US2193771A - Lubricating oil composition - Google Patents
Lubricating oil composition Download PDFInfo
- Publication number
- US2193771A US2193771A US167561A US16756137A US2193771A US 2193771 A US2193771 A US 2193771A US 167561 A US167561 A US 167561A US 16756137 A US16756137 A US 16756137A US 2193771 A US2193771 A US 2193771A
- Authority
- US
- United States
- Prior art keywords
- oil
- sulfur
- lanolin
- base
- sulfurized
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M135/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing sulfur, selenium or tellurium
- C10M135/02—Sulfurised compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
- C10M2219/00—Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
- C10M2219/02—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds
- C10M2219/024—Sulfur-containing compounds obtained by sulfurisation with sulfur or sulfur-containing compounds of esters, e.g. fats
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
- C10N2040/00—Specified use or application for which the lubricating composition is intended
- C10N2040/20—Metal working
- C10N2040/22—Metal working with essential removal of material, e.g. cutting, grinding or drilling
Definitions
- This invention relates to sulfurized lubricating compositions and has to do particularly with sulfurized lubricating oil compositions adapted for use as cutting oils, extreme pressure lubricants andthe like.
- a fish oil such as sperm oil, may be sulfurlzed under proper conditions to obtain a suitable product containing a high sulfur content, but such a product is undesirable because of its dark color.
- a saponifiable wax, such as lanolin, will take up considerable quantities of sulfur, although in lesser amount than sperm oil, to form a product of light color, but this material is undesirable because of its instability.
- sulfurizing a mixture of sperm oil and lanolin a product is obtained exhibiting the beneficial qualities of both, without the undesirable characteristics obtained by sulfurizing the materials separately. In this way, I may produce a sulfur I purpose intended.
- the invention is particularly applicable to the preparation of sulfur cuttingoils and for this purpose a light lubricating oil is used.
- lubricating compositions such as extreme pressure base lubricating oils and ex- 5 treme pressure gear lubricants, hypoid gear lubricants, etc., may be obtained by using mineral lubricating oils of higher viscosity.
- mineral lubricating oils of higher viscosity.
- sulfur cutting oils a light lubricating oil of about 60-150 viscosity range at 100 F.
- lubricating oils of the motor 011 range, for example 180 to 400 or 500 or higher viscosity at 100 F., may be employed, whilefor more viscous compositions, high viscosity lubri- 5 eating oils, such as heavy vacuum distillates, cylinder stocks or other residuums, ranging in viscosity from about 100 to 200 or 300, or highenat 210 F., are useful.
- the lanolin, sperm oil and sulfur were reacted for two hours at 320-330 F. to form a sul- 60 fur base, which was homogeneous and tested approximately 33% sulfur.
- the product contained approximately 16% of sulfur in uncombined form. 5.3% of this base wasadded to a lubricating oil by heating the base and oil, together at about 275 F. for about 54 to V hour to form a 5 homogeneous dispersion and to dissolve the free sulfur in the mineral oil.
- the final product gave the following tests:
- the present invention has the advantage of providing means for obtaining a sulfurized lubricating oil composition of light color and high stability as well as eflicient lubrication qualities.
- the invention is particularly useful in the preparation of light color sulfurized cutting oils which are stable against sedimentation and have efficient cutting qualities, and yet are sufflciently light colored to permit easy observance of the thread cutting or machining operations. 7
- a lubricating oil composition comprising petroleum lubricating oil and the product resulting from heating together sperm oil, lanolin and so sulfur to temperatures of about 320-330 F. to
- the improvement which comprises heating together sulfur, sperm oil and lanolin to temperatures of about 320-330 F. to obtain a sulfurized sperm oil-lanolin base, as a homogeneous product, and incorporating the resultant sulfurized sperm oil-lanolin base with a lubricating oil.
- the improvement which comprises heating together about equal quantities of sperm oil, lanolin and sulfur to 320-330 F. for two hours to form a sulfurized sperm oil-lanolin base, and then commingling the resultant sulfurized sperm oil-lanolin base with a lubricating oil.
- a sulfur base adapted for use in lubricating compositions comprising essentially the product resulting from heating together sperm oil, lanolin and sulfur under conditions to form a sulfurized sperm oil-lanolin base containing about 10-35% of total sulfur and which is adapted to be commingled with mineral lubricating oilto form a stable composition of good color having cutting and extreme pressure characteristics.
- a cutting oil consisting essentially of a blend of a light lubricating oil with a sulfurizedsperm oil-lanolin base so as to provide about 1-3% sulfur in the blend, the sulfurized sperm oil-lanolin base being'prepared by sulfurizing a mixture of spermoil and lanolin under conditions to give a stable product of good color when blended with the said light lubricating oil.
- a light colored stable cutting oil consisting essentially of a blend of a light lubricating oil with a sulfurized sperm oil-lanolin base in a proportion to provide about 1-3% sulfur in the blend, the sulfurized sperm oil-lanolin base resulting from heating a mixture of substantial proportions of both sperm oil and lanolin with sulfur underconditions effecting sulfurizatlon of both the sperm oil and the lanolin, providing a base containing about 10-35% of sulfur, and which forms a stable product of good color when blended with said light lubricating oil in the proportion stated.
- a light-colored stable cutting oil consisting essentially of a light pale lubricating oil with a sulfurized sperm oil-lanolin base in a proportion providing about 1-3% sulfur in the blend, the sulfurized sperm oil-lanolin base resulting from heating together substantially equal parts of sperm oil-lanolin and sulfur under conditions to sulfurize both the sperm oil and the lanolin and provide a base containing about 33% total sulfur, some of which total sulfur is in uncombined form, the base being combined with the lubricating oil by heating at elevated temperatures to dissolve said uncombined sulfur of the base in the lubricating oil to form a stable product of light color.
- a lubricating oil composition comprising mineral lubricating oil and a substantial amount of a sulfur base to impart cutting and extreme pressure characteristics thereto, said sulfur base resulting from heating together fish oil, lanolin and sufficient sulfur under conditions to form a sulfurized fish oil-lanolin base of such character as to produce a stable composition of good color 'when compounded in the mineral lubrieating oil in the said amount.
- the method which comprises heating sulfur with a mixture of fish oil and lanolin under conditions of time and elevated temperature as to form a sulfurized fish oil-lanolin base which can be dissolved in mineral lubricating oil in substantial amount to produce a stable composition of good color having cutting and extreme pressure characteristics, and commingling the resultant sulfurized fish oil-lanolin base in mineral lubricating oil under conditions and in sufiicient amount to produce the said composition having the properties above stated.
Description
PATENT OFFICE LUBRICATING OIL COMPOSITION Oney P. Puryear, Fishkill, N. Y., assignor, by
mesne assignments, to Texaco Development Corporation, New York, N. Y., a corporation of Delaware No Drawing. Application October 6, 1937,
Serial No. 167,561
14 Claims.
This invention relates to sulfurized lubricating compositions and has to do particularly with sulfurized lubricating oil compositions adapted for use as cutting oils, extreme pressure lubricants andthe like.
A fish oil, such as sperm oil, may be sulfurlzed under proper conditions to obtain a suitable product containing a high sulfur content, but such a product is undesirable because of its dark color.
0 A saponifiable wax, such as lanolin, will take up considerable quantities of sulfur, although in lesser amount than sperm oil, to form a product of light color, but this material is undesirable because of its instability. I have found that by sulfurizing a mixture of sperm oil and lanolin, a product is obtained exhibiting the beneficial qualities of both, without the undesirable characteristics obtained by sulfurizing the materials separately. In this way, I may produce a sulfur I purpose intended. The invention is particularly applicable to the preparation of sulfur cuttingoils and for this purpose a light lubricating oil is used. Other lubricating compositions, such as extreme pressure base lubricating oils and ex- 5 treme pressure gear lubricants, hypoid gear lubricants, etc., may be obtained by using mineral lubricating oils of higher viscosity. In the preparation of sulfur cutting oils, a light lubricating oil of about 60-150 viscosity range at 100 F. is employed, while in the preparation of more viacous lubricants, lubricating oils of the motor 011 range, for example 180 to 400 or 500 or higher viscosity at 100 F., may be employed, whilefor more viscous compositions, high viscosity lubri- 5 eating oils, such as heavy vacuum distillates, cylinder stocks or other residuums, ranging in viscosity from about 100 to 200 or 300, or highenat 210 F., are useful.
The following example will illustrate the invention as applied to the preparation of a cutting oil: 1
The lanolin, sperm oil and sulfur were reacted for two hours at 320-330 F. to form a sul- 60 fur base, which was homogeneous and tested approximately 33% sulfur. The product contained approximately 16% of sulfur in uncombined form. 5.3% of this base wasadded to a lubricating oil by heating the base and oil, together at about 275 F. for about 54 to V hour to form a 5 homogeneous dispersion and to dissolve the free sulfur in the mineral oil. The final product gave the following tests:
The cutting oil so formed was tested on a I Landis cutting machine with the following results:
Speed, R. P. M 48 -60 Speed, feet per minute- 30 37 Threads cut Good good 20 Smokin None none Chip sticking 0. K. O. K. Discoloration None none While I prefer to prepare a sulfur base by heating about equal amounts of sperm oil, lanolin and sulfur, it is to be understood that other proportions of these materials-may be used, if desired, as long as the advantages of the stabilizing qualities of the sperm oil and light color characteristics of the lanolin are obtained in the final products. Also in some cases it may be desirable to decrease the amount of sulfur and I may prepare sulfur bases in which the sulfur may range from 10-35% or more. The amount of the sulfur base which may be used is not 35 fixed at 6% for this may vary within quite wide ranges, but in general I prefer to use suflicient to produce in the finished product about 1-3% of sulfur.
The present invention has the advantage of providing means for obtaining a sulfurized lubricating oil composition of light color and high stability as well as eflicient lubrication qualities. The invention is particularly useful in the preparation of light color sulfurized cutting oils which are stable against sedimentation and have efficient cutting qualities, and yet are sufflciently light colored to permit easy observance of the thread cutting or machining operations. 7 Obviously many modifications and variations of the invention, as hereinbefore set forth, may be made without departing from the spirit and scope thereof and therefore only such limitations should be imposed as are indicated in the appended claims.
I claim:
1. A lubricating oil composition comprising petroleum lubricating oil and the product resulting from heating together sperm oil, lanolin and so sulfur to temperatures of about 320-330 F. to
form a sulfurized sperm oil-lanolin base.
2. In the manufacture of sulfurized lubricating oil compositions, the improvement which comprises heating together sulfur, sperm oil and lanolin to temperatures of about 320-330 F. to obtain a sulfurized sperm oil-lanolin base, as a homogeneous product, and incorporating the resultant sulfurized sperm oil-lanolin base with a lubricating oil.
3. In the manufacture of sulfurized lubricating compositions, the improvement which comprises heating together about equal quantities of sperm oil, lanolin and sulfur to 320-330 F. for two hours to form a sulfurized sperm oil-lanolin base, and then commingling the resultant sulfurized sperm oil-lanolin base with a lubricating oil.
4. A sulfur base adapted for use in lubricating compositions, comprising essentially the product resulting from heating together sperm oil, lanolin and sulfur under conditions to form a sulfurized sperm oil-lanolin base containing about 10-35% of total sulfur and which is adapted to be commingled with mineral lubricating oilto form a stable composition of good color having cutting and extreme pressure characteristics.
5. A sulfur base adapted for addition to lubricating oils to form cutting oils, extreme pressure lubricants and the like, comprising essentially the product obtained by heating together sperm oil, lanolin and sulfur to temperatures of about 320-330 F. to form a sulfurized sperm oil-lanolin .base.
6. A sulfur base adapted for addition to lubricating oils to form cutting oils, extreme pressure lubricants and the like, comprising essentially the product obtained by heating together about equal proportions of sperm oil, lanolin and sulfur to temperatures of about 320-330 F. to form a sulfurized sperm oil-lanolin base.
7. In the manufacture of sulfurized lubricating compositions, the improvement which comprises heating together sulfur, sperm oil and Ian-' olin, to temperatures of about 320-330 F. to obtain a sulfurized sperm oil-lanolin base as a homogeneous product, and then incorporating the resultant sulfurized sperm oil-lanolin base into a lubricating oil at a temperature of about 275 F. to obtain a uniform dispersion.
8. A cutting oil consisting essentially of a blend of a light lubricating oil with a sulfurizedsperm oil-lanolin base so as to provide about 1-3% sulfur in the blend, the sulfurized sperm oil-lanolin base being'prepared by sulfurizing a mixture of spermoil and lanolin under conditions to give a stable product of good color when blended with the said light lubricating oil.
9. A light colored stable cutting oil consisting essentially of a blend of a light lubricating oil with a sulfurized sperm oil-lanolin base in a proportion to provide about 1-3% sulfur in the blend, the sulfurized sperm oil-lanolin base resulting from heating a mixture of substantial proportions of both sperm oil and lanolin with sulfur underconditions effecting sulfurizatlon of both the sperm oil and the lanolin, providing a base containing about 10-35% of sulfur, and which forms a stable product of good color when blended with said light lubricating oil in the proportion stated.
10. A light-colored stable cutting oil consisting essentially of a light pale lubricating oil with a sulfurized sperm oil-lanolin base in a proportion providing about 1-3% sulfur in the blend, the sulfurized sperm oil-lanolin base resulting from heating together substantially equal parts of sperm oil-lanolin and sulfur under conditions to sulfurize both the sperm oil and the lanolin and provide a base containing about 33% total sulfur, some of which total sulfur is in uncombined form, the base being combined with the lubricating oil by heating at elevated temperatures to dissolve said uncombined sulfur of the base in the lubricating oil to form a stable product of light color.
11. A lubricating oil composition comprising mineral lubricating oil and a substantial amount of a sulfur base to impart cutting and extreme pressure characteristics thereto, said sulfur base resulting from heating together fish oil, lanolin and sufficient sulfur under conditions to form a sulfurized fish oil-lanolin base of such character as to produce a stable composition of good color 'when compounded in the mineral lubrieating oil in the said amount.
12. A lubricating oil composition according to claim 11, in which the fish oil is sperm oil.
13. In the manufacture of sulfur-containing lubricating compositions, the method which comprises heating sulfur with a mixture of fish oil and lanolin under conditions of time and elevated temperature as to form a sulfurized fish oil-lanolin base which can be dissolved in mineral lubricating oil in substantial amount to produce a stable composition of good color having cutting and extreme pressure characteristics, and commingling the resultant sulfurized fish oil-lanolin base in mineral lubricating oil under conditions and in sufiicient amount to produce the said composition having the properties above stated.
14. The method according to claim 13, in which the fish oil used is sperm oil, in which the sulfurized sperm oil-lanolin base contains uncombined as well as combined sulfur, and in which the said base is commingled with the mineral lubricating oil at a sufficiently elevated temperature to dissolve said uncombined sulfur of the base in the lubricating oil.
- ONEY P. PURYEAR.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US167561A US2193771A (en) | 1937-10-06 | 1937-10-06 | Lubricating oil composition |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US167561A US2193771A (en) | 1937-10-06 | 1937-10-06 | Lubricating oil composition |
Publications (1)
Publication Number | Publication Date |
---|---|
US2193771A true US2193771A (en) | 1940-03-12 |
Family
ID=22607864
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US167561A Expired - Lifetime US2193771A (en) | 1937-10-06 | 1937-10-06 | Lubricating oil composition |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2417283A (en) * | 1942-12-23 | 1947-03-11 | Standard Oil Dev Co | Lubricant |
US2439821A (en) * | 1942-08-19 | 1948-04-20 | Standard Oil Co | Lubricant preparation |
US2581132A (en) * | 1949-07-13 | 1952-01-01 | Texas Co | Lubricating oil |
-
1937
- 1937-10-06 US US167561A patent/US2193771A/en not_active Expired - Lifetime
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2439821A (en) * | 1942-08-19 | 1948-04-20 | Standard Oil Co | Lubricant preparation |
US2417283A (en) * | 1942-12-23 | 1947-03-11 | Standard Oil Dev Co | Lubricant |
US2581132A (en) * | 1949-07-13 | 1952-01-01 | Texas Co | Lubricating oil |
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