US2410626A - Means and method of treating surfaces - Google Patents

Means and method of treating surfaces Download PDF

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US2410626A
US2410626A US431131A US43113142A US2410626A US 2410626 A US2410626 A US 2410626A US 431131 A US431131 A US 431131A US 43113142 A US43113142 A US 43113142A US 2410626 A US2410626 A US 2410626A
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fluid
work
metalizing
unit
chamber
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Joseph M Boudreau
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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601Process or apparatus
    • C23C18/1619Apparatus for electroless plating
    • C23C18/1628Specific elements or parts of the apparatus
    • C23C18/163Supporting devices for articles to be coated
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601Process or apparatus
    • C23C18/1617Purification and regeneration of coating baths
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601Process or apparatus
    • C23C18/1619Apparatus for electroless plating
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601Process or apparatus
    • C23C18/1633Process of electroless plating
    • C23C18/1655Process features
    • C23C18/1658Process features with two steps starting with metal deposition followed by addition of reducing agent
    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23CCOATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C18/00Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
    • C23C18/16Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
    • C23C18/1601Process or apparatus
    • C23C18/1633Process of electroless plating
    • C23C18/1655Process features
    • C23C18/166Process features with two steps starting with addition of reducing agent followed by metal deposition

Definitions

  • This invention relates to means and method of treating surfaces and more particularly in carrying out the metalizing of electrically non conductive surfaces to render the same conductive and adapted thereby to be electro-plated.
  • the objects of the invention are to provide an improved means for accomplishing the purpose; to provide such a means which Will be automatic; to apply a reducing agent intermittently with application of a metalizing solution; to apply each in separate chambers; to obtain an even distribution of reducing agent and of metaliaing solution upon the article to be metalized; to apply the reducing agent and metalizing solution both in fluid form; to apply said fluids to the entire surface of the article; to provide for intermittent advance of the article from station to station and introduction into the fluid at each station; to provide for a plurality of fluid applying chambers and means for lifting the same simultaneously to several pieces of work; to improve upon previous methods of metalizing surfaces; to secure simplicity of construction, method and operation; and to obtain other advantages and results as may be brought out in the following description.
  • Figure 1 is a sectional View, partly in elevation, of one of the units of my improved means for treating surfaces
  • Figure 2 is a plan thereof
  • Figure 3 is an assembly illustrating a bank of units and article conveying and operating means employed in carrying out the method of my invention
  • Figure 4 is a sectional view on line IV-IV of Figure 1;
  • Figure 5 is a sectional View of amodified form of spray-head mounted in place in the spray chamber.
  • the reference numeral l designates a fluid-applying unit, which, for certain conveniences of use, is shown herein as comprising two chambers, one of which, H,
  • the upper chamber I I is of generally cylindrical shape with an upper flaring peripheral splash collar or apron l and a bottom funnel-like outlet 16, terminating in an outlet nipple I1.
  • the lower chamber 12 is shown with an upwardly directed entry socket l8 receiving said outlet nipple ll of the upper chamber II.
  • This lower chamber I2 is likewise preferablyfunnel-shape at its bottom leading to a .nipple l9 threaded or otherwise applied to the intake pipe 20 of the pump l3. That pump is of the usual centrifugal type.
  • the outlet pipe I4 is preferably of glass and attached to the pump by a union H.
  • the upper end of said pipe it meanother union 22 hereondetachably connecting with a spray head in the upper chamber l i Spray head 23 shown in Figures 1 and 2 preferably comprises a body in the form of a ring of pipe, the outer diameter of the ring being substantially the inside dimension of the chamber so the ring may be situated Within the chamber horizontally neXt the upper part thereof.
  • the ring of pipe constituting the body of said spray head is provided with suitable perforations 24 directed inwardly and slightly downward to obtain a cross spray of fluid in the chamber, such that an article introduced into the chamber from above through the ring will be thoroughly sprayed over its entire outer surface.
  • a lateral pipe 25 from the ring connects with said union 22 enabling the spray head to be removedreadily and another substituted.
  • FIG. 5 An alternative spray-head 23 is shown in Figure 5, the same comprising a nozzle-like body in this instance having the connecting pipe 25' applied at the bottom of the nozzle and extending to the side of the chamberand then upwardly to and laterally at the top of the chamber for connecting with said union 22.
  • Perforations 24' in the upper part of the nozzle of which some are directed outwardly-upward, enable the fluid to-spray as a fountain so that insides of articles may be sprayed thereby.
  • a plurality of units Ill arranged successively upon a platform 26, and, as a matter of convenience and economy, the several pumps are mounted upon and driven by a common shaft 2! in turn driven by a single motor 28 on said platform.
  • the platform is arranged to be raised and lowered, the operating means being here illustrated as cams 29 driven through bevel gears 30 from a shaft 3
  • This same motor-and shaft are geared to synchronously advance a workfeeding conveyor 33.
  • Said conveyor is shown as a continuous sprocket chain on which may be removably hung brackets '34 from which depend hooks-35 as shown to which the pieces of work 36 are hung.
  • the brackets and hooks are applied at intervals corresponding to the spacing of the units so that when one is suspended over a unit,
  • Advancement of theconveyor is with a step by step motion during the interval when the platform is lowered, so that while the conveyor is stationary with the brackets, hooks and Work alined with the units, the platform is raised and lowered thereby introducing the several pieces of work to the sprays of the corresponding units.
  • the step by step motion of the conveyor may sneeze be accomplished in any suitable manner, and for purposes of. i lu tration gearing somewhat similar to a Geneva movement is shown.
  • a stub shaft 31 carrying driving sprocket 38 for the conveyor chain is a pinion 35.
  • a rotatable member 40 in a common plane with said pinion has a segmental peripheral portion thereof provided with teeth 4] adapted to mesh periodically with the teeth of the pinion at which time the chain is advanced.
  • the toothed segment passes the pinion, the remaining part of said member having no teeth rotates without driving the pinion for a predetermined period, This represents the period of rest for-the conveyor.
  • Said member is continuously rotated, as by bevel gear connection with the cam-driving shaft 3
  • alternate units are supplied with difierent fluid.
  • the first unit may be used an appropriate fluid for preparing the surface. It
  • the second unit is intended for spraying of a metalizing fluid of a character, such as a silver compound that will be reduced in place on the work to a metallic status by the action of the reducing agent.
  • a metalizing fluid of a character such as a silver compound that will be reduced in place on the work to a metallic status by the action of the reducing agent.
  • An excess of this metalizing fluid adheres to the work and on the next or third step, the spray again consists of reducing agent in part acting ,on the metalizing material and adhering in excess of that then needed to reduce more of the metalizing material again sprayed on the work on thefourth step.
  • Adequate numbers of units may be provided for thus, alternately covering the'workto be sprayed by the reducing agent and metalizing fluid as often'as desired. After desiredthickness of metalizing material has been applied, the work may be removed or otherwise taken to the plating operations performed in usual manner for plating on metal surfaces.
  • the work to be metalized by my improved process may be and preferably is of an electrically non-conductive character.
  • said work Prior to'introduction to the apparatus here disclosed, said work should be suitably prepared to be receptive of the 'metalizingtreatment.
  • Such preparation in part governed by the constituency of the work, may be by sandblasting, chemical cleansing, bufling or otherwise:
  • An apparatus for metalizing surfaces comprising an elevating platform, a unit situated on said platform, means for suspending work over said unit, means to elevate the platform and unit and thereby introduce the work into the unit, and mean for spraying the work while situated in said unit.
  • An apparatus for .metalizing surfaces comprising an elevating platform, a plurality of units on said platform, means for suspending work over each of said units and periodioally'advance the work from one position over one unit' to a successive position over another unit, means to elevate the platform and units and thereby introduce the several pieces of work in the several units, and means for spraying the work while situated in said units.
  • a method of metalizing surfaces consisting in suspending a plurality of pieces of work and moving them in unison with a step-by-step motion, simultaneously including the several pieces of work each Within a spray unit individual to the piece of work between the step-by-step motion thereof, and spraying said pieces of work successively in each unit.
  • An apparatus for metalizing surfaces comprising a unit having a chamber having a bottom outlet, means for pumping fluid from the bottom outlet and spraying said fluid within the upper part of said chamber onto work suspended therein, and drcp-by-drop means having entry to the course of travel of the fluid between said bottom outlet and pumping means at a part in said course of travel where the fluid pressure is less than the force of gravity for replenishing by added concentrate the consumed fluid, whereby the concentrate is mixed with the fluid in transition to and before reaching the spray head.
  • a apparatus for metalizing surfaces comprising a unit having an upper chamber having a bottom outlet, a spray head mounted within said chamber in proximity to the top thereof, said unit having a lower chamber the inlet for which is the outlet of the upper chamber, a pump connected for returning fluid from the bottom of said lower chamber to said spray head and as a spray into the upper part of the upper chamber, and drop-by-drop means having entry to the course of travel of the fluid between discharge from the spray and said pump at a part in said course of travel where the fluid pressure is less than the force of gravity for replenishing by added concentrate the consumed fluid, whereby the concentrate is mixed with the fluid in transition to and before reaching the spray head.
  • a method of metalizing surfaces consisting in continuously circulating different spraying fluids, intermittently and successively subjecting the surfaces to the continuous sprays of said fluids, and continuously adding concentrate to the spray fluid as said fluid circulates, and reusing the fluid.
  • a method of metalizing surfaces consisting in continuously circulating a fluid through a spray head and back to source, introducing a surface in the spray from said spray head, and replenishing fluid used by drop-by-drop continuous addition of concentrate into the continuously circulating fluid.

Description

2 Sheets- Sheet 1 Filed Feb. 16, 1942.
INVENTOR JOEE??? MBWDIPEIY U Nov. 5, 1946.
J. M. BOUDREAU MEANS AND METHOD OF TREATING SURFACES 2 Sheets- Sheet 2 Filed Feb. 16, 1942 ATTORNEY Patented Nov. 5, 1946 UNITED STATES PATENT OFFICE MEANS AND METHOD OF TREATING SURFACES 7 Claims.
This invention relates to means and method of treating surfaces and more particularly in carrying out the metalizing of electrically non conductive surfaces to render the same conductive and adapted thereby to be electro-plated.
The objects of the invention are to provide an improved means for accomplishing the purpose; to provide such a means which Will be automatic; to apply a reducing agent intermittently with application of a metalizing solution; to apply each in separate chambers; to obtain an even distribution of reducing agent and of metaliaing solution upon the article to be metalized; to apply the reducing agent and metalizing solution both in fluid form; to apply said fluids to the entire surface of the article; to provide for intermittent advance of the article from station to station and introduction into the fluid at each station; to provide for a plurality of fluid applying chambers and means for lifting the same simultaneously to several pieces of work; to improve upon previous methods of metalizing surfaces; to secure simplicity of construction, method and operation; and to obtain other advantages and results as may be brought out in the following description.
Referring to the accompanying drawings in which like numerals of reference indicate similar parts throughout the several Views:
Figure 1 is a sectional View, partly in elevation, of one of the units of my improved means for treating surfaces;
Figure 2 is a plan thereof;
Figure 3 is an assembly illustrating a bank of units and article conveying and operating means employed in carrying out the method of my invention;
Figure 4 is a sectional view on line IV-IV of Figure 1; and
Figure 5 is a sectional View of amodified form of spray-head mounted in place in the spray chamber.
In the specific embodiment of the invention illustrated in said drawings, the reference numeral l designates a fluid-applying unit, which, for certain conveniences of use, is shown herein as comprising two chambers, one of which, H,
is above the other, l2, with the upper one draining into the lower one. The lower one in turn drains into a fluid pump 13, outlet pipe [4 of which conveys the fluid back to the upper chamber l I. The fluid is accordingly in continuous circulation in the unit.
While subjectto change as desired, the several parts comprising the unit as shown may have the following detail structure. The upper chamber I I is of generally cylindrical shape with an upper flaring peripheral splash collar or apron l and a bottom funnel-like outlet 16, terminating in an outlet nipple I1. "The lower chamber 12 is shown with an upwardly directed entry socket l8 receiving said outlet nipple ll of the upper chamber II. This lower chamber I2 is likewise preferablyfunnel-shape at its bottom leading to a .nipple l9 threaded or otherwise applied to the intake pipe 20 of the pump l3. That pump is of the usual centrifugal type. The outlet pipe I4 is preferably of glass and attached to the pump by a union H. The upper end of said pipe it meanother union 22 hereondetachably connecting with a spray head in the upper chamber l i Spray head 23 shown in Figures 1 and 2 preferably comprises a body in the form of a ring of pipe, the outer diameter of the ring being substantially the inside dimension of the chamber so the ring may be situated Within the chamber horizontally neXt the upper part thereof. The ring of pipe constituting the body of said spray head is provided with suitable perforations 24 directed inwardly and slightly downward to obtain a cross spray of fluid in the chamber, such that an article introduced into the chamber from above through the ring will be thoroughly sprayed over its entire outer surface. A lateral pipe 25 from the ring connects with said union 22 enabling the spray head to be removedreadily and another substituted.
An alternative spray-head 23 is shown in Figure 5, the same comprising a nozzle-like body in this instance having the connecting pipe 25' applied at the bottom of the nozzle and extending to the side of the chamberand then upwardly to and laterally at the top of the chamber for connecting with said union 22. Perforations 24' in the upper part of the nozzle of which some are directed outwardly-upward, enable the fluid to-spray as a fountain so that insides of articles may be sprayed thereby.
There are preferably a plurality of units Ill arranged successively upon a platform 26, and, as a matter of convenience and economy, the several pumps are mounted upon and driven by a common shaft 2! in turn driven by a single motor 28 on said platform. The platform is arranged to be raised and lowered, the operating means being here illustrated as cams 29 driven through bevel gears 30 from a shaft 3| in turn driven by a motor '32. This same motor-and shaft are geared to synchronously advance a workfeeding conveyor 33. Said conveyor is shown as a continuous sprocket chain on which may be removably hung brackets '34 from which depend hooks-35 as shown to which the pieces of work 36 are hung. The brackets and hooks are applied at intervals corresponding to the spacing of the units so that when one is suspended over a unit,
others will be also over corresponding units. Advancement of theconveyor is with a step by step motion during the interval when the platform is lowered, so that while the conveyor is stationary with the brackets, hooks and Work alined with the units, the platform is raised and lowered thereby introducing the several pieces of work to the sprays of the corresponding units.
The step by step motion of the conveyor may sneeze be accomplished in any suitable manner, and for purposes of. i lu tration gearing somewhat similar to a Geneva movement is shown. Accordingly on a stub shaft 31 carrying driving sprocket 38 for the conveyor chain, is a pinion 35. A rotatable member 40 in a common plane with said pinion has a segmental peripheral portion thereof provided with teeth 4] adapted to mesh periodically with the teeth of the pinion at which time the chain is advanced. When the toothed segment passes the pinion, the remaining part of said member having no teeth rotates without driving the pinion for a predetermined period, This represents the period of rest for-the conveyor. Said member is continuously rotated, as by bevel gear connection with the cam-driving shaft 3| thereby synchronizing operation of the platform and advancement of theconveyor.
In operation, alternate units are supplied with difierent fluid. In the first unit may be used an appropriate fluid for preparing the surface. It
may function in part to wash the surface and to wet it, and preferably is also a reducing agent applied so as to give complete surface coverage thereof on the article. The second unit is intended for spraying of a metalizing fluid of a character, such as a silver compound that will be reduced in place on the work to a metallic status by the action of the reducing agent. An excess of this metalizing fluid adheres to the work and on the next or third step, the spray again consists of reducing agent in part acting ,on the metalizing material and adhering in excess of that then needed to reduce more of the metalizing material again sprayed on the work on thefourth step. Adequate numbers of units may be provided for thus, alternately covering the'workto be sprayed by the reducing agent and metalizing fluid as often'as desired. After desiredthickness of metalizing material has been applied, the work may be removed or otherwise taken to the plating operations performed in usual manner for plating on metal surfaces.
' It is to be particularly noted that the work to be metalized by my improved process may be and preferably is of an electrically non-conductive character. Prior to'introduction to the apparatus here disclosed, said work should be suitably prepared to be receptive of the 'metalizingtreatment. Such preparation, in part governed by the constituency of the work, may be by sandblasting, chemical cleansing, bufling or otherwise:
Smooth or shiny surfaces are dulled and preferably minutely pitted so as to not only be readily 'wetted by the treating fluids, but to be adherent to the metalizing material.
In order to make the apparatus continuously operative and avoid necessity of draining the fluid periodically, as can be done if desired from drain valves at the bottom of the pump, means is provided to apply fresh concentrate directly to the fluid in use. As shown in Figure 1, an adjustable drip cup is shown on each unit, preferably situated at the top of the lower chamber l2. Concentrate of theparticular fluid for the unit is fed-by the drip cup at a rateadjusted to computed consumption by. the particular work bein treated; The drops of the concentrate become thoroughly mixed with the bulk. of the fluid in the chamber and pump before being sprayed from a as in the apparatus, and I do not wish to be un- .derstood as limiting myself .as set .forth in the following claims, when construed in the light of the prior art.
Having described the invention, I claim:
1. An apparatus for metalizing surfaces comprising an elevating platform, a unit situated on said platform, means for suspending work over said unit, means to elevate the platform and unit and thereby introduce the work into the unit, and mean for spraying the work while situated in said unit.
2. An apparatus for .metalizing surfaces comprising an elevating platform, a plurality of units on said platform, means for suspending work over each of said units and periodioally'advance the work from one position over one unit' to a successive position over another unit, means to elevate the platform and units and thereby introduce the several pieces of work in the several units, and means for spraying the work while situated in said units.
3. A method of metalizing surfaces consisting in suspending a plurality of pieces of work and moving them in unison with a step-by-step motion, simultaneously including the several pieces of work each Within a spray unit individual to the piece of work between the step-by-step motion thereof, and spraying said pieces of work successively in each unit.
4. An apparatus for metalizing surfaces comprising a unit having a chamber having a bottom outlet, means for pumping fluid from the bottom outlet and spraying said fluid within the upper part of said chamber onto work suspended therein, and drcp-by-drop means having entry to the course of travel of the fluid between said bottom outlet and pumping means at a part in said course of travel where the fluid pressure is less than the force of gravity for replenishing by added concentrate the consumed fluid, whereby the concentrate is mixed with the fluid in transition to and before reaching the spray head.
5. A apparatus for metalizing surfaces comprising a unit having an upper chamber having a bottom outlet, a spray head mounted within said chamber in proximity to the top thereof, said unit having a lower chamber the inlet for which is the outlet of the upper chamber, a pump connected for returning fluid from the bottom of said lower chamber to said spray head and as a spray into the upper part of the upper chamber, and drop-by-drop means having entry to the course of travel of the fluid between discharge from the spray and said pump at a part in said course of travel where the fluid pressure is less than the force of gravity for replenishing by added concentrate the consumed fluid, whereby the concentrate is mixed with the fluid in transition to and before reaching the spray head.
6. A method of metalizing surfaces consisting in continuously circulating different spraying fluids, intermittently and successively subjecting the surfaces to the continuous sprays of said fluids, and continuously adding concentrate to the spray fluid as said fluid circulates, and reusing the fluid.
7. A method of metalizing surfaces consisting in continuously circulating a fluid through a spray head and back to source, introducing a surface in the spray from said spray head, and replenishing fluid used by drop-by-drop continuous addition of concentrate into the continuously circulating fluid. 1 a
- JOSEPH M; BOUDREAU.
US431131A 1942-02-16 1942-02-16 Means and method of treating surfaces Expired - Lifetime US2410626A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2800876A (en) * 1953-12-07 1957-07-30 Smith Corp A O Spud fitting coating apparatus
US2873219A (en) * 1954-12-20 1959-02-10 Joseph B Brennan Metal-coated batt and method and apparatus for producing same
US2874072A (en) * 1956-09-17 1959-02-17 Gen Electric Autocatalytic copper plating process and solution
US2889237A (en) * 1955-06-09 1959-06-02 Cleanola Company Apparatus and method for applying coatings
US3027869A (en) * 1957-01-11 1962-04-03 Cleanola Company Spray apparatus for applying coatings
US3864148A (en) * 1971-10-14 1975-02-04 Kuraray Co Process for production of metal-plated fibers

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2800876A (en) * 1953-12-07 1957-07-30 Smith Corp A O Spud fitting coating apparatus
US2873219A (en) * 1954-12-20 1959-02-10 Joseph B Brennan Metal-coated batt and method and apparatus for producing same
US2889237A (en) * 1955-06-09 1959-06-02 Cleanola Company Apparatus and method for applying coatings
US2874072A (en) * 1956-09-17 1959-02-17 Gen Electric Autocatalytic copper plating process and solution
US3027869A (en) * 1957-01-11 1962-04-03 Cleanola Company Spray apparatus for applying coatings
US3864148A (en) * 1971-10-14 1975-02-04 Kuraray Co Process for production of metal-plated fibers

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