US2300286A - Electrical contact - Google Patents

Electrical contact Download PDF

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Publication number
US2300286A
US2300286A US392487A US39248741A US2300286A US 2300286 A US2300286 A US 2300286A US 392487 A US392487 A US 392487A US 39248741 A US39248741 A US 39248741A US 2300286 A US2300286 A US 2300286A
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US
United States
Prior art keywords
contact
silver
copper
metals
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
US392487A
Inventor
Jr Childress B Gwyn
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Fansteel Inc
Original Assignee
Fansteel Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Fansteel Inc filed Critical Fansteel Inc
Priority to US392487A priority Critical patent/US2300286A/en
Application granted granted Critical
Publication of US2300286A publication Critical patent/US2300286A/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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Classifications

    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01HELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
    • H01H1/00Contacts
    • H01H1/02Contacts characterised by the material thereof
    • H01H1/04Co-operating contacts of different material
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10STECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S428/00Stock material or miscellaneous articles
    • Y10S428/922Static electricity metal bleed-off metallic stock
    • Y10S428/9265Special properties
    • Y10S428/929Electrical contact feature

Definitions

  • the contacts should'be non-fusing, have a low contact resistance with a relative small contact pressure and be capable of maintaining low resistance in serviceafter a large number of operations.
  • the load may varyfrom purely resistive to purely inductive. It may be a combination of resistance and inductance. It may also include capacitative loads as well.
  • contact combinations for D. C. purposes wherein the contact on the posi- For relay tive side is characterized by the presenceof an appreciable quantity of a platinum group element and the contact on the negative side is made up of a refractory metal such as tungsten in combination with silver and in some cases modifying element.
  • the contacts for the positive side may be formed of alloys in the following
  • the .preferred contact materials for the negative side are' hard alloys of high conductivity characterized by a wear-resisting ingredient such as tungsten, molybdenum or their carbides or borides, plus a conductive ingredient such as silver, copper or alloys made up principally of these elements modified by lesser amounts of other elements such a one of the iron group metals, cadmium, zinc, arsenic or the alkali or alkaliearth metals.
  • the negative contacts may be formed of alloys having their ingredients present in the following range of proportions:
  • compositions for use according to the invention are:
  • a co-operating pair of electric make-and-break contacts one contact being formed of an alloy rich in at least one noble metal and the other contact being made up of a wearresistant constituent selected from the sixth group of the periodic system and a conductive constituent of the class consisting of silver, copper and alloys predominating in these metals.
  • An electric contact combination for D. C. operation the contact on one side of said combination having the composition Per cent At least one metal of the group platin palladium, gold 0-98 At least one metal of the group ruthenium,
  • the contact on the other side being made up of a wear-resistant constituent selected from the sixth group or the periodic system and a conductive constituent of the class consisting of silver, copper and alloys predominating in these metals.
  • An electric contact combination for D. C. operation the contact on one side of said combination being formed of an alloy rich in at least one noble metal and the contact on the other side of said combination having the composition I Percent Tungsten, molybdenum or the carbides thereof 20-80 Silver or copper 15-75 Modifying agent selected from the class consisting of iron, cobalt, nickel, cadmium, zinc, arsenic, the alkali metals and the alkaline earth metals 0-5 contact is made of a platinum group alloy and the other contact is made up of a tungsten group metal, a small amount of a modifying agent for said metal selected from the class consisting of carbon and boron and silver.
  • CHILDRESS B CHILDRESS B; GWYN, JR.

Description

' claims.
, contacts.
Patented Oct. 27, 1942 UNITED STATES PATENT OFFICE,
ELECTRICAL CONTACT Childress B. Gwyn, In, Bannockburn, I lL, assignor to Fansteel Metallurgical Corporation, North Chicago, 111., a corporation of New York No Drawing. Application May 3, 1941,
Serial No. 392,487
6 Claims. (01.200-166) tion of elements, methods of manufacture, and
the product thereof brought out and exemplified in the disclosure hereinafter set forth, the scope of the invention bein indicated in the appended While a preferred embodiment of the invention is described herein, it is contemplated that considerable variation may be made in the method of procedure and the combination of elements without departing from the spirit of the invention.
In voltage regulators or relays the contacts should'be non-fusing, have a low contact resistance with a relative small contact pressure and be capable of maintaining low resistance in serviceafter a large number of operations.
It is of importance in contact applications to consider the type of current load placed upon the This load will normally be through a resistive circuit in voltage regulators. I applications, on the other hand, the load may varyfrom purely resistive to purely inductive. It may be a combination of resistance and inductance. It may also include capacitative loads as well.
It has. been found that contacts in such services as mentioned above frequently fail on account of excessive material transfer. This transfer is a function of the electrical conditions at the time of make or break and it is also dependent upon the materials which are used for the contacts. It is well known that difierent metals and different alloys have widely diflferent characteristics in their ability to withstand transfer.
It is known that the tendency of the contact materials to transfer and of the contacts to fail is also dependent upon the contact polarity. That be difierent from a combination in which the ma- I terials of the positive and negative contacts are reversed. This is apparently dependent upon the characteristics of the different materials in the composition, including such factors as the arcing voltages, ionization potentials, sticking or nonfusing characteristics and the like.
According to the present invention, there is proposed the use of contact combinations for D. C. purposes wherein the contact on the posi- For relay tive side is characterized by the presenceof an appreciable quantity of a platinum group element and the contact on the negative side is made up of a refractory metal such as tungsten in combination with silver and in some cases modifying element.
I have found the most'suitable materials for the positive side to be alloys of a precious metal,
e. g. of the platinum group or gold with or without silver, which may also include small amounts of hardening metals such as the metals of the iron group or copper.
For most applications the contacts for the positive side may be formed of alloys in the following The .preferred contact materials for the negative side are' hard alloys of high conductivity characterized by a wear-resisting ingredient such as tungsten, molybdenum or their carbides or borides, plus a conductive ingredient such as silver, copper or alloys made up principally of these elements modified by lesser amounts of other elements such a one of the iron group metals, cadmium, zinc, arsenic or the alkali or alkaliearth metals.
For most uses the negative contacts may be formed of alloys having their ingredients present in the following range of proportions:
Tungsten, molybdenum or the carbides thereof- 20-80 Silver or copper -15 Modifying element 0-5 Examples of preferred compositions for use according to the invention are:
Positive side:
Per cent 1 range of compositions: I
' Per cent Platinum and/or palladium and/or gold" 0-98 Other metals of the platinum group 0-15 Silver 0-50, Iron group or copper 0-5 nickel, copper -5 Negative side:
a. Molybdenum 35 Tungsten carbide 25 Silver 20 Copper 20 b. Molybdenum 64 Silver- 35 Nickel 1 c, Tungsten 75 Copper 24 Cobalt 1 d. Tungsten carbide -l- 75 Silver 24.6 Copper 0.4
e. Tungsten Silver 45 Cadmium 5 In comparison tests of various of the preferred combinations of the present invention with other contact combinations, it has been found that combinations selected according to the invention operate for periods of the order of 300 to 5,000 hours which is far in excess of known previous combinations.
While the present invention as to its objects and advantages has been described here as carried out in specific embodiments thereof, it is not desired to be limited thereby but it is intended to cover the invention as broadly as the spirit and scope of the appended claims permit.
What is claimed is:
1. In combination a co-operating pair of electric make-and-break contacts, one contact being formed of an alloy rich in at least one noble metal and the other contact being made up of a wearresistant constituent selected from the sixth group of the periodic system and a conductive constituent of the class consisting of silver, copper and alloys predominating in these metals.
2. An electric contact combination for D. C. operation the contact on one side of said combination having the composition Per cent At least one metal of the group platin palladium, gold 0-98 At least one metal of the group ruthenium,
rhodium, osmium, iridium 0-15 Silver 0-50 At least one metal of the group iron cobalt,
and the contact on the other side being made up of a wear-resistant constituent selected from the sixth group or the periodic system and a conductive constituent of the class consisting of silver, copper and alloys predominating in these metals.
3. An electric contact combination for D. C. operation, the contact on one side of said combination being formed of an alloy rich in at least one noble metal and the contact on the other side of said combination having the composition I Percent Tungsten, molybdenum or the carbides thereof 20-80 Silver or copper 15-75 Modifying agent selected from the class consisting of iron, cobalt, nickel, cadmium, zinc, arsenic, the alkali metals and the alkaline earth metals 0-5 contact is made of a platinum group alloy and the other contact is made up of a tungsten group metal, a small amount of a modifying agent for said metal selected from the class consisting of carbon and boron and silver.
CHILDRESS B; GWYN, JR.
US392487A 1941-05-08 1941-05-08 Electrical contact Expired - Lifetime US2300286A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
US392487A US2300286A (en) 1941-05-08 1941-05-08 Electrical contact

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US392487A US2300286A (en) 1941-05-08 1941-05-08 Electrical contact

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Cited By (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2434305A (en) * 1943-10-12 1948-01-13 Int Nickel Co Electric contact
US2464591A (en) * 1944-04-04 1949-03-15 Mallory & Co Inc P R Method of bonding a tungsten member to a backing member
US2787688A (en) * 1951-07-10 1957-04-02 North Electric Co Contact material
US2793273A (en) * 1954-04-20 1957-05-21 Baker & Co Inc Electrical contact elements
US2806786A (en) * 1954-05-14 1957-09-17 Gen Electric Method of making sintered electrical contact material
US2812406A (en) * 1954-03-02 1957-11-05 Bell Telephone Labor Inc Electrical contact
US2815421A (en) * 1956-09-21 1957-12-03 Metals & Controls Corp Electrical contacts
US2821584A (en) * 1954-04-08 1958-01-28 Mycalex Electronics Corp Rotary switching device and contact elements therefor
US2978314A (en) * 1956-03-05 1961-04-04 Fairchild Camera Instr Co Compositions for electrical resistance films
US3065571A (en) * 1957-10-10 1962-11-27 Engelhard Ind Inc Composite material of platinum alloy and glass
US3134671A (en) * 1961-05-18 1964-05-26 Nobilium Products Inc Noble metals alloy containing gallium
US3155467A (en) * 1961-08-04 1964-11-03 Nippon Junsuiso Kabushiki Kais Palladium alloy permeable wall for the separation and purification of hydrogen
US3158469A (en) * 1962-08-08 1964-11-24 Stackpole Carbon Co Electrical contact
US3225169A (en) * 1964-02-24 1965-12-21 Stackpole Carbon Co Silver-refractory metal electrical contact having refractory metal carbide in the marginal layer of its active contact face
US3301641A (en) * 1964-01-27 1967-01-31 Mallory & Co Inc P R Tungsten-ruthenium alloy and powdermetallurgical method of making
US3310718A (en) * 1964-04-07 1967-03-21 Nytronics Inc Impedance element with alloy connector
US3411900A (en) * 1966-04-13 1968-11-19 North American Rockwell Brazing alloy composition
US3463636A (en) * 1967-01-03 1969-08-26 Trw Inc Constant conductivity alloys
US3499740A (en) * 1965-10-26 1970-03-10 Int Nickel Co Oxidation resistant coated article containing iridium,ruthenium,molybdenum or tungsten
US4081644A (en) * 1972-06-29 1978-03-28 Plessey Handel Investments A.G. Electrical contact material
US4409295A (en) * 1982-01-21 1983-10-11 Olin Corporation Electrical connector material
US4579787A (en) * 1983-12-14 1986-04-01 Degussa Aktiengesellschaft Material for low voltage current contacts
US5227250A (en) * 1991-09-20 1993-07-13 Fifth Dimension Inc. Glass-to-metal seal
US20090218647A1 (en) * 2008-01-23 2009-09-03 Ev Products, Inc. Semiconductor Radiation Detector With Thin Film Platinum Alloyed Electrode
CN102754292A (en) * 2010-02-17 2012-10-24 田中贵金属工业株式会社 Material for ignition plug electrode excellent in durability to spark erosion and discharge characteristics
US20130259736A1 (en) * 2012-03-14 2013-10-03 Victor Dyment Thermoregulatory Interactive Gold Alloys for Therapeutic Jewelry Items

Cited By (28)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2434305A (en) * 1943-10-12 1948-01-13 Int Nickel Co Electric contact
US2464591A (en) * 1944-04-04 1949-03-15 Mallory & Co Inc P R Method of bonding a tungsten member to a backing member
US2787688A (en) * 1951-07-10 1957-04-02 North Electric Co Contact material
US2812406A (en) * 1954-03-02 1957-11-05 Bell Telephone Labor Inc Electrical contact
US2821584A (en) * 1954-04-08 1958-01-28 Mycalex Electronics Corp Rotary switching device and contact elements therefor
US2793273A (en) * 1954-04-20 1957-05-21 Baker & Co Inc Electrical contact elements
US2806786A (en) * 1954-05-14 1957-09-17 Gen Electric Method of making sintered electrical contact material
US2978314A (en) * 1956-03-05 1961-04-04 Fairchild Camera Instr Co Compositions for electrical resistance films
US2815421A (en) * 1956-09-21 1957-12-03 Metals & Controls Corp Electrical contacts
US3065571A (en) * 1957-10-10 1962-11-27 Engelhard Ind Inc Composite material of platinum alloy and glass
US3134671A (en) * 1961-05-18 1964-05-26 Nobilium Products Inc Noble metals alloy containing gallium
US3155467A (en) * 1961-08-04 1964-11-03 Nippon Junsuiso Kabushiki Kais Palladium alloy permeable wall for the separation and purification of hydrogen
US3158469A (en) * 1962-08-08 1964-11-24 Stackpole Carbon Co Electrical contact
US3301641A (en) * 1964-01-27 1967-01-31 Mallory & Co Inc P R Tungsten-ruthenium alloy and powdermetallurgical method of making
US3225169A (en) * 1964-02-24 1965-12-21 Stackpole Carbon Co Silver-refractory metal electrical contact having refractory metal carbide in the marginal layer of its active contact face
US3310718A (en) * 1964-04-07 1967-03-21 Nytronics Inc Impedance element with alloy connector
US3499740A (en) * 1965-10-26 1970-03-10 Int Nickel Co Oxidation resistant coated article containing iridium,ruthenium,molybdenum or tungsten
US3411900A (en) * 1966-04-13 1968-11-19 North American Rockwell Brazing alloy composition
US3463636A (en) * 1967-01-03 1969-08-26 Trw Inc Constant conductivity alloys
US4081644A (en) * 1972-06-29 1978-03-28 Plessey Handel Investments A.G. Electrical contact material
US4409295A (en) * 1982-01-21 1983-10-11 Olin Corporation Electrical connector material
US4579787A (en) * 1983-12-14 1986-04-01 Degussa Aktiengesellschaft Material for low voltage current contacts
US5227250A (en) * 1991-09-20 1993-07-13 Fifth Dimension Inc. Glass-to-metal seal
US20090218647A1 (en) * 2008-01-23 2009-09-03 Ev Products, Inc. Semiconductor Radiation Detector With Thin Film Platinum Alloyed Electrode
US8896075B2 (en) 2008-01-23 2014-11-25 Ev Products, Inc. Semiconductor radiation detector with thin film platinum alloyed electrode
CN102754292A (en) * 2010-02-17 2012-10-24 田中贵金属工业株式会社 Material for ignition plug electrode excellent in durability to spark erosion and discharge characteristics
US20120269675A1 (en) * 2010-02-17 2012-10-25 Kunihiro Tanaka Material for spark plug electrode having excellent spark wear resistance and discharge properties
US20130259736A1 (en) * 2012-03-14 2013-10-03 Victor Dyment Thermoregulatory Interactive Gold Alloys for Therapeutic Jewelry Items

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