and with only a moderate central vertical velocity, it will be almost impossible for any solid particle, however fine, to emerge through the gas outlet 14. All solids therefore ultimately must find their way to the bottom where, if organic, they are burned and, if inorganic, they are smelted.
For some purposes the nozzle or nozzles 22 should be oscillated horizontally toward and from a tangential position while for other purposes it will be more effective to oscillate the nozzles on each side of a radial median position. In either case the spray emerging from the nozzle should be flattened in a vertical plane. Also, in either case, the vortex created by the air jets 20 will distort the liquor jet emerging from nozzle 22, extending the area of the chanrber wall covered by the jet in the direction of the vortex, while shortening the area covered by the jet in the direction opposite the vortex. Only the liquor jets oscillate. The air jets, while in substantially the same horizontal plane as the liquor jets, are fixed within that plane.
We claim:
A method of operating a substantially cylindrical com- Patented Oct. 1, 1957- 3 4i bustion chamber having its axis vertical and having a re- References Cited in the file of this patent stricted outlet for combustion products in its top surface UNITED STATES PATENTS comprising: introducing tangentially, approximately midway between top and bottom of the chamber, a jet of a 901,232 Eldred 1908 water slurry containing burnable and unburnable solids; 5 1530321 Pollock 1925 igniting and burning the burnable portion of saidv solids; 1779537 4 1930 introducing combustion air in a tangential jet in the same 2138278 1938 direction and in the plane of said slurry jet; introducing 2'161'110 Tofnlmson June 1939 additional combustion air in similar jets similarly directed 2357301 Bafley Sept 1944 adjacent the top and bottom of said chamber; allocating 10 2362066 Hales. 1944 the total air among the several jets to supply approximate- 2385'955 Tomhnson 1945 ly 50% of the air to the jets adjacent the slurry jet, 2535730 Gadet 1950 approximately 30% to the jet adjacent the bottom of the FOREIGN PATENTS chamber and the balance to the jet adjacent the top of the 305,270 Great Britain Feb 1, 1929 chamber; introducing all of said ets at a velocity such 10 117,071 Switzerland Aug 20, 1946 as to create and maintain a vortex which will heat fine particles adjacent the periphery of said combustion chamber thus preventing such particles from emerging through said outlet.
w a w a)
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Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3362360A (en) * 1966-12-05 1968-01-09 Broadway Res And Dev Corp Method and apparatus for incinerating waste material
US3457883A (en) * 1967-05-08 1969-07-29 Borge Richard Ankersen Incinerators and methods of incineration
US3581683A (en) * 1970-03-16 1971-06-01 Martin Collier Jr Refuse disposal apparatus and process
US3611954A (en) * 1970-05-08 1971-10-12 Du Pont Oxidative waste disposal
US3867251A (en) * 1972-04-04 1975-02-18 Angpanneforeningen Combustion of alkaline cooking liquor
US3885906A (en) * 1974-05-21 1975-05-27 Alexei Petrovich Shurygin Cyclone furnace
US3974021A (en) * 1974-08-27 1976-08-10 Mikhail Naumovich Bernadiner Process and cyclone reactor for fire decontamination of industrial waste water containing organic and refractory mineral impurities
US4054409A (en) * 1975-05-15 1977-10-18 Nippon Kokan Kabushiki Kaisha Swirling burners for use in hot blast stoves
US4194454A (en) * 1977-09-29 1980-03-25 Societe Nationale Elf Aquitaine Method for incinerating sludges
US4294178A (en) * 1979-07-12 1981-10-13 Combustion Engineering, Inc. Tangential firing system
US4380960A (en) * 1978-10-05 1983-04-26 Dickinson Norman L Pollution-free low temperature slurry combustion process utilizing the super-critical state
US4389979A (en) * 1979-09-03 1983-06-28 Oddmund Saxlund Method and apparatus for the operation of a boiler installation with stoker firing
US4604957A (en) * 1983-11-05 1986-08-12 Sunds Defibrator Ab Method for wet combustion of organic material
US4630556A (en) * 1982-02-17 1986-12-23 Atlantic Research Corporation Method for burning coal-liquid slurry fuels and apparatus therefor
US6237512B1 (en) * 1998-02-03 2001-05-29 Kiyoshi Nakato Waste liquid incinerator and method of incinerating waste liquid
US20100086886A1 (en) * 2007-03-02 2010-04-08 Johnson Leighta M Method and apparatus for oxy-fuel combustion

Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US901232A (en) * 1908-05-07 1908-10-13 Byron E Eldred Process of producing gas.
US1530321A (en) * 1923-08-30 1925-03-17 Pollock James Furnace for burning fine coal
CH117071A (en) * 1925-09-07 1926-10-16 Fischer Dr Roger Colloidal solution intended to serve as a carrier vehicle for radioactive substances and in particular for radium emanations.
GB305270A (en) * 1927-11-01 1929-02-01 Frederick Lindley Duffield Improvements in or relating to combustion chambers
US1779537A (en) * 1929-04-01 1930-10-28 Edward G Goodell Process of regenerating black liquors
US2138278A (en) * 1936-08-10 1938-11-29 Babcock & Wilcox Co Method of recovering heat and chemicals from waste liquors
US2161110A (en) * 1935-05-16 1939-06-06 Babcock & Wilcox Co Method of and apparatus for burning waste liquor
US2357301A (en) * 1941-03-07 1944-09-05 Babcock & Wilcox Co Fuel burning method and apparatus
US2362066A (en) * 1940-11-07 1944-11-07 Atlas Powder Co Process for treatment of nitrotoluol waste liquors
US2385955A (en) * 1941-04-08 1945-10-02 George H Tomlinson Manufacture of sulphite pulp
US2535730A (en) * 1947-10-08 1950-12-26 Gascogne Papeteries Process for the treatment of waste liquors derived from cellulose manufacture

Patent Citations (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US901232A (en) * 1908-05-07 1908-10-13 Byron E Eldred Process of producing gas.
US1530321A (en) * 1923-08-30 1925-03-17 Pollock James Furnace for burning fine coal
CH117071A (en) * 1925-09-07 1926-10-16 Fischer Dr Roger Colloidal solution intended to serve as a carrier vehicle for radioactive substances and in particular for radium emanations.
GB305270A (en) * 1927-11-01 1929-02-01 Frederick Lindley Duffield Improvements in or relating to combustion chambers
US1779537A (en) * 1929-04-01 1930-10-28 Edward G Goodell Process of regenerating black liquors
US2161110A (en) * 1935-05-16 1939-06-06 Babcock & Wilcox Co Method of and apparatus for burning waste liquor
US2138278A (en) * 1936-08-10 1938-11-29 Babcock & Wilcox Co Method of recovering heat and chemicals from waste liquors
US2362066A (en) * 1940-11-07 1944-11-07 Atlas Powder Co Process for treatment of nitrotoluol waste liquors
US2357301A (en) * 1941-03-07 1944-09-05 Babcock & Wilcox Co Fuel burning method and apparatus
US2385955A (en) * 1941-04-08 1945-10-02 George H Tomlinson Manufacture of sulphite pulp
US2535730A (en) * 1947-10-08 1950-12-26 Gascogne Papeteries Process for the treatment of waste liquors derived from cellulose manufacture

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3362360A (en) * 1966-12-05 1968-01-09 Broadway Res And Dev Corp Method and apparatus for incinerating waste material
US3457883A (en) * 1967-05-08 1969-07-29 Borge Richard Ankersen Incinerators and methods of incineration
US3581683A (en) * 1970-03-16 1971-06-01 Martin Collier Jr Refuse disposal apparatus and process
US3611954A (en) * 1970-05-08 1971-10-12 Du Pont Oxidative waste disposal
US3867251A (en) * 1972-04-04 1975-02-18 Angpanneforeningen Combustion of alkaline cooking liquor
US3885906A (en) * 1974-05-21 1975-05-27 Alexei Petrovich Shurygin Cyclone furnace
US3974021A (en) * 1974-08-27 1976-08-10 Mikhail Naumovich Bernadiner Process and cyclone reactor for fire decontamination of industrial waste water containing organic and refractory mineral impurities
US4054409A (en) * 1975-05-15 1977-10-18 Nippon Kokan Kabushiki Kaisha Swirling burners for use in hot blast stoves
US4194454A (en) * 1977-09-29 1980-03-25 Societe Nationale Elf Aquitaine Method for incinerating sludges
US4380960A (en) * 1978-10-05 1983-04-26 Dickinson Norman L Pollution-free low temperature slurry combustion process utilizing the super-critical state
US4294178A (en) * 1979-07-12 1981-10-13 Combustion Engineering, Inc. Tangential firing system
US4389979A (en) * 1979-09-03 1983-06-28 Oddmund Saxlund Method and apparatus for the operation of a boiler installation with stoker firing
US4630556A (en) * 1982-02-17 1986-12-23 Atlantic Research Corporation Method for burning coal-liquid slurry fuels and apparatus therefor
US4604957A (en) * 1983-11-05 1986-08-12 Sunds Defibrator Ab Method for wet combustion of organic material
US6237512B1 (en) * 1998-02-03 2001-05-29 Kiyoshi Nakato Waste liquid incinerator and method of incinerating waste liquid
US20100086886A1 (en) * 2007-03-02 2010-04-08 Johnson Leighta M Method and apparatus for oxy-fuel combustion
US8845323B2 (en) * 2007-03-02 2014-09-30 Air Products And Chemicals, Inc. Method and apparatus for oxy-fuel combustion

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