US2454034A - Process fob preparing sulfurized - Google Patents
Process fob preparing sulfurized Download PDFInfo
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- US2454034A US2454034A US2454034DA US2454034A US 2454034 A US2454034 A US 2454034A US 2454034D A US2454034D A US 2454034DA US 2454034 A US2454034 A US 2454034A
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- Prior art keywords
- oil
- sulfurized
- oils
- sulfur
- cutting
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- Expired - Lifetime
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- 238000000034 method Methods 0.000 title description 14
- 239000003921 oil Substances 0.000 description 52
- 235000019198 oils Nutrition 0.000 description 52
- 239000010730 cutting oil Substances 0.000 description 40
- 239000011593 sulfur Substances 0.000 description 34
- 229910052717 sulfur Inorganic materials 0.000 description 34
- 239000003054 catalyst Substances 0.000 description 32
- NINIDFKCEFEMDL-UHFFFAOYSA-N sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 32
- 239000000203 mixture Substances 0.000 description 28
- 239000010699 lard oil Substances 0.000 description 18
- 239000000314 lubricant Substances 0.000 description 18
- 239000010687 lubricating oil Substances 0.000 description 16
- 239000002480 mineral oil Substances 0.000 description 16
- 235000019645 odor Nutrition 0.000 description 16
- 239000010685 fatty oil Substances 0.000 description 10
- 238000002360 preparation method Methods 0.000 description 10
- ZAUVBVZMMZMKSQ-UHFFFAOYSA-N N-benzyl-4-ethoxyaniline Chemical compound C1=CC(OCC)=CC=C1NCC1=CC=CC=C1 ZAUVBVZMMZMKSQ-UHFFFAOYSA-N 0.000 description 8
- 150000002430 hydrocarbons Chemical class 0.000 description 8
- 230000001050 lubricating Effects 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 8
- 235000010446 mineral oil Nutrition 0.000 description 8
- 239000011541 reaction mixture Substances 0.000 description 8
- 238000006243 chemical reaction Methods 0.000 description 6
- 238000005520 cutting process Methods 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 6
- 239000010688 mineral lubricating oil Substances 0.000 description 6
- 235000014593 oils and fats Nutrition 0.000 description 6
- -1 p-Anisidine N-benzyl-p-anisidine Chemical compound 0.000 description 6
- 239000003208 petroleum Substances 0.000 description 6
- 241001062233 Salmonella enterica subsp. enterica serovar Texas Species 0.000 description 4
- 125000003545 alkoxy group Chemical group 0.000 description 4
- 125000004104 aryloxy group Chemical group 0.000 description 4
- 230000003197 catalytic Effects 0.000 description 4
- 239000003086 colorant Substances 0.000 description 4
- 238000005260 corrosion Methods 0.000 description 4
- 231100000078 corrosive Toxicity 0.000 description 4
- 231100001010 corrosive Toxicity 0.000 description 4
- 229910052739 hydrogen Inorganic materials 0.000 description 4
- 239000001257 hydrogen Substances 0.000 description 4
- 125000004435 hydrogen atoms Chemical class [H]* 0.000 description 4
- 229910052500 inorganic mineral Inorganic materials 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 239000011707 mineral Substances 0.000 description 4
- 125000002950 monocyclic group Chemical group 0.000 description 4
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 4
- 125000001424 substituent group Chemical group 0.000 description 4
- 238000005987 sulfurization reaction Methods 0.000 description 4
- 240000004246 Agave americana Species 0.000 description 2
- 235000008754 Agave americana Nutrition 0.000 description 2
- 241000272168 Laridae Species 0.000 description 2
- CCCMONHAUSKTEQ-UHFFFAOYSA-N Octadecene Chemical compound CCCCCCCCCCCCCCCCC=C CCCMONHAUSKTEQ-UHFFFAOYSA-N 0.000 description 2
- 241000669326 Selenaspidus articulatus Species 0.000 description 2
- 229940035295 Ting Drugs 0.000 description 2
- 240000008042 Zea mays Species 0.000 description 2
- 235000002017 Zea mays subsp mays Nutrition 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000004927 clay Substances 0.000 description 2
- 229910052570 clay Inorganic materials 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 235000005822 corn Nutrition 0.000 description 2
- 235000005824 corn Nutrition 0.000 description 2
- 235000012343 cottonseed oil Nutrition 0.000 description 2
- 239000002385 cottonseed oil Substances 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 238000005553 drilling Methods 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 238000003754 machining Methods 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000006011 modification reaction Methods 0.000 description 2
- 230000001264 neutralization Effects 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 239000003549 soybean oil Substances 0.000 description 2
- 235000012424 soybean oil Nutrition 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 150000003463 sulfur Chemical class 0.000 description 2
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M135/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
- C10M135/02—Sulfurised compounds
- C10M135/06—Esters, e.g. fats
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
- C10M2219/024—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2060/00—Chemical after-treatment of the constituents of the lubricating composition
- C10N2060/10—Chemical after-treatment of the constituents of the lubricating composition by sulfur or a compound containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2070/00—Specific manufacturing methods for lubricant compositions
Definitions
- My invention relates to a process for preparing sulfurized lubricating compositions and has to do particularly with procedure for preparing sulfurized lubricating oil compositions adapted for use as cutting oils, extreme pressure lubricants and the like.
- Cutting oil is used to cool and lubricate the tools and work pieces in the various metal form- 'ing operations which encounter extreme pressure, such as cutting, drilling and the like. Criteria by which cutting oils are judged incl'ude color, stability of oil with retention of quality with repeated re-use, odor particularly when heated and in-' creased life of cutting tool.
- the most efiective oils are those containing sulfur, and heretofore fatty oils have been heated in the presence of sulfur at very high temperatures and for such a length of time that various disagreeable charac terlstics have been imparted to the oil.
- My invention is particularly applicable to the preparation of sulfurized oils and fats for use in the manufacture of cutting oils and lubricants; these sulfurized oils and fats are comparatively free from obnoxious odors and have relatively light transparent colors and hence are far superior to sulfurized oils and fats on the market.
- a sulfurized oil which has been sulfurized in the presence of a catalyst, having the general formula wherein R and it" represent substituents selected from the class consisting of hydrogen, lower aliphatic radicals and monocyclic aromatic radicals and AR. is a benzene ring with a lower alkoxy or monocyclic aryloxy group attached to the ortho or para position.
- an oil, sulfur and a catalyst having the general formula set forth in the paragraph above are reacted in suitable proportions and under proper conditions to obtain a sulfur base, and then this sulfur base is dispersed in correct proportions in a lubricating oil of predetermined viscosity to obtain a lubricating composition having the desired characteristics for the purpose intended.
- This invention is particularly applicable to the preparation of sulfur-type cutting oils and for this purpose a light lubricating oil is used.
- Other lubricating compositions such as extreme pressure base lubricating oils and extreme pressure gear lubricants, hypoid gear lubricants, etc., may be obtained by using mineral lubricating oils of high viscosity.
- a light lubricating oil of about to 150 viscosity range at F. is employed.
- Example 1 This example illustrates one advantageous method of preparing sulfurized oils in accordance with this invention; an excellent sulfurized fatty oil being prepared from the following materials:
- the catalytically sulfurized lard oil or sulfur base so obtained was a stable, clear, transparent to the above procedure furization.
- the product was blended with a "10 liquid. It was substantially non-corrosive and free from obnoxious odors.
- This liquid sulfurized base was readilysoluble in a wide variety of mineral lubricating oils. When incorporated in mineral oils in amounts of from 1 to 25 per cent by weight based on the mineral oil, improved lubricants are readily obtained. For instance,- improved cutting oils and other lubricants maybe readily prepared in this way. The following example illustrates the preparation of one such im-' proved cutting oil.
- the bearing actually was 5 mg. heavier instead of losing weight as when corrosion .occurs.
- 22 pounds of the -catalytically sulfurized lard oil obtained in Example 1 were dissolved in 78 pounds of a commercial mineral'lubricating oil, namely, a paraflln oil of viscosity 100 S. U. S.
- the improved. cutting oil so obtained when subjected to standard lathe test gave outstanding perform:- ance, as compared to the mineral oil itself and a commercial cutting oil containing a small amount of sulfurized lard oil made without a catalyst.
- the lathe results obtained are given in the follow-
- the prior commercial cutting oil employed in the above test was a composition comprising 78 per cent of a, light parafllnic neutral oil blend and 22 per cent of sulfurized lard oil (non-catalytic) the parts being parts by weight. Non-catalytic sul-.
- furized lard oil in this commercial cutting oil was prepared by heating lard oil to 275-300 F., adding 10 per cent by weight of sulfur to 'the heated oil over a period of 2 hours, and then further heating this reaction mixture at 330-340 F. for hour.
- the improved cutting oil prepared in Example 2 ante is markedly superior to the prior commercial cutting oil as well as to the plain mineral oil employed in these comparative tests.
- Examples 1 and 2 ante are typical and illustrative of the improved results obtainable by the present invention.
- other catalytically sulfurized oils may beprepared as illustrated in Example 1 and employed in making other improved cutting oils and lubricants as illustrated in Example 2.
- other fatty oils such as corn, soybean oil, cottonseed oil, sperm oil and like fatty oils may be used in lieu of lard oil in Example 1 above.
- fatty' oils may be catalytically sulfurized byheating them with sulfur in the presence of a catalyst of the type described ante.
- sulfurized bases useful in making improved cutting oils may be prepared from petroleum oils, such as a 200 S. U. S. Texas 011, or from oleflnic hydrocarbons, such as octadecene and other oleflnic hydrocarbons obtained by the cracking of mineral, oils.
- the petroleum oils and the 0 "finic hydrocarbons readily react with sulfur and can be catalytically sulfurized with advantage using N-benzyl-p-phenetidine and similar catalysts.
- the following examples illustrate the catalytic sulfurization of petroleum oils and oleflnic hydrocarbons in accordance with this invention.
- Example 4 octadecene-i was sulfurized with 10 per cent by weight of sulfur using N-benzyl-p-phenetidine as the catalyst. In doing so, the octadecene-i was heated to 300 F. and 1 per cent by weight of N-benzyl-pphenetidine was-added. Next 10 per cent by weight of sulfur was added to the hot mixture and the reaction mixture maintained between 310 and 320 F. for 1 hours to complete the reaction.
- catalytically sulfurized bases having improved properties for The preparation of a catalytically sulfurized sperm oil is illustrated below.
- the catalytically sulfurized sperm oil may likewise be incorporated in various mineral lubricating oils to produce improved cutting oils and other lubricants having the present purposes.
- Example 5 In this example, a 200 S. U. S. Texas oil was sulfurized with 4 per cent by weight of sulfur using N-benzyl-p-phenetidine as the catalyst. In doing so, the Texas oil was heated to 350 F. and 1 per cent by weight of N-benzylp-Dhenetidine was added. Next 4 per cent by weight of sulfur was added to the hot mixture and the reaction mixture maintained between 340 F. and 350 Fnfor 4 hours.
- the sulfurized base so obtained was stable and it had a good odor. However if the catalyst was omitted in the foregoing procedure, the sulfurized product had objectionable odor. The final sulfur content of this product was 2.5 per cent by weight.
- the sulfurization of fatty oils and mineral oils can be effected at relatively low temperatures and with shorter periods of heating; the sulfurized oils, or bases so produced having a lighter color and other advantageous properties for the present purposes.
- a process of preparing a suliurized oil which comprises reacting sulfur with oil in the presence of a catalyst having the general formula n A B-Jk-B wherein R and R" represent substituents selected from the class consisting of hydrogen, lower aliphatic radicals and monocyclic aromatic radicals and AR is a benzene ring with alower alkoxy or monocyclic aryloxy group attached to the ortho or para position.
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Organic Chemistry (AREA)
- Lubricants (AREA)
Description
atented New. 3948 J PROCESS FOR PREPARING SULFURIZED LUBRICATING COMPOSITION Dayton P. Clark, Jr., Pittsburgh, Pa, assl znor to Gull Research & Development Company, Pitta. burgh, Pa., a corporation of Delaware I No Drawing; Application July 20, 1945,
My invention relates to a process for preparing sulfurized lubricating compositions and has to do particularly with procedure for preparing sulfurized lubricating oil compositions adapted for use as cutting oils, extreme pressure lubricants and the like.
Cutting oil is used to cool and lubricate the tools and work pieces in the various metal form- 'ing operations which encounter extreme pressure, such as cutting, drilling and the like. Criteria by which cutting oils are judged incl'ude color, stability of oil with retention of quality with repeated re-use, odor particularly when heated and in-' creased life of cutting tool. The most efiective oils are those containing sulfur, and heretofore fatty oils have been heated in the presence of sulfur at very high temperatures and for such a length of time that various disagreeable charac terlstics have been imparted to the oil.
My invention is particularly applicable to the preparation of sulfurized oils and fats for use in the manufacture of cutting oils and lubricants; these sulfurized oils and fats are comparatively free from obnoxious odors and have relatively light transparent colors and hence are far superior to sulfurized oils and fats on the market. I obtain this unexpected result by using a sulfurized oil which has been sulfurized in the presence of a catalyst, having the general formula wherein R and it" represent substituents selected from the class consisting of hydrogen, lower aliphatic radicals and monocyclic aromatic radicals and AR. is a benzene ring with a lower alkoxy or monocyclic aryloxy group attached to the ortho or para position. Among the catalysts used are p-Anisidine N-benzyl-p-anisidine N-dibenzyl-p-anisidine o-Anisidine N-benzyl-o-anisidine p-Phenetidine N-benzyl-p-phenetidine N-dibenzyl-p-phenetidine o-Phenetidine N-benzyl-o-phenetidine N-ethyl-p-phenetidine N-n-propyl-p-phenetidine p-Phenoxyaniline Furthermore, the process of my invention may be employed for sulfurizing mineral oils thus obviatments, but such treatment is Serial No. 606,271
3 Claims. (Cl. 260-399) V ing the necessity of preparing sulfurizedfatty bases which are added to mineral oils in order to obtain sulfurized cutting oils. Cutting oils and lubricants prepared from the sulfurlzed products of my invention are at least as effective as similar products prepared from present commercially available sulfurized substances, and are superior to such products in that they do not possess ob- Jectionable odors *and colors, are substantially non-corrosive, and are stable products. The light colored product so obtained permits easy observance of the thread cutting or machining operations. Many of the prior art Oils had to be subjected to treatment with acid and clay to improve the color, usually without permanent improvenot necessary in my invention.
In practicing my invention, an oil, sulfur and a catalyst having the general formula set forth in the paragraph above are reacted in suitable proportions and under proper conditions to obtain a sulfur base, and then this sulfur base is dispersed in correct proportions in a lubricating oil of predetermined viscosity to obtain a lubricating composition having the desired characteristics for the purpose intended. This invention is particularly applicable to the preparation of sulfur-type cutting oils and for this purpose a light lubricating oil is used. Other lubricating compositions such as extreme pressure base lubricating oils and extreme pressure gear lubricants, hypoid gear lubricants, etc., may be obtained by using mineral lubricating oils of high viscosity. In the preparation of sulfur-type cutting oils, a light lubricating oil of about to 150 viscosity range at F. is employed.
The following examples illustrate certain advantageous embodiments of my invention.
Example 1.-This example illustrates one advantageous method of preparing sulfurized oils in accordance with this invention; an excellent sulfurized fatty oil being prepared from the following materials:
Pounds Lard oil 89 Sulfur 10 N-benzyl-p-lphenetidine 1 added to the hot mixture. The reaction mixture v was then held at a temperature between 3 10 "and 320 F. for V hour to complete the reaction; The sulfurized oil was then cooled to room temperature.
The catalytically sulfurized lard oil or sulfur base so obtained was a stable, clear, transparent to the above procedure furization. The product was blended with a "10 liquid. It was substantially non-corrosive and free from obnoxious odors. This liquid sulfurized base was readilysoluble in a wide variety of mineral lubricating oils. When incorporated in mineral oils in amounts of from 1 to 25 per cent by weight based on the mineral oil, improved lubricants are readily obtained. For instance,- improved cutting oils and other lubricants maybe readily prepared in this way. The following example illustrates the preparation of one such im-' proved cutting oil. Y
. Example 2.In preparing this improved cut-.'
described for lard oil sulviscosity (8. U. S.) mineral oil (50:50) and the blend was. free of objectionable odor. The 50:50 blend was added to an automotive lubricating oil (0.5 per cent by weight) to determine its ability to prevent corrosion. The tests were made at 325-F. in an Underwood oxidation test using General Motors truck Cu-Pb bearings. After 5 hours,
the bearing actually was 5 mg. heavier instead of losing weight as when corrosion .occurs. When the automotive lubricating oil was used without the addition of the inhibitor represented in the ting oil, 22 pounds of the -catalytically sulfurized lard oil obtained in Example 1 were dissolved in 78 pounds of a commercial mineral'lubricating oil, namely, a paraflln oil of viscosity 100 S. U. S.
.and 01' color 2 on the N. P. A. scale. The improved. cutting oil so obtained when subjected to standard lathe test gave outstanding perform:- ance, as compared to the mineral oil itself and a commercial cutting oil containing a small amount of sulfurized lard oil made without a catalyst. The lathe results obtained are given in the follow- The prior commercial cutting oil employed in the above test was a composition comprising 78 per cent of a, light parafllnic neutral oil blend and 22 per cent of sulfurized lard oil (non-catalytic) the parts being parts by weight. Non-catalytic sul-.
furized lard oil in this commercial cutting oil was prepared by heating lard oil to 275-300 F., adding 10 per cent by weight of sulfur to 'the heated oil over a period of 2 hours, and then further heating this reaction mixture at 330-340 F. for hour. As shown by the test data given in the above table, the improved cutting oil prepared in Example 2 ante, is markedly superior to the prior commercial cutting oil as well as to the plain mineral oil employed in these comparative tests.
That is, Examples 1 and 2 ante are typical and illustrative of the improved results obtainable by the present invention. In the practice of this invention, other catalytically sulfurized oils may beprepared as illustrated in Example 1 and employed in making other improved cutting oils and lubricants as illustrated in Example 2. For instance, other fatty oils, such as corn, soybean oil, cottonseed oil, sperm oil and like fatty oils may be used in lieu of lard oil in Example 1 above.
50:50 mixture, there was a loss of 93 mg after a 5hour test period. Thus, a decided advantage is obtained when 0.5 per cent of .the 50:50 mixture is employed.
Also, in the practice of the present invention various other fatty' oils may be catalytically sulfurized byheating them with sulfur in the presence of a catalyst of the type described ante.
Further, other sulfurized bases, useful in making improved cutting oils may be prepared from petroleum oils, such as a 200 S. U. S. Texas 011, or from oleflnic hydrocarbons, such as octadecene and other oleflnic hydrocarbons obtained by the cracking of mineral, oils. The petroleum oils and the 0 "finic hydrocarbons readily react with sulfur and can be catalytically sulfurized with advantage using N-benzyl-p-phenetidine and similar catalysts. The following examples illustrate the catalytic sulfurization of petroleum oils and oleflnic hydrocarbons in accordance with this invention.
Example 4.-In this example, octadecene-i was sulfurized with 10 per cent by weight of sulfur using N-benzyl-p-phenetidine as the catalyst. In doing so, the octadecene-i was heated to 300 F. and 1 per cent by weight of N-benzyl-pphenetidine was-added. Next 10 per cent by weight of sulfur was added to the hot mixture and the reaction mixture maintained between 310 and 320 F. for 1 hours to complete the reaction.
The sulfurized baseso obtained was stable and light in color. It had'a good odor. 0n the-other hand, if the catalyst was omitted in the foregoing procedure, the sulfurized product was very sour and very dark in color. Thus, it is evident that the small amount of N- benzyl-p-phcnetidine employed as the catalyst in the foregoing example markedly alters the result of the reaction and facilitates .the production of light-colored,
- sulfurized bases having improved properties for The preparation of a catalytically sulfurized sperm oil is illustrated below. The catalytically sulfurized sperm oil may likewise be incorporated in various mineral lubricating oils to produce improved cutting oils and other lubricants having the present purposes.
Example 5; In this example, a 200 S. U. S. Texas oil was sulfurized with 4 per cent by weight of sulfur using N-benzyl-p-phenetidine as the catalyst. In doing so, the Texas oil was heated to 350 F. and 1 per cent by weight of N-benzylp-Dhenetidine was added. Next 4 per cent by weight of sulfur was added to the hot mixture and the reaction mixture maintained between 340 F. and 350 Fnfor 4 hours.
The sulfurized base so obtained was stable and it had a good odor. However if the catalyst was omitted in the foregoing procedure, the sulfurized product had objectionable odor. The final sulfur content of this product was 2.5 per cent by weight.
For instance, the sulfurized base obtained in In the foregoing examples, in lieu of N-benzylp-phenetidine, other catalysts of the type shown above may be employed and other improved sulfur bases and improved cutting oils prepared.
In general, by using catalysts in accordance with this invention, the sulfurization of fatty oils and mineral oils can be effected at relatively low temperatures and with shorter periods of heating; the sulfurized oils, or bases so produced having a lighter color and other advantageous properties for the present purposes.
While various amounts of the catalysts may be used, it has been found most desirable in attaining all of the beneficial results of this invention to use from about 0.1 per cent to 2 per cent of the catalyst and most preferably 1 per cent.
Obviously many modifications and variations of the invention, as hereinbefore set forth, may be made without departing from the spirit and scope thereof and therefore only such limitations should be imposed as are indicated in the ap pended claims.
What I claim is:
1. A process of preparing a suliurized oil which comprises reacting sulfur with oil in the presence of a catalyst having the general formula n A B-Jk-B wherein R and R" represent substituents selected from the class consisting of hydrogen, lower aliphatic radicals and monocyclic aromatic radicals and AR is a benzene ring with alower alkoxy or monocyclic aryloxy group attached to the ortho or para position.
As an improvement in preparing sulfurized EBEFEREltICES CITED The following references are of record in the file of this patent:
UNITED STATES PA'IiMTfi Number Name Date 2,137,584 Elsmere Nov. 22, 1938 2,179,063 Smith et a1. Nov. 7, 1939 2,179,066 Smith Nov. 7, 1939 2,206,151 Bennett July 2, 19% 2,237,096 Dearborn Apr. 1, 1941 2,338,829 Wemtz Jan. 11, 10% 2,378,803 Smith June 19, 1945
Publications (1)
Publication Number | Publication Date |
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US2454034A true US2454034A (en) | 1948-11-16 |
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Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
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US2454034D Expired - Lifetime US2454034A (en) | Process fob preparing sulfurized |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4487705A (en) * | 1971-02-19 | 1984-12-11 | Sun Ventures, Inc. | Oil containing a cosulfurized olefin-triglyceride blend |
Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2137584A (en) * | 1936-07-27 | 1938-11-22 | Hercules Powder Co Ltd | Method for the production of sulphur-containing high molecular weight compounds and the products thereof |
US2179063A (en) * | 1936-09-28 | 1939-11-07 | Gulf Oil Corp | Methods of making sulphurized sperm oils and the like |
US2179066A (en) * | 1936-10-29 | 1939-11-07 | Gulf Oil Corp | Manufacture of sulphurized sperm oil |
US2206151A (en) * | 1936-01-15 | 1940-07-02 | Mid Continent Petroleum Corp | Process of sulphurizing oils |
US2237096A (en) * | 1939-09-22 | 1941-04-01 | Frederick E Dearborn | Lubricant |
US2338829A (en) * | 1941-05-06 | 1944-01-11 | Du Pont | Chemical process and product |
US2378803A (en) * | 1945-06-19 | Lubricants |
-
0
- US US2454034D patent/US2454034A/en not_active Expired - Lifetime
Patent Citations (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2378803A (en) * | 1945-06-19 | Lubricants | ||
US2206151A (en) * | 1936-01-15 | 1940-07-02 | Mid Continent Petroleum Corp | Process of sulphurizing oils |
US2137584A (en) * | 1936-07-27 | 1938-11-22 | Hercules Powder Co Ltd | Method for the production of sulphur-containing high molecular weight compounds and the products thereof |
US2179063A (en) * | 1936-09-28 | 1939-11-07 | Gulf Oil Corp | Methods of making sulphurized sperm oils and the like |
US2179066A (en) * | 1936-10-29 | 1939-11-07 | Gulf Oil Corp | Manufacture of sulphurized sperm oil |
US2237096A (en) * | 1939-09-22 | 1941-04-01 | Frederick E Dearborn | Lubricant |
US2338829A (en) * | 1941-05-06 | 1944-01-11 | Du Pont | Chemical process and product |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4487705A (en) * | 1971-02-19 | 1984-12-11 | Sun Ventures, Inc. | Oil containing a cosulfurized olefin-triglyceride blend |
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