US2400003A - Electric contact - Google Patents

Electric contact Download PDF

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Publication number
US2400003A
US2400003A US483334A US48333443A US2400003A US 2400003 A US2400003 A US 2400003A US 483334 A US483334 A US 483334A US 48333443 A US48333443 A US 48333443A US 2400003 A US2400003 A US 2400003A
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United States
Prior art keywords
contact
gold
indium
contacts
silver
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US483334A
Inventor
Franz R Hensel
Kenneth L Emmert
James W Wiggs
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Duracell Inc USA
Original Assignee
PR Mallory and Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by PR Mallory and Co Inc filed Critical PR Mallory and Co Inc
Priority to US483334A priority Critical patent/US2400003A/en
Application granted granted Critical
Publication of US2400003A publication Critical patent/US2400003A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01HELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
    • H01H1/00Contacts
    • H01H1/02Contacts characterised by the material thereof
    • H01H1/04Co-operating contacts of different material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S29/00Metal working
    • Y10S29/022Method or apparatus using indium

Definitions

  • This invention relates to electric contacts and the composition thereof.
  • An object of the invention is to improve electric contacts and contact compositions.
  • the present invention contemplates an electrical contact combination or set in which the positheir properties. Likewise, up to a few percent of tive contact is formed from gold or a gold base alloy containing indium and the negative contact is formed predominately from silver or from silver base alloys. Such contact sets are characterized by high corrosion resistance and can be used in industrial atmospheres without the formation of a tarnish film-thereon which would increase the electrical resistanceof the contacts.
  • the contact combination is useful for such appli cations as pressure exerting welding electrodes and as well as electric make-and-break contacts since such contacts have good tensile and compressive strength as well as a high degree of hardness.
  • the wear resistant properties of the contact render it useful also in high speed relays where the frequency of make and break operations is extremely high.
  • the contacts of the present invention may contain ' Per cent Indium 0.5 to 25 Gold Balance
  • the preferred range of composition is Per cent Indium 0.5 to 8.5
  • the gold used may be either pure gold or one of 20%, and hence are sometimes present in proportions still higher than if the higher carat golds were used in making the compositions.
  • iron group metals particularly nickel or cobalt may be added to the compositions in some cases to further improve platinum or palladium may be present.
  • ingredients which are commonly alloyed with gold, copper and silver may also be present, such as tin, manganese and silicon. In any case the percentage of sold will exceed by weight and the elements other than indium may be presentup to about 30%. Manganese, if present, is used in proportions up to 2% by weight.
  • Examples of electric contact and welding electrode compositions which are suitable are:
  • alloy of this invention may be used for contacts of either polarity they are most useful for the positive contact.
  • compositions or alloys for the negative side. of the contact pair are pure silver and silver alloys, for example cent Palladium or platinum 0.5 to 5 Silver Balance
  • the gold base alloys containing indium can be manufactured by standard procedures such as melting, casting and then rolling or drawing, according to the type of contact or welding electrode tip to be fabricated.
  • the alloys of gold and indium iorm a solid solution up to about 8.5% indium by weight.
  • the solid solubility of indium in gold decreases with temperature and therefore alloys may be'heat treated in order to increase the electrical conductivity or the physical properties.
  • Such a heat treating may consist in quenching from 400 to 700 0., depending upon the composition, and the subsequent aging temperature may vary from 150 to 400 C.
  • the aging time may vary from several minutes up to several hours, depending upon the ageing temperature and weight of the piece.
  • a pair of ctr-operating contacts for D. C. operation comprising a positive contact i formed of a gold-indium alloy cooperating with a negative contact 3 formed of silver or silver alloy.
  • the contacts are mounted on operating arms 2 and l respectively, which are arranged in a relay, switch or similar device to open and close the contacts in order to make and break a D. C. circuit, the positive ter- 1.
  • An electric contact combination wherein the positivecontact is formed of a gold base alloy containing indium and the negative contact is formed of a material from the group comprising pure silver and silver alloys.
  • An electric contact combination wherein the positive contact is formed of a 801d base alloy containing indium, and the negative contact is formed predominantly of silver.

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  • Contacts (AREA)

Description

May 7, 19460 F. R, HENSEL ET AL 2,400,003 IILECTRIC CONTACT Filed April 16, 1945 4 Mam/VF ca/vT/icT z POSIT/VE CONT/{6f Fiahz Z flrzsel Kennel]; Z- Emma) INVENTORS BY 2 Z z i 2 Patent ed May 7, 1946 W. Wiggs, Indianapolis, Ind., a'sslgnors to P.-R. Mallory dt 00., Inc., Indianapolis, Ind., a corporation of Delaware Application April 1c, 1943, Serial No. 483,334
.2 Claims.
This invention relates to electric contacts and the composition thereof.
An object of the invention is to improve electric contacts and contact compositions.
Other objects of the invention will be apparent from the description and claims.
The present invention contemplates an electrical contact combination or set in which the positheir properties. Likewise, up to a few percent of tive contact is formed from gold or a gold base alloy containing indium and the negative contact is formed predominately from silver or from silver base alloys. Such contact sets are characterized by high corrosion resistance and can be used in industrial atmospheres without the formation of a tarnish film-thereon which would increase the electrical resistanceof the contacts. The contact combination is useful for such appli cations as pressure exerting welding electrodes and as well as electric make-and-break contacts since such contacts have good tensile and compressive strength as well as a high degree of hardness.
The wear resistant properties of the contact, along with its other properties render it useful also in high speed relays where the frequency of make and break operations is extremely high.
In the drawing the figure shows a pair of cooperating contacts embodying features of the present invention. a
The contacts of the present invention may contain ' Per cent Indium 0.5 to 25 Gold Balance The preferred range of composition is Per cent Indium 0.5 to 8.5
Gold Balance The gold used may be either pure gold or one of 20%, and hence are sometimes present in proportions still higher than if the higher carat golds were used in making the compositions.
Up ,to a few percent of iron group metals, particularly nickel or cobalt may be added to the compositions in some cases to further improve platinum or palladium may be present.
Other ingredients which are commonly alloyed with gold, copper and silver may also be present, such as tin, manganese and silicon. In any case the percentage of sold will exceed by weight and the elements other than indium may be presentup to about 30%. Manganese, if present, is used in proportions up to 2% by weight.
Examples of electric contact and welding electrode compositions which are suitable are:
l (a) Indium -3 g? Gold 97.5 (b) Indium 5 Gold..- 95 (c) Indium '8 Gold- 92 (a) Indium 5 Gold '71 Silver 24 (e) Indium 5 G Silver 12.5 Copper 12.5 (,f') Indium 5 Gold "70 Copper 25 (g) Indium 8 Gold 69 Copper 3 Nickel 15 Zinc 5 One of the problems encountered in make-andbreak contacts is the tendency of material to transfer from the face of one contact to the other contact and thereby build up a projection on the second contact leaving a pitted or eroded area on the first contact. The contact compositions of the present invention are remarkably free of such tendency to transfer in both A. C. and D. C. circuits where either one or both contacts is formed of this material.
While the alloy of this invention may be used for contacts of either polarity they are most useful for the positive contact.
Suitable compositions or alloys for the negative side. of the contact pair are pure silver and silver alloys, for example cent Palladium or platinum 0.5 to 5 Silver Balance The gold base alloys containing indium can be manufactured by standard procedures such as melting, casting and then rolling or drawing, according to the type of contact or welding electrode tip to be fabricated.
The alloys of gold and indium iorm a solid solution up to about 8.5% indium by weight. The solid solubility of indium in gold decreases with temperature and therefore alloys may be'heat treated in order to increase the electrical conductivity or the physical properties. Such a heat treating may consist in quenching from 400 to 700 0., depending upon the composition, and the subsequent aging temperature may vary from 150 to 400 C. The aging time may vary from several minutes up to several hours, depending upon the ageing temperature and weight of the piece.
Referring to the drawing a pair of ctr-operating contacts for D. C. operation are shown comprising a positive contact i formed of a gold-indium alloy cooperating with a negative contact 3 formed of silver or silver alloy. The contacts are mounted on operating arms 2 and l respectively, which are arranged in a relay, switch or similar device to open and close the contacts in order to make and break a D. C. circuit, the positive ter- 1. An electric contact combination wherein the positivecontact is formed of a gold base alloy containing indium and the negative contact is formed of a material from the group comprising pure silver and silver alloys.
2. An electric contact combination wherein the positive contact is formed of a 801d base alloy containing indium, and the negative contact is formed predominantly of silver.
FRANZ R. HENSEL.
H L. WT. JAMES W. WIGGS.
US483334A 1943-04-16 1943-04-16 Electric contact Expired - Lifetime US2400003A (en)

Priority Applications (1)

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Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2456979A (en) * 1945-01-19 1948-12-21 Gen Electric Speed governor
US2526455A (en) * 1947-08-30 1950-10-17 Lionel Corp Relay
US2596454A (en) * 1949-09-10 1952-05-13 Metals & Controls Corp Gold alloys
US2675447A (en) * 1950-10-05 1954-04-13 Toastswell Company Inc Switch and circuit structure for electric heaters
US2793273A (en) * 1954-04-20 1957-05-21 Baker & Co Inc Electrical contact elements
US2813790A (en) * 1953-01-27 1957-11-19 Western Gold & Platinum Compan Gold-copper-indium brazing alloy
US2942068A (en) * 1955-01-19 1960-06-21 Itt Coordinate switching unit
US3002074A (en) * 1959-06-08 1961-09-26 Daystrom Inc Relay contact system
US3076253A (en) * 1955-03-10 1963-02-05 Texas Instruments Inc Materials for and methods of manufacturing semiconductor devices
US3519416A (en) * 1968-01-05 1970-07-07 Western Gold & Platinum Co Quaternary brazing alloy composition
US3661569A (en) * 1969-06-19 1972-05-09 Battelle Memorial Institute Low energy contacts
US4069370A (en) * 1975-09-13 1978-01-17 W. C. Heraeus Gmbh Electrical contact material, and terminal
US4339644A (en) * 1979-10-08 1982-07-13 W. C. Heraeus Gmbh Low-power electric contact
US4378479A (en) * 1977-02-22 1983-03-29 Siemens Aktiengesellschaft Permanent current switch for short circuiting a superconducting magnet
US4385029A (en) * 1981-04-27 1983-05-24 The United States Of America As Represented By The Secretary Of The Navy Gold based compounds for electrical contact materials

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2456979A (en) * 1945-01-19 1948-12-21 Gen Electric Speed governor
US2526455A (en) * 1947-08-30 1950-10-17 Lionel Corp Relay
US2596454A (en) * 1949-09-10 1952-05-13 Metals & Controls Corp Gold alloys
US2675447A (en) * 1950-10-05 1954-04-13 Toastswell Company Inc Switch and circuit structure for electric heaters
US2813790A (en) * 1953-01-27 1957-11-19 Western Gold & Platinum Compan Gold-copper-indium brazing alloy
US2793273A (en) * 1954-04-20 1957-05-21 Baker & Co Inc Electrical contact elements
US2942068A (en) * 1955-01-19 1960-06-21 Itt Coordinate switching unit
US3076253A (en) * 1955-03-10 1963-02-05 Texas Instruments Inc Materials for and methods of manufacturing semiconductor devices
US3002074A (en) * 1959-06-08 1961-09-26 Daystrom Inc Relay contact system
US3519416A (en) * 1968-01-05 1970-07-07 Western Gold & Platinum Co Quaternary brazing alloy composition
US3661569A (en) * 1969-06-19 1972-05-09 Battelle Memorial Institute Low energy contacts
US4069370A (en) * 1975-09-13 1978-01-17 W. C. Heraeus Gmbh Electrical contact material, and terminal
US4378479A (en) * 1977-02-22 1983-03-29 Siemens Aktiengesellschaft Permanent current switch for short circuiting a superconducting magnet
US4339644A (en) * 1979-10-08 1982-07-13 W. C. Heraeus Gmbh Low-power electric contact
US4385029A (en) * 1981-04-27 1983-05-24 The United States Of America As Represented By The Secretary Of The Navy Gold based compounds for electrical contact materials

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