US2241262A - Electrical contact - Google Patents

Electrical contact Download PDF

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Publication number
US2241262A
US2241262A US301314A US30131439A US2241262A US 2241262 A US2241262 A US 2241262A US 301314 A US301314 A US 301314A US 30131439 A US30131439 A US 30131439A US 2241262 A US2241262 A US 2241262A
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United States
Prior art keywords
silver
contacts
ruthenium
electrical contact
metals
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Expired - Lifetime
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US301314A
Inventor
Keitel Christian William
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Baker and Co Inc
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Baker and Co Inc
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Priority to US301314A priority Critical patent/US2241262A/en
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Publication of US2241262A publication Critical patent/US2241262A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01HELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
    • H01H1/00Contacts
    • H01H1/02Contacts characterised by the material thereof
    • H01H1/021Composite material
    • H01H1/023Composite material having a noble metal as the basic material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/922Static electricity metal bleed-off metallic stock
    • Y10S428/9265Special properties
    • Y10S428/929Electrical contact feature
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12771Transition metal-base component
    • Y10T428/12861Group VIII or IB metal-base component
    • Y10T428/12875Platinum group metal-base component
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10TTECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00Stock material or miscellaneous articles
    • Y10T428/12All metal or with adjacent metals
    • Y10T428/12493Composite; i.e., plural, adjacent, spatially distinct metal components [e.g., layers, joint, etc.]
    • Y10T428/12771Transition metal-base component
    • Y10T428/12861Group VIII or IB metal-base component
    • Y10T428/12896Ag-base component

Definitions

  • This invention relates to electrical contact elements suitable for use in making and breaking of electric current, and is directed primarily to the improvement of electrical contacts consisting of silver and silver alloys.
  • Electrical contacts should have high current carrying capacity and low surface contact resistance. They should be resistant to oxidation and have great mechanical strength. In operation they should be subject to as little metal transfer as possible so as to avoid pitting and sticking. High melting point also is desirable as it decreases the deleterious consequences of arcing.
  • -Electrical contacts are usually manufactured of platinum, alloys of platinum, tungsten or silver. Of these metals, fine silver has found the widest use, as it is relatively cheap, has excellent current carrying capacity and does not oxidize easily. Silver contacts, however, are subject to the disadvantage that their contact resistance may increase in use, for instance in the presence of sulphurous gases and that they tend to stick particularly when the current used is too high. Furthermore, such contacts are deficient in hardness.
  • a prime object of my invention is to provide a novel and improved electrical contact element that shall be hard, shall have high current carrying capacity, low surface contact resistance. high melting point, resistance to oxidation, 8. minimum tendency to pitting and sticking and great mechanical strength.
  • refractory metals of the platinum group comprising the metals ruthenium, rhodium, iridium and osmium, particularly ruthenium.
  • These metals do not form completely homogeneous solid solutions with silver and for this reason contacts of silver combined with such metals can be provided by melting only when small percentages of the refractory metals above mentioned'are incorporated, such as up to about 10%.
  • Contacts of silver combined with large percentages of ruthenium or other refractory platinum group metals therefore, are manufactured by powder metallurgical methods.
  • Electrical contacts according to my invention may comprise small amounts of. one or more of the refractory platinum group metals, for instance ruthenium, either alone or in combination with another one or more of such metals as rhodium, osmium and iridium, in amounts up to 10% or 15%, or they may contain larger amounts of such metals, for instance up to over In all cases the crystal structure of the alloys is finer than that of pure silver.
  • the refractory platinum group metal content is high, such as 90% or the construction material for my contacts is of course produced by powder metallurgical methods, the silver serving essentially as a binder for the refractory platinum group metal or metals particles.
  • Electrical contacts according to my invention have a great variety of useful applications. They have high current carrying capacity and low surface contact resistance. They have greater hardness, greater mechanical strength, and higher melting point than silver contacts, and have been found to resist deformation and sticking to a considerable degree.
  • My invention is equally applicable to electrical contacts of palladium or alloys of silver such as alloys of silver and palladium.
  • electrical contacts of an alloy of palladium and silver in equal amounts theaddition of for instance l% ruthenium increases the Rockwell B. hardness from 44 to 62 when cast, from 93 to 95 when hard, and from 51 to 63 when annealed at 800 C. for 30 minutes.
  • Tungsten contacts have thus been backed by copper in United States Patent No. 1,089,907, by steel or iron in United States Patent No. 1,181,742, or by nickel and nickel alloys in United States Patent No. 1,155,- 426; precious metal contacts have similarly been backed by less expensive metals, such as silver or platinum contacts backed by copper in German Patent No. 203,904, gold or platinum contacts backed by nickel or steel as in United States Patent No. 1,469,043, or silver contacts backed by Monel or stainless steel as for instance described in United States Patent No.
  • my electrical contacts may also be manufactured from composite metal so that the efiective contact surface consists of the alloys described by me and backed, in accordance with old well-known practice, by another dissimilar metal, such as nickel, Monel, iron, steel, stainless steel, and so forth.
  • Figure 1 is a fragmentary side elevational view of a thermostatic switch having one form of contact element attached thereto, and
  • FIG. 2 is a perspective View of another type of contact element embodying my invention.
  • the contact element l is shown as having its shank riveted or otherwise suitably secured to a bimetallic thermostatic strip 2.
  • the contact element as comprising a base or backing 3 of a base metal or base metal alloy, and a facing disc or contact surface 4 formed of the alloy of my invention.
  • the facing disc 4 may be secured to the backing or body 3 in any suitable manner as by welding or soldering.
  • An electrical contact element formed of a metal taken from the group comprising silver and palladium, combined with at least one metal taken from the group comprising ruthenium, rhodium, iridium and osmium.
  • An electrical contact element formed of silver combined with ruthenium.
  • An electrical contact element formed of silver combined with ruthenium, the ruthenium constituting from 0.1% to of the whole and the remainder being silver.
  • An electrical contact element formed of an alloy of silver and ruthenium containing up to 15% ruthenium, the remainder being silver.
  • An electrical contact element formed of silver combined with ruthenium, the ruthenium constituting the major proportion, and the remainder being silver.
  • An electrical contact element formed of an alloy of silver, palladium and ruthenium.
  • An electrical contact element formed of an alloy of silver combined with ruthenium.

Description

y 6, 1941- c. w. KEITEL 2,241,262
ELECTRICAL CONTACT Filed Oct. 26, 1939 QY T BYW J TORNEY Patented May 6, 1941 2,241,262 ELECTRICAL CONTACT Christian William Keitel, East Orange, N. 3., as-
signor to Baker & Company, Inc., Newark, N. 3., a corporation of New Jersey Application October 26, 1939, Serial No. 301,314
7 Claims.
This invention relates to electrical contact elements suitable for use in making and breaking of electric current, and is directed primarily to the improvement of electrical contacts consisting of silver and silver alloys.
Electrical contacts should have high current carrying capacity and low surface contact resistance. They should be resistant to oxidation and have great mechanical strength. In operation they should be subject to as little metal transfer as possible so as to avoid pitting and sticking. High melting point also is desirable as it decreases the deleterious consequences of arcing.
-Electrical contacts are usually manufactured of platinum, alloys of platinum, tungsten or silver. Of these metals, fine silver has found the widest use, as it is relatively cheap, has excellent current carrying capacity and does not oxidize easily. Silver contacts, however, are subject to the disadvantage that their contact resistance may increase in use, for instance in the presence of sulphurous gases and that they tend to stick particularly when the current used is too high. Furthermore, such contacts are deficient in hardness.
Various attempts have been made to overcome the disadvantages of silver contact elements by incorporating metal carbides, cadmium, magnesium, gold, palladium, platinum and others, but no thorough success has been obtained by any of such additions. The addition of base metals increases the tendency to build up surface resistance and usually decreases the melting point. The admixture of precious metals is usually benei'lcial, but attempts heretofore made to incorporate precious metals have not succeeded in eliminating the shortcomings of silver contacts to a satisfactory degree.
A prime object of my invention is to provide a novel and improved electrical contact element that shall be hard, shall have high current carrying capacity, low surface contact resistance. high melting point, resistance to oxidation, 8. minimum tendency to pitting and sticking and great mechanical strength.
Other objects are to provide such an electrical contact that shall be free from the objections to the known silver contact elements but shall possess the desirable characteristics of silver contacts; and to obtain other advantages and results as will be brought out by the following description.
I have now found that the properties of silver contacts can be improved considerably by the incorporation therein of refractory metals of the platinum group, comprising the metals ruthenium, rhodium, iridium and osmium, particularly ruthenium. These metals do not form completely homogeneous solid solutions with silver and for this reason contacts of silver combined with such metals can be provided by melting only when small percentages of the refractory metals above mentioned'are incorporated, such as up to about 10%. Contacts of silver combined with large percentages of ruthenium or other refractory platinum group metals, therefore, are manufactured by powder metallurgical methods.
The admixture of even small amounts of such refractory metals, for instance, 0.5% ruthenium, has been found to increasethe hardness and 'melting point of silver contacts and to decrease sticking. Electrical contacts according to my invention may comprise small amounts of. one or more of the refractory platinum group metals, for instance ruthenium, either alone or in combination with another one or more of such metals as rhodium, osmium and iridium, in amounts up to 10% or 15%, or they may contain larger amounts of such metals, for instance up to over In all cases the crystal structure of the alloys is finer than that of pure silver. In cases where the refractory platinum group metal content is high, such as 90% or the construction material for my contacts is of course produced by powder metallurgical methods, the silver serving essentially as a binder for the refractory platinum group metal or metals particles.
Electrical contacts according to my invention have a great variety of useful applications. They have high current carrying capacity and low surface contact resistance. They have greater hardness, greater mechanical strength, and higher melting point than silver contacts, and have been found to resist deformation and sticking to a considerable degree.
My invention is equally applicable to electrical contacts of palladium or alloys of silver such as alloys of silver and palladium. In the case of electrical contacts of an alloy of palladium and silver in equal amounts theaddition of for instance l% ruthenium increases the Rockwell B. hardness from 44 to 62 when cast, from 93 to 95 when hard, and from 51 to 63 when annealed at 800 C. for 30 minutes.
The crystal structure of my contacts isfiner, pitting and sticking decreased, and hardness, mechanical strength and melting point are increased. Decrease of crystal size in pronounced degree was observed even with admixtures of as little as 0.1% ruthenium.
Electrical contacts are often manufactured of composite metal in which the contact element itself comprises a thin eifective surface of the electrical contact metal hacked or supported by base metals usually of lower cost than the metal of the electrical contact. Tungsten contacts have thus been backed by copper in United States Patent No. 1,089,907, by steel or iron in United States Patent No. 1,181,742, or by nickel and nickel alloys in United States Patent No. 1,155,- 426; precious metal contacts have similarly been backed by less expensive metals, such as silver or platinum contacts backed by copper in German Patent No. 203,904, gold or platinum contacts backed by nickel or steel as in United States Patent No. 1,469,043, or silver contacts backed by Monel or stainless steel as for instance described in United States Patent No. 1,925,856. It should be understood, therefore, that my electrical contacts may also be manufactured from composite metal so that the efiective contact surface consists of the alloys described by me and backed, in accordance with old well-known practice, by another dissimilar metal, such as nickel, Monel, iron, steel, stainless steel, and so forth.
For the purpose of illustrating possible preferred embodiments of my invention, I have shown two forms of contacts in the accompanying drawing in which Figure 1 is a fragmentary side elevational view of a thermostatic switch having one form of contact element attached thereto, and
Figure 2 is a perspective View of another type of contact element embodying my invention.
As above indicated, my invention may be embodied in various structural forms of electric contact elements for many different types of electrical apparatus, and the specific embodiments herein illustrated should be understood as being only as examples of two possible types of contact elements. a
In Figure 1, the contact element l is shown as having its shank riveted or otherwise suitably secured to a bimetallic thermostatic strip 2.
In Figure 2 I have shown the contact element as comprising a base or backing 3 of a base metal or base metal alloy, and a facing disc or contact surface 4 formed of the alloy of my invention. The facing disc 4 may be secured to the backing or body 3 in any suitable manner as by welding or soldering.
Having thus described my invention, what I claim is:
1. An electrical contact element formed of a metal taken from the group comprising silver and palladium, combined with at least one metal taken from the group comprising ruthenium, rhodium, iridium and osmium.
2. An electrical contact element formed of silver combined with ruthenium.
3. An electrical contact element formed of silver combined with ruthenium, the ruthenium constituting from 0.1% to of the whole and the remainder being silver.
4. An electrical contact element formed of an alloy of silver and ruthenium containing up to 15% ruthenium, the remainder being silver.
5. An electrical contact element formed of silver combined with ruthenium, the ruthenium constituting the major proportion, and the remainder being silver.
6. An electrical contact element formed of an alloy of silver, palladium and ruthenium.
7. An electrical contact element formed of an alloy of silver combined with ruthenium.
CHRISTIAN WILLIAM KEITEL.
US301314A 1939-10-26 1939-10-26 Electrical contact Expired - Lifetime US2241262A (en)

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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2486341A (en) * 1945-06-30 1949-10-25 Baker & Co Inc Electrical contact element containing tin oxide
US2600175A (en) * 1946-09-11 1952-06-10 Metals & Controls Corp Electrical contact
US2786104A (en) * 1952-11-04 1957-03-19 Muirhead & Co Ltd Rotary stud switches
US2789187A (en) * 1953-12-03 1957-04-16 Siemens Ag Electrical contact devices, particularly for high switching frequency and high current loading
US2812406A (en) * 1954-03-02 1957-11-05 Bell Telephone Labor Inc Electrical contact
US2928915A (en) * 1955-06-11 1960-03-15 Vigren Sten Daniel Arrangement in polarized relays
US2931876A (en) * 1957-04-17 1960-04-05 Mc Graw Edison Co Electric contact
US3311729A (en) * 1965-10-04 1967-03-28 Deringer Mfg Company Electrical contact and method of forming the same
US3413584A (en) * 1965-08-30 1968-11-26 Emerson Electric Co Thermoresponsive switch
US3477845A (en) * 1967-01-03 1969-11-11 Mcintyre John W Silver base alloy for making electrical contacts
US3569653A (en) * 1969-01-31 1971-03-09 Engelhard Min & Chem Electrical contact and contact assembly
US4348566A (en) * 1979-03-29 1982-09-07 Fujitsu Limited Rhodium electrical contact of a switch particularly a reed switch
EP0145924A2 (en) * 1983-12-14 1985-06-26 Degussa Aktiengesellschaft Material for low-current contacts
US4574014A (en) * 1983-09-29 1986-03-04 G. Rau Gmbh & Co. Process for manufacturing a formed contact part

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2486341A (en) * 1945-06-30 1949-10-25 Baker & Co Inc Electrical contact element containing tin oxide
US2600175A (en) * 1946-09-11 1952-06-10 Metals & Controls Corp Electrical contact
US2786104A (en) * 1952-11-04 1957-03-19 Muirhead & Co Ltd Rotary stud switches
US2789187A (en) * 1953-12-03 1957-04-16 Siemens Ag Electrical contact devices, particularly for high switching frequency and high current loading
US2812406A (en) * 1954-03-02 1957-11-05 Bell Telephone Labor Inc Electrical contact
US2928915A (en) * 1955-06-11 1960-03-15 Vigren Sten Daniel Arrangement in polarized relays
US2931876A (en) * 1957-04-17 1960-04-05 Mc Graw Edison Co Electric contact
US3413584A (en) * 1965-08-30 1968-11-26 Emerson Electric Co Thermoresponsive switch
US3311729A (en) * 1965-10-04 1967-03-28 Deringer Mfg Company Electrical contact and method of forming the same
US3477845A (en) * 1967-01-03 1969-11-11 Mcintyre John W Silver base alloy for making electrical contacts
US3569653A (en) * 1969-01-31 1971-03-09 Engelhard Min & Chem Electrical contact and contact assembly
US4348566A (en) * 1979-03-29 1982-09-07 Fujitsu Limited Rhodium electrical contact of a switch particularly a reed switch
US4574014A (en) * 1983-09-29 1986-03-04 G. Rau Gmbh & Co. Process for manufacturing a formed contact part
EP0145924A2 (en) * 1983-12-14 1985-06-26 Degussa Aktiengesellschaft Material for low-current contacts
EP0145924A3 (en) * 1983-12-14 1985-08-07 Degussa Aktiengesellschaft Material for low-current contacts
US4579787A (en) * 1983-12-14 1986-04-01 Degussa Aktiengesellschaft Material for low voltage current contacts

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