US2495148A - Method of manufacturing continuous electrodes - Google Patents
Method of manufacturing continuous electrodes Download PDFInfo
- Publication number
- US2495148A US2495148A US684096A US68409646A US2495148A US 2495148 A US2495148 A US 2495148A US 684096 A US684096 A US 684096A US 68409646 A US68409646 A US 68409646A US 2495148 A US2495148 A US 2495148A
- Authority
- US
- United States
- Prior art keywords
- mass
- electrode
- pipe
- lye
- sulphite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 238000004519 manufacturing process Methods 0.000 title description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 24
- 229910052742 iron Inorganic materials 0.000 description 12
- LSNNMFCWUKXFEE-UHFFFAOYSA-L sulfite Chemical compound [O-]S([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-L 0.000 description 12
- 239000011230 binding agent Substances 0.000 description 10
- 239000002699 waste material Substances 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- 238000004939 coking Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 238000007493 shaping process Methods 0.000 description 6
- 239000000203 mixture Substances 0.000 description 5
- 239000000571 coke Substances 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000008018 melting Effects 0.000 description 4
- 239000007789 gas Substances 0.000 description 3
- 229920005610 lignin Polymers 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- RHZUVFJBSILHOK-UHFFFAOYSA-N anthracen-1-ylmethanolate Chemical compound C1=CC=C2C=C3C(C[O-])=CC=CC3=CC2=C1 RHZUVFJBSILHOK-UHFFFAOYSA-N 0.000 description 2
- 239000003830 anthracite Substances 0.000 description 2
- 239000003575 carbonaceous material Substances 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- ZETCGWYACBNPIH-UHFFFAOYSA-N azane;sulfurous acid Chemical compound N.OS(O)=O ZETCGWYACBNPIH-UHFFFAOYSA-N 0.000 description 1
- LVGQIQHJMRUCRM-UHFFFAOYSA-L calcium bisulfite Chemical compound [Ca+2].OS([O-])=O.OS([O-])=O LVGQIQHJMRUCRM-UHFFFAOYSA-L 0.000 description 1
- 235000010260 calcium hydrogen sulphite Nutrition 0.000 description 1
- 159000000007 calcium salts Chemical class 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 238000010309 melting process Methods 0.000 description 1
- 238000010310 metallurgical process Methods 0.000 description 1
- 239000000025 natural resin Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229920001864 tannin Polymers 0.000 description 1
- 235000018553 tannin Nutrition 0.000 description 1
- 239000001648 tannin Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H05—ELECTRIC TECHNIQUES NOT OTHERWISE PROVIDED FOR
- H05B—ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL
- H05B7/00—Heating by electric discharge
- H05B7/02—Details
- H05B7/06—Electrodes
- H05B7/08—Electrodes non-consumable
- H05B7/085—Electrodes non-consumable mainly consisting of carbon
- H05B7/09—Self-baking electrodes, e.g. Söderberg type electrodes
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B35/00—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
- C04B35/515—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
- C04B35/52—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbon, e.g. graphite
- C04B35/528—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbon, e.g. graphite obtained from carbonaceous particles with or without other non-organic components
- C04B35/532—Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbon, e.g. graphite obtained from carbonaceous particles with or without other non-organic components containing a carbonisable binder
Definitions
- the known type of continuously self-burning electrodes is based on melting down in a sheet iron pipe a plastic mass consisting of crushed anthracite or coke, to which are added pitch and tar as binding agent. As this mass becomes completely liquefied by heating and firstly assumes a solid state and then is coked at relatively high temperatures, it is necessary that the sheet iron pipe follows the electrode mass down into the bath and is here corroded away with the same. it is here to be noted that coking of the mass is necessary in order to obtain a sufliclent electrical conductivity.
- the sheet iron pipe may not be separated from the mass is that the latter sticks and adheres to the sheet iron.
- the disadvantage of this electrode is that the sheet iron envelope increases the cost of the electrode, nrlinarily because of the relatively high costs of manufacturing the envelope, which generally takes place by welding or riveting. Further the addition of iron received by the bath through melting down of the sheet pipe may act uniavorably in certain metallurgical processes.
- a constructional form oi self-burning elec trodes has been suggested in which the sheet iron pipe or mantel is avoided by suspending the electrode at its lower portion, which has heen burnt to such a degree that it has sufiicient to permit of the attachment of the suspension means.
- the diiliculty of constructing a continuous electrode without an iron mantel has been that has had no binding agent for the mass which,
- the binding agent is of such a nature that it binds and cokes at a relatively moderate temperature, at 200-300 C., for example it is possible in practice in this zone, without difllculty, to supply the current by means of ordinary current supplying laws.
- the quantity of suiphite lye which should be added in order to obtain a suflicient binding power may advantageously be fixed at between ill-35%, and that the subsequent drying may suitably take place at a temperature of above loll C.-"lld C.
- waste lye as used above and in the claims shall be understood waste lye from the production of sulphlte cellulose, regardless of Whether it refers to the ordinary sulphite process, which operates with calcium bisulphite, or other sulphite processes, for example one in which ammonia bisulphite is used.
- a solution according to the invention may eventually also be produced by the mixing of its individual components.
- the invention will be particularly applicable in connection with a stationary pipe or mantel, mounted above the bath, which shapes the electrode and holds it together until the mass, through the influence of heat, has turned consistent so that it may be passed down into the furnace as it is being consumed.
- a casing of heat resisting material through which the hot gases from the melting bath are passed in such a way that the pipe and consequently the electrode mass is heated to a few hundred degrees, so that the mass which is passed through the pipe stiffens and hardens and forms a firm, glutinated mass.
- this embodiment is shown diagrammatically: I designates the furnace arch, 2 the bath surface and 3 the casing of heat resisting material mounted on the furnace arch.
- the shaping pipe 4 which at the top is provided with a funnel shaped expansion 5 in which the electrode mass consisting of a premixed mass of, for example 90% cokeand/or anthracite powder and about concentrated sulphite lye is stamped down.
- the hot gases from the furnace pass through the casing 3 and out through a discharge pipe 1, which is provided with a control damper 8. Through influence of heat from the gas the electrode mass will first stiffen and thereupon coke to a consistent electrode.
- Below the pipe 4 are mounted current supplying jaws, in-
- the current is supplied through the lead III, which is suitably passed through the casing I.
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Ceramic Engineering (AREA)
- Physics & Mathematics (AREA)
- Plasma & Fusion (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Discharge Heating (AREA)
- Processing Of Solid Wastes (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NO244709X | 1943-05-08 |
Publications (1)
Publication Number | Publication Date |
---|---|
US2495148A true US2495148A (en) | 1950-01-17 |
Family
ID=19904980
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US684096A Expired - Lifetime US2495148A (en) | 1943-05-08 | 1946-07-17 | Method of manufacturing continuous electrodes |
Country Status (4)
Country | Link |
---|---|
US (1) | US2495148A (en, 2012) |
CH (1) | CH244709A (en, 2012) |
GB (1) | GB614107A (en, 2012) |
SE (1) | SE120959C1 (en, 2012) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2526876A (en) * | 1948-05-08 | 1950-10-24 | Elektrokemisk As | Method of handling continuous electrodes |
US3619465A (en) * | 1968-12-09 | 1971-11-09 | Montedison Spa | Method for operating self-baking electrodes |
US4527329A (en) * | 1978-10-31 | 1985-07-09 | Carboindustrial S.A. | Process for the manufacture "in situ" of carbon electrodes |
US4704230A (en) * | 1983-03-08 | 1987-11-03 | Georgia-Pacific Corporation | Lignosulfonate/urea binder for particulate composites |
US5360465A (en) * | 1989-09-29 | 1994-11-01 | Georgia-Pacific Corporation | Particulate fertilizer dust control |
Citations (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE294661C (en, 2012) * | ||||
US617979A (en) * | 1899-01-17 | Method of manufacturing graphite articles | ||
US704993A (en) * | 1900-01-08 | 1902-07-15 | Frederick C Weber | Electric smelting-furnace. |
US722411A (en) * | 1902-05-15 | 1903-03-10 | Eugene Howard Moore | Electric furnace. |
US964268A (en) * | 1906-11-09 | 1910-07-12 | Continuous Zinc Furnace Company | Apparatus for smelting ores yielding a volatile metal. |
US1434395A (en) * | 1920-01-30 | 1922-11-07 | Metal & Thermit Corp | Electric furnace |
US1483507A (en) * | 1923-07-06 | 1924-02-12 | Rosstacony Crucible Company | Refractory article and method of making the same |
US1498582A (en) * | 1921-01-24 | 1924-06-24 | Norske Elektrokemisk Ind As | Electrode holder |
US1544151A (en) * | 1923-03-20 | 1925-06-30 | Union Carbide Corp | Method of and apparatus for forming continuous electrodes |
US1640735A (en) * | 1923-05-16 | 1927-08-30 | Norske Elektrokemisk Ind As | Process of making channeled continuous electrodes |
US1757695A (en) * | 1925-09-30 | 1930-05-06 | Norske Elektrokemisk Ind As | Electrode |
US1983267A (en) * | 1930-07-18 | 1934-12-04 | Theodore C Browne | Electrical conductive element and process of manufacture |
US2073356A (en) * | 1933-04-18 | 1937-03-09 | Norske Elektrokemisk Ind As | Electrode suspension |
AT154016B (de) * | 1934-04-07 | 1938-08-10 | Nicolaas Cramer | Verfahren zur Herstellung von ungebrannten feuerfesten und/oder isolierenden Massen, Steinen, Auskleidungen, Schutzanstrichen u. dgl. aus keramischen Stoffen. |
GB500455A (en) * | 1936-12-24 | 1939-02-09 | Robert Mautsch | Improvements relating to electric furnaces for melting metals |
US2154271A (en) * | 1937-03-02 | 1939-04-11 | Carborundum Co | Refractory article |
US2159183A (en) * | 1928-10-05 | 1939-05-23 | Norske Elektrokemisk Ind As | Self-baking electrode |
US2169563A (en) * | 1936-07-08 | 1939-08-15 | Det Norske Aktiesclskab For El | Electrode and its suspension |
US2185772A (en) * | 1935-12-23 | 1940-01-02 | Carborundum Co | Mold for refractory cast materials |
-
1944
- 1944-04-18 SE SE321144A patent/SE120959C1/sv unknown
- 1944-05-17 CH CH244709D patent/CH244709A/de unknown
-
1946
- 1946-07-05 GB GB20207/46A patent/GB614107A/en not_active Expired
- 1946-07-17 US US684096A patent/US2495148A/en not_active Expired - Lifetime
Patent Citations (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US617979A (en) * | 1899-01-17 | Method of manufacturing graphite articles | ||
DE294661C (en, 2012) * | ||||
US704993A (en) * | 1900-01-08 | 1902-07-15 | Frederick C Weber | Electric smelting-furnace. |
US722411A (en) * | 1902-05-15 | 1903-03-10 | Eugene Howard Moore | Electric furnace. |
US964268A (en) * | 1906-11-09 | 1910-07-12 | Continuous Zinc Furnace Company | Apparatus for smelting ores yielding a volatile metal. |
US1434395A (en) * | 1920-01-30 | 1922-11-07 | Metal & Thermit Corp | Electric furnace |
US1498582A (en) * | 1921-01-24 | 1924-06-24 | Norske Elektrokemisk Ind As | Electrode holder |
US1544151A (en) * | 1923-03-20 | 1925-06-30 | Union Carbide Corp | Method of and apparatus for forming continuous electrodes |
US1640735A (en) * | 1923-05-16 | 1927-08-30 | Norske Elektrokemisk Ind As | Process of making channeled continuous electrodes |
US1483507A (en) * | 1923-07-06 | 1924-02-12 | Rosstacony Crucible Company | Refractory article and method of making the same |
US1757695A (en) * | 1925-09-30 | 1930-05-06 | Norske Elektrokemisk Ind As | Electrode |
US2159183A (en) * | 1928-10-05 | 1939-05-23 | Norske Elektrokemisk Ind As | Self-baking electrode |
US1983267A (en) * | 1930-07-18 | 1934-12-04 | Theodore C Browne | Electrical conductive element and process of manufacture |
US2073356A (en) * | 1933-04-18 | 1937-03-09 | Norske Elektrokemisk Ind As | Electrode suspension |
AT154016B (de) * | 1934-04-07 | 1938-08-10 | Nicolaas Cramer | Verfahren zur Herstellung von ungebrannten feuerfesten und/oder isolierenden Massen, Steinen, Auskleidungen, Schutzanstrichen u. dgl. aus keramischen Stoffen. |
US2185772A (en) * | 1935-12-23 | 1940-01-02 | Carborundum Co | Mold for refractory cast materials |
US2169563A (en) * | 1936-07-08 | 1939-08-15 | Det Norske Aktiesclskab For El | Electrode and its suspension |
GB500455A (en) * | 1936-12-24 | 1939-02-09 | Robert Mautsch | Improvements relating to electric furnaces for melting metals |
US2154271A (en) * | 1937-03-02 | 1939-04-11 | Carborundum Co | Refractory article |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2526876A (en) * | 1948-05-08 | 1950-10-24 | Elektrokemisk As | Method of handling continuous electrodes |
US3619465A (en) * | 1968-12-09 | 1971-11-09 | Montedison Spa | Method for operating self-baking electrodes |
US4527329A (en) * | 1978-10-31 | 1985-07-09 | Carboindustrial S.A. | Process for the manufacture "in situ" of carbon electrodes |
US4704230A (en) * | 1983-03-08 | 1987-11-03 | Georgia-Pacific Corporation | Lignosulfonate/urea binder for particulate composites |
US5360465A (en) * | 1989-09-29 | 1994-11-01 | Georgia-Pacific Corporation | Particulate fertilizer dust control |
Also Published As
Publication number | Publication date |
---|---|
GB614107A (en) | 1948-12-09 |
SE120959C1 (en, 2012) | 1948-02-24 |
CH244709A (de) | 1946-09-30 |
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