JPH01201459A - Parts combining high toughness with wear resistance - Google Patents

Parts combining high toughness with wear resistance

Info

Publication number
JPH01201459A
JPH01201459A JP2713588A JP2713588A JPH01201459A JP H01201459 A JPH01201459 A JP H01201459A JP 2713588 A JP2713588 A JP 2713588A JP 2713588 A JP2713588 A JP 2713588A JP H01201459 A JPH01201459 A JP H01201459A
Authority
JP
Japan
Prior art keywords
wear resistance
high toughness
less
carburizing
parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2713588A
Other languages
Japanese (ja)
Inventor
Kunio Namiki
並木 邦夫
Toshimitsu Kimura
利光 木村
Tomohito Iikubo
知人 飯久保
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Daido Steel Co Ltd
Original Assignee
Daido Steel Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Daido Steel Co Ltd filed Critical Daido Steel Co Ltd
Priority to JP2713588A priority Critical patent/JPH01201459A/en
Publication of JPH01201459A publication Critical patent/JPH01201459A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To obtain parts combining high toughness with wear resistance by subjecting a steel with a specific composition to the prescribed carburizing treatment by an ion carburizing method and then to quench-and-temper treatment. CONSTITUTION:A steel having a composition consisting of 0.3-0.7% C, <=1.5% Si, <=2.0% Mn, 3-15% Cr, <=5.0% Mo, further <=2.0% V and/or <=3.0% W, and the balance Fe with inevitable impurities is refined. This steel is carburized by an ion carburizing method so that the area ratio of carbide in the cross section within 0.1mm from the surface is regulated to >=10% and is then subjected to quench-and-temper treatment under the ordinary conditions, by which the parts combining high toughness with wear resistance can be prepared. Further, it is desirable that the above parts are tools for cold working.

Description

【発明の詳細な説明】[Detailed description of the invention] 【産業上の利用分野】[Industrial application field]

本発明は、高い靭性を有し、表面が耐摩耗をもつ部品と
くに冷間加工用工具に関する。 [従来の技術] 各種の機械を構成する構造用部品の製造に当り、熱間で
の加工を行なわず温間または冷間で加工するだけで済ま
せる傾向が強くなってきた。 これに伴い、冷間加工の
加工条件も、次第にきびしくなってきている。 このため、鍛造用の金型など冷間加工に使用する工具に
は、苛酷な条件下での使用に耐えられるよう、表面の耐
摩耗性に加えて、工具全体が高い靭性をそなえることが
要求されている。 [発明が解決しようとする問題点] 本発明の目的は、こうした要求にこたえ、耐摩耗性およ
び高い靭性をあわせもった部品、とくに冷間加工用工具
を提供することにある。
The present invention relates to parts having high toughness and wear-resistant surfaces, particularly tools for cold working. [Prior Art] When manufacturing structural parts that make up various machines, there is a growing tendency to only perform warm or cold processing without hot processing. Along with this, the processing conditions for cold working are becoming increasingly strict. For this reason, tools used for cold working, such as forging dies, are required to have high toughness in addition to surface wear resistance in order to withstand use under harsh conditions. has been done. [Problems to be Solved by the Invention] An object of the present invention is to meet these demands and provide a component, particularly a cold working tool, that has both wear resistance and high toughness.

【課題を解決するための手段】[Means to solve the problem]

本発明の高靭性耐摩耗部品は、C:0.3%超過0.7
%以下、Si:1.5%以下、Mn:2.0%以下、C
r:3〜15%およびMo:5.0%以下に加えて、V
:2.0%以下およびW:3.0%以下から選んだ1種
または2種を含:有し、残部Feおよび不可避な不純物
からなる鋼をイオン浸炭法により浸炭して表面からO,
1m以内の断面における炭化物面積率を10%以上とし
、焼入れ焼戻し処理してなる。 イオン浸炭法による浸炭処理は、浸炭炉内を真空度1O
−2TOrr程度に減圧して部品を加熱し、浸炭ガスで
ある炭化水素ガスを炉内に導入し、炉内圧力を数T o
rrまで高め、部品を陰極として、別に設けた陽極との
間に電圧を印加してグロー放電を生じさせることによっ
て、行なう。 浸炭に先立って、後記する実施例に示す
ように、Arおよび川霧囲気下におけるグロー放電をし
ばらく行ない、部品の表面の清浄化を行なうことが好ま
しい。 浸炭層の焼入れ焼もどし処理は、在来の熱処理
と同様の条件で行なえばよい。 代表的には、1000
〜1100℃からの油冷またはガス冷による焼入れ→5
00〜700″Cに30分〜2時間保持したのち空冷に
よる焼戻しである。
The high toughness wear-resistant parts of the present invention have C: 0.7% exceeding 0.3%.
% or less, Si: 1.5% or less, Mn: 2.0% or less, C
In addition to r: 3 to 15% and Mo: 5.0% or less, V
A steel containing one or two selected from: 2.0% or less and 3.0% or less W, with the remainder being Fe and unavoidable impurities is carburized by an ion carburizing method to remove O, O,
The carbide area ratio in a cross section within 1 m is 10% or more, and is quenched and tempered. Carburizing treatment using the ion carburizing method uses a carburizing furnace with a vacuum level of 1O.
The pressure is reduced to about -2 TOrr, the parts are heated, and hydrocarbon gas, which is carburizing gas, is introduced into the furnace, and the pressure inside the furnace is reduced to several Torr.
rr and apply a voltage between the component as a cathode and a separately provided anode to generate glow discharge. Prior to carburizing, it is preferable to carry out glow discharge under an Ar and river mist atmosphere for a while to clean the surface of the part, as shown in the examples below. The quenching and tempering treatment of the carburized layer may be performed under the same conditions as conventional heat treatment. Typically, 1000
Quenching by oil cooling or gas cooling from ~1100℃→5
After holding at 00 to 700''C for 30 minutes to 2 hours, tempering is performed by air cooling.

【作 用】 従来、冷間加工に使用する工具は、炭素含有量の高い鋼
を材料として製作されており表層から合部に至るまで高
い硬度を有するが、その代り靭性はあまり高くない。 
そこで発明者らは、熱間加工用の工具鋼が比較的靭性が
高いことに着目し、これで製作した部品を浸炭して表面
を硬化させることにより表層部に耐摩耗性を与え、合部
の靭性を利用して、苛酷な使用条件に耐える冷間加工用
の工具部品をつくることに成功した。 本発明で使用する鋼の合金成分のはたらきと、組成範囲
の限定理由を、以下に説明する。 C:0.3%超過0.7%以下 Cは部品の強度を得るために加える元素でおる。0.3
%を超えない含有量では、十分な合部強度が得られず、
一方0.7%を超えて含有すると、合部が硬くなりすぎ
て靭性が低下する。 Si:1.5%以下 3iを多量に含有すると鍛造性が低下するとともに浸炭
性が阻害され、また脱炭が促進されるので、1.5%を
上限値とした。 1.47 Mn:2.0%以下 Mnは焼入れ性を向上させるために添加する。 他の元素とのバランスを考慮して適宜の量を添加すれば
よいが、2.0%を上回る含有量では、被削性が低下す
る。 Cr:3〜15% Crは炭化物形成元素として、所定の炭化物量を確保す
るために加える。 浸炭時のC濃度はOrの含有量の増
大とともに増す。 また、Crを含有させると炭化物の
球状化が促進される。 含有量が3%未満では、これら
の効果が十分でなく、一方、15%を上回ると浸炭層の
炭素量が多くなりすぎ、網目状の炭化物が析出して機械
的性質を低下させる。 Mo:5.0%以下、 V:2.0%以下およびW:3.0%以下から選んだ1
種または2種 これらはいずれも炭化物形成元素であって、含有量の増
加につれて浸炭量を増加させる。 ただし、これらの元素は素材製造時にも炭化物を形成し
、とくに粗大な一時炭化物は靭性および疲れ強さを低下
ざる。 これを防止するため、上記のように限界を定め
た。 本発明の部品は、上記の鋼に、表面から0.1履以内の
断面における炭化物の面積率が10%以上となるように
浸炭処理したものである。 炭化物の面積率が10%を
下回るものは、十分な耐摩耗性が得られない。 浸炭処理の手段として、現在主流となっているガス浸炭
法は、高いカーボンポテンシャルで操業するとスーティ
ングが生じて浸炭ムラが生じやすい。 また、炭化水素
系ガス等を変成して使用する浸炭ガスは酸化性でおるた
め、浸炭に伴って部品の表面に粒界酸化層が生成するこ
とが避けられない。 このため表面近傍の焼入れ性が低
下し、不完全焼入れ組織が生じる。 従って、必要な硬
さを1qるためには強い冷却を必要とし、焼割れが生じ
やすいという難点がある。 真空浸炭法は、浸炭ムラが
生じやすく、形状の複雑な部品を均一に浸炭することが
できない。 これに対し、減圧下でグロー放電を利用したイオン浸炭
処理は、Cl−13や03H8をそのまま浸炭ガスとし
て使用するので粒界酸化層が形成されない。 また、真
空浸炭法のざらに約1/100という低圧下で操業する
ため、はとんどスーテイングは生じない。 ざらに、グ
ロー放電がひきおこすプラズマ状態が処理される部品の
全面を覆うので、複雑な形状をした部品に対しても、均
一に浸炭することが可能である。
[Function] Conventionally, tools used for cold working are made of steel with a high carbon content and have high hardness from the surface layer to the joint, but their toughness is not very high.
Therefore, the inventors focused on the fact that tool steel for hot working has relatively high toughness, and by carburizing the parts manufactured using this tool to harden the surface, they imparted wear resistance to the surface layer. By taking advantage of the toughness of this material, we succeeded in creating tool parts for cold working that can withstand harsh working conditions. The functions of the alloy components of the steel used in the present invention and the reasons for limiting the composition range will be explained below. C: more than 0.3% and less than 0.7% C is an element added to increase the strength of parts. 0.3
If the content does not exceed %, sufficient joint strength cannot be obtained,
On the other hand, if the content exceeds 0.7%, the joint becomes too hard and the toughness decreases. Si: 1.5% or less If a large amount of 3i is contained, forgeability is reduced, carburizability is inhibited, and decarburization is promoted, so 1.5% is set as the upper limit. 1.47 Mn: 2.0% or less Mn is added to improve hardenability. It may be added in an appropriate amount taking into consideration the balance with other elements, but if the content exceeds 2.0%, machinability will deteriorate. Cr: 3-15% Cr is added as a carbide-forming element to ensure a predetermined amount of carbide. The C concentration during carburization increases as the Or content increases. Further, when Cr is included, spheroidization of carbide is promoted. If the content is less than 3%, these effects will not be sufficient, while if it exceeds 15%, the amount of carbon in the carburized layer will be too large, and network-like carbides will precipitate, reducing mechanical properties. 1 selected from Mo: 5.0% or less, V: 2.0% or less, and W: 3.0% or less
Species or two These are both carbide-forming elements, and as their content increases, the amount of carburization increases. However, these elements also form carbides during material production, and especially coarse temporary carbides deteriorate toughness and fatigue strength. To prevent this, we have set the limits as described above. The parts of the present invention are obtained by carburizing the above-mentioned steel so that the area ratio of carbides in the cross section within 0.1 inch from the surface is 10% or more. If the area ratio of carbides is less than 10%, sufficient wear resistance cannot be obtained. Gas carburizing, which is currently the mainstream method for carburizing, tends to cause sooting and uneven carburizing when operated at high carbon potential. Further, since the carburizing gas used by modifying hydrocarbon gas or the like is oxidizing, it is inevitable that a grain boundary oxidation layer will be formed on the surface of the part as a result of carburizing. As a result, the hardenability near the surface deteriorates, resulting in an incompletely hardened structure. Therefore, strong cooling is required to reduce the required hardness by 1q, and there is a problem that quench cracking is likely to occur. The vacuum carburizing method tends to cause uneven carburizing, and cannot uniformly carburize parts with complex shapes. On the other hand, in the ion carburizing process using glow discharge under reduced pressure, Cl-13 or 03H8 is used as the carburizing gas, so no grain boundary oxidation layer is formed. In addition, since the process is operated at a pressure approximately 1/100 times lower than that of vacuum carburizing, sooting hardly occurs. In general, since the plasma state caused by the glow discharge covers the entire surface of the part being treated, it is possible to uniformly carburize even parts with complex shapes.

【実施例】【Example】

表に示す組成の合金を溶製した。 Nα1は比較例であ
り、NQ2〜8が本発明に従う材料である。 各材料の試験片をイオン浸炭炉に入れて炉内を1O−2
Torrまで減圧し、1050℃に加熱侵、Arおよび
H2を供給して炉内圧を2Torrに調整した。 試験
片を陰極とし、陽極との間に50O■の直流電圧を印加
して、グロー放電を起させた。 前処理として20分間
、ArおよびHのイオンによる表面清浄化を行なってか
らArおよび町を排気した。 続いて炉内にC3H8を
送り込んで、圧力2Torrで1時間、浸炭処理した。 その俊、1050℃に加熱されている試験片にN2を吹
きつけるガス冷却により、焼入れをした。 ただし、Nα8の試験片は、1150℃に加熱して油冷
することにより焼入れした。 焼もどしは、Nα1の試
験片を500℃に、他の試験片を600℃に、いずれも
1時間保持してから放冷する方法をとった。 得られた試験片の表面硬さ、表面から0.18以内にお
ける炭化物面積率、衝撃値(IORノツチ値シャルピー
試験片)および比摩耗量を測定した。 比摩耗量は、大
館式摩耗試験機を用いて測定した。 測定条件は下記の
とおりである。 相手円板  SK6   HRB90 最終荷重  6.51 摩擦距離  200am 摩擦速度  2.0TrL/sec 以上の結果を、表にあわせて示す。 このデータかられ
かるように、本発明に従った部品は比較例のものより靭
性が高く、耐摩耗性はほぼ同等である。
An alloy having the composition shown in the table was melted. Nα1 is a comparative example and NQ2-8 are materials according to the invention. A test piece of each material was placed in an ion carburizing furnace, and the inside of the furnace was heated to 1O-2.
The pressure was reduced to Torr, heated to 1050°C, and Ar and H2 were supplied to adjust the furnace internal pressure to 2 Torr. The test piece was used as a cathode, and a DC voltage of 50 O was applied between it and the anode to cause glow discharge. As a pretreatment, the surface was cleaned with Ar and H ions for 20 minutes, and then the Ar and gas were evacuated. Subsequently, C3H8 was fed into the furnace and carburized at a pressure of 2 Torr for 1 hour. At that time, the test piece, which had been heated to 1050°C, was quenched by gas cooling by blowing N2. However, the Nα8 test piece was quenched by heating to 1150°C and cooling with oil. For tempering, the Nα1 test piece was held at 500°C, and the other test pieces were held at 600°C for 1 hour, and then allowed to cool. The surface hardness, carbide area ratio within 0.18 from the surface, impact value (IOR notch value Charpy test piece), and specific wear amount of the obtained test piece were measured. The specific wear amount was measured using an Odate type wear tester. The measurement conditions are as follows. Mating disc SK6 HRB90 Final load 6.51 Friction distance 200am Friction speed 2.0TrL/sec The above results are shown in the table. As can be seen from this data, parts according to the invention are tougher than those of the comparative example and have approximately the same wear resistance.

【発明の効果】【Effect of the invention】

本発明の高靭性耐摩耗部品は、その名のとおり、合部が
高い靭性を有し、表層部が耐摩耗性を担うものである。  これを、たとえば冷間加工用の工具に応用すれば、従
来の工具では実施できなかったような苛酷な条件下での
冷間加工が可能になる。 特許出願人   大同特殊鋼株式会社 代理人  弁理士  須 賀 総 夫
As the name suggests, the high-toughness wear-resistant parts of the present invention have high toughness at the joints and wear resistance at the surface layer. If this is applied to tools for cold working, for example, it becomes possible to perform cold working under severe conditions that would not be possible with conventional tools. Patent applicant Daido Steel Co., Ltd. Agent Patent attorney Souo Suga

Claims (2)

【特許請求の範囲】[Claims] (1)C:0.3%超過0.7%以下、Si:1.5%
以下、Mn:2.0%以下、Cr:3〜15%およびM
o:5.0%以下に加えて、V:2.0%以下およびW
:3.0%以下から選んだ1種または2種を含有し、残
部Feおよび不可避な不純物からなる鋼をイオン浸炭法
により浸炭して表面から0.1mm以内の断面における
炭化物面積率を10%以上とし、焼入れ焼戻し処理して
なる高靭性耐摩耗部品。
(1)C: over 0.3% but not more than 0.7%, Si: 1.5%
Below, Mn: 2.0% or less, Cr: 3-15% and M
In addition to o: 5.0% or less, V: 2.0% or less and W
: A steel containing one or two selected from 3.0% or less, with the balance consisting of Fe and unavoidable impurities, is carburized by the ion carburizing method to reduce the carbide area ratio to 10% in a cross section within 0.1 mm from the surface. A high toughness wear-resistant part made by quenching and tempering the above.
(2)冷間加工用工具である請求項1の部品。(2) The part according to claim 1, which is a cold working tool.
JP2713588A 1988-02-08 1988-02-08 Parts combining high toughness with wear resistance Pending JPH01201459A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2713588A JPH01201459A (en) 1988-02-08 1988-02-08 Parts combining high toughness with wear resistance

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2713588A JPH01201459A (en) 1988-02-08 1988-02-08 Parts combining high toughness with wear resistance

Publications (1)

Publication Number Publication Date
JPH01201459A true JPH01201459A (en) 1989-08-14

Family

ID=12212610

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2713588A Pending JPH01201459A (en) 1988-02-08 1988-02-08 Parts combining high toughness with wear resistance

Country Status (1)

Country Link
JP (1) JPH01201459A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5122000A (en) * 1990-04-27 1992-06-16 Nippon Seiko Kabushiki Kaisha Rolling bearing
JPH0578792A (en) * 1991-03-27 1993-03-30 Nippon Piston Ring Co Ltd Rotary type fluid compressor
JPH0586442A (en) * 1991-03-27 1993-04-06 Nippon Piston Ring Co Ltd Rotary type fluid compressor
WO2005066383A1 (en) * 2003-12-22 2005-07-21 Caterpillar Inc. Method for carburizing a steel article and steel article thus obtained with improved wear resistance
JP2008520839A (en) * 2004-11-09 2008-06-19 シエフレル・コマンデイトゲゼルシヤフト Method of heat treating a part made of fully hardened heat resistant steel and part made of fully hardened heat resistant steel
EP2503016A1 (en) * 2009-11-17 2012-09-26 Villares Metals S/A Steel with high temper resistance

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5122000A (en) * 1990-04-27 1992-06-16 Nippon Seiko Kabushiki Kaisha Rolling bearing
JPH0578792A (en) * 1991-03-27 1993-03-30 Nippon Piston Ring Co Ltd Rotary type fluid compressor
JPH0586442A (en) * 1991-03-27 1993-04-06 Nippon Piston Ring Co Ltd Rotary type fluid compressor
WO2005066383A1 (en) * 2003-12-22 2005-07-21 Caterpillar Inc. Method for carburizing a steel article and steel article thus obtained with improved wear resistance
US7169238B2 (en) 2003-12-22 2007-01-30 Caterpillar Inc Carbide method and article for hard finishing resulting in improved wear resistance
JP2008520839A (en) * 2004-11-09 2008-06-19 シエフレル・コマンデイトゲゼルシヤフト Method of heat treating a part made of fully hardened heat resistant steel and part made of fully hardened heat resistant steel
EP2503016A1 (en) * 2009-11-17 2012-09-26 Villares Metals S/A Steel with high temper resistance
EP2503016A4 (en) * 2009-11-17 2013-06-26 Villares Metals Sa Steel with high temper resistance

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