US2520334A - Method of selective carburization - Google Patents

Method of selective carburization Download PDF

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US2520334A
US2520334A US773352A US77335247A US2520334A US 2520334 A US2520334 A US 2520334A US 773352 A US773352 A US 773352A US 77335247 A US77335247 A US 77335247A US 2520334 A US2520334 A US 2520334A
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gears
carburizing
articles
bores
carburized
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Robert J Peters
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Borg Warner Corp
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    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/06—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases
    • C23C8/08—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using gases only one element being applied
    • C23C8/20—Carburising
    • C23C8/22—Carburising of ferrous surfaces
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C8/00—Solid state diffusion of only non-metal elements into metallic material surfaces; Chemical surface treatment of metallic material by reaction of the surface with a reactive gas, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C8/04—Treatment of selected surface areas, e.g. using masks

Definitions

  • This invention relates to the carburizing of gears and other articles having bores, the articles being particularly of steel.
  • Steel gears for some purposes necessarily must have the diameters of their bores controlled within close limits.
  • Heat treating of the gears, including carburiz ing, has the effect of producing some distortion and change in diameters of the bores of the gears, and for this reason it has been found d sira le Fe b e eht h b s e t h s after they have been hardened by heat treating.
  • an object of the invention to provide an improved method of carhurizing in which the amount of carburizing gas admitted Within the bores of the gears is controlled so that the inside surfaces of the gears are carburized less than the outer surfaces.
  • Fig. 1 is a schematic sectional view of a carburizing apparatus in which the method of the invention is illustrated as being practiced;
  • Fig. 2 is a detailed sectional view of a portion oi one of the gear holding trays utilized in the method of the invention showing the gears stacked thereon preparatory to carburizing;
  • Fig. .3 is a detailed view .on an enlarged scale showing one .of the washers used between the gears when the gears are stacked as shown in Fig. 2.
  • I utilize a standard carburizing furnace (although any other furnace of any suitable type may be used instead) which may include a combustion chamber NJ formed between a muflie I! and the outer housing 1-2 of the furnace.
  • a standard carburizing furnace which may include a combustion chamber NJ formed between a muflie I! and the outer housing 1-2 of the furnace.
  • an atmosphere l3 of carburizing gas which is circulated by means of a pump I4, being drawn from the forward region of the muffie through a pipe [5 and returned to the rearward region of the muffle through a pipe
  • the carburi-zing gas may be a mixture of 18 to 20% of carbon monoxide, l to 3% of methane, 3 8 to 40% of hydrogen and 3-8 to 40% of nitrogen, and there may be traces of other miscellaneous hydrocarbons and moisture, although carburizing gas of these proportions is satisfactgry, it will be understood that carburizing gas of other proportions and constituents instead may be used, this particular gas being mentioned only by way of
  • the respective ends of the muflle H are closed by c s r membe s 11 and re pectively, which ma be e con en n l v al s al doors ada ed to b raised e al t n an at one en nd th e t hem-th th r e o he ay l9 and th ears sta ke her n
  • the washers 2B are of such a material :as to allow only a predetermined amount of the carburizing gas to pass therethrough and into contact with the bores 25.
  • asbestos is a suitable material for such purpose and it furthermore is capable of withstanding the high temperatures within the carburizin'g furnace.
  • preparing the gears for carburizing they are first threaded on to a rod or pin 27 which is 4 threaded into a base 28 of a tray 59.
  • a washer 26 is put below the first gear 28a threaded on the rod 21 and the other washers 26 are put between adjacent gears 20 as they are threaded on the rod 21.
  • a washer 26 is placed on top of the uppermost gear 201) of the stack, and a nut 29 is secured on to the threaded upper end of the rod 21 for securing the stack of gears together.
  • the gears are so stacked together, they are passed through the carburizing atmosphere of the furnace and a predetermined amount of the carburizing gas passes through the asbestos separators and into the chamber formed by the coinciding bores 25 of the gears.
  • the stacked gears are fed through the furnace being admitted at one end and coming out of the furnace at the other end, and during such a course, the external surfaces of the gears 2i! are carburized to a much greater extent than are the bores of the gears, due to the inhibiting action of the asbestos separators 25.
  • the carburizing of the external surfaces of the gears was such as to produce, after the gears were subsequently heated and quenched according to standard procedure a Rockwell hardness of C58 to C62 with the untreated steel having only a hardness of approximately C13.
  • the inhibiting effect of the asbestos washers 26 was such that a carburizing within the bores 25 of the gears was only such as to produce a hardness of C25 to 035. This latter hardness was substantially above the hardness of the steel in its untreated condition but was substantially less than the hardness of the outer surfaces of the gears.
  • the carburizing just described is preliminary to other steps in a normal hardening process.
  • the work is maintained in the carburizing atmosphere a normal carburizing period which may range from 14 to 16 hours and the work is then discharged and lowered into a quenching bath, whence it is carried through a cleaning bath and a tempering furnace (not shown).
  • the bores of the gears are finished all as desired. If the gears are desired with splined bores, splines 200 (see Fig. 2) may be cut in the bores 25 preliminary to any hardening operations, and a final sizing broach may be used in the bores of the gears after hardening.
  • a method of carburizing articles of steel having a bore in which the inside of the bore is carburized to a substantial extent but less than the outer surfaces of the article which method includes, stacking the articles together so that their bores substantially coincide with each other to form a chamber, closing said chamber with asbestos which is permeable to some extent to carburizing gas, and placing the articles in a heated carburizing atmosphere.
  • a method of carburizing articles of steel having a bore in which the-inside of the bore is carburized to a substantial extent but less than the outer surfaces of the article which method includes, stacking the articles together so that their bores substantially coincide, placing separators between said articles, said separatorsbeing of asbestos whichis permeable to some extent to carburizing gas, and placing the articles in a heated carburizing medium.
  • a method of carburizing articles of stee in which portions of the surfaces of the articles are carhurized to a less extent than the remaining surfaces of the articles which method'includes, masking the surfaces of the article to be carburized to a less extent with a permeable masking material comprised of asbestos which is impregnated with copper and copper oxide, and placing the article in a carburizing atmosphere.
  • a method of carburizing articles of steel having a bore in which the inside of the bore is carburized to a substantial extent but less than the outer surfaces of the article which method includes stacking the articles together so that their bores substantially coincide with each other and placing permeable separators between said articles, said separators being impregnated with metallic copper and copper oxide to restrict the permeability thereof, and placing the articles in a carburizing atmosphere.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)

Description

Aug; 29, 1950 R. J. PETERS METHOD OF SELECTIVE CARBURIZATION Filed Sept. 11. 1947 Patented Aug. 29, 1950 ariam; .or snn pTivE CARBURIZATION Robert J. Peters, Muncie, Ind, assig nor to Borg Warner .Corporation, Chicago, 111., a corporah n ef l ih is Applicafipxl September 11, 1-947, Serial No. 773,352
(01. nag-.14)
4 Glaims. 1
This invention relates to the carburizing of gears and other articles having bores, the articles being particularly of steel.
Steel gears for some purposes, as for example for use in transmissions, necessarily must have the diameters of their bores controlled within close limits. Heat treating of the gears, including carburiz ing, has the effect of producing some distortion and change in diameters of the bores of the gears, and for this reason it has been found d sira le Fe b e eht h b s e t h s after they have been hardened by heat treating.
he e e he s th hewe r. e a e t e gears must he e eeme a dne less h n t a o he ente u f e of the ea s bu yet sh ld be ha de hen h st e n its e heiti h be o e heat treating. In a gear having internal splines in its nal o m he sea is efe a y e li y eeh s b e h at re h d th s e is finished internally by a final sizing breach after ard n n hence a ises the ee for a ha ness in the bore of the gear materially less than the hardness on the outer surfaces of the gear.
It is therefore an object of the present invention to provide an improved method for carburizing gears or similar objects haying bores so that the articles within their bores have a substantial amount of carburizing but yet are carburized to a less extent than the outer surfaces of the articles.
To this end it is an object of the invention to provide an improved method of carhurizing in which the amount of carburizing gas admitted Within the bores of the gears is controlled so that the inside surfaces of the gears are carburized less than the outer surfaces.
' It is therefore a more specific object of the inventlon to prcvide an improved method of car,- burizing gears or similar articles which includes stacking the gears with their bores substantially e ei h n hle h e h' r t r o ehe t e e other material allowing only a predetermined amount of carburizing gas to pass therethrough between the gears, prior to placing the gears in a heated carburizing atmosphere.
Other objects, advantages and uses of the invention will become more apparent after reading the following specification and claims and after consideration of the drawing forming a part of the specification, wherein:
Fig. 1 is a schematic sectional view of a carburizing apparatus in which the method of the invention is illustrated as being practiced;
Fig. 2 is a detailed sectional view of a portion oi one of the gear holding trays utilized in the method of the invention showing the gears stacked thereon preparatory to carburizing; and
Fig. .3 is a detailed view .on an enlarged scale showing one .of the washers used between the gears when the gears are stacked as shown in Fig. 2.
Like characters of reference designate like parts in the several views.
In the practice of the invention, I utilize a standard carburizing furnace (although any other furnace of any suitable type may be used instead) which may include a combustion chamber NJ formed between a muflie I! and the outer housing 1-2 of the furnace. Within the mufile H there is maintained an atmosphere l3 of carburizing gas which is circulated by means of a pump I4, being drawn from the forward region of the muffie through a pipe [5 and returned to the rearward region of the muffle through a pipe The carburi-zing gas may be a mixture of 18 to 20% of carbon monoxide, l to 3% of methane, 3 8 to 40% of hydrogen and 3-8 to 40% of nitrogen, and there may be traces of other miscellaneous hydrocarbons and moisture, Although carburizing gas of these proportions is satisfactgry, it will be understood that carburizing gas of other proportions and constituents instead may be used, this particular gas being mentioned only by way of example.
The respective ends of the muflle H are closed by c s r membe s 11 and re pectively, which ma be e con en n l v al s al doors ada ed to b raised e al t n an at one en nd th e t hem-th th r e o he ay l9 and th ears sta ke her n The a hle p ere I 3 Wi hin th mu l i ma n n d a e urizih tem ratur s i he nei hborh f 700) y eemb st e wi in the h m e f a suita e fue pre erabl h d c bon gas, wh h ma h nt o uced th f e pip s 2.1 and 22 adin th u he o sing I2. In such atmos h re he s e r 2e abso b ca b n hem the eerb rizins as. li t n h o n which is disposed of by combustion at the mouth h the mu le when t oo s H and 8 a e r ise ,Fresh cer u izing s ma be i t oduc d t end, the inv n on em lhys se ara ors in t e r h of washers 26 placed between adjacent gears 20 as the gears are mounted on the trays I9. The washers 2B are of such a material :as to allow only a predetermined amount of the carburizing gas to pass therethrough and into contact with the bores 25. I have found that asbestos is a suitable material for such purpose and it furthermore is capable of withstanding the high temperatures within the carburizin'g furnace.
In preparing the gears for carburizing they are first threaded on to a rod or pin 27 which is 4 threaded into a base 28 of a tray 59. A washer 26 is put below the first gear 28a threaded on the rod 21 and the other washers 26 are put between adjacent gears 20 as they are threaded on the rod 21. A washer 26 is placed on top of the uppermost gear 201) of the stack, and a nut 29 is secured on to the threaded upper end of the rod 21 for securing the stack of gears together.
After the gears are so stacked together, they are passed through the carburizing atmosphere of the furnace and a predetermined amount of the carburizing gas passes through the asbestos separators and into the chamber formed by the coinciding bores 25 of the gears. The stacked gears are fed through the furnace being admitted at one end and coming out of the furnace at the other end, and during such a course, the external surfaces of the gears 2i! are carburized to a much greater extent than are the bores of the gears, due to the inhibiting action of the asbestos separators 25.
In one particular set-up, cited only by means of example, the carburizing of the external surfaces of the gears was such as to produce, after the gears were subsequently heated and quenched according to standard procedure a Rockwell hardness of C58 to C62 with the untreated steel having only a hardness of approximately C13. The inhibiting effect of the asbestos washers 26 was such that a carburizing within the bores 25 of the gears was only such as to produce a hardness of C25 to 035. This latter hardness was substantially above the hardness of the steel in its untreated condition but was substantially less than the hardness of the outer surfaces of the gears.
I have found that as an alternative to using plain asbestos washers 26, good results are obtained also in using such washers which have been previously soaked in solutions containing appropriate salts and subsequently baked in an oven to drive out the acid and moisture. One such salt is copper sulphate and the subsequent baking leaves a residue of metallic copper and copper oxide, and this residue resists the diffusion of the carbonaceous gases through the asbestos to the inner surfaces of the gears. The other salts of copper are also useful for this purpose, and the salts of tin and nickel are useful for this purpose also, but to a less degree. Ihe copper in the copper salts apparently also has the additional function of breaking down the carbonaceous gas to form carbon at least to a greater extent than the salts of other metals mentioned and hence its greater usefulness.
It will be understood that the carburizing just described is preliminary to other steps in a normal hardening process. The work is maintained in the carburizing atmosphere a normal carburizing period which may range from 14 to 16 hours and the work is then discharged and lowered into a quenching bath, whence it is carried through a cleaning bath and a tempering furnace (not shown). After the gears have been so hardened, the bores of the gears are finished all as desired. If the gears are desired with splined bores, splines 200 (see Fig. 2) may be cut in the bores 25 preliminary to any hardening operations, and a final sizing broach may be used in the bores of the gears after hardening.
I wish it to be understood that my invention is not to be limited to the specific constructions, arrangements, methods and processes hereinbefore described except only insofar as the claims may be so limited, as it will be understood to those skilled in the art that changes may be made without departing from the principles of the invention. In particular, I wish it to be understood that although I have shown and described a gas carburizing furnace through which the parts to be carburized are passed, my invention is also suitable for use in connection with carburizing agents which may be liquid or solid hydrocarbons as are used at present in conventional casehardening operations.
I claim:
1. A method of carburizing articles of steel having a bore in which the inside of the bore is carburized to a substantial extent but less than the outer surfaces of the article, which method includes, stacking the articles together so that their bores substantially coincide with each other to form a chamber, closing said chamber with asbestos which is permeable to some extent to carburizing gas, and placing the articles in a heated carburizing atmosphere.
2. A method of carburizing articles of steel having a bore in which the-inside of the bore is carburized to a substantial extent but less than the outer surfaces of the article, which method includes, stacking the articles together so that their bores substantially coincide, placing separators between said articles, said separatorsbeing of asbestos whichis permeable to some extent to carburizing gas, and placing the articles in a heated carburizing medium.
3. A method of carburizing articles of stee in which portions of the surfaces of the articles are carhurized to a less extent than the remaining surfaces of the articles, which method'includes, masking the surfaces of the article to be carburized to a less extent with a permeable masking material comprised of asbestos which is impregnated with copper and copper oxide, and placing the article in a carburizing atmosphere.
4. A method of carburizing articles of steel having a bore in which the inside of the bore is carburized to a substantial extent but less than the outer surfaces of the article, which method includes stacking the articles together so that their bores substantially coincide with each other and placing permeable separators between said articles, said separators being impregnated with metallic copper and copper oxide to restrict the permeability thereof, and placing the articles in a carburizing atmosphere.
ROBERT J. PETERS.
REFERENCES CITED The following references are of record in th file of this patent: I
UNITED STATES PATENTS Number l iaroe Date 1,459,409 McQuaid June 10, 1923 1,716,191 Schermer et al June 4, 1929 2,275,133 Davis Mar. 3, 1942 2,439,637 Steinmeyer Apr. 13, 1948

Claims (1)

  1. 3. A METHOD OF CARBURIZING ARTICLES OF STEEL IN WHICH PORTIONS OF THE SURFACES OF THE ARTICLES ARE CARBURIZED TO A LESS EXTENT THAN THE REMAINING SURFACES OF THE ARTICLES, WHICH METHOD INCLUDES, MASKING THE SURFACES OF THE ARTICLE TO BE CARBURIZED TO A LESS EXTENT WITH A PERMEABLE MASKING MATERIAL COMPRISES OF ASBESTOS WHICH IS
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Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3136664A (en) * 1959-12-15 1964-06-09 Sedis Transmissions Mec Steel transmission chain
US3172788A (en) * 1963-08-26 1965-03-09 Method of.making and heat treating food waste disposer shredding rings
US3226254A (en) * 1961-06-09 1965-12-28 Siemens Ag Method of producing electronic semiconductor devices by precipitation of monocrystalline semiconductor substances from a gaseous compound
US3873376A (en) * 1972-02-16 1975-03-25 Daimler Benz Ag Method for case hardening workpieces
US4154628A (en) * 1976-11-15 1979-05-15 Mannesmann Aktiengesellschaft Quench hardening of gears
US5085713A (en) * 1988-07-22 1992-02-04 Mitsubishi Denki Kabushiki Kaisha Method of forming a partially carburized starter output shaft
US20070144103A1 (en) * 2005-12-28 2007-06-28 Jtekt Corporation Method of manufacturing hollow member
US20070224075A1 (en) * 2006-03-24 2007-09-27 Gkn Sinter Metals, Inc. Forged carburized powder metal part and method

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1459409A (en) * 1922-01-09 1923-06-19 Timken Roller Bearing Co Process of carburizing hollow articles
US1716191A (en) * 1927-10-24 1929-06-04 Nathan H Schermer Method of treating metallic bodies on one surface
US2275133A (en) * 1940-01-02 1942-03-03 Borg Warner Method of carburizing
US2439637A (en) * 1943-11-06 1948-04-13 American Car & Foundry Co Method of preparing weldable ferrous members having high carbon faces

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US1459409A (en) * 1922-01-09 1923-06-19 Timken Roller Bearing Co Process of carburizing hollow articles
US1716191A (en) * 1927-10-24 1929-06-04 Nathan H Schermer Method of treating metallic bodies on one surface
US2275133A (en) * 1940-01-02 1942-03-03 Borg Warner Method of carburizing
US2439637A (en) * 1943-11-06 1948-04-13 American Car & Foundry Co Method of preparing weldable ferrous members having high carbon faces

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3136664A (en) * 1959-12-15 1964-06-09 Sedis Transmissions Mec Steel transmission chain
US3226254A (en) * 1961-06-09 1965-12-28 Siemens Ag Method of producing electronic semiconductor devices by precipitation of monocrystalline semiconductor substances from a gaseous compound
US3172788A (en) * 1963-08-26 1965-03-09 Method of.making and heat treating food waste disposer shredding rings
US3873376A (en) * 1972-02-16 1975-03-25 Daimler Benz Ag Method for case hardening workpieces
US4154628A (en) * 1976-11-15 1979-05-15 Mannesmann Aktiengesellschaft Quench hardening of gears
US5085713A (en) * 1988-07-22 1992-02-04 Mitsubishi Denki Kabushiki Kaisha Method of forming a partially carburized starter output shaft
US20070144103A1 (en) * 2005-12-28 2007-06-28 Jtekt Corporation Method of manufacturing hollow member
EP1803951A2 (en) * 2005-12-28 2007-07-04 JTEKT Corporation Method of manufacturing hollow member
EP1803951A3 (en) * 2005-12-28 2011-01-12 JTEKT Corporation Method of manufacturing hollow member
US20070224075A1 (en) * 2006-03-24 2007-09-27 Gkn Sinter Metals, Inc. Forged carburized powder metal part and method
US7718116B2 (en) * 2006-03-24 2010-05-18 Gkn Sinter Metals, Inc. Forged carburized powder metal part and method

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