US2711959A - Welding steel for developing high surface hardness under impact - Google Patents
Welding steel for developing high surface hardness under impact Download PDFInfo
- Publication number
- US2711959A US2711959A US466661A US46666154A US2711959A US 2711959 A US2711959 A US 2711959A US 466661 A US466661 A US 466661A US 46666154 A US46666154 A US 46666154A US 2711959 A US2711959 A US 2711959A
- Authority
- US
- United States
- Prior art keywords
- steel
- surface hardness
- under impact
- steels
- welding
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910000831 Steel Inorganic materials 0.000 title description 35
- 239000010959 steel Substances 0.000 title description 35
- 238000003466 welding Methods 0.000 title description 19
- 229910052799 carbon Inorganic materials 0.000 claims description 13
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 12
- 230000014509 gene expression Effects 0.000 claims description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 8
- 239000012535 impurity Substances 0.000 claims description 4
- 229910052742 iron Inorganic materials 0.000 claims description 4
- 239000000203 mixture Substances 0.000 claims description 4
- 230000000694 effects Effects 0.000 claims description 3
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 13
- 239000011572 manganese Substances 0.000 description 13
- 239000010955 niobium Substances 0.000 description 11
- 239000011651 chromium Substances 0.000 description 9
- 229910052748 manganese Inorganic materials 0.000 description 8
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 7
- 229910045601 alloy Inorganic materials 0.000 description 7
- 239000000956 alloy Substances 0.000 description 7
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 6
- 238000004458 analytical method Methods 0.000 description 6
- 229910052804 chromium Inorganic materials 0.000 description 6
- 229910052750 molybdenum Inorganic materials 0.000 description 6
- 239000011733 molybdenum Substances 0.000 description 6
- 229910052759 nickel Inorganic materials 0.000 description 6
- 229910052721 tungsten Inorganic materials 0.000 description 6
- 229910052720 vanadium Inorganic materials 0.000 description 5
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 4
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 4
- 239000010937 tungsten Substances 0.000 description 4
- 238000007792 addition Methods 0.000 description 3
- 238000005552 hardfacing Methods 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 229910000617 Mangalloy Inorganic materials 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000011159 matrix material Substances 0.000 description 2
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 2
- 241000269350 Anura Species 0.000 description 1
- 206010011469 Crying Diseases 0.000 description 1
- 229910001096 P alloy Inorganic materials 0.000 description 1
- 229910052774 Proactinium Inorganic materials 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- SMDHCQAYESWHAE-UHFFFAOYSA-N benfluralin Chemical class CCCCN(CC)C1=C([N+]([O-])=O)C=C(C(F)(F)F)C=C1[N+]([O-])=O SMDHCQAYESWHAE-UHFFFAOYSA-N 0.000 description 1
- XCNJCXWPYFLAGR-UHFFFAOYSA-N chromium manganese Chemical compound [Cr].[Mn].[Mn].[Mn] XCNJCXWPYFLAGR-UHFFFAOYSA-N 0.000 description 1
- VNNRSPGTAMTISX-UHFFFAOYSA-N chromium nickel Chemical compound [Cr].[Ni] VNNRSPGTAMTISX-UHFFFAOYSA-N 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- -1 i. e. Substances 0.000 description 1
- 238000009533 lab test Methods 0.000 description 1
- ZAUUZASCMSWKGX-UHFFFAOYSA-N manganese nickel Chemical compound [Mn].[Ni] ZAUUZASCMSWKGX-UHFFFAOYSA-N 0.000 description 1
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 1
- 235000012054 meals Nutrition 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229910052702 rhenium Inorganic materials 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 238000005482 strain hardening Methods 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/24—Selection of soldering or welding materials proper
- B23K35/30—Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
- B23K35/3053—Fe as the principal constituent
- B23K35/308—Fe as the principal constituent with Cr as next major constituent
- B23K35/3086—Fe as the principal constituent with Cr as next major constituent containing Ni or Mn
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/24—Selection of soldering or welding materials proper
- B23K35/30—Selection of soldering or welding materials proper with the principal constituent melting at less than 1550 degrees C
- B23K35/3053—Fe as the principal constituent
- B23K35/3073—Fe as the principal constituent with Mn as next major constituent
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/38—Ferrous alloys, e.g. steel alloys containing chromium with more than 1.5% by weight of manganese
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10S428/00—Stock material or miscellaneous articles
- Y10S428/922—Static electricity metal bleed-off metallic stock
- Y10S428/9335—Product by special process
- Y10S428/939—Molten or fused coating
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T428/00—Stock material or miscellaneous articles
- Y10T428/12—All metal or with adjacent metals
- Y10T428/12493—Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
- Y10T428/12771—Transition metal-base component
- Y10T428/12861—Group VIII or IB metal-base component
- Y10T428/12951—Fe-base component
- Y10T428/12972—Containing 0.01-1.7% carbon [i.e., steel]
Definitions
- This invention relates to welding steel, i. e., steel which can be weld-deposited, which has important improved characteristics. Our improved welding steel is superior to previously existing welding steels in developing surface hardness and has other superior properties.
- Austenitic steels of a number of analyses have been used successfully for hard facing applications.
- the steels suitable for such use being austenitic or largely so, have a relatively low level of hardness as deposited but have the property of work hardening under impact to higher surface hardness levels which resist wear.
- the utility of such steels to resist wear therefore depends upon (1) the original hardness level; (2) the speed with which hardness is increased under impact; and (3) the level of increased hardness produced under impact.
- An undesirable property in such steels for many applications is the property of deforming or squashing down which the steel undergoes in developing its hardened surface. That property is especially undesirable in applications such as deposits on rail ends, switch frogs, etc., in which the metal should remain standing up in place as it develops its hard surface.
- Table I is a tabulation of the properties of three known alloy steels numbered consecutively from 1 to 3, inclusive. They are typical austenitic type alloy welding steels now widely used for hard surfacing. No. 1, sold under various names including Hardalloy 118, is a nickel-manganese steel based on the old Hadfield steel analyses (similar steels are being used with molybdenum at the relatively low level of approximately 1% substituted for all of the nickel and with properties rather similar to the nickelmanganese alloys). The physical properties appearing in the table show that the metal is quite soft as deposited with a yield strength of less than half the tensile strength. Under impact the surface hardness of the metal increases.
- a laboratory test which has been developed for such materials is to subject a standard sample rod to 2500 blows of foot-pounds each.
- the hardness of the pounded metal is compared with the initial value to show the rate of increase, and the amount of squashing down which has occurred is also measured.
- the final hardness shown under the hammer test values would continue to increase, if the test were continued, to a maximum value between and Rc at 80,000 blows.
- the additional squashing which would occur after the first 2500 blows is negligible as compared with the squashing effected by the first 2500 blows.
- the l-lardallay 118 went from a surface hardness of 13 Re to 39 Re and at the same time the standard specimen decreased .068 in height.
- Table II shows the results of tests made with certain improved welding steels which we have developed.
- n A Jr a Referring to steel No. 6 of Table H, with that analysis steel vanadium is approximately twice as powerful as pound test values and hardness levels before and after molybdenum. Tungsten and columbium can be subpounding are approximately the same as for the modified stituted respectively for all or part of the molybdenum 188 type (Nos. 2 and 3 of Table I) but the tensile and vanadium. The limits for molybdenum and/or strength, yield strength and elongation are much im- 6 tungsten plus 2 vanadium and/or columbium are set as proved. a function of the carbon content by positive values of Steels Nos. 4 and 5 of Table II, which we developed, the expressions given; negative values are treated as zero.
- the austenitizers copfound to be most useful and show that while the properper and cobalt may be present in limited quantities. ties vary somewhatahigh general level is maintained over lU Silicon will normally be present in quantities up to 1.5 the ranges evidenced. or even 2% since it is present in the commercial ma-
- the chromium terial available as core wire and is usually used as a content of the welding steel should be in the range deoxidizer in the coatings of coated welding electrodes.
- Ni Q to 4% The first is the balance between the austenitizers (C, Mn, N Mn-i-ZNi 13 to 22%, Ni, N) and ferritizers (Cr, W, Mo, Cb, V). This balan Cr 11 to 21%. must be adequate to produce a strong matrix. With all N 0 to 30%, the austenitizers near the low limits of their ranges and Mo and/0r W 0 to 5%. the ferritizers near the high limits of their ranges the V and/or Cb 0 to 2%.
- C stands for the per cent. of carbon in the welding steel and only positive values of such expressions are significant, negative values being treated as Zero; the balance, except for impurities which do not substantially affect the properties of the steel, being iron.
- An article comprising a structure having welded thereto a deposit which under impact develops high surface hardness without excessive shrinkage having substantially the following composition:
- C stands for the per cent. of carbon in the welding steel and only positive values of the expression C-.70 are significanhnegative values being treated as zero; the balance, except for impurities which do not substantially afieet the properties of the steel, being iron.
- An article comprising a structure having welded lit thereto a deposit which under impact develops high surface hardness without excessive shrinkage having substantially the following composition:
- C stands for the per cent. of carbon in the Welding steel and only positive values of such expressions are significant, negative values being treated as zero; the balance, except for impurities which do not substantially affect the properties of the steel, being iron.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Heat Treatment Of Steel (AREA)
- Arc Welding In General (AREA)
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE542504D BE542504A (enrdf_load_stackoverflow) | 1954-11-03 | ||
US466661A US2711959A (en) | 1954-11-03 | 1954-11-03 | Welding steel for developing high surface hardness under impact |
FR1134233D FR1134233A (fr) | 1954-11-03 | 1955-10-31 | Acier de soudure destiné à augmenter la dureté superficielle au choc |
GB31395/55A GB785808A (en) | 1954-11-03 | 1955-11-02 | Welding steel for developing high surface hardness under impact |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US466661A US2711959A (en) | 1954-11-03 | 1954-11-03 | Welding steel for developing high surface hardness under impact |
Publications (1)
Publication Number | Publication Date |
---|---|
US2711959A true US2711959A (en) | 1955-06-28 |
Family
ID=23852627
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US466661A Expired - Lifetime US2711959A (en) | 1954-11-03 | 1954-11-03 | Welding steel for developing high surface hardness under impact |
Country Status (4)
Country | Link |
---|---|
US (1) | US2711959A (enrdf_load_stackoverflow) |
BE (1) | BE542504A (enrdf_load_stackoverflow) |
FR (1) | FR1134233A (enrdf_load_stackoverflow) |
GB (1) | GB785808A (enrdf_load_stackoverflow) |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2949355A (en) * | 1955-07-27 | 1960-08-16 | Allegheny Ludlum Steel | High temperature alloy |
US3118760A (en) * | 1961-04-24 | 1964-01-21 | American Brake Shoe Co | Welding rods |
US3151979A (en) * | 1962-03-21 | 1964-10-06 | United States Steel Corp | High strength steel and method of treatment thereof |
US4121953A (en) * | 1977-02-02 | 1978-10-24 | Westinghouse Electric Corp. | High strength, austenitic, non-magnetic alloy |
US4394169A (en) * | 1981-05-15 | 1983-07-19 | Kabushiki Kaisha Kobe Seiko Sho | High strength austenite steel having excellent cold work hardenability |
GB2205854A (en) * | 1987-06-18 | 1988-12-21 | Agency Ind Science Techn | Erosion resistant alloys |
EP0338204A3 (de) * | 1988-02-25 | 1992-07-01 | TRW Motorkomponenten GmbH & Co KG | Hartstofflegierung |
CN107009046A (zh) * | 2017-03-28 | 2017-08-04 | 武汉科技大学 | 用于超低温高锰钢焊接的钨极氩弧焊实芯焊丝 |
CN107052618A (zh) * | 2017-03-28 | 2017-08-18 | 武汉科技大学 | 制备lng贮罐的高锰钢用全自动埋弧焊实芯焊丝 |
Families Citing this family (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT374396B (de) * | 1982-09-15 | 1984-04-10 | Voest Alpine Ag | Verfahren zur herstellung eines herzstueckes, insbesondere herzstueckspitze, aus stahl fuer schienenkreuzungen oder -weichen |
AT389833B (de) * | 1986-10-29 | 1990-02-12 | Voest Alpine Ag | Verfahren zur herstellung von herzstuecken unter verwendung eines stahles x 120 mn 13 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT152291B (de) * | 1936-10-07 | 1938-01-25 | Boehler & Co Ag Geb | Chrom-Mangan-Stähle mit 0¨01 1¨5% Kohlenstoff, 5 25% Chrom, 10 35% Mangan. |
US2671726A (en) * | 1950-11-14 | 1954-03-09 | Armco Steel Corp | High temperature articles |
US2698785A (en) * | 1952-12-31 | 1955-01-04 | Armco Steel Corp | Age-hardening austenitic stainless steel |
-
0
- BE BE542504D patent/BE542504A/xx unknown
-
1954
- 1954-11-03 US US466661A patent/US2711959A/en not_active Expired - Lifetime
-
1955
- 1955-10-31 FR FR1134233D patent/FR1134233A/fr not_active Expired
- 1955-11-02 GB GB31395/55A patent/GB785808A/en not_active Expired
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AT152291B (de) * | 1936-10-07 | 1938-01-25 | Boehler & Co Ag Geb | Chrom-Mangan-Stähle mit 0¨01 1¨5% Kohlenstoff, 5 25% Chrom, 10 35% Mangan. |
US2671726A (en) * | 1950-11-14 | 1954-03-09 | Armco Steel Corp | High temperature articles |
US2698785A (en) * | 1952-12-31 | 1955-01-04 | Armco Steel Corp | Age-hardening austenitic stainless steel |
Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2949355A (en) * | 1955-07-27 | 1960-08-16 | Allegheny Ludlum Steel | High temperature alloy |
US3118760A (en) * | 1961-04-24 | 1964-01-21 | American Brake Shoe Co | Welding rods |
US3151979A (en) * | 1962-03-21 | 1964-10-06 | United States Steel Corp | High strength steel and method of treatment thereof |
US4121953A (en) * | 1977-02-02 | 1978-10-24 | Westinghouse Electric Corp. | High strength, austenitic, non-magnetic alloy |
US4394169A (en) * | 1981-05-15 | 1983-07-19 | Kabushiki Kaisha Kobe Seiko Sho | High strength austenite steel having excellent cold work hardenability |
GB2205854A (en) * | 1987-06-18 | 1988-12-21 | Agency Ind Science Techn | Erosion resistant alloys |
FR2616807A1 (fr) * | 1987-06-18 | 1988-12-23 | Agency Ind Science Techn | Alliages presentant une excellente resistance a l'erosion |
GB2205854B (en) * | 1987-06-18 | 1991-02-27 | Agency Ind Science Techn | Erosion resistant alloys |
EP0338204A3 (de) * | 1988-02-25 | 1992-07-01 | TRW Motorkomponenten GmbH & Co KG | Hartstofflegierung |
CN107009046A (zh) * | 2017-03-28 | 2017-08-04 | 武汉科技大学 | 用于超低温高锰钢焊接的钨极氩弧焊实芯焊丝 |
CN107052618A (zh) * | 2017-03-28 | 2017-08-18 | 武汉科技大学 | 制备lng贮罐的高锰钢用全自动埋弧焊实芯焊丝 |
CN107052618B (zh) * | 2017-03-28 | 2019-03-19 | 武汉科技大学 | 制备lng贮罐的高锰钢用全自动埋弧焊实芯焊丝 |
Also Published As
Publication number | Publication date |
---|---|
BE542504A (enrdf_load_stackoverflow) | |
FR1134233A (fr) | 1957-04-09 |
GB785808A (en) | 1957-11-06 |
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