Classifications

• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
  • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
  • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
  • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
  • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
  • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
  • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
  • D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
  • D06M15/263—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof
  • D06M15/267—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of unsaturated carboxylic acids; Salts or esters thereof of unsaturated carboxylic esters having amino or quaternary ammonium groups
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
  • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
  • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
  • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
  • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
• • D—TEXTILES; PAPER
  • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
  • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
  • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
  • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
  • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
  • D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
  • D06M15/423—Amino-aldehyde resins
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T428/00—Stock material or miscellaneous articles
  • Y10T428/31504—Composite [nonstructural laminate]
  • Y10T428/31855—Of addition polymer from unsaturated monomers
  • Y10T428/3188—Next to cellulosic
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
  • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
  • Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
  • Y10T442/20—Coated or impregnated woven, knit, or nonwoven fabric which is not [a] associated with another preformed layer or fiber layer or, [b] with respect to woven and knit, characterized, respectively, by a particular or differential weave or knit, wherein the coating or impregnation is neither a foamed material nor a free metal or alloy layer
  • Y10T442/2369—Coating or impregnation improves elasticity, bendability, resiliency, flexibility, or shape retention of the fabric
  • Y10T442/2393—Coating or impregnation provides crease-resistance or wash and wear characteristics

Definitions

• This invention relates to the treatment of cellulosic textile materials and to the products thereof.
• the invention is concerned with the production of cellulosic textiles. specifically cotton fabrics, having improved properties (e. g., better resistance to creasing or wrinkling) by a process which comprises impregnating the textile with a particular combination of impregnants within a definite range of proportions of each. Conditions also are so maintained that the amount of combined impregnants which are retained by the textile is kept within definite limits.
• my process of improvin the properties of cotton and other cellulosic textiles comprises impregnating such textiles with ,a combination of (1) a curable (more particularly heat-curable) product of partial reaction of ingredients comprising melamine and formaldehyde, e. g., dimethylol melamine, trimethylol melamine, the heat-curable or thermosetting alkylated, specifically methylated, methylol melamines, etc., which partial reaction product is at least partly soluble and preferably substant: ally completely soluble in Water, and (2) a film-iorming, substantially water-insoluble, thermopastic product of polymerization of a polymerizable mass including a lower alkyl acrylate, e.
• a curable (more particularly heat-curable) product of partial reaction of ingredients comprising melamine and formaldehyde, e. g., dimethylol melamine, trimethylol melamine, the heat-curable or thermosetting alkyl
• the partial reaction product of 1) is cured in situ in intimate contact with the polymerization product of (2) to a substantially water-insoluble state.
• the total amount of the products of (1) and (2) that are applied to the cellulosic textile material is such that the finished textile contains from abouts to about 40%, more particularly from to 30%, by weight of the dry (net dry) textile, of a substantially washfast impregnant consisting of the product of (1) III-139.4)
• thermoplastic materials impart increased resistance to creasing or wrinkling to the textile, but, at least in the case of cotton fabrics or cloths, such contentions are inconsistent with available evidence.
• a thermoplastic impregnant when applied alone to a cellulosic textile material, specifically a cotton fabric, in amounts such as are employed in practicing my invention merely imparts a permanent non-spring finish to the fabric. There is no substantial improvement, if any, in the resistance of the fabric to creasing or wrinkling, and in many cases the tendency of the treated fabric to crease or wrinkle is even greater than that of the untreated fabric.
• the present invention is a solution to the problem of imparting a higher degree of crease resistance to cotton textiles, and e pecially to mercerized cotton fabrics, than has been obtained with the prior treating agents and to effect this result while at the same time obviating or minimizing losses in the tensile strength of the and specifically cotton fabrics, can be rendered resistant to creasing and the losses in tensile strength either obviated or materially lessened by treating the fabric as briefly described in the first and second paragraphs of this specification and more fully hereafter.
• the present invention is a solution to the problem of imparting a higher degree of crease resistance to cotton textiles, and e pecially to mercerized cotton fabrics, than has been obtained with the prior treating agents and to effect this result while at the same time obviating or minimizing losses in the tensile strength of the and specifically cotton fabrics, can be rendered resistant to creasing and the losses in tensile strength either obviated or materially lessened by treating the fabric as briefly described in the
• the degree of crease resistance imparted to the fabric is greater than that obtained by using only a curable methylated methylol melamine or other curable, water-soluble or -dispersible product of partial reaction of ingredients comprising melamine and formaldehyde. This was wholly unexpected and unpredictable, since the thermoplastic polymerization product alone does not impart markedcrease resistance, if any, to a cotton fabric.
• thermoplastic polymerization product would obviate or decrease the loss in 'tensile strength which'normally results when a cotton textile is impregnated with a curable methylated methylol melamine, v or equivalent curable product of partial reaction of ingredients comprising melamine and formaldehyde, and thereafter dried and cured, since from the known properties of thermoplastic polymers and copolymers it would not be expected that such materials would co-act, physically or otherwise, with the methylated methylol melamine or equivalent material so that the embrittlement of the textile, as evidenced by a decrease in its tensile strength, would be obviated or minimized.
• the impregnated cotton and other cellulosic textiles of my invention also are resistant to shrinking, as well as to wear and abrasion.
• the finish is durable and is not removed by washing in water.
• the hand may be varied considerably, for example, by varying the kind and amount of thermoplastic modifier employed and by variations in the impregnating and finishing operations. In some cases. it may be stiffer than that of fabrics containing a cured methylated methylol melamine alone, which is a characteristic that is desired in many types of cellulosic textiles.
• the curable partial reaction products of ingredients comprising melamine and formaldehyde which are used in practicing my invention are at least partly soluble in water, the preferred reaction products being those which are substantially completely soluble therein, either in the form of a true solution or a colloidal dispersion.
• melamine reaction products that may be employed are those which comprise one or more polymethylol melamines, more particularly di-, tri-, tetra-, pentaor hexamethylol melamine or mixtures thereof.
• Such products may be produced in known manner by effecting reaction under neutral or alkaline conditions between melamine and an aqueous solution of formaldehyde in the ratio of 1 mol of the former to from 2 Lo 6 or more mols of the latter.
• the mass advantageously is maintained at a temperature not less than about 70 C. during the reaction.
• reaction temperature In order to minimize polymerization of the monomer, it is usually desirable to keep the reaction temperature from exceeding about 90 C.
• the curable, methylated or methyl alcoholreacted methylol melamines, moreparticularly methylated polymethylol melamines, are especially suitable for use in practicing my invention. They may be prepared, for example, by effecting reaction under acidic conditions between a polymethylol melamine and methyl alcohol in the ratio of 1 mol of the former to from 2 to 6 mols of the latter, depending upon the number of methylol groupings in the melamine derivative and the extent of methylation (or etherification) desired. The reaction is stopped before the product becomes hydrophobic, alkali is added in an amount at least sufficient to neutralize the reaction mass, after which the mass is dehydrated under vacuum.
• methylated methylol melamine more particularly poly- (methoxymethyl) melamine
• Such methylated methylol melamines are miscible with water in all proportions at room temperature and are stable on storage at F. for at least two weeks.
• thermoplastic polymerization products are prepared by known methods. Although a polymer of a lower alkyl (e. g., methyl, ethyl, propyl, tert.-butyl, amyl, etc.) ester of acrylic acid may be used as the thermoplastic modifier, I prefer to employ copolymers or interpolymers of such esters (or mixtures thereof) with a suitable proportion of one or more other monomers which are compatible and copolymerizable therewith to yield a water-insoluble, fllm-forming thermoplastic copolymerization product which is flexible or pliable in film form.
• a polymer of a lower alkyl e. g., methyl, ethyl, propyl, tert.-butyl, amyl, etc.
• the monovinyl compounds both aliphatic and armomatic
• the vinyl esters of saturated aliphatic monocarboxylic acids e. g., vinyl acetate, vinyl propionate, vinyl butyrate, etc
• the monovinylsubstituted cyclic compounds for instance styrene and the various nuclearly substituted styrenes (e.
• acrylamide and the N-monoand -di-alky1 acrylamides e. g., N- methyl acrylamide, N-diethylacrylamide, etc. alkacrylic compounds, including the acids, esters, nitriles and amides, e.
• methacrylic, ethacrylic, etc. acids, methacrylamide, ethacrylamide, etc., and the N-monoalkyl and -dialkyl substitution products thereof, methacrylonitrile, ethacrylonitrile and other hydrocarbon-substituted acrylonitriles, the methyl, ethyl, propyl, isopropyl, n-butyl, isobutyl, amyl, e.c., esters of methacrylic, ethacrylic, etc., acids; the allyl and methallyl esters of saturated monocarboxylic acids, e.
• Suitable compounds of this class are those which, like 1,3-butadiene, are compatible and copolymerizable with the lower alkyl acrylate to yield a water-insoluble, film-forming thermoplastic copolymerization product which is flexible or pliable in film form.
• the monomeric material which is copolymerized with the monomeric lower alkyl acrylate may constitut as much as 90% by weight of the mixture of monomers, but usually I employ a thermoplastic modifier obtained by polymerization of a mixture containing, by weight, from 70 to 90% of the lower alkyl acrylate and from 30 to 10% of the other copolymerizable monomer. I prefer to use copolymers of, by weight, from '70 to 90% of ethyl acrylate and from 30 to 10% of styrene or acrylonitrile.
• the polymers and copolymers used in practicing my invention are either substantially water-insoluble per se or yield substantially water-insoluble compositions when the reactive melamine derivative is cured in intimate contact with the polymer or copolymer.
• thermoplastic polymerization products may be prepared in any suitable manner but advantageously are produced by emulsion polymerization (or copolymerization) technique, for example as described in the copending application of Edward. L. Kropa, Serial No. 636,279, now abandoned, .filed December 20, 1945, with particular reference to the emulsion copolymerization of styrene and certain acrylic esters.
• curable, methylated methylol melamine, more particularly methylated polymethylol melamine, or other curable partial reaction product of ingredients comprising melamine and formaldehyde and the thermoplastic polymerization product are ordinarily, and preferably, applied to the cellulosic material in the form of an aqueous dis-- persion or emulsion containing the aforemen tionedingredients, e. g., in a concentration of from 8 to 40%, more particularly from 10 to 30%,
• the reactive melamine resin may be in dissolved state and the thermoplastic modifier dispersed in the aqueous solution of the dissolved melamine resin.
• a suitable catalyst may be added to the aqueous dispersion. e. g., oxalic acid, acetic acid, phosphoric acid, diammonium hydrogen phosphate, ethyl ammonium phosphate, diammonium phthalate, ammonium chloride, zinc chloride, and others which are known to be catalysts for ouring such reaction products.
• the amount of catalyst may be varied as desired or as conditions may require, but ordinarily the catalyst is employed in an amount corresponding to from 0.5 to 5% by weight of the melamine derivative.
• the curable methylated methylol melamine or other melamine derivative of the kinds aforementioned and thermoplastic polymerization product are employed in the ratio of, by weight, 1 part of the former to from 1 to 3 parts (preferably from 1 to 2 parts) of the latter.
• the thermoplastic modifier must be used in a weight ratio which is at least equal to that of the melamine derivative in order to obtain the results (e. g., better crease resistance, minimizing or obviating tensile strength losses, etc.) hereinbefore set forth. If a weight ratio of thermoplastic modifier to melamine derivative materially above 3 to 1 be employed,-the impregnated cloth is excessively weighted, usually has a non-drapey hand and is not satisfactory for use in applications (e.
• the melamine derivative and thermoplastic polymerization product may be applied to the cotton fabric or other cellulosic textile material in various ways.
• the curable reaction product and thermoplastic modifier are applied in the form of an aqueous dispersion
• the dry or substantially dry cellulosic fabric to be treated may be immersed in the dispersion. and then passed through pressure rolls or padders to secure uniform impregnation and a controlled removal of the excess dispersion.
• the fabric or other textile may be impregnated by other methods, e. g., by spraying or by means of suitable boxes located on a mangle.
• aqueous dispersion as used generally herein with reference tothe aqueous composition containing the reactive melamine resin and thermoplastic modifier includes within its meaning aqueous dispersions in which the reactive melamine resin is present either dissolved in the aqueous phase in the form of a true solution or colloidal dispersed in the said phase.
• aqueous dispersion by the cotton or other cellulosic material being treated should be adjusted so that the finished textile will contain from 8 to 40%, more particularly from 10 to 30%, by weight Of the dry textile, of the cured resin (e. g., cured methylated methylol melamine) admixed with the particular thermoplastic modifier employed in the ratio of, by weight, from 1 to 3 parts (preferably from 1 to 2 parts) of the latter for each part of the former.
• the cured resin e. g., cured methylated methylol melamine
• the amount of aqueous dispersion picked up by the cellulosic textile may be varied as desired or as conditions may require and may range, for example, from about 40 to about or more by weight of the dry textile depending, for example, upon the particular textile treated, method and conditions of treatment, concentration of solids in methylated polymethylol melamine.
• the impregnating bath amount of solids and properties desired in the finished textile, etc.
• the wet, impregnated cotton fabric or' other cellulosic textile material is then dried and cured.
• the drying and curing temperatures may be varied considerably, but ordinarily temperatures within the range of about 200 F. to about 400 I".
• the impregnated fabric may be ployed) admixed with the thermoplastic poly-- merization product, e. g., polymeric ethyl acrylate a copolymer of ethyl acrylate and styrene or acrylonitrile, etc., to a substantially water-insoluble condition.
• the drying and curing operation is flexible and may be varied to suit ,the available equipment. Continuous methods are preferred.
• drying and curing also may be effected by framing the impregnated fabric to width, as on a pin tenter, drying the framed fabric, batching it upon a shell and then allowing it to stand hot for a period sumcient to complete the drying (if not entirely dried Previously) and to convert the solid impregnant in situ to a water-insoluble state.
• drying and curing for 2 r 3 hours at 200 F. may be required. Heating the dried fabric for 1 minute at 340 F. or for a shorter time at a higher temperature has effectively water-insolubilized the impregnant.
• the finishing treatment usually consists in washing the treated textile, e. g., in an aqueous 150'-190 F. solution containing. by weight, from 0.1 to 0.2% of soapand 0.1% soda ash, followed by rinsing in hot water at the same temperature, drying and then calendering either hot or cold.
• the process of the present invention may be used in treating both uncolored and colored goods. It is applicable to the treatment of both bleached and unbleached cotton goods, as well as mercerized cotton fabrics. Surprisingly, the results are generally better, especially in plant operations, on mercerized, more particularly scoured and mercerized or bleached and mercerized, materials than on unmercerized cotton textiles.
• the methylated methylol melamine used in all of the examples was a substantially completely water-soluble, heat-curable or thermosetting
• This material is prepared by the following process: One mol of melamine is mixed with 3.3 mol's of aqueous 37% formaldehyde previously adjusted to a pH of approximately 8.0, the temperature being raised to 70 C. and maintained at this point until a clear solution is obtained.
• the solution powder is alkylated by admixture with twice its weight of 95% methanol containing 0.5% of oxalic acid crystals, based on the weight of the methylol melamine. The mixture is heated to 70 C. and held at this temperature for approximately minutes, or
• the bath was made by diluting with water a composition comprising about 80% methylated methylol melamine and 20% water. and the resulting product was then stirred into an emulsion ofthe polymerization product.
• Impregnation was carried out by soaking the fabric material for about V minute in the bath and squeezing the impregnated fabric through a padder so that the amount of liquid impregnant retained by the fabric .(so called "wet pick-up") was about 90% by weight of the dry fabric. The squeezed fabric was then heated for 6. minutes at 290 F. to dry the fabric and to cure the applied resinous composition, that is, curable methylated methylol melamine admixed with the particular polymerization product employed, to a substantially water-insoluble state.
• the dried textile was then given a mild washing for 2 minutes in an aqueous 160 F. solution containing 0.1% soap and 0.1% sodium bicarbonate, followed by thorough rinsing in water at 160 F. and squeezing of the rinsed fabric.
• the fabrics employed in this example were x 80 cotton percale and mercerized cotton twill.
• the bath compositions each contained 30% by weight of solids, of which 10% of the bath composition was methylated methylol melamine and 20% was a thermoplastic polymerization product.
• a bath containing 10% by weight of methylated methylol melamine and no thermoplastic additive was included in the series of tests.
• the wet pick-up was about by weight of the dry fabric.
• the finished fabric contained about 27 by weight of the dry fabric, of solid, resinous impregnant of which A; was cured methylated methylol melamine resin and 3:; was thermoplastic modifier. Tables I and 11 show the thermoplastic materials employed and test data on the treated and lightly washed fabrics.
• Total T. B. Lpcrease Resistance (W plus F in cm.) in the tables refers to the total values of crease resistance of samples of the treated fabrics out along the warp and along the weft, using the apparatus and procedure developed by Tootal Broadhurt Lee Company. Ltd. (Manchester, England) and described in publications of this company. In this test, strips of fabric time the distance between theends of the sample is measured by means of a calibrated plane mir- EXAMPLE 2 Same as Example 1 with the exception that the bath contained 22%% solids (736% methylated methylol melamine plus 15% of the thermoplastic modifier). The wet pick-up was about 90% by weight of the dry cloth. Table III shows the thermoplastic materials employed and test data on the treated and lightly washed fabrics.
• T. B. L. crease-resistance rating is the distance in centimeters between the ends of the sample after it has been subjected to the treatment described above.
• the total T. B. L. crease-resistance values reported in the tables are in each case the sum of the values obtained upon testing a strip of the fabric out along the warp and another strip out along the weft or filling.
• Example 1 Same as Example 1 with the exception that the bath contained 15% solids (5% methylated methylol melamine plus 10% of the thermoplastic modifier). The wet pick-up was about 90% by 5 weight of the dry cloth. Table IV shows the thermoplastic modifiers employed and test data on the treated and lightly washed fabrics.
• Table IV Mercerized cotton twlll-% metlwlated methylol melamine and thermoplastic modifier 'r I] 'r tal ggg o: '1. is. L. Test No. Thermoplastic Additive Strength g: gfi ifg @5 (Approx. (w plus F Percent) in cm Untreated mercerized 192 4.2
• EXAMPLE 4 fabric is approximately the same as that of the Same as Example 1 with the exception that 20 untreated fabric- 5 impregnating baths comprising, by weight, 10% of methylated methylol melamine and 10%, 15%, Same as Example 1 with the exception that im- 20% and of a copolymer of 80% ethyl acrylpregnating baths comprising, by weight, 10% oi.
• the wet pick-up was about 90% by copolymer present), and 10%, 15% and 20% of weight of the dry cloth. the same copolymer (with no methylated methylol melamine present).
• the baths containing Table V' Resm solids bath methylated methylol melamine also contained a h t Th 1 U A llllng accelerator of the kind and in the perfig gfi i as centage mentioned under Example 1.
• the resin Test Mel solids in the various baths are shown in Table VII.
• Table VI Total Tensile Total T -B L
• Table VIII ShOWS test data obtained on the W sltrellggthlb (g'leaie Rgsistanoe treated and washed samples.
• TestNm pus m pus mcm' comparison data also are given on a sample of Li ht 1 Hr Li ht Hr the untreated mercerized broadcloth which had 5 was ⁇ ; i been immersed in water and dried prior to testing for tensile strength and crease resistance.
• thermoplastic modifiers mentioned 128 in Tables I to IV, inclusive are employed alone in treating cotton percale or mercerized cotton ms twill, that is, in the absence of methylated meth- 07 5.9 ylol melamine but with other conditions the same as when the methylated methylol melamine alone From the results of the above tests it will be or with the thermoplastic modifier is used, the noted that the combination of the thermoplastic total T. B. L.
• crease resistance of the impregnated copolymer and methylated methylol melamine 13 provides a treated cloth having a materially improved crease resistance as compared with the untreated cloth and much better than that shown by cloths which have been treated with the a '14 treatment herein described also may be applied to other textiles which are composed substantially or mainly of cellulose or regenerated-celluloses, e. g., linen, hemp, jute, ramie, sisal, cellulose methylated methylol melamine alone or with acetate rayons, cellulose acetate-butyrate rayons, various percentages of the thermoplastic copclysaponified acetate rayons, viscose rayons, cuprammer alone.
• cellulose or regenerated-celluloses e. g., linen, hemp, jute, ramie, sisal, cellulose methylated methylol melamine alone or with acetate rayons, cellulose acetate-butyrate rayons,
• the combination of monium rayons, ethyl cellulose, etc., and mixtures treating agents yields a treated cloth having a thereof with each other or with cotton.
• the higher tensile strength than that obtained by invention is particularly applicable to the treatusing methylated methylol melamine alone.
• ment of cotton fabric material, specifically mer- Similar results are obtained when other 00- cerized cotton cloth, and hence such textiles are polymers, e. g., copolymers of, by weight, 70-85% preferred for treating to improve their properethyl acrylate and 30-15% styrene, copolymers ties as hereinbefore described.
• curable methylated methylol melamine or other Ex I I LE 6 curable product of partial reaction of ingredients Pounds comprising melamine and formaldehyde and the resulting combination or admixture may be used
• Examples of such polymerization products are the polymers (or copolymers) obtained Curing accelerator as in Example 1 2 water Sumcient to make 100 gallons by polymerizing, alone or admixed 1th each other or with other monomers, the monomeric
• Curing accelerator as in Example 1 2 water Sumcient to make 100 gallons by polymerizing, alone or admixed 1th each other or with other monomers, the monomeric
• the above ingredients were mixed to yield an materials hereinbefore mentioned with particuimpregnflting b which had a D 0
• This lar reference to compounds that may be copolybath was used in a plant run in treating four merized with a lower alkyl acrylate to yield codiiferent cellulosic fabric materials.
• the dry polymers suitable for use in practicing the presfabrics were passed continuously at 48 yards per ent invention.
• Such polymers and copolymers minute through the bath (2 dips and 2 nips). however, are not equivalent, in the relationship in the bath temperature being 80 F.
• the impregwhich they are used, to the polymers and copolynated fabrics were dried in a pre-drier at 220 F. mers of the lower alkyl acrylates. and then in a tenter frame at 300 F., followed The terms textile and "textile material" as by heating for 1 minute at 340 F.
• methylated methylol melamine admixed with include within their meaning filaments, fibers, the ethyl acrylate-styrene copolymer to a subthreads, yarns, twisted yarns, etc., as such or stantially water-insoluble state.
• the process of improving the properties of cord fabric (cloth No.
• treated cloths (W plus F in cm.) Hand and finish of treated cloths... G0od... Good Good Very good.
• a process as in claim 1 which includes the additional steps of washing the treated textile material in an aqueous soap-containing solution followed by rinsing in water; drying the washed and rinsed textile; and calendering thedried textile.
• component of (2) is a thermoplastic product of polymerization of a mixture of monomers of which not less than 50% by weight thereof is ethyl acrylate and the remainder acrylonitrile.
• the filmforming substance of (2) is a copolymer of monomers consisting of, by weight, from about 70% to about 90% of ethyl acrylate and from about 30% to about 10% of styrene.
• thermoplastic material of 2 is a copolymer of monomers consisting of, by weight, about 90% ethyl acrylate and about 10% styrene.
• a cotton fabric material which is resistant to creasing and which contains from 10 to 30%, by weight of the dry fabric material, of a combination of (l) a substantially water-insoluble, cured product which, prior to curing, is a curable methylatedmethylol melamine and (2) a filmforming substance consisting essentially of a substantially water-insoluble, thermoplastic product of polymerization of polymerizable monomers, said polymerizable monomers consisting of, by weight, from 50 to 100% of ethyl acrylate and up to 50% of styrene.
• thesaid polymerization product being present in the combination thereof with i the said curable methylated methylol melamine, before curing of the latter, in a weight ratio corresponding to from 1 to 3 parts thereof for each part of the said curable methylated methylol melamine, and the said cotton fabric material from 10 to 30%, by weight of the dry fabric material, of a combination of (1) a substantially water-insoluble, cured product which, prior to curing, is a water-soluble, curable methylated methyl melamine and (2) a thermoplastic material which is a copolymer of monomers consistin: of, by weight, from about 70% to about 90% asaaoao of ethyl acrylate and from about 30% to about of styrene, the said copolymer being present in the combination thereof with the said curable methylated methylol melamine, before curing of the latter, in a weight ratio corresponding to from 1 to 2 parts thereof for each part of the said curable methylated methyl
• a cellulosic fabric material which is resistant to creasing and which is impregnated with from about 10% to about 30%, by weight of the dry fabric material, of a combination of (1) a substantially water-insoluble, cured product which, prior to curing, is a water-soluble, curable methylated methylol melamine and (2) a copolymer of 90% ethyl acrylate and 10% styrene, the said copolymer being present in the combination thereof with the said curable methylol melamine, before curing of the latter, in a weight ratio corresponding to from 1 to 2 parts thereof for each part of the said curable methylated methylol melamine, and the said cellulosic fabric material having a higher tensile strength and a better crease resistance than the same celluloslc fabric material which has been similarly impregnated with the same amount of the same product of (1) but none of the copolymer of (2).
• the method of rendering a cotton-containing fabric material resistant to shrinking and otherwise improving its properties which comprises immersing the material to be treated in an impregnating bath maintained at a temperature of about 80 F., said bath having a pH of about 'I and being constituted of Emulsion ofa copolymer of ethyl acrylate and 10% styrene (25% solids)
• Curing accelerator consisting essentially of a mixture of diammonium hydrogen ph osphate (curing catalyst) and hexamethylene tetramine (buffering agent) in the ratio of about 30 parts of the former to about 4 parts of the latter 2 Water Sufiicient to make gallons adjusting the wet pick-up of the fabric so that the amount of cured methylated methylol melamine plus the aforementioned copolymer of ethyl acrylate and styrene on the fabric (after drying and curing) averages about 11.8% by weight of the dried fabric, of which about 5%
• a method as in claim 15 which includes the additional step of cold calendering the dried fabric.

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• Chemical Or Physical Treatment Of Fibers (AREA)

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Cited By (26)

Citations (4)

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• 0
  • BE BE485717D patent/BE485717A/xx unknown
  • NL NL71547D patent/NL71547C/xx active
• 1947
  • 1947-11-10 US US785188A patent/US2536050A/en not_active Expired - Lifetime
• 1948
  • 1948-10-08 GB GB2627348A patent/GB664993A/en not_active Expired
  • 1948-10-27 FR FR974362D patent/FR974362A/fr not_active Expired
  • 1948-11-03 ES ES0185807A patent/ES185807A1/es not_active Expired
• 1950
  • 1950-09-30 DE DEA3923A patent/DE936029C/de not_active Expired

Patent Citations (4)

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