US2180827A

US2180827A - Electric contacting element

Info

Publication number: US2180827A
Application number: US277076A
Authority: US
Inventors: Franz R Hensel; Kenneth L Emmert
Original assignee: PR Mallory and Co Inc
Current assignee: Duracell Inc USA
Priority date: 1939-06-02
Filing date: 1939-06-02
Publication date: 1939-11-21
Anticipated expiration: 1956-11-21

Description

Patented Nov. 21, 1939 ELECTRIC CONTACTING ELEMENT Franz R. Reuse] and Kenneth L. Emmert, In-

dianapolis, Ind., assignors to P. R. Mallory & 00., Inc., Indianapolis, Ind, a corporation of Delaware No Drawing. Application June 2, 1939, Serial No. 277,076

Claims. (Cl. 200 -1166) This invention relates to alloys and metal compositions and is concerned more particularly with alloys which have improved physical and electrical characteristics.

5 It is one of the objects of the invention to provide a silver base material which can be used for electrical make and break contacts, retaining very low contact resistance, having negligible material transfer, and having great resistanceunder severe electrical loads, to welding and stick ing.

Another object of the invention is to provide a new silver base alloy which has increased tensile properties and which shows a high resistance to tarnishing and corrosion.

Other objects of the invention will be apparent from the following description, taken in connection with the appended claims.

While a preferred embodiment of the invention is described herein, it is contemplated that a considerable variation may be made in the method of procedure and the combination of elements without departing from the spirit of the invention.

The present invention contemplates a composition which is basically silver, to which has been added magnesium and zinc. In the formation of the new alloy, it is preferable to provide a composition of the materials specified in the following proportions:

Silver Substantially the balance The preferred range of magnesium is .1 to 8%,

because up to that percentage, the magnesium is taken up in alpha solid solution in silver and We have found that silver and magnesium, up to 8%, can be alloyed very readily, and the cast ingots can be rolled, swaged or drawn into desirable shapes, such as sheet, bar stock, wire, strip and the like. Silver and zinc form a solid solution up to approximately 25%.

The class of alloys described in the present invention are ternary solid solutions of magnesiumzinc-silver, except in the case of the high magnesium percentages where a duplex structure will exist. We have investigated a series of compositions and have found that the following alloys,

which are given by way of example only, have shown very excellent results when used for electrical contacts:

The ingredients in the proportions named above, or other suitable proportions falling with- 20 in the broad specifications of this patent, may be melted together by conventional methods and poured into suitable molds.

It was found desirable to add the magnesium in the form of a silver-magnesium master alloy 25 of high magnesium concentration. Alloys of this type have a lower melting point, and therefore will go readily into the silver melt. Since silvermagnesium has a tendency to oxidize and form a dross, it has been found desirable to melt such 30 alloys either in a reducing or neutral atmosphere,

or to use suitable fluxes which cover the melt.

The addition of magnesium in the form of a master alloy has also reduced the loss of magnesium and therefore has made it possible to 35 hold closer tolerances in chemical composition. The resultant alloys have improved physical properties, particularly the alloys with a higher magnesium content. It was found that by raising the magnesium content up to about 10%, a 4 tensile strength could be reached which exceeded 60,000 p. s. i., with elongation values in excess of 30%. The amount of zinc used in these alloys was in the neighborhood of 2 to 10%.

.[t was possible with an alloy containing 3% 45 zinc and 3% magnesium, to obtain a Brinell hardness of after cold swaging. At the same time, the tensile properties were raised similarly. The electrical conductivity of alloys of such compositions are in the neighborhood of 5 20% I. A. C. S. Tests were made to study the tarnish resistance of these materials. These tests were carried out by passing hydrogen sulphide of various concentrations into a bell jar in which the samples of the alloys were suspend- 5g magnesium retained considerable strength even, 'after complete annealing. The tensile strength. of alloys containing '2 to magnesium and 3];

to zinc, exceeding values of 35,000 to 40,000

' p. s. i. tensile strength, and at the same time the elongation of the materials, was very high.

The alloys of the class described have shown very excellent qualities when used for electrical contact purposes. A comparison test was conducted, wherein contacts of similar physical dimensions were tested on a resistive inductive circuit at 470 cycles per minute, and wherein the current flowing in the circuit was increased periodically to obtain the definite current values of alloys in the nature described above, in comparison with contact materials produced in the prior art. The amount of material transfer from one contact to another was used as the prime method of comparison.

An-alloy was tested containing 3% zinc and 3% magnesium under these conditions, and it was found that the limiting current of this material was 15 amps. as compared with 12 amps. for fine silver or coin-silver, and the material transfer was .005 as compared with .010 to .012 for fine and coin silver.

The final contact resistance of these new alloys, the scope of the compositions of which are given above, did not substantially exceed the values obtained for fine silver under identical test conditions.

We have further found that the wear resistance of our alloys may be increased by adding small amounts of ,such elements as copper, nickel, cobalt, iron or manganese. Such additions raise the softening point of the alloys and have no appreciable detrimental electrical effects.

The improved alloys described in the present invention have been found useful for a large number of electrical contact applications, such as, for instance, sensitive direct current relays, overload cut-outs, voltage regulators, indicatin and recording guagers, thermostatic controls and the like. Our improved alloy is also very useful for applications which must operate in sulphurous atmospheres, such as railway signal equipment, telegraph apparatus, circuit breakers in smelting plants and chemical factories, etc. I

We have also found that alloys of the compositions covered by the present invention are very suitable for use in differential contact combinations. Such combinations have the advantages of obtaining very low contact resistance, negligible transfer and great resistance to welding or sticking .under heavy current loads and high operation frequencies. We have also found it advisable to add alloys of the compositions described, to refractory metals or mixtures, such as metals taken from the tungsten and molybde- -num group, and their compounds, such as car- ;bides, nitrides and borides, and the metals of the group nickel, iron and cobalt. Instead of making metal compositions in which fine silver is added to such refractory bases, we have found that superior performance can be obtained by using our improved alloy for bonding the pressed or pressed and sintered refractory material. The final composition of mixtures which we have under consideration may be for instance, tungsten, 2% magnesium, 5% zinc, balance silver; or, 40% nickel, 2% magnesium, 7% zinc, balance silver.

The alloys of the present invention also have a commercial advantage, because the addition of magnesium in the percentages contemplated, provides a material of low specific gravity and therefore it is possible, with such low tensile alloys, to produce a large number of contacts per unit weight of material.

While the present invention as to its objects and advantages has been described herein as carried out in specific embodiments thereof, it is not desired to be limited thereby, but it is intended to cover the invention broadly, within the spirit and scope of the appended claims.

What is claimed is: a

1. An electric contact formed of an alloy composed of .05 to 15% magnesium, .5 to 25% zinc, and the balance substantially all silver.

2. An electric contact formed of an alloy composed of .05 to 8% magnesium, .5 to 25% zinc, and the balance substantially all silver.

3. An electric contact formed of an alloy composed of 1 to 4% magnesium, .5 to 25% zinc, and the balance substantially all silver.

4. An electric contact formed of a metal composition of particles of refractory material selected from the group consisting of tungsten and molybdenum and their compounds interspersed and bonded with an alloy of .05 to 15% magnesium, .5 to 25% zinc and the balance substantially all silver. I

5. An electric contact formed of a metal composition of metal selected from the group consisting of nickel, cobalt and iron in finely divided state interspersed and bonded with an alloy of .05 to 15% magnesium, .5 to 25% zinc and the balance substantially all silver.

FRANZ R. HENSEL. KENNETH L. EMMERT.