US2453816A - Rust preventive slushing compound for cartridge clips - Google Patents

Rust preventive slushing compound for cartridge clips Download PDF

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Publication number
US2453816A
US2453816A US544328A US54432844A US2453816A US 2453816 A US2453816 A US 2453816A US 544328 A US544328 A US 544328A US 54432844 A US54432844 A US 54432844A US 2453816 A US2453816 A US 2453816A
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United States
Prior art keywords
rust preventive
cartridge clips
compound
slushing compound
solvent
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Expired - Lifetime
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US544328A
Inventor
Schindler Hans
Paul T Anderson
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Pure Oil Co
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Pure Oil Co
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Priority to US544328A priority Critical patent/US2453816A/en
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Publication of US2453816A publication Critical patent/US2453816A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M1/00Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants
    • C10M1/08Liquid compositions essentially based on mineral lubricating oils or fatty oils; Their use as lubricants with additives
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/102Aliphatic fractions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/104Aromatic fractions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/106Naphthenic fractions
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/108Residual fractions, e.g. bright stocks
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/125Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of eight up to twenty-nine carbon atoms, i.e. fatty acids
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/10Carboxylix acids; Neutral salts thereof
    • C10M2207/12Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/129Carboxylix acids; Neutral salts thereof having carboxyl groups bound to acyclic or cycloaliphatic carbon atoms having hydrocarbon chains of thirty or more carbon atoms
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2219/00Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2219/04Organic non-macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions containing sulfur-to-oxygen bonds, i.e. sulfones, sulfoxides
    • C10M2219/044Sulfonic acids, Derivatives thereof, e.g. neutral salts
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2010/00Metal present as such or in compounds
    • C10N2010/08Groups 4 or 14
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10NINDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/12Inhibition of corrosion, e.g. anti-rust agents or anti-corrosives

Definitions

  • This invention relates to slushins oils and more particularly to slushinz oils suitable for preventmetal articles such as cartridge clips, shells and other ordnance goods.
  • the object of this invention is to provide an ei'- tective rust preventing alushing compound for Pal-herum" cartridse clips and other ordnance goods. 4 v y
  • ahiehly eective rust preventing smelling ⁇ compound can he prepared by saponlryln wool grease with lltharse to make a lead wool grease soap havin'ga neutralization number between 2.5-4 and 'preferably approximately 3 and mixing the lead wool grease roep with a iight lubricating oil and vrettiuiz agent and a thinner in proper proportions.
  • Ordnance speclilcatiou for slashing compound for Parkeriredf cartridee clips Ordnance speclilcatiou for slashing compound for Parkeriredf cartridee clips.
  • -'Ihe finished hot soap is mixed with a. low viscosity mineral lubricating oil. preferably one having a viscosity vfrom Blite 150 seconds Beybolt at 100' F; From 15 to 3l) parte by weight of. leadwool grease soap may he mixed with from te 5i)V parts by weight or the lubricating oil and these figures represent the percentages orA these ingredients in the ilnal composition.
  • 4lil wetting containing such es dloctyl ester of sodium salio-succinio acid is added to the mixture in is present in the mixture to the extent of lv to 3%. Any higher alcohol ester o! an alkali metal sulfo-succinlo acid may he used in place oi the dioctyl ester and preferably esters of alcohols having from 8 to 18 carbon atoms in the molecule.
  • composition made as above described, has e semi-solid or greasy texture.
  • This material is thinned with a nvdrocarbon solvent having a boiling range up to about 400 F.. such as Stoddard solvent, to the extent desired which will depend on the thiclmess oi the film required on the coated object.
  • a nvdrocarbon solvent having a boiling range up to about 400 F.. such as Stoddard solvent, to the extent desired which will depend on the thiclmess oi the film required on the coated object.
  • Any light hydrocarbon solvent having a flash point above 100 F. may be used.
  • composition prepared in accordance with our invention passed the United States amounts suoli that it
  • the slushine oli is generally applied to the ob'- 'runnins the obie'cte in the to remove excess semi-solid against rusting.
  • the amount of Stoddard solvent is 28.1%
  • the amount of solvent may be more or lesb, depending on the thickness ot the film it is desired to leave on the coated object. Where a heavy film is desired, the amounto the solvent is low. wher- 6 l" light nlm is desired. the ammint o! the solvent-gingen.
  • a sluehing oil composition consisting of from 1li-30% by weicht oflead-wool crease soap having a neutralization number of about 3.
  • Saybolt from l-8% by ⁇ weight ot a higher'alcohol ester oi' an alkali metal eulfo-succinic acid and the balance a low-boiling hydrocarbon liquid having a ilnsh point 0l' at lestlDO P.
  • a slushins oll consisting of. the following substances in approximately the following parte by weight: wool grease-17.3: inname-3.5: dioetyl ester of sodium sulfo-succioie acid- 2; Pennsylvania neutral mineral oil having a viscosity of 100 seconds Saybolt at 100 lip-49.1; Stod- 3 dard solvent-28.1, and in which the litharge and wool grease are combined to funn o. iead-woo1 grease soap having a. neutralization number of about 3.
  • a siushing oil consisting o! 30 to 50 per cent by weight of light mineral lubricating oil, 15 to 30 per cent by weight of lead-wool grease soap having a. neutralization number of about 3, from 1-3 per cent by weight of av higher alcohol ester cf an alkali metal suifo-succinin acid, and the balance a low-boillnkhydmarbogiiquid HANS SCHINDLER. PAUL T. ANDERSON.

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)

Description

'inerusngo'i Patented Nov. 16,1948
siusnmo ron. cammen curs Hana Schindler, Evanston, and Paul LT. Anderson.
The Pure RUST PREVENTIVE mk ma mi pany. Uhioaxo.
.dei il :eine:
OilCom Ill., a corporation ofOliio No Drawing. Annulation Inl! 10, 19, Bel'il N0. 544,828
4 Cla'lml. (GL 10B-1Q) This invention relates to slushins oils and more particularly to slushinz oils suitable for preventmetal articles auch as cartridge clips, shells and other ordnance goods.
The object of this invention is to provide an ei'- tective rust preventing alushing compound for Pal-herum" cartridse clips and other ordnance goods. 4 v y We have discovered that ahiehly eective rust preventing smelling` compound can he prepared by saponlryln wool grease with lltharse to make a lead wool grease soap havin'ga neutralization number between 2.5-4 and 'preferably approximately 3 and mixing the lead wool grease roep with a iight lubricating oil and vrettiuiz agent and a thinner in proper proportions.
Ordnance speclilcatiou for slashing compound for Parkeriredf cartridee clips.
Percent by weicht Common wool grease I'LSA Litharge Diootyr ester of eodium :culto-succinle 'In preparing our sllushini compound, ordinary wool grease, degres or lanolin is mixed with suicientlitharge to produce a soap having a neutralization number of 2.5-4 when completed and preferably around 3. The wool grease and the litharge are heated to e temperature o! approximately '350 F. for aperiod oi three hoursl with agitation in order to complete the saponlilcatio'n.
-'Ihe finished hot soap is mixed with a. low viscosity mineral lubricating oil. preferably one having a viscosity vfrom Blite 150 seconds Beybolt at 100' F; From 15 to 3l) parte by weight of. leadwool grease soap may he mixed with from te 5i)V parts by weight or the lubricating oil and these figures represent the percentages orA these ingredients in the ilnal composition. 4lil wetting aient such es dloctyl ester of sodium salio-succinio acid is added to the mixture in is present in the mixture to the extent of lv to 3%. Any higher alcohol ester o! an alkali metal sulfo-succinlo acid may he used in place oi the dioctyl ester and preferably esters of alcohols having from 8 to 18 carbon atoms in the molecule.
'I'he composition, made as above described, has e semi-solid or greasy texture. This material is thinned with a nvdrocarbon solvent having a boiling range up to about 400 F.. such as Stoddard solvent, to the extent desired which will depend on the thiclmess oi the film required on the coated object. Any light hydrocarbon solvent having a flash point above 100 F. may be used.
The following composition prepared in accordance with our invention passed the United States amounts suoli that it The slushine oli is generally applied to the ob'- 'runnins the obie'cte in the to remove excess semi-solid against rusting.
Although in the iormula above let forth the amount of Stoddard solvent is 28.1%, the amount of solvent may be more or lesb, depending on the thickness ot the film it is desired to leave on the coated object. Where a heavy film is desired, the amounto the solvent is low. wher- 6 l" light nlm is desired. the ammint o! the solvent-lebten.
By following the procedure abovej';eet"forth in the preparation ot the compound. onli by adherins to the quantities of the eeverallnsredients previously ect forth. a ueetul and edective slashing oil is produced.
We claim:
l. A sluehing oil composition consisting of from 1li-30% by weicht oflead-wool crease soap having a neutralization number of about 3. trom Sil-50% by weiaht oi mineral oil having a vlecoaiw at F, of from 0to 150 seconds Saybolt, from l-8% by `weight ot a higher'alcohol ester oi' an alkali metal eulfo-succinic acid and the balance a low-boiling hydrocarbon liquid having a ilnsh point 0l' at lestlDO P.
2. A siushing oli in accordance withyclahn 1 in which the este: ls dlootyi eater o: sodium sono suceinic acid and the low-boiling hydrocarbon is Stoddard solvent.
3. A slushins oll consisting of. the following substances in approximately the following parte by weight: wool grease-17.3: inname-3.5: dioetyl ester of sodium sulfo-succioie acid- 2; Pennsylvania neutral mineral oil having a viscosity of 100 seconds Saybolt at 100 lip-49.1; Stod- 3 dard solvent-28.1, and in which the litharge and wool grease are combined to funn o. iead-woo1 grease soap having a. neutralization number of about 3.
4. A siushing oil consisting o! 30 to 50 per cent by weight of light mineral lubricating oil, 15 to 30 per cent by weight of lead-wool grease soap having a. neutralization number of about 3, from 1-3 per cent by weight of av higher alcohol ester cf an alkali metal suifo-succinin acid, and the balance a low-boillnkhydmarbogiiquid HANS SCHINDLER. PAUL T. ANDERSON.
REFERENCES m2.-
The followingr references are of record llx'xjthe nie of this patent:
Nuinber 4 UNITED STATES PATENTS Name Date Ekenberg Mar. 14, 1899 Morgan Jan. 4, 1941 Waugh Feb. 15. 1944 Adams et al May 16, 1944 Wachter Aug. 29. 1944 Ruedrich Jan. 1. 1946 Kollen et al Mar. 25. 1947 FQREIGNPATEN'IS 'Cfolmty Date Great Britain May 18, 1921 Great Britain June 14, 1939
US544328A 1944-07-10 1944-07-10 Rust preventive slushing compound for cartridge clips Expired - Lifetime US2453816A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2627474A (en) * 1949-11-08 1953-02-03 Texas Co Rust preventive compositions containing a wax-soap base
US2856299A (en) * 1956-02-24 1958-10-14 Exxon Research Engineering Co Water-displacing agent

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB507335A (en) *
US620899A (en) * 1899-03-14 Martin ekenberg
US1364134A (en) * 1920-02-16 1921-01-04 Edgar G Behr Rust-preventing mixture for metals
GB163474A (en) * 1920-02-18 1921-05-18 Otto Reynard Improvements in or relating to the protection of surfaces
US2342027A (en) * 1941-04-18 1944-02-15 Tide Water Associated Oil Comp Inhibited oil
US2348715A (en) * 1941-06-25 1944-05-16 Standard Oil Co Slushing composition
US2357276A (en) * 1942-06-29 1944-08-29 Shell Dev Corrosion inhibiting coating composition
US2392102A (en) * 1941-02-01 1946-01-01 Tide Water Associated Oil Comp Rust preventive composition
US2418075A (en) * 1945-11-05 1947-03-25 Union Oil Co Rust-preventive composition

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB507335A (en) *
US620899A (en) * 1899-03-14 Martin ekenberg
US1364134A (en) * 1920-02-16 1921-01-04 Edgar G Behr Rust-preventing mixture for metals
GB163474A (en) * 1920-02-18 1921-05-18 Otto Reynard Improvements in or relating to the protection of surfaces
US2392102A (en) * 1941-02-01 1946-01-01 Tide Water Associated Oil Comp Rust preventive composition
US2342027A (en) * 1941-04-18 1944-02-15 Tide Water Associated Oil Comp Inhibited oil
US2348715A (en) * 1941-06-25 1944-05-16 Standard Oil Co Slushing composition
US2357276A (en) * 1942-06-29 1944-08-29 Shell Dev Corrosion inhibiting coating composition
US2418075A (en) * 1945-11-05 1947-03-25 Union Oil Co Rust-preventive composition

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2627474A (en) * 1949-11-08 1953-02-03 Texas Co Rust preventive compositions containing a wax-soap base
US2856299A (en) * 1956-02-24 1958-10-14 Exxon Research Engineering Co Water-displacing agent

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