US2374214A - Conductive papers - Google Patents

Conductive papers Download PDF

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Publication number
US2374214A
US2374214A US286804A US28680439A US2374214A US 2374214 A US2374214 A US 2374214A US 286804 A US286804 A US 286804A US 28680439 A US28680439 A US 28680439A US 2374214 A US2374214 A US 2374214A
Authority
US
United States
Prior art keywords
paper
conductive
web
conducting
mannitol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US286804A
Other languages
English (en)
Inventor
Bernard L Kline
Curt E Mobius
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Western Union Telegraph Co
Original Assignee
Western Union Telegraph Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to BE460345D priority Critical patent/BE460345A/xx
Application filed by Western Union Telegraph Co filed Critical Western Union Telegraph Co
Priority to US286804A priority patent/US2374214A/en
Priority to GB11634/40A priority patent/GB537770A/en
Priority to DEI3198D priority patent/DE902111C/de
Priority to FR889820D priority patent/FR889820A/fr
Application granted granted Critical
Publication of US2374214A publication Critical patent/US2374214A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B41PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41MPRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00Duplicating or marking methods; Sheet materials for use therein
    • B41M5/20Duplicating or marking methods; Sheet materials for use therein using electric current
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03Non-macromolecular organic compounds
    • D21H17/05Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/14Carboxylic acids; Derivatives thereof
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63Inorganic compounds
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00Processes or apparatus for adding material to the pulp or to the paper
    • D21H23/76Processes or apparatus for adding material to the pulp or to the paper characterised by choice of auxiliary compounds which are added separately from at least one other compound, e.g. to improve the incorporation of the latter or to obtain an enhanced combined effect
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/20Conductive material dispersed in non-conductive organic material
    • H01B1/22Conductive material dispersed in non-conductive organic material the conductive material comprising metals or alloys
    • HELECTRICITY
    • H04ELECTRIC COMMUNICATION TECHNIQUE
    • H04LTRANSMISSION OF DIGITAL INFORMATION, e.g. TELEGRAPHIC COMMUNICATION
    • H04L13/00Details of the apparatus or circuits covered by groups H04L15/00 or H04L17/00
    • H04L13/02Details not particular to receiver or transmitter
    • H04L13/06Tape or page guiding or feeding devices
    • HELECTRICITY
    • H04ELECTRIC COMMUNICATION TECHNIQUE
    • H04NPICTORIAL COMMUNICATION, e.g. TELEVISION
    • H04N1/00Scanning, transmission or reproduction of documents or the like, e.g. facsimile transmission; Details thereof
    • H04N1/23Reproducing arrangements
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/03Non-macromolecular organic compounds
    • D21H17/05Non-macromolecular organic compounds containing elements other than carbon and hydrogen only
    • D21H17/06Alcohols; Phenols; Ethers; Aldehydes; Ketones; Acetals; Ketals
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63Inorganic compounds
    • D21H17/67Water-insoluble compounds, e.g. fillers, pigments
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H17/00Non-fibrous material added to the pulp, characterised by its constitution; Paper-impregnating material characterised by its constitution
    • D21H17/63Inorganic compounds
    • D21H17/67Water-insoluble compounds, e.g. fillers, pigments
    • D21H17/69Water-insoluble compounds, e.g. fillers, pigments modified, e.g. by association with other compositions prior to incorporation in the pulp or paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H21/00Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties
    • D21H21/14Non-fibrous material added to the pulp, characterised by its function, form or properties; Paper-impregnating or coating material, characterised by its function, form or properties characterised by function or properties in or on the paper
    • DTEXTILES; PAPER
    • D21PAPER-MAKING; PRODUCTION OF CELLULOSE
    • D21HPULP COMPOSITIONS; PREPARATION THEREOF NOT COVERED BY SUBCLASSES D21C OR D21D; IMPREGNATING OR COATING OF PAPER; TREATMENT OF FINISHED PAPER NOT COVERED BY CLASS B31 OR SUBCLASS D21G; PAPER NOT OTHERWISE PROVIDED FOR
    • D21H23/00Processes or apparatus for adding material to the pulp or to the paper
    • D21H23/02Processes or apparatus for adding material to the pulp or to the paper characterised by the manner in which substances are added

Definitions

  • the present invention relates generally to a novel conducting paper, and more particularly to a light colored conducting paper and the method of rendering the fibrous structure of the paper electrically conductive.
  • the principal object of this invention is to produce a novel light colored recording paper suitable for use without preparation or treatment supplementary to the recording rocess.
  • Another object of this invention is to produce a metal bearing recording paper which is electrically conductive.
  • a still further object of this invention is to provide a paper containing aluminum powder and suitable for electrical recording.
  • a still further object of this invention is to provide a method of rendering a light colored paper containing aluminum prowder electrically conductive.
  • Such material may for example be solid aliphatic and aromatic alcohols, both monohydric and polyhydric, Or aldehyde or ketone type materials with or without a dissolved electrolyte.
  • mannitol also known as mannite. This is a hexahydric alcohol and is obtainable in white powder form.
  • a second important material is .diglycol stearate, that is, a stearic acid ester of diethylene glycol, which gives results comparable with those of mannitol'
  • Another material which will serve as aprotecting medium is erythritol, which is a tetrahydric alcohol;
  • erythritol which is a tetrahydric alcohol.
  • Each of the polyhydric alcohols mentioned is a simple polyhydric alcohol.
  • Other materials may be resorcinol, a dihydroxybenzene, which may be considered a phenolic alcohol, monohydric alcohols where there are tenor more atoms of carbon in the molecule, certain sugars such as dextrose, maltose and sucrose and certain hydroxy and dibasic acids such as succinic or malic acid.
  • Higher aldehydes such as paraldol and lactic aldehyde and ketones such as benzophenone are solids and may also be utilized in the same manner.
  • Preferred protective materials are solid polyhydric alcohols and their derivatives; however, related materials and their derivatives, such as aldehydes, ketones, sugars and certain hydroxy acids exhibit the same tendencies. Esters of alcohols such as camauba wax are also suitable.
  • These materials may be melted and mixed with from 30 to of metal powder, such as aluminum, and allowed to cool.
  • metal powder such as aluminum
  • This mixture is found to be electrically conductive and may therefore be incorporated in fibrous sheets I such as paper.
  • Aluminum is cited by way of example only, since it is obvious that other powdered metals may be substituted, such as copper, brass, bronze, iron, zinc, etc.
  • These metallic powders which are obtained in flaky form, such as aluminum, copper, brass, bronze, etc. are preferred due to the greater light reflecting proper-. ties thereof and hence lighter color.
  • any of the mixtures of one of the materials named above and a metal powder may be incorporated into a sheet of paper by first introducin the aluminum or other metal powder into a beater with the paper pulp in the usual manner, and after the web is at least partially dried the mixturemay be impregnated with an aqueous or alcoholic solution of one of the materials named above, preferably diglycol stearate or mannite.
  • the web may be impregnated by running the ierring the vehicle from a roll to the web.
  • glycol stearate and iorm a conducting mixture with the metal powder in the paper.
  • Conductive papers of this nature are usually provided with a color-changing material whereby the passage 01 marking current through the paper produces a color change in accordance with the desired pattern to be reproduced thereon.
  • Materials such as lead thiosulphate, lead thiocyanate or mercuric sulphide may-be put in the beaters with the metallic powder whereby the material becomes an integral part of the fibrous structure of the paper.
  • the coloring material may also be incorporated as a layer external to the web or the paper.
  • a conducting paper comprising a fibrous body containing a mixture of finely divided metal particles and a solid, fusible compound of the class consisting of monohydric alcohols, simple polyhydric alcohols, and sugars, dispersed throughout said fibrous body, said compound pro moting conductive intimacy of said metal particles.
  • a conducting paper comprising a fibrous body containing a mixture of finely divided metal particles and mannitol dispersed throughout said fibrous body, said mannitol promoting conductive intimacy of said metal particles.
  • a conducting paper comprising a fibrous body containing a mixture of finely divided metal particles and erythritol dispersed throughout said fibrous body, said erythritol' promoting conductive intimacy of said metal particles.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Signal Processing (AREA)
  • Dispersion Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Multimedia (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Computer Networks & Wireless Communication (AREA)
  • Paper (AREA)
  • Liquid Developers In Electrophotography (AREA)
  • Electrophotography Using Other Than Carlson'S Method (AREA)
  • Photoreceptors In Electrophotography (AREA)
US286804A 1939-07-27 1939-07-27 Conductive papers Expired - Lifetime US2374214A (en)

Priority Applications (5)

Application Number Priority Date Filing Date Title
BE460345D BE460345A (xx) 1939-07-27
US286804A US2374214A (en) 1939-07-27 1939-07-27 Conductive papers
GB11634/40A GB537770A (en) 1939-07-27 1940-07-12 Conductive paper
DEI3198D DE902111C (de) 1939-07-27 1940-07-27 Aufzeichnungstraeger aus elektrisch leitendem Papier fuer Bildfunk- zwecke u. dgl. und Verfahren zu seiner Herstellung
FR889820D FR889820A (fr) 1939-07-27 1941-03-22 Papier conducteur d'électricité pour appareils télégraphiques et analogues

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US286804A US2374214A (en) 1939-07-27 1939-07-27 Conductive papers

Publications (1)

Publication Number Publication Date
US2374214A true US2374214A (en) 1945-04-24

Family

ID=23100223

Family Applications (1)

Application Number Title Priority Date Filing Date
US286804A Expired - Lifetime US2374214A (en) 1939-07-27 1939-07-27 Conductive papers

Country Status (5)

Country Link
US (1) US2374214A (xx)
BE (1) BE460345A (xx)
DE (1) DE902111C (xx)
FR (1) FR889820A (xx)
GB (1) GB537770A (xx)

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2654170A (en) * 1949-01-17 1953-10-06 Minnesota Mining & Mfg Disintegrable label and washable container labeled therewith
US2662803A (en) * 1949-06-29 1953-12-15 Faximile Inc Recording method and apparatus
US2726179A (en) * 1952-01-07 1955-12-06 Bosch Gmbh Robert Recording tapes having a metal layer applied by vapour deposition
US2870689A (en) * 1952-12-04 1959-01-27 Helen E Brennan Method of producing strip material
US3062700A (en) * 1960-02-11 1962-11-06 Harold R Dalton Static discharging paper
US3132989A (en) * 1961-02-27 1964-05-12 Carrier Corp Thermally conductive paper containing dendritic metal particles
US3351740A (en) * 1962-08-09 1967-11-07 Olympia Werke Ag Punching apparatus
US3493369A (en) * 1964-04-03 1970-02-03 Appleton Coated Paper Co Low electrical resistance varnish coatings on an insulating base
US3874995A (en) * 1971-03-30 1975-04-01 Us Army Method of making aluminized paper
FR2341884A1 (fr) * 1976-02-19 1977-09-16 Mita Industrial Co Ltd Element et procede d'enregistrement electrique
FR2432543A1 (fr) * 1978-08-04 1980-02-29 Western Electric Co Procede pour lier ensemble des elements de circuit avec un conducteur adhesif contenant un agent ameliorant la conductivite et elements de circuit pour la mise en oeuvre du procede
US4806410A (en) * 1986-09-18 1989-02-21 Ranpak Corp. Processes for the production of antistatic or static dissipative paper, and the paper products thus produced, and apparatus utilized
US20090036850A1 (en) * 2007-07-31 2009-02-05 Davis-Dang Nhan Sensor products using conductive webs
US20120055641A1 (en) * 2007-07-31 2012-03-08 Kimberly-Clark Worldwide, Inc. Conductive Webs
US20130264019A1 (en) * 2010-12-15 2013-10-10 Condalign As Method for forming an anisotropic conductive paper and a paper thus formed
WO2022174236A1 (en) * 2021-02-10 2022-08-18 Illinois Tool Works Inc. Sheet assembly for forming one or more cards

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3022213A (en) * 1958-02-13 1962-02-20 Michigan Res Lab Inc Conductive web and method of making same
US2993816A (en) * 1960-03-30 1961-07-25 Du Pont Conducting textryls

Cited By (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2654170A (en) * 1949-01-17 1953-10-06 Minnesota Mining & Mfg Disintegrable label and washable container labeled therewith
US2662803A (en) * 1949-06-29 1953-12-15 Faximile Inc Recording method and apparatus
US2726179A (en) * 1952-01-07 1955-12-06 Bosch Gmbh Robert Recording tapes having a metal layer applied by vapour deposition
US2870689A (en) * 1952-12-04 1959-01-27 Helen E Brennan Method of producing strip material
US3062700A (en) * 1960-02-11 1962-11-06 Harold R Dalton Static discharging paper
US3132989A (en) * 1961-02-27 1964-05-12 Carrier Corp Thermally conductive paper containing dendritic metal particles
US3351740A (en) * 1962-08-09 1967-11-07 Olympia Werke Ag Punching apparatus
US3493369A (en) * 1964-04-03 1970-02-03 Appleton Coated Paper Co Low electrical resistance varnish coatings on an insulating base
US3874995A (en) * 1971-03-30 1975-04-01 Us Army Method of making aluminized paper
FR2341884A1 (fr) * 1976-02-19 1977-09-16 Mita Industrial Co Ltd Element et procede d'enregistrement electrique
FR2432543A1 (fr) * 1978-08-04 1980-02-29 Western Electric Co Procede pour lier ensemble des elements de circuit avec un conducteur adhesif contenant un agent ameliorant la conductivite et elements de circuit pour la mise en oeuvre du procede
US4806410A (en) * 1986-09-18 1989-02-21 Ranpak Corp. Processes for the production of antistatic or static dissipative paper, and the paper products thus produced, and apparatus utilized
US20090036850A1 (en) * 2007-07-31 2009-02-05 Davis-Dang Nhan Sensor products using conductive webs
US20120055641A1 (en) * 2007-07-31 2012-03-08 Kimberly-Clark Worldwide, Inc. Conductive Webs
US8381536B2 (en) * 2007-07-31 2013-02-26 Kimberly-Clark Worldwide, Inc. Conductive webs
US8697934B2 (en) 2007-07-31 2014-04-15 Kimberly-Clark Worldwide, Inc. Sensor products using conductive webs
US20130264019A1 (en) * 2010-12-15 2013-10-10 Condalign As Method for forming an anisotropic conductive paper and a paper thus formed
US9169601B2 (en) * 2010-12-15 2015-10-27 Condalign As Method for forming an anisotropic conductive paper and a paper thus formed
WO2022174236A1 (en) * 2021-02-10 2022-08-18 Illinois Tool Works Inc. Sheet assembly for forming one or more cards

Also Published As

Publication number Publication date
DE902111C (de) 1954-01-18
GB537770A (en) 1941-07-04
FR889820A (fr) 1944-01-20
BE460345A (xx)

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