US2258935A - Alloy steel roll - Google Patents
Alloy steel roll Download PDFInfo
- Publication number
- US2258935A US2258935A US274446A US27444639A US2258935A US 2258935 A US2258935 A US 2258935A US 274446 A US274446 A US 274446A US 27444639 A US27444639 A US 27444639A US 2258935 A US2258935 A US 2258935A
- Authority
- US
- United States
- Prior art keywords
- roll
- silicon
- chrome
- nickel
- steel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 229910000851 Alloy steel Inorganic materials 0.000 title description 12
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 32
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 18
- 229910052710 silicon Inorganic materials 0.000 description 18
- 239000010703 silicon Substances 0.000 description 18
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 17
- 229910052759 nickel Inorganic materials 0.000 description 16
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 10
- 229910052799 carbon Inorganic materials 0.000 description 10
- 238000005096 rolling process Methods 0.000 description 9
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 8
- 229910052750 molybdenum Inorganic materials 0.000 description 8
- 239000011733 molybdenum Substances 0.000 description 8
- 229910001018 Cast iron Inorganic materials 0.000 description 6
- 229910000831 Steel Inorganic materials 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 239000010959 steel Substances 0.000 description 6
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 5
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 3
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 3
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 3
- 229910052748 manganese Inorganic materials 0.000 description 3
- 239000011572 manganese Substances 0.000 description 3
- 229910052717 sulfur Inorganic materials 0.000 description 3
- 239000011593 sulfur Substances 0.000 description 3
- 229910001208 Crucible steel Inorganic materials 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 238000013459 approach Methods 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- QKJXFFMKZPQALO-UHFFFAOYSA-N chromium;iron;methane;silicon Chemical compound C.[Si].[Cr].[Fe] QKJXFFMKZPQALO-UHFFFAOYSA-N 0.000 description 1
- 230000002301 combined effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000000737 periodic effect Effects 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B27/00—Rolls, roll alloys or roll fabrication; Lubricating, cooling or heating rolls while in use
Definitions
- I have found, however, that I can produce a roll of alloy steel including manganese, silicon. chrome, nickel and molybdenum, and by so proportioning the elements to the carbon, sulfur and phosphorous I am able to obtain a roll which is much harder than the usual cast alloy steel ture the scleroscope hardness'of the surface of a mild chill cast iron roll and at the same time I have eliminated or at least minimized to a point of substantial elimination the fire cracks and checks which heretofore have been the limiting factor in connection with the hardness of the.
- the immediate area of the surface of a roll that is in intimate contact with steel being rolled may at times be subject to a temperature between two thousand and twentyfive hundred degrees while the area of the roll surface diametrically opposed therefrom may be of a temperature not exceeding two hundred degrees, and whenit is realized that the surface temperature-of the roll may undergo a number of rapid changes from one extreme to the other within a relatively short period of time, one will appreciate the tremendous surface expansion and contraction strains to which the roll is being continually subjected.
- the surface of the roll does not fire or water crack to either large horizontal or circumferential fire cracks as has heretofore been customary in other alloy rolls but merely crazes and that there appears to be no tendency for the crazes to increase either in the horizontal or vertical magnitude so that a new surface can be produced on the roll by removing as little as from to V of an inch from the surface of the roll.
- rolls of th instant type are usually of considerable diameter they may be easily machined to remove the shallow crack forming crazes without materially reducing th diameter of the roll.
- a mill roll for rolling hot metal comprising a steel alloy containing from .80% to 1.90% of carbon, from .80% to 1.10% of manganese, .35% silicon, .45% chrome, 35% molybdenum, and from 1.25% to 1.90% nickel.
- a mill roll for rolling hot metal comprising a steel alloy containing between .75% to 1.90% of carbon, approximately 1% to 1.50% of manganese, .33%;% silicon, chrome and molybdenum, and a nickel content of between three and four times the percentage of silicon.
- a mill roll for rolling hot metal comprising a steel alloy having between 1% and 1.90% carbon, approximately 1% manganese, less than silicon, chrome and molybdenum, and approximately 1.50% nickel.
- a mill roll for rolling hot metal comprising a steel alloy containing approximately 1% of carbon, 1% of manganese, less than .50% of silicon, chrome and molybdenum, and a nickel content varying from 1.25% to 1.90% of the total composition.
- a mill roll for rolling hot metal comprising an unquenched steel alloy having a surface hardness between 47 and 57 Shore and containing carbon and manganese in substantially equal percentages, also containing a small percentag: of silicon and a substantially equal percentagi of chrome, and between 2% and 3% nickel, th percentage of nickel being greater than the com bined percentages of silicon and chrome.
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Reduction Rolling/Reduction Stand/Operation Of Reduction Machine (AREA)
Description
atented Oct. 14, 1941- UNITED STATES PATENT OFFICE ALLOY STEEL ROLL 7 Harold A. Lomax, Wyomissing, Pa.
No Drawing.
Application May 18 1939,
Serial No. 274,448
Claims.
- brittle nor subject teglazing and of a, quality substantiallly equal to that of a mildly chilled cast iron roll heretofore produced.
It is of course well known that chilled cast iron rolls, due to the metal adjacent their periphery being intensely 'hard, are capable of being highly polished to have a finer surface than that generally found on cast steel rolls but cast iron rolls cannot be used in the rolling of steel at high temperatures where heavy duty produces excessive shocks to rolls as this process would destroy the rolls by breakage or the chill surface by fire cracking and materially decrease the efficiency and usefulness of the rolls. Furthermore, .cast iron rolls are extremely brittle and are often cracked and broken if an attempt is made to use the same in place of the softer or less fragile steel roll.
It has been found in previous attempts that as the surface hardness of an alloy steel roll is increased the tendency for such surface to fire crack or check is also increased with every added increment of hardness and that as 'a result where the surface of the rollis hardened to a point where it possesses long wearing qualities it will,
after a comparatively short space 'of time, present a maze of fire cracks and checks varying in width and depth from microscopic cracks to cracks of appreciable width and of a depth of v a quarter of an inch or more and consequently producing upon the steel passing beneath the roll periodic impressions or a corresponding pattern which will remain on the steel throughout the.
successive rolling steps and which requires the grinding of the surface of the steel in order to remove the life cracks and check marks placed thereon during the early rolling operation.
I have found, however, that I can produce a roll of alloy steel including manganese, silicon. chrome, nickel and molybdenum, and by so proportioning the elements to the carbon, sulfur and phosphorous I am able to obtain a roll which is much harder than the usual cast alloy steel ture the scleroscope hardness'of the surface of a mild chill cast iron roll and at the same time I have eliminated or at least minimized to a point of substantial elimination the fire cracks and checks which heretofore have been the limiting factor in connection with the hardness of the.
roll surface.
In carrying out the invention I preferably employ for heavy duty rolling proportions of the above mentioned compounds so that the finished product will approximate the following analysis:
Per cent Car n .90 to 1.20 Manganese .80 to 1.00 Silicon Chrome .40 to 5D Nickel w 1.60 Molybdenum .35 Sulfur .05 Phosphorous .045
. brittle roll. However, by the addition of nickel,
. inch.
roll and in which the surface approaches in texchrome and molybdenum in substantially the percentages named above the tensile strength of the casting has been raised to over one hundred and ten thousand (110,000) pounds per square This is vastly in excess of the strains to which the roll is subjected in mill operations and, therefore, the roll is practically unbreakable under ordinary uses.
I have found that by a variation in the quantity of nickel to silicon and/or chrome content I am able to control and maintain the desirable characteristics of the roll which I have pointed out heretofore.
When it is realized that the immediate area of the surface of a roll that is in intimate contact with steel being rolled may at times be subject to a temperature between two thousand and twentyfive hundred degrees while the area of the roll surface diametrically opposed therefrom may be of a temperature not exceeding two hundred degrees, and whenit is realized that the surface temperature-of the roll may undergo a number of rapid changes from one extreme to the other within a relatively short period of time, one will appreciate the tremendous surface expansion and contraction strains to which the roll is being continually subjected.
It is believed that the fire resisting qualities of this'roll are obtained by the low silicon and chrome content and by maintaining the balance between the silicon and chrome relative to the nickel content. Thus, in the roll which is produced in accordance with this invention it will be observed from the analysis given above that both the silicon and chrome are maintained at a comparatively low point, namely approximately from .30% to .50%, whereas the nickel content is from three to four times as great as the percentage of either the silicon or chrome.
Where this percentage arrangement has been followed it is found that the surface of the roll does not fire or water crack to either large horizontal or circumferential fire cracks as has heretofore been customary in other alloy rolls but merely crazes and that there appears to be no tendency for the crazes to increase either in the horizontal or vertical magnitude so that a new surface can be produced on the roll by removing as little as from to V of an inch from the surface of the roll. As rolls of th instant type are usually of considerable diameter they may be easily machined to remove the shallow crack forming crazes without materially reducing th diameter of the roll. This is another distinct advantage over cast iron rolls for if rolls of the latter type are machined to remove the fire cracks the thickness of the chill is materially decreased to the utter detriment of the roll. It will, of course, be obvious that this characteristic of the instant roll greatly lengthens its life and maintains the roll at full strength throughout its life and the absence of horizontal or circumferential fire cracks enables the roll to produce a finished product free from fins, seams and laps which has been common practice in the alloy steel rolls heretofore produced.
While the general proportions as set forth will produce a roll having a hardness measured by the Shore scleroscope from forty-eight (48) to fifty-eight (58), depending upon the percentage of nickel, silicon and chrome as wellas the percentage of carbon, the extreme hardness of the roll surface does not aifect the frictional gripping qualities of the roll surface and there is, therefore, no tendency for the surface to glaze which is a common defect in previous alloy steel rolls wher an attempt has been made to increase the surface hardness through even the lower figure of the Shore scleroscope reading.
By changes in the ratio of the nickel, silicon, chrome and carbon I may increase or decrease the hardness of the roll surface and in this manner am able to produce a roll which is particular- 1y adapted for the use to which the same is to be put. As an example, where I wish to produce an xtremely hard roll surface, having reference to a Shore test between fifty-four and fifty-seven. I have found that by using the following percentages this result may be obtained:
Per cent Carbon 1.72 Manganese .95 to 1.10 Silicon .41 Chrome .36 Nickel 1.83 Molybdenum .42 Sulfur .034 Phosphorous .045
Other changes in percentages may be made without departing from the scope of my invention, the main novelty of which would appear to be the use of a comparatively high percentage of carbon and maintaining the silicon and chrome at approximately one third of one percent and maintaining the nickel content between three and four times th percentages of either chrome or silicon with slight variations, either plus or minus, in amounts herein given.
Having thus described my invention what I claim and desire to secure by Letters Patent is:
1. A mill roll for rolling hot metal comprising a steel alloy containing from .80% to 1.90% of carbon, from .80% to 1.10% of manganese, .35% silicon, .45% chrome, 35% molybdenum, and from 1.25% to 1.90% nickel.
2. A mill roll for rolling hot metal comprising a steel alloy containing between .75% to 1.90% of carbon, approximately 1% to 1.50% of manganese, .33%;% silicon, chrome and molybdenum, and a nickel content of between three and four times the percentage of silicon.
3. A mill roll for rolling hot metal comprising a steel alloy having between 1% and 1.90% carbon, approximately 1% manganese, less than silicon, chrome and molybdenum, and approximately 1.50% nickel.
4. A mill roll for rolling hot metal comprising a steel alloy containing approximately 1% of carbon, 1% of manganese, less than .50% of silicon, chrome and molybdenum, and a nickel content varying from 1.25% to 1.90% of the total composition.
5. A mill roll for rolling hot metal comprising an unquenched steel alloy having a surface hardness between 47 and 57 Shore and containing carbon and manganese in substantially equal percentages, also containing a small percentag: of silicon and a substantially equal percentagi of chrome, and between 2% and 3% nickel, th percentage of nickel being greater than the com bined percentages of silicon and chrome.
HAROLD A. LOM'AX.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US274446A US2258935A (en) | 1939-05-18 | 1939-05-18 | Alloy steel roll |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US274446A US2258935A (en) | 1939-05-18 | 1939-05-18 | Alloy steel roll |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| US2258935A true US2258935A (en) | 1941-10-14 |
Family
ID=23048229
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| US274446A Expired - Lifetime US2258935A (en) | 1939-05-18 | 1939-05-18 | Alloy steel roll |
Country Status (1)
| Country | Link |
|---|---|
| US (1) | US2258935A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3088196A (en) * | 1960-06-02 | 1963-05-07 | Metallizing Engineering Co Inc | Metallizing wire |
-
1939
- 1939-05-18 US US274446A patent/US2258935A/en not_active Expired - Lifetime
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3088196A (en) * | 1960-06-02 | 1963-05-07 | Metallizing Engineering Co Inc | Metallizing wire |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US2258935A (en) | Alloy steel roll | |
| US2289449A (en) | Die steel for hot working | |
| US2115465A (en) | Rolling mill roll | |
| US2030343A (en) | Alloys | |
| US1602995A (en) | Nonferrous alloy | |
| JPS59129757A (en) | Material for composite roll with superior heat crack resistance and wear resistance | |
| US2268280A (en) | Brake shoe | |
| US2336246A (en) | Steel roll | |
| US2104980A (en) | Steel alloy | |
| US2253385A (en) | Steel | |
| US2762704A (en) | Cast iron alloy | |
| US2174286A (en) | Ferrous alloy | |
| US1952575A (en) | Collet steel | |
| US2336247A (en) | Steel roll | |
| US2166795A (en) | Sintered hard alloy for machining hard castings | |
| US2047873A (en) | Free cutting alloys | |
| RU2250137C2 (en) | Grinding member for grinding disc | |
| US1870580A (en) | Cast iron roll | |
| US1697083A (en) | Ferrous base article of manufacture | |
| US2281460A (en) | Method of manufacturing chilled cast iron and product thereof | |
| US1558918A (en) | Steel alloy for the rollers of pilger rolling mills | |
| US2300792A (en) | Manufacture of rolls | |
| US2276689A (en) | Drawing die | |
| GB467546A (en) | Improvements in and relating to wire and bar drawing dies and holder | |
| US2228908A (en) | Ferrous alloy mill roll |